山东省九校2022-2023学年化学高三第一学期期中学业质量监测模拟试题（含解析）

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2022-2023
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+CuSO4aq
=ZnSO4aq
+Cus
AH=-216kJ
moH,EᱥEᡂᱥB.CaCO3s
=CaOs
+COg
AH=+178.2kJ-mol1,Eᡂᱥ2C.2HClg
=Hg
+C12s
AH=+92.3kJ«mol1,ImolHClᙠ¢£ᘤᑖ¥7¦592.3kJḄ2D.0.5molN2K1.5molH2@\¢Ḅ£ᘤᐙᑖ7ᡂNHKg
,¦19.3kJ,ᐸᓄª«¬N2g
+3H2g
.2NH3g
AH=-38.6kJmol13ஹ^ᑡcdḄgOYA.®ᐗ°Ḅᓄᔠᱥ±.:g®ᓄᱥB.ᵫ%³´ᐗ°µᡂḄ¶·ᱥ±gᓄᔠᱥC.¸\7&ᑮḄ¸º»ᵯḄᱥgᵯ¥D.Tᨵ.´ᐗ°Ḅᱥ%kg½ᔠᱥ4ஹ^ᑡ¥¾¿ÀÁ«ᡈÿḄª«¬%ḄgA.ᰚÅjÆÇ$%ÈᵨÉÊË|ÌÍSih+2NaOHNazSiCh+hhOB.ᙠÎÏᮞḄÑ5ºOᨵ1-
ÒH2O2&ᑮL2I-+HO+2H+=L+O2T+2H2O22C.ÓḄÔowÕ$⊤☢ØᡂÙÚ⁐OᡈÚ⁐YCÜÝ3Fe+4H20g
Fe3Ch+4H2D.“84º”OᨵᦔᡂᑖNaClO
K“Gᔓᮣ”Oã⌕ᡂᑖå⏚Y½ᔠÈᵨ¦5çèCIO+Cl+2H+=Cht+HO25ஹéᕜãëᐗ°XஹYஹZஹWìíîᦪðñòᜧ$ᐸYஹWᜐ\³.ãë$YஹZḄìíᨬ᜜Ýᵯíᦪ÷K}\9,XḄøᓫúᓄᱥWḄᓫµᡂḄ½ᔠèûüᐝkᡂWḄúᓄᱥKþÿᔠᱥ஺ᑡḄA.:rX
vrY
vrZ
vrW

1B.YḄᓄᱥḄឋWḄC.WḄᓄᱥḄᓄᱥ⏚ឋXḄD.YᑖXஹZ"ᡂḄᓄᔠᱥ$ᐸᡠ'ᓄ()Ḅ*+,-6ஹᑡᨵᐵᡈ1ᨵᐵ23Ḅ45Ḅ()A.SiO289NaOH:;<=>9HF:;<=ᙳ@ᡂAB$ᡠCSiO?DEFឋᓄᱥB.S02BGᑖHᐭJᐸ:;ᙳ9CKᵯ$ᡠCSaBNH3ᙳDEᵯ4MC.“OPQ”STᒹ'Ḽ“WXᑮMX”ḄZ([\$-]>ᒹ'^ᱥᳮBᓄ(XᓄD.Blaᐹᨵ,-Ḅᐗbcᡂ$ᡠC“co?Bd&DE-bf"g7ஹ0.6mol-L"Fe2(SO4)3BL2mol
L“CuSO4Ḅᔠ:;200mL,hᐭWijᐙᑖ<=l$mn:;JFe?+CM+ᱥMḄWpq21,ᑣhᐭijḄᱥMḄWq()A.0.30molB.0.22molC.0.16molD.0.48mol8ஹs⊤uᑡ<=Ḅvwxy()A.z⏚{Ḅ4<=CHCOO+HO+=CHCOOH+HO3332B.|⏚┛~WḄNaOH:;<=Ca2++2HCO+2OH=CaCOl+2HO+CO32C.{:;ᓄ|<=CHO+CO+HO=C6HOH+CO6522SD.⏚~WḄi<=3Fe+8H++2NO=3Fe3++2NOf+4H2஺9ஹᓄ(PCk)ᨵᔠᡂJ⌕Ḅᓄᑺ$9ᵫ᝞<=ᑴnPCh(g)+C12(g)^^^PC1(g)AH=-93.0kJ/mol5$ᙠឤq2.0LḄᘤJᐙᐭ2.0molPCbB1.0molCL,]l<=⊝᝱஺¡¢ᦪ¤᝞⊤ᡠu஺t/s050150250350n(PCI5)/mol00.240.360.400.40ᑡḄA.ᓣ¦$⊝ᔣ<=wᔣ¨©B.ªᜧ¬$ᓄᑖ®ᑖᦪªᜧ$<=¯᳛h±C.²$<=Ḅᓄ(⊝³ᦪḄᦪ´q஺6D.0~150sᑁḄv(PC1)=2.4x10-3mol/(L-s)310ஹẆ·⊤¸N2OCOᙠFe¹ᵨ»@<=ḄsWXᓄ¼<=ᔊx᝞¾ᡠu$ᑡ┯ÀḄ

2A.<=Á~xÂ*ÄÅB.Fe*Æ<=ḄᓄsÇÈC.Á<=Éᙠ2LḄᘤJÊË$̦<=¯̱᳛D.Fe*+N20-Fe0*+NzஹFeO++CO-Fe++CO?FÍ<=ᙳqμ=11ஹᑡ45Ï¡ḄwxyÐᑏḄÄÅA.Na2cO3:;ᜐᳮÓJḄCaSOCa2++CO32===CaCO143B.Ômnᓄ╆:;ḄpH<7NH++2HO^^NH3H2O+HO+423C.HNChÖ×Ø~ÙÚ<=ḄÛÜAg+2H++NO3-=Ag+4-NOt+H2O2D.ᔣᱥMḄWpq11ḄNaOHBNa2cChᔠᱥJhᐭ~WA⏚OH-+CO3*+2H+=HCO3-+H2O12ஹÝḄA.Þ@ßDEᔠᱥ$;DEàáᱥB.z⏚ஹâãB~ᓄ{ᑖDE⏚ஹãBãឋᓄᱥC.᯼Ḅdᓄ;ᓄᙳDEᓄ(Xᓄ$᯼ḄåæDEᱥᳮXᓄD.ᓄiஹᨵ⁐èᴻBêëìíg13ஹîᕜðñòᐗbWஹXஹYஹZḄóᦪôõªᜧ$ᐸJöᨵYq÷Dᐗb஺WஹYஹZᨬ᜜úᵯᦪpBq12WXஹYZᑖ-ᕜðûXZ"ᡂḄᓄᔠᱥ9üý⏚ῖ⇨஺
ᑡ┯ḄA.
WḄᓫ᝱B.ZḄᓄᱥᐳᓄᔠᱥC.XYḄᜧXc(CD>c(H+)>c(OH)B.aH+4ḄᵯRS)ᨬᜧ

