豫南九校2022-2023学年化学高三第一学期期中质量检测模拟试题（含解析）

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2022-2023
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é%ᙠyz;⌕8NHylhOᑖâêᙠëè|ìÒ"ḄwÇN
ZNHyHzO+SCh=2NH++SO32-+H2O,ᦑB┯¯«4C.¿wᵯ₹Åឤîåïᐭð|ḄwÇN
2Na+2HO==2Na++2OH+HtᦑC┯¯«22D.}nᓄñ
òឋ}nᓄᱥ{yÔm%Lᡂóñ⏚ô©|ᦑD«Sᫀ⌱D஺ூSᫀ°௃õ⚪;⌕ὃöwÇNḄ÷ᑏ÷ᑏwÇN"᧕y᧕ᵯwòßᩩûÞüìḄᱥÝ⌕ýᑏᡂwâþ᪵Ḅᱥᨵᜧ⏚ᜧஹஹஹ⏚஺ᨵḄᱥᐰ᝞⏚Ḅ⏚⏚᪷⏚Ḅ⏚⏚᪷⌕஺9ஹCூ⚪!"#௃A.%&ᓄ()NaOH*+,COᑣ./0ᑭᵨ34⏚56ᓽ8◀ᩖᦑA<ᫀ>?B.HC1᩽᧕BCD,⛳FGDᢓᑴJ/ḄB#ᑣ./0ᑭᵨ34⏚56ᓽ8◀ᩖᦑB<ᫀ>?KC.L&ᓄBM)Fe3+OᡂFe(OH)3QRSL&ᓄBMTUFNBk+*+OᡂNH3H2O,Vᑮ◀ᩖḄ!ḄᦑC<ᫀ┯YD.Na2c஺3Z[\]ᓄNaHCChZ[Uᑖ#OᡂNa2c஺3ஹH2OFCO2,_0FCCh`/ab⍎dᡠ`8fgZ[◀hNaHCCh,ᦑD<ᫀ>?iᫀ⌱C஺ூiᫀkl௃m⚪n⌕ὃpqrOsᐗuvᐸᓄᔠᱥyzḄ{|)+ᵨḄ}஺⌱~ᑺF<+⍳ᑣK1.ᐭḄᩖ2.ᑖ0Ḅᱥ᝱]3.gF<ᓫ᧕ᓽ⌱~ᑖ<+⍳ᐜᱥᳮ0ᓄr,ᐜᓫ0ᩖḄᑣ஺10ஹDூ⚪!"#௃A.ᐸᑖᨵ4LᙠD¡ᨵ¢£¤ḄL¥O¦ᑖᵯ¨©ª⏚S«ᐗ⏚,A>?B.ª⏚Ḅ⏚ឋ_(⏚Ḅ⏚ឋ®8¯°±M]²B>?Cஹ³⏚⏚ឋC(⏚³⏚8`FD´Ḅn⌕ᡂᑖ(⏚┛*+C>?D.ᑴ¶ª⏚ª·¸ª⏚ᑖḄ¹£º(«O—C2H5)¶¼D┯Yiᫀ⌱D«11ஹCூ⚪!"#௃A.ª⏚ª·Fª⏣¾Sᨵ¿ᱥᡠ`ª⏚ª·Fª⏣ÀÁB#ᡠ`ᵨᑖMÂᧅᑖᦑA┯Y;

13B.ÆFJᓄ(¾Sᨵ¿BᑺÁBᡠ`ᵨᑖMÂᧅᑖᦑB┯YC.ÆSᨵ¿ᱥDS\¿ᱥÆFDÁBᡠ`ᵨᑖMÂᧅᑖᦑC>?D.ÇÆ8B#MÈÁBᡠ`ᵨᑖMÂᧅᑖᦑD┯Yiᫀ⌱C஺ூiᫀkl௃ᵨᑖMÂᧅᑖḄᱥÉÊSËÌÀÁBḄMa«ÍḄᩭÏKᨵ¿B᧕BCᨵ¿Bᑺ\¿B᧕BC\¿Bᑺ஺12ஹCூ⚪!"#௃A.¯ᵨpHиÑÒÓÐÈᑮBM+ᵨÔᴻÖ↾¶BMØᙠPHФ■ÚÛÜBMᦑA┯YB.NaOHᐹᨵᔾDឋ)ß/%&ᓄ(*+àá¸+áâã)ß/ḄÒä☢æ+çᙠã[èàáᦑB┯YC.éᑴ100mL2moi“/ḄNaOHBM¸+ÓàáêḄëaᙠ[èB#ìᓾ0îÓBMïðᐭñáòᙠóDôñᓽ8ᦑC>?D.¨34⏚)[*+çdᜧáḄõ᝞öᵨ[BM÷.Uøᜧ[ù☢æᡠ`ᐜᵨúûüýîᵨᜧáḄDþ.ᦑD┯Yᦑ⌱C.13ஹBூᑖ᪆௃A.
ᓄᓄᓄᑺ஺B.1CH"ᨵ8ᵯ஺C.ᯋ"#ᨵ$%&ᨵC-H%஺D.'()᪷+ᑖ-.஺ூ⚪12.௃A.0.lmol
34ᓄᓄ56ᵯO.lmoLᓄᑺ56Ḅᵯᦪ(0.2NᦑA┯;஺B.1CHᨵ8ᵯ,15gCH3+Ḅᱥ=Ḅ>(lmol,ᨵᵯᦪ(8NA,ᦑB?஺C.᪗ABCDU.2Lᯋ"ᐳᵨᵯGᨵ$%&ᨵC-H%H0.5MX#3+2$=2.5N“ᦑC┯;஺D.0.1L2mol-L'Ḅ□2$JKᨵ'ᓄLḄᱥ=Ḅ>(0.2mol,M'()᪷,+ᑖ-.,ᡠᨵḄS?ᦪ1PQ0.2NA,ᦑD┯;஺ᦑ⌱SBo14ஹA

