浙江省六校联盟2021-2022学年高考化学全真模拟密押卷含解析

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11D.FeᙠÅÆFes஺ஹ3molFeÇᐰhiÉÊ8molᵯ5.6gFeḄᱥeḄ!0.1mol,ᑣᐸhiÉÊḄᵯᦪ|XO.1mol=^ymol,ᦑÉÊḄᵯᦪN¢0.34,D┯lmᦑᔠᳮ⌱⚗!B.3ஹBூ
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᪆௃A.⏚!´ᵯ]eᙠèé¹êëᵯ·ìí·ᓄí!³ᵯ]eᙠ\®Çᐰᵯ·ᡠpH¿rḄ²⏚⏚᝞îèé¿rïᦪᑣð⏚í·ñᜧ¢⏚ᡠòpH=4Ḅ²⏚⏚ᑖèéᡂpH=5Ḅ®óᡠ\Ḅð⏚ᐭ\Ḅᜧ¢²⏚A⚗┯lmB.⏚ᡈᢓᑴ\ᵯ·xᨵ´·Ḅ²ö÷\ᵯ·ᡠíᓄᢓᑴ\ᵯ·ஹ⏚ö÷\ᵯ·íᓄ\ᵯ·¹N¢y⏚®\ᵯ·¹B⚗┯lmC.y⏚᪷·╆᪷·¿úö÷\]ᡠû⏚ü®┤᪷·ñᜧ¢y⏚╆C⚗umD.¿rþ<⏚Ḅñÿᜧᐸᵯᡠὅᵯὅᡠ10mL0.1mol/LḄ⏚100mL0.01mol/LḄ⏚H+ḄᱥḄὅὅD⚗┯ᫀ⌱C஺ூ௃D⚗"᧕┯⌕%&ᱥḄ'(ᱥḄ)"*+ᭆ-10mL0.1mol/LḄ⏚lOOmLO.Olmol/LḄ⏚ᱥḄ.ᯠ012ᱥḄ')1ᑣᵯ)1஺5ஹDூ
᪆௃A.CaO5ᨵ789ឋᦑ)<■>?@ḄAᓄCD

12ᫀ⌱D஺6ஹBூ
᪆௃A.XY|X(}~᪀ᡂ9ᵯ}~"z᩽AᵯZpO2+2%O+4e-=4OH-,}~▬ḄpHᜧXY|▬ᦑA┯B.XY|X(}~᪀ᡂ9ᵯ}~"z᩽AᵯZpO2+2H2O+4e-=4OH-,ᦑBz{C.XY|X}~ῖ⇨Yᱨ□᩽Ḅ▢᩽XḄᩞᧇ"]ḄXY2)<╅ᔲᑣ(hᦑC┯D.᜜¢ᵯ£}~}~H▢᩽¤¥XY|X(}~ᵨL¦§¨¢ᵯ£z᩽§XY|X,ᑣ}~ᜫᵯZeῖ⇨ᦑD┯ᦑ⌱B஺ூ௃ª⚪ὃXYḄᔾAῖ⇨®ឋᡈ°ឋ±᛻³XY᧕pᔾAῖ⇨z᩽"AᵯZpᡂ´A᪷Z¶{ᱨ□᩽Ḅ▢᩽·eḄXYHz᩽p89஺7,Bூ
᪆௃A⚗ஹấ¸XY¹ºXYᑖ»¦ᜐ_ᵨᑴHKLMᩞᧇᦑAz{B⚗ஹp¾ᮞᐹᨵᔾhឋ)ᐹᨵ89ឋ_ÀÁÂᑺ)<ÀᢙAᓄᑺᦑB┯C⚗ஹÅÆÇᓄᔾᦈᜧḄÉᐹᨵᑴÊHᵨËᵨHᑴÊᑺᦑCz{D⚗ஹÌÍ⏚Îᐹᨵ89ឋ_À?@■ῖᑺ%&ᵨᙠÐÑÒÓÕᑁᦑDz{ᦑ⌱B஺8ஹAூ