3C.x=1.0D.cH*+cNH3H2O
=0.5x-1
mol-L115ஹ
ᑡUV/,ᐸ/-YḄ4Z[ᐵḄᨵ
A.\]^ᵨᓄ`NH5SO4abcd⏚ឋeᜧ+fghiB.NaHSCh9:ᕈ⏚ឋC.kᓄl9:m◀op#ᑴr⊤☢Ḅ┤ᦿD..xᑴAgNCh9:+ᵨyz⏚9ZAgNCh{F16ஹ
ᑡV|}⌕ᘤᑺḄ⌱ᑮV|ḄḄ⌱⚗}⌕ᘤᑺV|ḄAஹ\⚠ᧅஹ⏀ஹ-⏚ᑴᦈḄkB⏀ஹᴻ¡ஹ¢f£ஹ¤¥¦NaCl9:¢f9:§ᑮᨔFCᙊªஹஹ«ஹ¬¦Ḅ3ஹ4®¯°±V|D¬²ஹ³⁐µᴻஹ⏀-⏚ஹ¶·:ᯚ⁐¹ºV|ூ⌱⚗A௃Aூ⌱⚗B௃Bூ⌱⚗C௃Cூ⌱⚗D௃D17ஹ
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A.Cu-ZnᵯÀSH.SO.B.ÁÂḄÃCuSO.iM18ஹÄÅ)*+ᔣ2.0LឤÈÉÊÈᘤ/ᐙᐭ2moiSO2ImolOz,fg¹º2SOg
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⊤:t/s02468n(SOa)/mol00.81.41.81.8
ᑡOPḄ()A.¹ºᙠÙ2sḄÑᙳÛ᳛V(O2)=0.4mol
LãsãB.äᢝᐸæᩩè;+FGéᑮ1.0L,Ñ⊝ᦪêeᜧC.ëì)
+íî*ᔣÈᘤ/ᐙᐭ4moiSO3,ᑮÑ⊝*+SO3Ḅïᓄ᳛ᜧ$10%D.ឤ*+ᔣðÈᘤ/ñᐙᐭ2moiSthஹImolO,¹ºᑮòÑ⊝n(S()3)/n(SO2)eᜧ219ஹNAõ⊤ö÷8øùᦪḄú஺
ᑡOPḄ()A.
+124gP4/ᡠûP—Püᦪ4NAB.lOOmLlmolLTFeCb9:/ᡠûFe?+ḄᦪO.INAC.᪗
U.2Lᵬᔠᱥᦪ2NAD.ᘤ2moiSO2ImoKhᓄᑖ"ᦪ2NA20ஹ$%&ᵨCO2O3()Mn(hᑴᜓCL,C஺ᐗ./Co?+Ḅ123ᙠ஺ᑡ6789:Ḅ;A.<=ᓄឋ?CoO>C1223B.@AḄHC1ᐰCDCO2O3=ᓄC.EFᡂ1᥅IJKLὑ1᥅ICO2O3D.ᑴᜓNOPḄJKᡠ◤CO2O3SPTMnChU21ஹᔠᳮḄWXYZ;[ᑭ]ᡂᓄ^WXḄᨵ`ab஺ᑡᨵᐵᓄ^WXḄYZᔠᳮḄ;A.ᙠdKᵨeffᰀhiᑴjk=ᓄiB.lᵨmnḄopᑖqỚḄsJᓄtuvC.JKwᐭyᓄzuvT{J|Ḅ}~ឋD.MSKwᐭCuSO,uvT{⏚⏚Ḅ⏚ឋ22ஹᵬஹ8OSḄ⏣ᧇᵯ(᝞ᡠ)஺ᑡp9:Ḅ;

5r*£*3~WOr+HOCMOH+NaOHZCH..COO-▢ᵬA.ᵬᙳᵯᓄᓄB.XஹZ᩽ᑖὑᱥḄ⏣!"#ᵬஹ$%Ḅᵯ&ᦪ()C.YஹW᩽ὑ*+ᱥḄ()!XஹZ᩽ὑ⏣ḄᱥḄ,()D.Z᩽-.Ḅᵯ᩽/0:CH3cH2OH+5OH-4e=CH3COO+4H2஺3ஹ4⌱6⚪(ᐳ84ᑖ)23ஹ(14ᑖ)ᓄᔠᱥGᔠᡂ=ᨔᩞᧇḄABC!DE✏GAஹ⏚IᧇᔠᡂGḄJK᝞M:ANI'1----4---------OOSOCL$%?R—C—OH--------->RC—C1OPMᑡR⚪:(DBḄS᪀UV;AḄᓄWX—.(2)ᵫAஹB.ᡂCḄ/0\];ᵫ£.ᡂFḄ/0\]—o(3)DA`*abḄWXcᑏeᙠghᩩjMFklNaOHḄ⏣m=/0.ᡂGḄᓄnoV(4)Eᨵqr)ᑖs᪀C!tlMᑡᩩjḄEḄ)ᑖs᪀Cᨵr஺জwxᨵyz{|}ঝḄCCLm=⁐■ECH—CH᳝(5)᯿"o!D⏚(CH3cH2COOH)ஹwIᧇᑴᜓᨵᑖ&ḄᔠᡂJK(ᑺ⌱)஺24ஹ(12ᑖ)ᱥ᪍ᩔᡈᢓᑴ!ḄᔠᡂJK᝞M:

6HO-CH-COOHsB(CHBO)&7(¡5)஺HN-CH-C2\1H-CH-CHO-H-COOHO-C—H-COOH^"-Cᐸ᪍¢£¤1.yz¥})¦ᙠ)§z¨I&ḄS᪀©ª«Ḅ!¬-.ῃ®/0I-CT¯°ῃ®_1=o+H2OORCH-CNRCH-COOH2.RCHOiicN/oir(1)ᐵ᪍ᑖ&!Mᑡ²³´µḄ.A.ᑖ&VCl6H18N3O5B.ᑖ&A`4z¶ឋ¨I&C.Imol¸ᱥᨬqk3moiNaOH/0D.-.{|ஹgᡂஹ*ᓄஹº»/0(2)/0জḄᓄnoV,CHIḄ¼ᵨo3(3)ᑏeᵞ¿⏚(H2N-CH2—COOH)C-.ºᔠ.ᡂ3ÀḄS᪀UV¤஺(4)ᑏe3r)tlMᑡᩩjḄᓄᔠᱥCḄ)ᑖs᪀C¤»জᑖ&A`wx!©`#*“§0§0§”cঝᑖ&A`ᨵ3r©)ᓄx᛻ḄÆI&஺CHjHO-CH-COOH(5)ᑭᵨÈᨵ£É⚪AÊËḄ/0!Ì஺ᔠᡂḄJK஺(ᵨ"oÍ⊤Ï!ᑺOCHjOCHj⌱)__________________25ஹ(12ᑖ)ÑÒ.ÓAÔÔ◤⌕×Øᔠ+CAḄN஺ஹ!`ÙÚÛ«!ᐸA§rn³Ḅݼ᝞M¤জ¬0.20011?+᪵ßᐭ⏚ᓄḄH2஺ám=A!NOஹâᐰä*ᓄNO(+᪵AḄᐸ+C©åk/0)!g®æçè100.00mLঝéh!◀ë#ḄH?஺ácঞ{20.00mL¸m=!gᐭ20.()OmL8.000x10-olL-1FeSOm=!ᐙᑖ/0cm4টᵨ5.000x1(T3molï|m=ñ«ᒕóḄFe?+,ôõὑK?5஺:m=20.00mL,