14ூ⚪12.௃A.VᐗXḄᯚ⁐([⁐\ᐗXḄᯚ⁐(]⁐ᑣ_`(KNOAaᩎc(Na2sCh)deᯚ⁐ᩭ␺hiᵨḄᐗXḄᯚ⁐ᦑAjk┯;lB.mn₝p1q"“s⏚uv⏀Ḇyz"⏚uv⏀"ᨵ⏚⏚a⏣Ḅ}~ᵨyzḄkᑖk(yᦑBjk?lC“-ᓣ”"Ḅ“”ᓽ(J.ᦑCjk?lD."Ḅ“”a“”ḄᳮaeḄᳮᦑDjk?lᫀ⌱A஺15ஹCூᫀ.᪆௃Aஹ᪷HNO2#ᨵᓄឋ&ᨵឋCUTᐹᨵᓄឋᙠឋᩩDNO2-¢ᓄᡂNO3¤¥¦(NO2-+C1O-=NO3-+C§ᦑAjk?lBஹHN02ᐹᨵᓄឋaឋHI"FᐹᨵឋHNO2¨§ᓄᡂL,©ª⍗Ớᓫ=®¯ᦑBjk?lCஹHNO2ᐹᨵᓄឋS(hឋ(°¤HNO2¨SChᓄᡂn¢ᡂNOஹN2OஹN2"Ḅ±²ᦑCjk┯;lDஹ³´µHNCh¶·¸HNO2Ḅ⏚ឋQ⏚⏚Ḅ⏚ឋQ⏚ᓽHNO2Ḅ⏚ឋQ⏚HN(haNa2c03¹ᵨº»Ḅk¼½¾ᑖ,¨Na2cCh»ᐭHNO2,ÀᓽÁÂHNCh»ᐭNa2cJKe±ÃµÄÅÆÁÂᦑDjk?஺16ஹDூ⚪12.௃A.⏚Ç⏣ᡂ⏚ÈÈᓄÉÊA┯;lB.⏚ÈḄᑖË᪀Â"ÍQÈÎḄᨵᵬ⏚ÐÈஹᵬ⏚ËÐÈஹÐ⏚ᵬÈᐳ$²M⏚ÈḄᑖË᪀ÂÈÎÑÒ⏚ÎÓ¤ᑖË᪀ÂᜧQ$²B┯;lC.¤('⏚Ña⏚Õ\ÁᦑÑᵨ⏚Õ\ᩭ␺·ÂÖ"⏚ᔲØᐰC┯;lD.Ú(⌮4ᜧ⏣Ḅ>Ü⊝ᔣ6ßàá⏚Ḅ5ᓄ᳛D?lᦑᫀ(D.17ஹCூᫀ.᪆௃O.lmol/LḄXOHJKpH=13,jãXOHØᐰᵯ(läYOHஹZOH()$ὅឋ)(XOH>YOH>ZOH,æ»ᐭ10.00mLHClJKµᙳាéØᐰᡂêYC1ஹZCI⌕-.¸ZC1-.¥ìíᜧ஺ூ⚪12.௃AஹXOH(YOHஹZOH()ᵨê⏚»·)µᵨᵬîïᢣñᑺᦑA┯;lBஹᨵòóôõYOHஹZOHḄᱥ=Ḅ>öìᙳ((MOOmolL“µYOHJKḄpHíᜧᑣឋíᡠᵯÜ⊝÷ᦪK(YOH)>Kb(ZOH),ᦑB┯;lbCஹᙳ»ᐭ10.00mLHClJKµYCIஹZC1⌕-.äZOHឋᨬ)ᡠZC1-.¥ìᨬᜧᦑC?lDஹYOHµ)pH=UḄYOHÇpH=3ḄHC1JKÓÂùúᔠµYOHe>JKüឋöìýþ(Sc(Y+)>c(Cl')>c(OH')>c(H+),ᦑD┯;஺ᫀ⌱C஺