᪆௃A.ᑴ×⏚ØÙᵨÉÚᣚᘤ_ᐙᑖᑭᵨ<ᦑAz{B.ßàáᑴ°â᪆äNaHCChḄåÅæᐭp¾ᮞ_è±ᑭᵨNH3,ᦑB┯C.ᔠᡂÆéêÉæÉÙë⊝⌮ᔣïðᦑC┯D.´(ñpᡂñᓄ´)"_⌮)òᙠᓄóë⊝ḄïðᦑD┯ᦑᫀéA஺9,Aூ
᪆௃A.ôᐗö⏚ᑖ÷ᵯø*÷éP᪷ùH2XUH++HX-,C(H+)=û==üýþÿ'^10-3,a


133,ᦑAB.ঝᜐាᡂNaHX,᪷ᵯ₹ឤc(Na+)+c(H+)=2c(X2-)+c(HX-)+c(OFF)ឤc(H+)+c(HX)=c(X22-)+c(OIT)c(Na+)+2c(H+)+c(HX)=3c(X2-)+c(HX-)+2c(OH-),ᦑB┯2C.FhXNaOHាᡂNazS,!Ḅ#$%&টᜐ#$%&ᦑC┯D.টᜐាᡂNazX,c(Na+)>2c(X2-)>c(OH")>c(HX-)>c(H+),ᦑD┯(ᫀAூ+௃-⚪ὃ01⏚3!#$45&67ᐜᑖ᪆!;Ḅ<ᱥ&>᪷ᵯ₹ឤஹᱥᧇឤஹឤᑖᑖ᪆67AᐗC⏚DḄEFGH&ᑖIGH&JKILAᐗC⏚EFᵯM&ᑖIᵯM&JKIL஺10ஹDூ
᪆௃ᵫP!QRST&UVᧇᵯWḄX2H2S+O2=2S+2H2஺&U!Yᓄ[\]^ᑺஹ`a\`ᓄᑺ஺Yᓄ[bᐭᑮᵯ᩽a,ᡠgaᵯ᩽\h᩽&iḄᵯ᩽2112s+2O"4e-=S2+2H2O`abᐭᑮᵯ᩽b,ᡠgbᵯ᩽\᩽஺U!ᵯjkᦪ4mᵯ&ᡠgᵯn!opq4moiᵯ&᩽rὑImoKh,iḄᵯ᩽O2+4e-=2OVtuᡠv&D&⌱D஺+-⚪ὃ0Ḅ\^ᵯW^ᳮ஺ᙠ^ᵯW!K$ᨵKmSg{i|}Ḅ`ᓄ]^i&ᐸ!]^ᑺᙠh᩽ᜫᵯi`ᓄ&ᵯ᜜ᵯnpᔣ᩽`ᓄᑺᙠ᩽uᑮᵯi]^&ᵯ$ᔣkᡂᵯp஺ᙠᑏᵯ᩽&⌕᪷ᵯHḄ⏚3ឋᑖ᪆ᵯ᩽Ḅ<ᱥ\ᔲ$ᙠ&᝞<ᱥᵯHḄM&⌕ᔠᙠKᑏX&\Ḅᵯ᩽஺ᨵVᧇᵯWḄh᩽ᩖ&ᡃSgᐜᑏX&>ᑏ᩽&ᨬ;᪷X᩽ᑏh᩽஺-⚪!ᵯH\`M¡¢ᵯH&ᡠg᩽\`aᵯ£ᡂ`M&£ᓄ¤ᓫ&Sgᐜ¦ᑨ¨஺11ஹCூ
᪆௃A.©ᨵªª«¬&ᡠgSgi®&ᦑAB.2-¯°±²\ᨵ³ᱥ&´ᵬ¯&¶·´G&ᦑBC.ᑖ!©ᨵᵬ°&^·Sᐳ☢&ᦑC┯D.©ᨵªª«¬&»⏚ឋ¼┤⏚¾´¿À⁐&ᦑDᦑ⌱C,12ஹDூ
᪆௃AஹHPW{ÂᙠÃ⊤☢ÅÆஹ᧕´ᨵ³´ᑺÈgÉ»ᵨË&ÌᐸhÍᙠAÎÍ¢(᝞ấÑÒஹC)uᑣ