7$%?Fe2++NO+H+—NOT+Fe3++H2O()CrO'+Fe2++H+—Cr3++Fe"+H?஺()2পNO⌕NO,ᑏ¡NODHO=ᓄNO"Ḅqo¢2V22(2)K£NzஹNONO2,ᵫ¥¦F2NO20N?஺§K¨3ᙠ§©PḄN?O/NOஹ⊤<ᔠ4KḄ«ᡂ¬ᜧ®¯°xḄ±²(³“¬ᜧ”“8¶”ᡈ“¸¹”)஺(3)º»¼ঝᔠKNOPḄ¾©¿À²(³“Áᜧ”“Á¹”ᡈ“ÂÃÄ”)஺v(4)K᪵N஺ஹNḄPmolm-3.(aᶇ3ÇᨵᦔᦪÉᑏ¡ZÊk¢)26ஹ(10ᑖ)ᵬᙠAËᩩÍ&Î=ᓄÏKÐᱥ◀ÒmK᜜ÎᨵtḄ=ᓄᱥ஺Ôᓄ^¹«ᑭᵨ᝞ÕÖ×ØᐸÐᱥ஺[Ú▅Üᧇ]জCOßàáâuv?CO+2[Ag(NH3)2]++2OH-=2Ag+2NH4++CO32-+2NH3oঝC112Oã⁐8àAg+ߦF?CU2O+2H+=CU2++CU+H2OO(1)ÕÖAḄᓄ^o¢2(2)ᢥKæoᔣᔜÕÖéêᑮìḄíî[ïA-_஺(³Éðñò)(3)$%KÐᱥᨵCO,ᑣÕÖC&ôõᑮḄö÷;§ÕÖFḄøᵨ(4)ù¿úÕÖDᜐüýþᐰC¶ã⁐஺YZWXÿ
⁐ᨵCU2O—o27ஹ(12ᑖ)⏚(LFeOQ⁐ᦔḄᜐᳮᑺᑭᵨKC1O!FeCbᙠ#ឋ%&'()ᑴᜓ,-./0123RFeCh45᝞7஺9:;জFeCL᧕=>100࠷?@AᓣCঝKC1OᙠD&E'F2Gᓄ()2ᡂKCIOjঞK⁐ḄK2FeO4᧕LஹMLN#OLP⏣ᙠ05CḄR#ឋDSTᙠ⏚ឋUV#ឋᩩX'Y!()2ᡂFe(OH)3Z02஺

8(1)öᘤXḄḄWXAA/0Ḅø&noV§஺(2)ᵨ#KOH◀ùkCL/0.ᡂKC1O,úûᑮḄ§¼ᵨ!ᑏeýAᑴᜓKzFed,ḄᓄnoV—!¸þ⌱6Ḅÿ
(3)ᑴᜓḄ⏚ᨵKOHஹKCkFe(OH)3ᩖ⊡ᐙ᦮(#$%&⏚ஹ'()ஹ*⏣ஹ⛳-NaOH./ஹ⛳-KOH./ஹ0Ḅ1KOH./ஹ2))஺জ6789Ḅ⏚.:7;ঝ=>>/?:2)@ᔣ>/Bᐭ⛳-KOH./;ঞᤅFஹ☟?ஹ=>ᵨ—JK23LᙠNOPQRPQ஺28ஹ(14ᑖ)✏YZ([᪀᝞^Iᡠa)bᵨ⌶deḄ✏ᧇᵫ✏YZhᑡ^aḄjkl)ᩰ⏚஺7nজKMnCUஹOH-pq&CHsCH=CHCH2cH3_CILCOOH+CH3cHzCOOHঝH3O+}~ᑡ⚪:(1)✏YZᑖḄḄ,IlfHIḄ.(2)ᨵᱥIIIḄ[᪀,ᙠkᓄ=H-HIḄḄb(3)ᑡᐵ:ᨵᱥIஹIIஹIIIஹIVḄḄb(⌱¡¢£)஺A.jᵨFeCL./ᩭ␺©H-IIIB.IV᪶¬ᐳ®¯°ᐳᨵ4±²C.IஹHஹHIᙳj´µḄ¶·ᓄ¸./¹⁐D.Imollᨬ¿-5moiᙳÂÃBᡂ(4)ᑏÆ)ᩰ⏚Ç=9NaHCOs./ḄᓄÊ
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9(5)ᓄᔠᱥIVᨵ¿±ÍᑖÎ᪀ÏÐᔠᑡÑÒᩩÔḄÕ✏ÖÍᑖÎ᪀Ïᐳᨵ±஺জ⍗·ᓄ./ÂÃØ⁐ঝÂÃ)Ù-ÚÛᐸ᪶¬ᐳ®¯°ᐳᨵ5±ᔾᦈ²ßᔾᦈ²☢áâ1:2:2:2:1ÍᑖÎ᪀ÏḄ[᪀29ஹ(10ᑖ)ãäᓄᱥ(NOx)ஹCO2-SthåÏæ⌼ᡂè᛻⚪஺êë᯼íåîïᓄÊ
ðᜐᳮj#óô⁐èõஹ⁚÷᣸ஹíᱥᑭᵨḄ஺(1)pq¯åÇᵬ⏣Ḅëûüᑖ©285.8kJ
mol“ஹ726.5kJ
moH,ᑣCChÇÆÃ/᝱ᵬ⏣Ç/᝱)ḄüᓄÊ
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6moicCh8molH2ᐙᐭᘤ2LḄᘤ᝞CO2(g)+3H2(g)^CHOH(g)+HO(g)=-49.0kJ-moP1,!5!!32জḄᩩ(“!"”“$"”ᡈ“&'"(”)ঝᑡ,-./012ᑮ4⊝6᝱Ḅ(89)a.;ᔠ=>Ḅ4ᙳ@AᑖCDEFᢝHIb.C(hH2ḄᱥDḄEKLFᢝHIC.CO2H2ḄMᓄ᳛@Pd.3vR(H2)=VS(CH3OH)e.lmolCO2ᡂḄUVᨵ3moiH—HXYZঞH2ḄᱥDḄE[V\Iᓄ]^᝞_`^ᡠbcdᦋIfgᩩh`icjk%ᱥDḄE[V\Iᓄ]^᝞_m^ᡠb஺o`^@Lcm^ᦋIḄᩩp.iot/min(3)᝞_fᵬ⏣sᧇᵯvwxḄb'_஺DCyᣚ{(|ᨵDC.}~)ḄᙳIL2moi“”H2sCh஺ᵯ᩽aḄᵯ᩽,ᵯvᨵImole•MVḄDEK—g(Ꮇᱥὑ,ᶍ=>Ḅ)஺IX