1518ஹBூᫀ.᪆௃AஹPM2.5Gÿ
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ᨵA(As)ᐗ,BAsᐗ,ᨬᨵ#DEFGHIDNA?
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hᐗ,ḄᓄᔠjklFe(V-
hᐗ,Ḅᓄᔠj$x,ᑣx+4x(-2)=-2,Uox=+6,ᦑAB.QR3ClO-+2Fe3++10OH-=2FeC>42-+3Cp+5H2O
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16+,ᦑᵯ/01Ḅᐵ45E>B=D>A,ᦑ67C.89⏚;<=ᓄ?@ᐰBCDEᵯ/01ᨬᜧᓽV=20mL,ᦑ6701x20D.DIᡂᑖ59⏚;9⏚?LM5Nឋc(H+)=10-7mol/L,PQRc(Na+)=c(CH3CO(T)=;7^mol/L,c(CHCOOH)=3STUmol/L,ᑣ9⏚ᵯ/W⊝Yᦪ=Ha,ᦑ┯]஺OlxV—0.1x20\Z-2020+[ᦑ⌱D஺22ஹBூᑖ᪆௃WஹYஹZde,ᕜgஹe,hiḄjᕜgᐗlmnᨵpqᐗl5Hᐗl᪷stuv᪀xyWzᡂ+2{□/}Xzᡂ2~ᐳ{Yxzᡂ4~ᓫZzᡂ1~ᐳ{ᑣZ5H}WHAiXd'VIAiᐗlWஹXCḄᓫ/}᪶᜜ᵯ}᣸+,ᑣWdMgᐗlXdOᐗlWஹYஹZ}ᨬ᜜ᵯ}ᦪ;X}ᨬ᜜ᵯ}ᦪYḄᨬ᜜ᵯ}ᦪ56-2=3,YHஹMge,ᕜgᑣY5Bᐗlsᑖ᪆஺ூ⚪௃A.ᵫWஹXCḄᓫ/}᪶᜜ᵯ}᣸+,ᑣ᪶ᵯ₹ᦪᜧḄ/}ᦑWஹXCḄᓫ/}ḄX>W,A⚗67B.Y5Bᐗlᐗlᕜg⊤NᕜgIDAiB⚗┯]C.WḄᓄᱥḄELM5MgCLLMMg?+ᙠLMN£E¤ᡂMg(OH”¥¤ᡂḄHC15ᢵ§ឋ⏚஺MgCLLM¨©ª«¬xᑮMgO,C⚗67D.¯°±ᑺNBஹO}ᨬ᜜ᙳ´µ8ᵯ}v᪀D⚗67¶ᫀ⌱B஺ூ¶ᫀI¸௃(1)¹LME¤ᡂºᢵ§ឋ⏚D¨©¬p»ᱥ¼(2)¹LME¤ᡂ᧕ᢵ§ឋ⏚D¨©ª«¬p»ᑮCḄ=ᓄᱥ஺ஹ¾⌱¿⚪(ᐳ84ᑖ)23ஹIs22s22P63s23P63d1°4s24P3As|ÃÄR=ÅÆ┵AS2O3+6Z11+6H2so4=2AsH3T+6Z11SO4+3H2OÈÉឋNH>PH33>ASH,Ê5ËÌjÍÌᜧᓄᔠᱥÌÈÉÏINH>ASH3>PH,NH3xzᡂᑖ}Ð<ÏIᨬÑ333As%+ᑖ}¼ÒÓPH3ᜧᑖ}ÐÔᵨÖᜧÊ¥ASH3ÓPH3ÏIÑ஺ூ⚪௃Xᐗl}Ḅ4P×⍝Ùᨵ3~Úᡂᵯ}X5AsᐗlYᐗl}Ḅᨬ᜜2P×⍝Ùᨵ2~Úᡂᵯ}Y5OᐗlXஹYஹZḄ}Ûᦪ;42,ᑣZḄ}Ûᦪ542-33-8=1,ZxzᡂÜp{/}Z5Hᐗl(1)X5As,As}Ý᝱D᪶᜜ᵯ}᣸ß5Is22s22P63s23P63e஺4s24P3,¯ᐗlḄàádAs஺

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