14ᨵᦔÖ×gu·Ø&Ù¼ᐸÚᓄÛឋ&⌱⚗ABஹ᪷P!ÝÞST&ßHPWhÍF40%àᑮ⛳&âᓄ᳛ᨬ¼&⌱⚗BCஹᵨHPW/ấÑÒäåæçÚᓄᑺèY⏚&SéEêᜓῖ⇨·Ø&⌱⚗CDஹÚᓄᑺ·»î⊝k&·ᦋ£ᔣ|}Ḅñò&⌱⚗D·஺(ᫀ⌱D஺13ஹBூH᪆௃X^ᨬ᜜óᵯᦪ\᪶᜜ᵯóᦪḄ3õ&ᵫᨬ᜜óᵯᦪ·öq8m&ᡠgX\஺&ᑣZ\S஺YḄᨬ¼÷ᨬøh÷Ḅäᦪ6,ùúYûJWA,YஹZüᕜþ&ᑣY\ChW\ÿᕜ
ᐗᨬᜧḄ,ᡠWNa஺A.YᐗᐸᨬᓄᱥḄᓄᱥᓄHC1O4,⌱⚗A┯"#BஹX%W&ᡂḄ(ᓫ*ᐹᨵ-.ᵯ01᪀᪶ᵯ₹ᦪ6ᜧ67ᑣ(ᓫ*:X>W,⌱⚗B:;#CஹX(C1)Ḅ<=>ឋ@Az(S)ḄᡠHC1ḄBCឋ@AH2sḄ⌱⚗C┯"#DஹX%W&ᡂḄᓄᔠᱥNa2OஹNa2(h▢ஹ□*GᦪHᙳ1:2,⌱⚗D┯"஺Jᫀ⌱B஺14>CூM᪆௃A.◌ᘤᙠSᑴUVWXYZᩖḄᱥᳮ]ᓄ%ᓄ]ᓄᦑA:;#B._`>AabcdSeᨵSᯖghḄiᕡᦑB⚗:;#C.*kᣚm>AᓄnmᦑC┯"#D.o□pᵯqᐝᵯsḄᩞᧇᓫcấᦑD⚗:;#ᦑJᫀC,15ஹBூM᪆௃wxyiCO2ஹSO2z{|ᮞᔾᦈXᡂ1CaCO3ஹCaSOj,i1p{U|ᮞᔾᦈḄN2ஹNOஹCO,i1ᐭiX,ᵨᓄᜐᳮᑮḄNaNO2,XzipUᔲᑣᑮ⏚NaNO2%ᨵNH4+ḄXᡂiXᡂiᑣi2ᨵCOஹN2,ᣓᑺᡠᣓḄi⌕CO஺A.wxyiCO2ஹSO2z{|ᮞᔾᦈXᡂCaCChஹCaSO,ᓄ┛Uᑣ1⌕ᨵCa(OH)2ஹ3CaCChஹCaSOa,ᦑA:;#B.ᵫᑖ᪆z¥i1p{U|ᮞᔾᦈḄN2ஹNOஹCO,i1ᐭiX,ᵨᓄᜐᳮᑮḄNaNO,XzipUᔲᑣᑮ⏚ᦑB┯"#2C.i2ᨵCOஹN2,¦ᣓᑺᑮi§CO,ᡠᣓḄi⌕CO,■©iᦑC:;#D.NaNCh%ᨵNH4+ḄXᡂiXᡂiWXᓄª*nV

15NH4++NO2-NT+2HO,ᦑD:;;22ᦑ⌱B஺16ஹAூ
᪆௃A.¬®¯>Aabc°±U²³abc]ឋA⌱⚗:;#B.´⏚µ?H¸U¹ºzᑴz»MḄº´⏚ᛛᧇB⌱⚗┯"#CH,—CH—COOHC.“¾¿”Ḅ⌕ᡂᑖCaCCh,>AÁÂ>AᨵÁᑖᓄᔠᱥC⌱⚗┯"#D.ÃᵫÄŧ|ᮞ|SᑴÆᡂḄD⌱⚗┯"#Jᫀ⌱A஺17ஹCூ
᪆௃Ç⊤ᐗᡃÊËÌÍÎÏÐÑ஺CÒÓᕜ
VIAᐸÌÆÔAஹBஹCஹDᑖÕCஹNஹOஹSi.ூ
௃A.ᵯ0ᦪ6Ö6ᜧ#.ᕜ