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ef>᪆hஹ⌱j⚪lᐳᒹo22pq⚪஺rq⚪ᙳtᨵpuᔠ⚪wḄ⌱⚗h1ஹCூ⚪ze>௃A.⇷}~AᨵᯖḄᕡ⌼☩O~Aᨵᕡᵨᑖ⇷}Z⌼☩A⚗B.2ᚗᨵᛛᧇᚗᛛᧇᚗY32¡B⚗C.¢P⏣£¤ᧇ¥OᵨLᩔ§ஹ¨©75%Ḅªᵨ⏀¬ᵨLᩔ§ஹ¨©C⚗┯¯D.ᒹo°±²©ᙠᑁḄ²©´ᵫ~¶ᡂ·¸Y~¹ឋ~ᜫ»2ᳮឋD⚗cᫀ⌱C஺2ஹBூᑖ᪆௃A.()ᱥḄ½Y¾ᜧL2ᡂᱥḄ½Y¾ÀÁ¸()B.()ᱥḄ½Y¾qL2ᡂᱥḄ½Y¾Àᔾ¸()C.Ã()Àᔾ¸()D.Ã()À⌮()஺ூ⚪ze>௃A.Æ()ᱥ½Y¾ீ2ᡂᱥ½Y¾ᑣ()ᔾ¸()¥Ã()AH<0,A⚗┯¯B.Æ()ᱥ½Y¾ீ2ᡂᱥ½Y¾ᑣ()ᔾ¸()Ã()AH>0,B⚗C.᪷ʸᓄ\Ë5Ì2HClg
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AH=+92.3kJ-moH:HC1ᑖ>ᔾ¸()C⚗┯¯D.()N2
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+3H2
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-2NH3
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⌮()ÍO.SmoMZ1.5molH2ÎLÏÐḄÑᘤᐙᑖ()2ᡂNHKg
qLl.Omol,Á¸19.3kJ,ᑣ¸ᓄ\Ë5Ì)ÀN2
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-2NH3
g
AHீ-38.6kJmol“D⚗┯¯cᫀ⌱B஺3ஹBூcᫀ>᪆௃AஹÕᓄᱥᵫÖᐗضᡂḄᓄᔠᱥᐸᐗØÕᐗØᦑA┯¯BஹᓄᔠᱥᵫOÛᐗضᡂḄᓄᔠᱥᦑBCஹᵯ>ÝᵯḄÞßàáâãäåCChḄYæÝᵯ¥ÝᵯḄÞßOCChâãᵯÞ32çèCO2Oᵯ>ᦑC┯¯Dஹ᝞éᐗضᡂêë᪀OÛḄᱥíᔠîLíᔠᱥ᝞ïðZñòïᦑD┯¯஺4ஹBூcᫀ>᪆௃A.ᰚô#AOYᵨõöïᵨ∍çÀὅ();SiO2+2NaOH=^=Na2SiO3+H2O,A;

11B.ᙠúûᮞḄýþ(ᨵr)H2O2ᑮL2r+H2O2+2H+=I+2HO,B┯22C.Ḅ⊤☢ᡂ⁐(ᡈ⁐)!"ᓄ$%3Fe+4HO2=Fe3O4+4H2,C&'2D.“84()*”(ᨵᦔᡂᑖNaClO).“0ᔓᮣ”(3⌕ᡂᑖ5⏚)7ᔠ9ᵨ;<"ᓄ=>?@ABCD%CIO+C1+2H+=Cht+HO,D&';2Fᫀ⌱B஺5ஹBூFᫀL᪆௃OᕜQ3RᐗTXஹYஹZஹW>UVᦪXYZᜧᐸYஹWᜐ^_`3RYஹZḄ>Uᨬ᜜ᵯUᦪd.e^9,XḄfᓫhᓄᱥWḄᓫjkᡂḄ7ᔠDlmᐝo<ᡂWḄhᓄᱥ.pq7ᔠᱥ஺CL7ᔠmᐝo<ᡂWḄhᓄᱥHC1.pq7ᔠᱥ஺XrCᐗTYrC1ᐗTᐸYஹWᜐ^_`3RYrFᐗTYஹZḄ>Uᨬ᜜ᵯUᦪd.e^9,ZrMgᐗTAஹ>Ust:r(X)>r(Y),r(Z)>r(W)ᦑA┯Bஹ_3RᐗTḄhᓄᱥvwឋ⌲z{|vwឋHF>HC1,ᦑB&';CஹC1Ḅ"ᓄᱥḄᓄᱥ⏚ឋ}`w~CḄ,᝞:⏚ឋHCO>HC1O,23ᦑC┯DஹC1ᑖCஹMgᡂḄᓄᔠᱥᐸᡠᓄḄ}_CC1ᡂᐳMgC1ᡂUᦑD┯஺ᦑ⌱B஺6ஹCூFᫀL᪆௃A⚗SiO2NaOH*?@<ᡂNazSiCh.HO,Si(hHF*?@<ᡂSiF.HO,SiCh22^⏚ឋ"ᓄᱥ┯B⚗SO2*ḄᵯUᵫSO2?@<ᡂḄH2so3ᵯBᩭḄ}SO2ᵯḄN%*ḄᵯUᵫNH3?@<ᡂḄNH3HOᵯBᩭḄ}N%ᵯḄSCh.NH3ᙳ^ᵯLj┯C⚗ᜮḄᡂᑖCaCO3,“”;

123Fe+8H++2NO=3Fe2++2NOf+4HO32ᦑ⌱B஺ூFᫀÉÊ௃CO2.¾¿À*ஹYC⏚5*?@ᙳᑮNaHCCh,ËᱥCO2ḄÌᐵ஺9ஹCூᑖ᪆௃᪷Ï?@ḄÐÑᱥjḄ.Ò⊝®PC15ᱥjḄᑏB¼?@Ḅ“$ÕÖ”¢×ØᓄÒ⊝Ùᦪ?@Ú᳛eÜ஺ூ⚪º»L௃A.?@H<0,&?@AᓣÞßàÒ⊝ᔣ⌮?@¥ᔣâãᦑA┯;B.ZᜧäᔜᱥjḄæàZᜧ?@Ú᳛çèᓄᑖUéᑖᦪ}ᦑB┯;C.ᵫ⊤oê250s®?@ëᑮÒ⊝®n(PCl)=0.4mol,ᑣᨵ5PCl(g)+Cl(g)____\PCl(g)325©ª(mol)210Iᓄ(mol)0.40.40.44⊝(mol)1.60.60.40.4molc(PJ)OT5¼ßàì?@ḄᓄÒ⊝ÙᦪK=íî`-=ᦑC&';c(PCl)-c(Cl)L6molO.omol632x--------2L0.36molD-ᑁḄv(PCh)=v(PCk)=^=——=1.2xl0-3mol/(L.s)'ᦑD┯஺
t150sᦑFᫀ⌱%C»10ஹCூFᫀL᪆௃Aஹ?@ᱥḄóôÞ<ᡂᱥḄóôᑣ?@A?@ᡠ¢?@ḄAHV0,ᦑA&'BஹFe+õᓄᑺ÷ø¼?@Ḅèᓄô,ᡠ¢Fe+9¼?@Ḅèᓄô{ùᦑB&'Cஹ¼?@Ḅó?@rNO+CO=N2+CO2,2?@Á¦9ᵨúõᓄᑺõᓄᑺḄèឋßàᨵᐵûᨵᙠ〉þḄßàᑁᢵᓄᑺḄᓄឋ᳛ᦑC┯Dஹᵫ!"#Fe++N2OTFeO++N2ஹFeCT+CO-FeYCCh$%&'ᱥḄ)*+ᡂᱥḄ)-ᡠ/$%ᙳ123ᦑD45ᦑ⌱C஺11ஹBூ9ᫀ;᪆௃A.>?@ḄA⏚┛DE*>◤⌕HᶇᓄJKB.L᪷>;NEOpH<7C.PQRS⏚+ᡂḄ'NOTUD.RV⏚W-ᦑXYᓄZ[\⏚Z&]ᐰ_Q`+ᡂaᓄZஹbYᓄ\TU[>஺ூ⚪de;௃A.A⏚┛DE*>f1ᱥᙠhijkKlᑏnop45ḄhijkK1q

