2021-2022学年湖北省十堰市高一（下）期末化学试卷（附答案详解）

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2021-2022
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çèᓄᨬêeᑮ᝞஺Ḅ஺ᑣḄëV᳛%(ÂaஹbஹwḄ2345ᐗ7Ḅ9:1000/⊤îO)஺ïëV᳛=;ᧇ4=ᐗ7Ḅ>9:018.᯼òóôºY0¦õöDᜧḄSO2øù᣸öSO2Ḅûüý0¦þᡂ⏚ÿ,ᓻ᛻஺(1)ᑭᵨῃ◀ḄSO?஺ᙠNazSg!"ᔾᦈ%ᑏ'Na2s஺3ᔾᦈSO?+,Ḅ-./012o(2)"45SO2Ḅ᣸789ᵨ“┛<=>”஺“┛<=>”ᓽABCᮞEF>Ḅ᯼HIᔠKLAF>᯼HMBḄSO2Nᓄ"CaS0,ᑣBCᮞASO2Nᓄ"CaSᑁSB+,ḄᓄT/01",UV+,4"WᳮᜐᳮItF>1.6%Ḅ᯼H_ᳮ`ab5cᐭkgBCᮞ஺(3)“┛<=>”_᯼HKLg0MBḄCOhiCaS஺4SB+,IE+,H,lmῃ>ᦔ᳛+,I:CaSO^s)+4C0(g)=CaS(s)+4CO(g)AH=-175.6/c/-21mol-11+,H2CaSO(s)+CO(g)UCaO(s)+SO(g)+CO(g)AH=+218.40•4222mol-1

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13টcஹdÎØÙᡂQᵯÚd᩽áᑣd!᩽äå]æឋd>c,A.ᵫজটZùúCn>c,ᦑA┯B.ᵫঝèd>a,ᵫঞèb>c,üýùúd>cC.ᵫজùúa>b,ᵫঝèd>a,ᵫঞèb>c,ᦑᵫজঝঞÃùúäå]kឋd>a>b>c,ᦑC+D.ᵫজùúa>b,ᵫঝèd>a,ᵫটùúd>c,üýÄᑮaRcḄᐵ®ᦑD┯ᦑ⌱C»ᨵaஹbஹcஹdḄᱏᐭ⏚⏚ᵨᡂ"ᵯ$%&"ᵯ$'()Ḅ*+᩽ஹ'()Ḅ*-᩽./012345஺7⚪1"ᵯ$"ᳮ:;<ὃ>()ឋ@AᑨCDE"ᵯ$-+᩽ᑨCFGH47⚪ᐵJ⚪KLᓫ஺15.ூ5ᫀ௃Bூ4᪆௃4TUVWḄᑖYZ:C6H12,1bc⏣ḄᑖYZ:஺3%0,hi஺3/76-“2஺2-noᑖYZ:C7H14,qᐗsḄtuᑖᦪ:72%,ᑣ“C”2"tuᑖᦪ:T72%x"=84%,ᑣ“”2஺”Ḅtuᑖᦪ:T100%-84%=16%,}Ḅtuᑖᦪ~:T16%x^«1814.2%,ᦑ⌱TB«UVWḄᑖYZ:C6H12,1-c᱃ḄᑖYZ:஺3%஺hi஺346)2஺2—noᑖYZ:஺7/4,᪷.qᐗsḄtuᑖᦪ"NḄtuᑖᦪᯠᓽ“஺”Ḅtuᑖᦪ0}ᐗsḄtuᑖᦪ./஺7⚪ὃ>ᐗstuᑖᦪḄ៉ᨵᱥ᪀ᡂᓽ045⚪Kᜧ஺16.ூ5ᫀ௃ᳫ■¡¢£¤ᢵ¦ᩭḄ¨⏚¦©ª«¬¨⏚¨®Ḅ4CHCWOOH+CH3CH2OHCH3cl8OOCH£H3+HO17.6232ூ4᪆௃4T(1)°2±ᘤaḄ³´:ᳫµ¶ᱏḄ*ᵨH■¡¢£ᦑ5ᫀ:Tᳫ·■¡¢£·(2)°2⛳NazC%ᨵ3»*ᵨᑖ¼Hᔾᦈᢵ¦ᩭḄ¨⏣ஹ¤ᢵ¦ᩭḄ¨⏚¦©ª«ஹ¬¨⏚¨®Ḅ4ᦑ5ᫀ:T¤ᢵ¦ᩭḄ¨⏚¦©ª«·¬¨⏚¨®Ḅ4·(3)¨⏚¤¨⏣ᙠÀ⏚*ᵨÁª«©ᡂ¨⏚¨®ÂᑣᑴĨ⏚¨®ª«ḄᓄÆF⏚ÇZ:CH3cl&OOH+CHCHOHCHC18OOCH^H+HO,32332ấ⏚1S16ᦑ5ᫀ:TCHC00H+CH3CH2OHCHCOOCH^H+82஺·333É14⚓ᐳ18⚓