ᐗᨬ᜜0ᵯᦪ6Ö67ÌÆÔᜧ7ᐵÙSi>C>N>O,A┯"#B.XᡂḄᓄᱥÚᨵᑖ§ÛᑖÜz&ᡂÝB┯"#C.A%C&ᡂḄ▢*zpᨵCOஹC2O4,C:;#D.CḄᓫc|ÞpßᵯSißᩞᧇà°áâpßᵯNஹOḄᓫcᙠà°áßᵯD┯"஺ᦑ⌱C஺18ஹCூ
᪆௃AஹãäeL§FeWXᓄᔠᦑA┯"#BஹåæÛḄXᡂ⌕ᵨçèḄpHéêᦑB┯"#Cஹë⏚ìᓄឋí@ᙠà°áîz%ïÂ⏚ðXiᦑC:;#Dஹñ%ïò⏚ᑴóÓᓄò⌕ãäᦑD┯"஺JᫀC஺19ஹBூ
᪆௃A.1G✏õöḄᑖᨵ÷GøøùݧúG᷊üᦑImol✏õö%ýḄH2ãᡂ◤⌕ÿὑ3m0IH2,A┯

16B.1✏Ḅᑖᨵᑖᨵᐗ᪀ᡂᨵḄᓄᔠᱥB$%CH.OC.&'()&᪀ᡂḄ*)☢,Ḅ᪀-✏.&0ᑖ᪗ᱯ345Ḅ6&7ᕜ9:'ᐭH,CCH.Ḅ<&=>ᙠ@A☢BC┯D.✏7⏚ឋEF⏚GHIJKLᓄMNO⏚ឋEF⏚GHIP⁐R✏7STJKUᡂMNOVTP⁐,MNX-=:@D┯Yᫀ⌱B஺20ஹDூ
᪆௃A.^ᨵ_ᱥ7`:'Ḅ&Ḅab&Bcᨵd&=>JKefMNᦑA┯B.^ᑖᨵhImol^ᨵ_ᱥᨵImolhhTijKᡂk⏣`m>ImolNaOHJKMNᦑB┯C.^ᑖ=ᡈ<=>7SJKUᡂMNᦑC┯D.'()=@&ᡈ&oḄ⛳&qrឋ&ᡠ7:'Ḅ&ஹᐗB7O:'Ḅ&ஹᐗB'(ᵬḄ&ᙳqrឋ&ᦑD$%YᫀqD஺ூ௃7`:'Ḅ&Ḅab&Bᨵd&JKefMN7`:'Ḅ&Bᨵd&JKLᓄMN'()=@&ᡈ&oḄ⛳&qrឋ&஺21ஹDூ
᪆௃vᕜwᐗxXஹYஹZஹWḄ&yᦪ{|}ᜧ஺mᑴᑺᑣmqNH3,ᑣXqH⁐,p⍗q⁐ᑣpqNONᐗxḄᓫdᓄᱥ*ᵯiᡠW=*OஹN,ᑣYqN,ZqO,W&Ḅᨬ᜜ᵯᦪ*X7Z&ᨬ᜜ᵯᦪᐸᓫdᓄᱥrHTᐰᵯᑣWqCLூ
௃A.ᵯᦪᜧᵯᦪ:@&yᦪᜧᡠᓫC1>N3>O2>H+,ᦑA┯B.YqN,ᐸᵯq2s22P3,ᵯ¡⍝⊤¤¥q¦|¨ᦑB┯

17H*C.rmᡂ©ᓄᔠᱥÿᓄ

᪷ḄᵯNH
ᦑC┯H.H.D.ᙠᓄᑺḄᩩᡂNO,ᦑDᦑᫀD஺22ஹDூ᪆௃0.5gᎷ$%&'()*%&ᐸ,R,%&-.