13CO2+CaSO^^CaCO3+SO?",ᦑA⚗┯®¯34B.ᙠ±ᓄ²c³᪷µ¶c·¸⏚ឋcpH<7,ᐸ¼C½¾NH4++2H2O^=^NHyH2O+HO+,3ᡈNH4++H2O^=iNH3
H2O+H+,ᦑB⚗R¿¯C.ÀHNO3ÁÂÃÄÅḄÆÇcᡂNO,ÈHNth,É1R¿Ḅ¼C½¾3Ag+4H++NO=33Ag++NOf+2H2O,ᦑC⚗┯®¯D.ᔣᱥDḄEKL11ḄNaOHNa2cCh;ᔠᱥËᐭEÀÌ⏚cḄOH-CCh”ᙳµÍᐰcᐸR¿Ḅ¼C½¾OH-+CO32-+3H+=CO2T+2H20,ᦑD┯®¯ᦑÏᫀ⌱BoூÏᫀÓÔ௃Ö⚪D⌱⚗᧕┯ÓcÙ⏚ÚoÀÌ⏚`DḄCO3?-oH+Ḅcᐸ¾ᑖÛcÜgÛCO2+H+=HCO,Ý⏚EcᑣᡂḄHCCh-µßàoH+ÜáÛHCO3+H+=CO2T+HO,É⌱⚗332ÀÌ⏚Ecᨬãä⌕æᱥCO2,ÈHHCChஹ12ஹAூ⚪çè௃A.éêëì$íᾦï⏚ᵞêñòᡂḄcóô;ᔠᱥc±|õgìᱥDcóôö÷ᱥcᦑAR¿¯B.øᓄÚo¶◀úᡂûøᓄÚüᡂø=cHýឋøᓄᱥcᦑB┯®¯C.᯼Ḅ=ᓄoᓄஹÿ
ᨵᱥᡂᙳᓄᓄᦑC┯D.ᓄᱥᦑD┯ᦑ⌱A஺ூᫀ"#௃%⚪Ḅ᧕┯"D,⌕*+,ᔠᱥ*+.ᑖᓄ0ᓄ஺13ஹDூᫀ2᪆௃4ᕜ678ᐗ:WஹXஹYஹZḄ;<=ᦪ?@AᜧXCZDᡂḄᓄᔠᱥEFG⏚ῖ⇨ᑣXO,ZSi,YLᐗ:CZMᕜ6ᑣYᙠOPᕜ6ᑣYEQNaஹMgᡈALSWஹYஹZᨬ᜜Vᵯ<ᦪX012,YWCXMᕜ6;<=ᦪZX[ᑣ\᝞^ᑖ_`abcYNa,ᑣ?dWஹYஹZᨬ᜜Vᵯ<ᦪX012,efWḄᨬ᜜Vᵯ<ᦪ7,;<=ᦪZX(O)ᜧgᔠ⚪+hicYMg,ᑣ?dWஹYஹZᨬ᜜Vᵯ<ᦪX012,efWḄᨬ᜜Vᵯ<ᦪ6,;<=ᦪjX(O),gᔠ⚪+hicYALᑣ?dWஹYஹZᨬ᜜Vᵯ<ᦪX012,efWḄᨬ᜜Vᵯ<ᦪ5,Nᐗ:gᔠ⚪+klᡠnWN,XO,YALZSi,doᑖ᪆p஺ூ⚪qr2௃A.stsu^WḄᓫ<N2,wᦑA⚗yz

14B.Z1Si,ᐸXᓄᱥ1tuᑖiᑁḄᓄJwxᨵSi-Hᐳ{w1ᐳ{ᓄᔠᱥᦑB⚗45C.ᙠᐗᕜ⊤@ᑮiᜧXO,Y1ALᑣiḄᜧᐵ1qXVY,ᦑC⚗45D.XQZᡂḄᓄᔠᱥ1SiCh,"Q++ᡂV[>1⏚ឋYᓄᱥᦑD⚗┯9ᫀ⌱D஺14ஹDூ9ᫀ;᪆௃AஹbnEO⏚ឋEO@c(CD>c(NH+)>C(H+)>C(OH),A┯Bஹa'V⏚EO4Xhiᨬᜧ>ḄᵯhkᨬB┯Cஹ᝞x=1.0,ᑣcbὅាL᪷>;EO⏚ឋpH=7,¡¢>W-x>l,C┯DஹcnEO@ឋ᪷£ᵯ₹¥ឤ"#╆᪷hi¨*ahiᙳ'0.5mol/L஺᪷£©i¥ឤ"#nEO@c(NH3H2O)=0.5(x-1)mol-L1,D459ᫀ⌱D஺15ஹBூ⚪de;௃A⚗ஹ(NH஺2sO,ª*«⏚¬V᪷hiᙠEO@>;®¯EOᕈ⏚ឋN±²⏚ឋᜧ+³´QVµ>;ᨵᐵᦑA┯B⚗ஹNaHSO¶'«⏚«⏚KV,A⏚XZᙠEO@]ᐰᵯh+ᡂXhiஹZhi[A⏚᪷hi¸NEOᕈ⏚ឋQVµ>;¹ᐵᦑB45C⚗ஹaᓄ᪶ª*«⏚¬V᪷hiᙠEO@>;®NEOᕈ⏚ឋ⏚[┤+ᡂV[>ᡠ/EO"f¼½¾◀ÀªᑴÂ⊤☢Ḅ┤ᦿQVµ>;ᨵᐵᦑC┯D⚗ஹS⏚Pª*«⏚¬VPhiᙠEO@>;®¯ᐸEOᕈ⏚ឋ1ᢓᑴPhi>;ᙠÆᑴÇEOnᵨRS⏚E;S⏚PÉUQVµ>;ᨵᐵᦑD┯ᦑ⌱B஺16ஹAூ⚪de;௃A.ᑴÊ`ᦈÌÍÎḄaTÏᑴÊḄaTÐÑ◀ᩖஹÍÎÓ◤⌕ÔTÕஹ⛳[×V>[A⏚ᵨØ⚠ÚᧅÜÝᵨᑖOÚᧅᦑAÞᑮßàdḄB.áNaClEOâaᓄZᨔU◤⌕⏀åæஹçᴻéஹáêஹëìíBÞᑮßàdḄC.ïðñòßà◤⌕ᙊôõÕஹ®Töஹõ÷ஹLíøஹÍÎḄ¢Tஹ>CÞᑮßàdḄD.ùLú↾RV⏚ᙠ¹⁐ýᯚÿ
⁐↾᪵ᙠ⁐ᯚᯚ⁐⌕⁐ᴻDᑮḄ"#ᫀ⌱A஺17ஹDூ⚪*+௃A.ᙠCu-Zn-ᵯ/0ᵫ23456ឋZn>Cu,ᡠ9Zn:;᩽Cu:=᩽A┯?"B.@AḄBCD@AEᵯFḄ=᩽GH:□᩽BAEᵯFḄ;᩽GH:ᵯFḄ▢᩽B┯?"

15c.Lᱏ╄OD╄PEᵯFḄ;᩽GH:▢᩽╄Q34EᵯFḄ=᩽GH:□᩽C┯?"D.ᙠᵯ+D□᩽CRcrᜫTᵯUV:CL,C12EKIWXYᣚ[\]XL,LE^_`aV:⁐ᙠ▢᩽H+bcᵯUV:H2,dḄefghijᵨᔣm᣸hiopᦈrD=s"ᦑᔠᳮ⌱⚗xD஺18ஹDூ⚪*+௃A.[\ᙠy2sDzᑁᵨ|}ᓄ⊤Ḅᙳ᳛v=Ac/At=0.8moK2.0L-^2s=0.2mol»L1*s1,ᓄ[\᳛g2ᦪg}iḄᙳ᳛:O.ZmobL-^s-1xl/2mol«LJ=0.1mobL^s1,ᦑA┯?"B.fD⊝ᦪḄVᓄVᓄᡠ9⊝ᦪVᦑB┯?"C.ᵫ⊤ᙠfmᐙᐭ2moiSO2ImolCh⊝DXᡂḄSO3:L8moLᵫᦔ⊝,ᐙᐭ2moiSth,ᑣSO3Ḅ⊝£ᓄ᳛:10%,D=[\x¤jḄ[\¥¦fm§¨Dᔣ©ᘤ0ᐙᐭ4moiS(h,᪷¬᩽▲£ᓄḄ®¯ᔣ©ᘤ0ᐙᐭ4moiSO3,¥2ᢗᐭ4moi±}ᓄ2moi}i²³±}ᓄḄ´µ¶·ᐸ£ᓄ᳛,ᦑC┯?"D.fV,¹ᐙᐭ2molSO1molOD,¥2º©ᘤḄ»j¼,²ᜧ,⊝=ᔣ¾6ᡠ9n(SO3)/n(SO)222²ᜧᦑD=s஺ᦑ⌱D஺19ஹCூ⚪*+௃A.m124gp4ḄᱥÀḄ´xImoLᵫ2ÁÂx=Ã☢Å᪀Çᨵ6ÉP-PÊËᐸ0ᡠÇP-PÊᦪ:6N1,A┯?"B.LÌUᙠ`a0Í+ᡠ9100mLImol•L-iFeCb`a0ᡠÇFe3+Ḅᦪj20.INA,B┯?"C.ᵬÏÐÑᑖUᙳÇᨵ4ÉÓ-U᪗ÕÖ×mU.2LᵬÏÐÑØᔠᱥḄᱥÀḄ´x0.5nwLᐸ0ÇÓ-Uᦪ:2NA,C=s"D.[\2so2+O22sChx⌮[\ËeÚ©ᘤ02molSO21molO2Ûᓄ[\ÜᑖUÝᦪᜧ22NA,D┯?஺#ᫀ⌱C஺ூ#ᫀÞß௃à⚪á⌕âᱥÀÅ᪀ஹÍ+ஹ£¾ᵯUஹ⌮[\ãfὃåà⚪¥ægç©᧕é⌕êëஹìíîïæDðñòóo☢Ḅô஺ÁÂḄÅ᪀x+#ḄõÞñòEᵬÏ=Ã☢Å᪀Ḅö÷஺20ஹBூᑖ᪆௃᪷¬cᜫᵯUùឤ-Uùឤcû[\Ḅᓄoüý:CO2O3+6HCI(ÿ)=2COCL+CLT+3H20
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°஺-ᑴᜓᡂᱥḄḄᵬᵫOHOHᐭ"#$%ᐗ"'ᙠ)ឋᩩ,-./ᑮ1ᨵḄᨵ3ᱥ4ᐭ56⏚84⏚ឋᩩ,-9:/ᑮ;ᱥ஺ூ⚪>?:௃পA.ᵫA᪀CDEFGH᪍Ḅᑖ$DG6H19N3O5S,ᦑA┯MNB.O4PQRSḄ#$TឋU#$ᑣWXYZ5#$[\OḄU#$]ᐗ◀[_`#$᜜ḄbPU#$ᙳTឋUdᐗeYf\OḄU#$TឋUᦑTឋUᐳ4PᦑBhiNC.j-OHᐹᨵ⏚ឋlYNaOH.e_-COOHlYNaOH.e_Imolᑖ$eᨵ2moimnᙠ)ឋᩩ,-o9:ᑣImolpᱥqᨬsY4moiNaOHᦑB┯M஺D.1ᨵt.4ᡂ1ᨵ_u.ju.vᓄ1ᨵZ_f.xyᦑDhi;ᦑ{ᫀ⌱BDCHjফ᪷ᑖ᪆AḄA᪀CDD+ju᧕vᓄ4ᐭCH3I0HOCH3■vᓄ;CH3ᦑ{ᫀ:+Nju■vᓄ;OCH3

20-OH(3)CḄA᪀CD,C_ᵞZ⏚oῃ9xᔠᡂmn,ᵞZ⏚(H2N-CH2-COOH)_C.xᔠP?9VEjN-CH-C-NH-CH2C-OHᡈHN-CH-C-NH-CH-C-OH;:ᡂ%mḄA᪀CDQAOHOHP?9PH'N-CH-C-NH-CHC-OHᡈH2N-CH2-C-NH-CH-C-OHᦑ{ᫀ0HOHHiN-CH-G-OH(4)1ḄRᑖ᪀◤ᑖ$D\RA᪀QRḄᨵ3ᱥCḄᑖ$DC8H9஺3,ᩩ,জᑖ$eOH1Q1vn“
0
0
”Nঝᑖ$e1ᨵ3QRᓄ᛻Ḅ5#$ᑖ$eo1ᨵ
P¡bPᵬ,
PuNᡈὅbPᵬbPu
P`v£nNbPC%O,
P`v£nᑣ¤ᔠ⌕¦ḄA᪀CD(¨ᑏªP);