⏚0123R+2HC1=RCL+H23n(5)=87ᖪ=025mol,᪷:12g23<n(R)=n(H)=0.25mol,ᑣRḄ>ᙳ᥅ABC=—=EF~-=48g/mol,HᔠᱥK%&Ḅ᥅ABC1Lᨵᜧ2O48g/mol-PO48g/molḄ᝞RSNaᣚU+2*V,ᐸ᥅ABCX46g/mol<48g/mol,╅Ḅ᥅ABC24g/mol<48g/mol,᝞RSAlᣚU+2*Vᐸ᥅ABCX18g/molV48g/mol,FeḄ᥅ABC56g/mol>48g/mol,ᐸKPO48g/molḄᨵZ[\ᜧO48g/mol]ᨵ^ᡠ`abᨵFe,ᦑ⌱D஺ூef௃hi⚪◤⌕ᳮh“>ᙳ᥅ABCo”Ḅ1ᵨhi⚪rsᵨ“>ᙳᵯ᥅ABCo”sᵨto%&Ḅ>ᙳᵯ᥅ABC=24g/mol,ᐸKuஹ╅ஹvஹ^Ḅᵯ᥅ABCᑖx23g/molஹ12g/molஹ9g/mok28g/mol.)ஹy⌱z⚪(ᐳ84ᑖ)23ஹFeSO2FeSOJ8LFe03+S0T+S03t2Fe3++S032+HO=2Fe2++SO2+2H+442224ூ᪆௃i⚪ὃ}~ᱥḄ2ᫀ$஺Xᵫ[ᓄᔠᱥᡂSX,ᐭ⁐⁐ḄᨵS02,SX,ᐭCK,Xᐰᔾᦈ]ᑮ`[⏚,᪷:ᓄ01S0+H0=HS04,SO+HO=HSO22223224<XᵫS02-S03[ᡂ஺ᙠ2K¡KSCNᕈ⁐£¤KᨵFe3+,¥⁐¦(ᓄ^஺(1)᪷:§¨ᑖ᪆¦AᑖhᡂSthஹSO3-ᓄ^ªᐗ¬Ḅᓄᔠ*®^ᐗ¬Ḅᓄᔠ*ᓣ°ᑣAFeSOo4(2)᪷:§¨ᑖ᪆01জḄᓄ23ZFeSCh/LFezCh+SChT+SChT஺(3)XSChஹSO3ḄHᔠᱥ,ᐭNaOHK²01ᡂª⏚u-³ª⏚u³ª⏚᪷´ᐹᨵ¶·ឋᓄ^-ª⏚01ᡂª⏚^2ª⏚^Fe3+ᐹᨵᓄឋSth?-Fe3+²ᓄ¶·01ᡂFe?+-SO4*,᪷:ᜫᵯ¼ឤஹᵯ₹¼ឤ-·¼ឤ¿>ᑣ01টKᡂAḄ´232Fe3++SO.?+HO=2Fe2++SO?+2H+.2

1824ஹAgClᐳSiO+2OH=SiO2+HO232ூi᪆௃᪷®⚪ᔜᱥ±ᓄᐵ³D´µ¶E,E>7dLᓄ·MNKᡂF,F7¸¹ḄºLᓄMNKᡂD,»¼Dq½⏚>´µᑖi¾-_ᩞᧇA3M4ᵫÂÃÄᐗxÅᡂᐗxMbƺᕜwVAÇNqNᐗxAᐗxq)ᐗx,CஹEᙳqAᐗxÈA3M4NqSi3N”%ÉAqSi,EqSi(h,FqNazSiCh,ᑣDqHzSiCh,G7Ê⏚ËMNKᡂ=HÌÊ⏚ḄÍÎH,ᑣÈGᨵCbHqAgCLᦑCqSiCL,BqCh;ᵫSiCL+3H2=4HCl+H2Si()3,KᡂGHCl(1)HḄᓄÏ¥qAgCl(2)ᓄᔠᱥSi3N4ᨵḄᓄÏX