21H3C—5
᪷⚪e¬ḄIÊËῃÍஹ_1n+H2OO7X-OCH2.RCHOHCN/OH®"°
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’ᑴᜓᡂᱥḄḄᵬᵫOHOHᐭ"#$%ᐗ"³ᙠ)ឋᩩ,-./ᑮ1ᨵḄᨵ3ᱥ4ᐭ56⏚84⏚ឋᩩ,-9:/ᑮ;ᱥᑣᔠᡂ´µ¶᝞-:CHjCHCfaCHOHO-CH-CNHO-CH-COOH6cHjOCH3OCHjdCHjOCH3CHOHO-CH-CNHO-CH.COOHᦑ{ᫀ:25ஹ2NO+3HO=2H++2NO+2HOQ¸ᜧ8.33x1032232ூ⚪>?:௃
1
ºNO,»⌕NO,NOHzO?vᓄNO,H2O2¼#9᪷ᵯ$¾ឤ_ᵯ₹¾ឤᑏÁÂ$D2NO+3HO=2H++2NO+2HO22320ফÃᜧÄÅÆᯠ2NO2=NQ4È.ÉÊËᵫÌNth_N2O4eN_OḄÍÎÏ1:2,ᡠoNO,eḄx=2QÈÑḼÓ⊝ḄÉÊÕᓄ஺3
ºÖᨵ◀×H2O2,ᑣH2O2ÈØὑFeSCh,ÚÛᒕÝḄFeSChÞßàᐭḄKzCrzCháÞâᔠãeNO,1äḄåæAçè¸ᜧ஺4
éêeØὑḄnCrO-
=5.000xlO^mol/Lx20.00mLx10_3L/mL=1.000x10^mol2ᵫàæëḄ+6Fe?++14H*=6Fe"+2C;+7ì஺ᑣnÓFe2+
=6nCrO;
=6x1.000xlO^mol=6.000x10-4mol2YNOḄFe2+ḄᱥqḄänÓFe2+
=8.000x10-2mol/Lx20.00mLxlO3L/mL-6.000x10-4mol=1.000x10-3mol

22NḄᱥqḄänN
=n
NO
=H
NO
=-^^-J=|xlO-3molAã᪵eNOஹeNḄ1ä=-xIO-3molx54-0.2m3=-x10-2mol-m~3«8.33x1O-3mol-஺3626^AI4C3+12HC1=3CHt+4A1CUA->F-*D-*B-»E-*C->Gîïᑁᨵñ⁐óᡂ◀×ᵬôeᩖqã4"ᓄ5_9Þäö⁐ó4ᐭ〉äøù⏚ºúûü⁐ᑣýþ1CU2Oூᑖ᪆௃ÿA
⏚ALC3ᡂᓄᵬᵬᙠᩩᓄᱥ◀!"᜜ᨵ%ḄᓄᱥᡂḄᵬ'()Fᔾᦈ,ᨵḄᓄ-./'()Dᓄ'()B01ᡂḄ!"'()E01ᦈᡂᱥ2ᓄ%'()C
Ḅ3456178ᓄ%CO93456:CO+2[Ag(NH)]++2OH-=2Ag+2NH++CO2+2NH,ᨬ<ᵨ᣸!?ᔾᦈᦈ@A஺32433(1)ஹ⏚ALC3ᡂᓄᵬ஺(2)ஹ)A
⏚ALC3ᡂᓄᵬᵬᙠᓄᱥ◀!"᜜ᨵ%ḄᓄᱥᡂḄᵬ'()Fᔾᦈ,ᨵḄᓄ-./'()Dᓄ'()B01Ḅ01ᡂḄ!"'()E01ᦈᡂᱥ2ᓄ%'()C
3456178ᓄ%CO93456:CO+2[Ag(NH)]++2OH-=2Agi+2NH4++CO32-+2NH3,ᨬ<ᵨ᣸!?ᔾᦈᦈ@A஺32(3)ஹDᨵ8ᓄ%C
3456E8ᓄ%ᡂ3ᓫGF◀Hᵬ
ᩖG஺(4)012஺JK⁐M9Ag+N:CU2O+2H+=CU2++CU+HO,56JO⁐PQᡂK⁐Rᐭ2〉UV⏚:W56XO⁐YZD[\ᑣ7ZDᨵCU2஺஺ூ⚪`ab௃)A
⏚Al4c3ᡂᓄᵬᵬᙠᩩᓄᱥ◀!"᜜ᨵ%ḄᓄᱥᡂḄᵬ'()Fᔾᦈ,ᨵḄᓄ-./'()Dᓄ'()B01Ḅ01ᡂḄ!"'()E01ᦈᡂᱥ2ᓄ%'()C
3456178ᓄ%CO93456:CO+2[Ag(NH3)2]++2OH-=2Ag+2NH++CO32-+2NH3,ᨬ<ᵨ᣸!?ᔾᦈᦈ@A஺4(1)ஹ)A
⏚Al4c3ᡂᓄᵬḄᓄdefgJ:AI4C3+12HC1=3CHT+4A1C1,43ᦑiᫀJ:AI4C3+12HC1=3CHt+4AlCl;43(2)ஹ)A
⏚AI4C3ᡂᓄᵬᵬᙠᩩᓄᱥ◀!"᜜ᨵ%ḄᓄᱥᡂḄᵬ'()Fᔾᦈ,ᨵḄᓄ-./'()Dᓄ'()B01Ḅ01ᡂḄ!"'()E01ᦈᡂᱥ2ᓄ%'()C
3456178ᓄ%CO93456:CO+2[Ag(NH)]++2OH-=2Ag+2NH4++CO32-+2NH3,ᨬ<ᵨ᣸!?ᔾᦈᦈ@Aᢥl32eᔣᔜ)opᑮrḄstuvJ:A—F-D—B—E—C-G,ᦑiᫀJ:ATFTDTB—ETC—G

23(3)ஹDᨵ8ᓄ%C
3456E8ᓄ%ᡂ3ᓫGxyᑁᨵ{⁐RᡂF◀Hᵬ
ᩖGᓄ-!ᦑiᫀJ:xyᑁᨵ{⁐Rᡂ|◀Hᵬ
ᩖGᓄ-!|(5)ஹ}~<)Dᜐxy
RᐰXJK⁐17ZK⁐R
DᨵCsOḄe?J:UK⁐Rᐭ〉UV⏚:W56XO⁐YZD[\ᑣ7ZDᨵCU2O,ᦑiᫀJ:UK⁐Rᐭ〉UV⏚W56XO⁐ᑣ7ZDCU2O஺27ஹឤ6ᧅ2MnO+10Cr+16H+=2Mn2++5CLT+8H2஺ឋ■KzFeCh9!3KClO+2FeCI+10KOH=2KFeO4+9KCI+5H2O!ḄKOH56⏣32ூᑖ᪆௃)A
⏚9⏚ᡂ⏚᧕ᢵNᑣᡂḄ
DᨵHC1!ᩖG⛳¢!◀HHCL£V⏚◀H!"9¤ᙠḄᩩᡂᓄ¤FeChᙠ100࠷prQᓣ¦ᑣᙠ)D
KCK)569FeCbᙠឋ§¨ᑴᜓ¤⏚ᨵ«)Eᔾᦈ¬Ḅ஺ூ⚪`ab௃(1)ᘤXJឤ6ᧅ|)A
┤⏚9⏚ᡂᓄ═ஹ![\efgJ2MnO+10C1+16H+=2Mn2++5ChT+8HO2(2)KC1O569FeCbᙠឋ§¨ᑴᜓ¤⏚±ᵨ(UKOHឋ■KzFeCh9!|KC1O,FeChKOHJᱥ¤⏚JᡂᱥḄefgJ3KClO+2FeCb+10KOH=2K2FeO4+9KCl+5H20¨²ᙠ§¨³´ᙠ!
³´|(3)জKzFeChµ5¶56ᙠ05࠷Ḅឋ56
·¸¹ᙠ⏚ឋº»ឋᩩᑖbᑣ¤⏚¼½5¶ḄKOH56஺ঞKzFeO¾M5¶⏣ᑣᵨ⏣¿À஺28ஹÁÂ%%ÃÄÅ`ḄÆᑮÇÈÉÊÂḄËᵨ±ÌMEᓄACCCST-.0^*8ᐳ13Î11(IIÏ8ூᑖ᪆௃ᓄᔠᱥi!bÑᑮnJClyᵫwḄ~᪀Ôn->mNÅn
ÉÊÂ
H\EᵬÂÅᡂÕᑣinJÕNᓄÑᑮ2⏚9w,2⏚92⏣NÖ×ᡂ×ᱥVJuc=1Rccu'ÙÚw9HINÅᡂ!ᩰ⏚ᨬÜḄᱥ
ÝᨵÉÊÂYZÞßàáHU-t-C-C-U-CngHn-inḄ`ḄÆᑮÇÈÉÊÂḄËᵨ■E⏚ឋ═⏚56ᓄ஺

24i
᪷ã✏åæᑖ\~᪀i⚪|ii
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H\EᵬÂÅᡂmCH2CT-COOH2
HIḄ~᪀çgJÉÊÂ᧕Eᓄ஺
3
᪷ãᨵᱥIஹIIஹHIஹIV~᪀ᑖ᪆஺
4
èÂé9%⏚-ê56ᡂ2ᓄ%ÉÊÂMé9%⏚-ê|
5
IVḄë✏ìPᑖí᪀YZDᨵîïPQðñᩩ:জ⍗ᓄ¤56Nô⁐YZDᨵÉÊÂঝéN!b3öYZDᨵᵬ⏚÷ᡂḄÁÂᨵ2øÅÂJ-OHஹ-CHzOOCH,ᨵùஹúஹû3Îᨵ3øÅÂJ:-OHஹ-CH3ஹ-OOCH,~ᔠ¹2ü8ᑨþ஺ூ⚪`ab௃
D✏åæᑖ\
Ḅÿ
ḄஹiiTinḄ
2ᨵᱥHIḄ᪀ஹᨬḄᱥ!"ᨵ#$%&'(n-niḄ)Ḅ*+ᑮ-.#$Ḅ/ᵨ12345ᓄ3
A.ID!37ᙠ#$II!7ᙠ#$9:ᵨFeCb;<ᩭ␺?II@IH,ᦑABCB.W!37ᙠD᪀ᡠ:᪶GᐳIJKᨵ6LMᦑB┯Oc.IஹIIஹm!ᙳ7ᙠ9:1QḄRSᓄ;—OH
5
WḄk✏mnᑖp᪀qrᨵVWnstuᩩwজ⍗Sᓄz;

25ঝ᪷¶ᑨÈ⊝Ê᝱Ḅ¶¿Àᑖ᪆ঞÍÎᙠÏÍÎḄẠÑJYḄᱥ¢ḄÒÓÔÈ⊝BᔣÖׯᜧ¬Ø(ᡈ¯ᜧCO2±²)È⊝ÛBᔣÖ×(3)᪷¶ÏᵯÝḄÏᳮÞ᩽Z[5ᓄஹB᩽Z[àÏ¿Àᑖ᪆஺ூ⚪)á~௃(1)âãJYXᵬ⏣Ḅåæ·ᑖ?285.8kJmolL726.5kJ-mor',ç(JজH2(g)+1/202(g)=HO(1)H=-285.8kJ
mol"ঝCH30H(1)+3/2O(g)=CO(g)+2HO(1)AH=-726.52222ᵫ¸¹º»9ãᵨজx3-ঝ½CO2X%[<᝱ᵬ⏣X<᝱}Ḅ·ᓄefgCO2(g)+3H2(g)=CH3OH(l)+H2஺পëḄ·H=-285.8kJ
moPx3-(-726.5kJ.mol1)=-130.9kJ
moH,ᦑᫀCO(g)+3H(g)=CHOH(l)+HO(1)H=-130.9kJmol,.2232(2)জâãCO2(g)+3H2(g)^CHOH(g)+HO(g),ëḄì$<(),ðñì!!<(),©ªótuôõAH-TAS<0,ô32õë¾Z¿ÀḄᩩw*©ªᦑᫀ©ª஺ঝa.ëö÷YqḄᱥ¢ḄÒZ[ñᓄḄøᔠYqḄÈᙳùDᑖú¢Ò-ᢝ3ñ%&ᔜýᑖḄ±²-ᢝ3ñᑨëþᑮᓄeÈ⊝Ê᝱ᦑaBCb.CCh@H2Ḅᱥ¢ḄÒ2-ᢝ3ñ⊤
ὅḄᑨᑮᓄ⊝᝱ᦑbc.
ὅḄᓄ᳛ᔲᑮ⊝᝱"ᐵᦑc┯%d.3V(H»=v⌮(CHQH),⊤(⌮)᳛ᑨᑮᓄ⊝᝱ᦑde.lmolCfh*ᡂḄ,-ᨵ3moiH-H/01⌮)᳛ᑮ⊝᝱ᦑe஺ᦑ3ᫀ56abe஺ঞ8ᦋ:;<=ᩩ?@ABCD<=EFH2ḄᱥHḄIJ-Kᓄ᝞MNOPᡠ(OPᙠSOPḄTẠVWXḄᱥHḄIYZ⊝ᔣ\]^ᜧ`a(ᡈ^ᜧCO2)⊝eᔣ\]ᦑOPᡠfḄ<=ᩩ?ᦋ^ᜧ`a(ᡈ^ᜧCO2)ᦑ3ᫀ5^ᜧ`a(ᡈ^ᜧCO2)஺(3)g(hMNijklᵯ᩽aSᧇCH30Hpq,stᱥ5CO2pH+,CH30HNuᐗwᓄᔠy5-2,CO2Nuᐗwᓄᔠy5+4,1aᵯ᩽VCH30Hᜫ|ᵯ}ᵯ᩽a~᩽ᑣᵯ᩽b᩽bᵯ᩽SᧇChpH+,sḄtᱥ5H2O,ᐗwᓄᔠyᵫ01-2,*S5ᵯHH2sijᑏlᵯ52cH3OH+3O2=2CO2+4H2O,@ᑏl5ᓫḄ᩽63Ch+12e-+l2H+=6m0,ᵨY|᩽ᓽiFᑮ~᩽56CHOH+HO-6e-=CO2T+6H+\Imolᵯ}-HIYl/6xl2g=2g,32;⌕ᨵlmolH+H}ᣚAᐭHIY1g,᩽5O2+4H++4e=2H2O,HI^32gxi/4=8g,V\ᩭḄlgH+,¡CḄHI¢£58g+lg+2g+lg=12g,ᦑ3ᫀ5CHOH+HO-6e=CO+6H+,12஺322