-qᐳ(3)SiO2HiNaOHHIJKMNḄÐÑ¥qSiO2+2OH=SiO2+HOo3225ஹÒÓIḄMnCLÔÕ7AgNO,MNÖᡂÍÎᵬ×1.1111ØÙBÚÛÉÜÝ2-3|ÞFßÒÓàIáâᑁ,äåᓾçèéÞᜧᦈëì■᎔ᔾᔾᦈðூi᪆௃(1)জᵬ@ÏḄÐᫀºLᓄ═7óô⏚MNKᡂìᓄ═ÔÕ7Ê⏚ËMNᦑMN=õঝᵨøùÛÉø⏚⌱ᵬ×Ýᢣ¤ᑺ{®ÛÉûü¸ÑḄᓄÏMNɹýþØÙÛÉÜÝ2-3|ÿᙳঞCaCO3()ᒕḄCaCChᵫᑖ⏚┛ᓄᡂ⏚═ᒕḄ!"#$ᜧট'()*+,⏚-ᡂ./01ᑖ᪆345Zn*0ᐭ789:;ᐸ=-.?᪵789ABCᐙᑖ.EFGHIGJᑁᑣ/""MNOP᣸◀SᐸTUVWXYZ[/"\]^_`ὃὶcᑮefghḄABZcᑮ/"ijᓾS஺/"Ḅ"Mmnᕈp஺(2)Aᑴrs/Bᵨᔣv᣸wxᦈzs/C■᎔ᔾDᔾᦈ~/■w/஺ூ3௃(1)জᵬIḄᫀᓄ,⏚-ᡂsᓄ═#⏚ᦑZᵨᩭ79:,⏚Ḅ,B1ঝᵨnn⏚B⌱ᵬᢣᑺr¢᪵21.11mL,ᵨLlHlmolL£NaOH᪗¥¦9§ὑ22.11mL,

19eª«¢᪵:,⏚_ᵫCHClVHC¬CNaOHVNaOHB«,⏚Ḅ_®l.llllmolL1ঞ᪷(Ksp(CaCOj)=2.8x11-9,(nCO)=2.3xir“⏚═ḄKspp⏚┛±ᵫᑖ⏚┛ᓄᡂKspM3⏚═ᒕḄ!"#$ᜧ?᪵²ᩭḄ!"NO³´µ¶$±টa.·IḄᫀ5Y¸¹:Ḅ789)*Ḅº»¼f½)¾ᑮ7ᶇ¦9:b.EFÀÁJ◞1ᑖÃÄr/""M./""M⌲ÆN±/""M⌲ÆN±ḄÇWf/"ijᓾᑮÈÉÊÉ_jᓾᑮÈÉÀ/""MËᦋÍ/¹ḄÎÏ9☢ÑÒÏ9☢ÎÏ/"Ḅmn$±ÓGÄᦪ«Ḅ"M$ᜧ(2)᪷(ÕÖ×BᔜÕÖḄᵨᑖÙfAᑴrs/Bᵨᔣv᣸wxᦈzs/C■᎔ᔾDᔾᦈ~/■w/஺26ஹᑖ9ÛᧅCaCO+2H+=Ca2++H2O+COt◀ÝC(h/":ÞᐭḄHCINaOH¦9ᔾᦈiḄCCh/"322Na2Ch+2CO2=2Na2co3+Cht,2NaO+2H2O=4NaOH+O2t½ßàáḄᩈᩩäᐭå:æᩈᩩçèéêChᵬ¦229ᵫë⁐Í®⁐íîᑖÃïᑁðÍᓄ79.5%ூ
᪆௃A:CaCO3+2HCl=CaCL+H2O+CO2T
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