14(4)20g¨⏚ḄᱥtḄu:Í₹=033mol,46g¨⏣ḄᱥtḄu:ÏÐ=Imol,ᑣª«Ñ¨⏣Òuᵨ¨⏚¨⏚¨®ḄÓ᳛ÕÖ×ᑴب⏚¨®Ḅtu:60%xὑx88g/M஺/=17.6g,ᦑ5ᫀ:T17.6·(5)ᨵᱥM¤¨⏚Ü:Ýᱥ¤¨⏚¨®Ü:ᑖÞ᪀<ᑣßàᩩâḄMᨵCHCHCHCOOH^(CH)CHCOOH,᪀32232ᦑ5ᫀ:T2஺(1)°2±ᘤaḄ³´:ᳫµãᱏḄ*ᵨH■¡¢£·(2)⛳Na2c஺3ä¨⏚ஹ4¨⏣ஹ¬¨⏚¨®Ḅ4·(3)¨⏚¤¨⏣ᙠÀ⏚*ᵨÁª«©ᡂ¨⏚¨®·(4)20g¨⏚ḄᱥtḄu:60-*“=0.33mo/,46g¨⏣ḄᱥtḄu:ᯅ◤=Imol,ᑣª«Ñ¨⏣Òuᵨ¨⏚¨⏚¨®ḄÓ᳛·মßàᩩâḄMᨵCH3cH2cH2஺஺04(஺3)2஺“஺஺஺“᪀஺7⚪ὃ>¨⏚¨®Ḅᑴᜓëìὃ>Æ©íîḄ«ᵨäïð⚪ñ஺17.ூ5ᫀ௃òᜧ⏚ÑóḄôõ☢÷øù4ú᳛ûü⏚ᦔ᳛SiOFe3+Mn2++2HCO^=MnCO1+COT+H0s^2NH-HO+Mn2++2322322HC஺=2MnCC>31+2N”j+2%஺■MnOᓄᓄ2ூ᪆௃!(1)$%&'()*ᜧ⏚-./0Ḅ23☢56789:᳛6<=⏚-ᦔ᳛6ᵫ)@ᑖ᪆(B6CDEᨬGHᑮḄ/JKLᨵSO9஺26ᦑRᫀT!*ᜧ⏚-./0Ḅ23☢56789:᳛6<=⏚-ᦔ᳛USiOQ2(2)7ᐭWᓄX90Y⁚pH\Ḅ]Ḅ^◀`90KḄFe3+,defgC“2+ஹ+jk6ᦑRᫀT!Fe3+;(3)“j╎”.n⏚┡pq⏚Wrsttᡂq⏚═jk6Ḅwxyz{TMn2++2HC0g=MnCOI+COT+“2஺ᡈp~tᡂq⏚6ᓽwxyz{T322NH-H0+Mn2++2HCO1=2MnCOI+2NHj+2HO,3232ᦑRᫀT!Mn2++2HCC>3=MnCOI+COT+HO^.2NH-HO+Mn2++322322WCO3=2MnCOI+2N£+2HOQ32(4)MnO᧕ᓄ6ᙠq⏚7ᑖ.⌕ᐭAr,᣸KḄ■MnOᓄ6ᦑRᫀT!■MnOᓄU(5)(:”(7/)4஺஺3ᑖᡂᓄஹ~Oᓄq6KᐗḄᓄᔠᙳ¡ᨵst¢ᓄ6^ᓄUCzKst!2CuO+2NH2஺"=஺Ḅ஺+M+3H2஺6ᵫ(BtᡂImolᓄ©ªὑ2moi®6ᦑRᫀT!ᓄU2U

15(6)¯B°&KnᐗḄ±²ᑖᦪTa%,ᩖ±KeLnᐗOᐗ6᪷¶ᓄ·{CuFeS2(BᐗḄ±²ᑖᦪ¸Ta%,wkg¹º°&»@¼½ᓄᨬGHᑮbgCḄ஺6ᑣḄ<¿᳛T6À"28.*100%=ÁÂ,lOOOwxa%9awᦑRᫀT!Á஺9aw°&(Ã⌕ᡂᑖ^C“FeS2,LIJ9஺2)OÅ═&(Ã⌕ᡂᑖ^M71O2,LIJÆ02஺3)ᐜÈÉ$%6*ᜧ⏚9.Ḅ23☢56Ê7ᐭËn⏚⏚-6ᐸK8஺2e9Í⏚6ÎÏᓄᱥ9Í⏚tᡂn⏚Ñ6“71஺2ஹCuFeSzpn⏚sttᡂᓫ±SOn⏚┡ஹn⏚ஹn⏚Ñ,CD◀ᩖE7WᓄXY⁚90pH◀`90KḄFe3+,ᡠHD0K7ᐭ~ஹq⏚WÑstM/++2HC0*=MnCO1+CO?+HO,Ô½ᓄTq⏚╎jk63227ᐭ~Ô½ᓄTCU(N/)4C03)ᐭW6gMnC3ᙠ◞ÖᩩØÙᑖᡂMnO,Cu(N“3)4CO3ᑖᡂᓄஹ~OᓄqUᓄÊp®Hᑮᓄ©6¶ᑖ᪆R஺Ú⚪)ᱥ±ḄᑴᜓÞßὃáâᔠᱥᑖw<ãḄäᔠᵨ6T=⚣ὃç6èéᓄêëì6íîïzᑖ᪆éâᔠᱥᑖwyðஹstḄTRḄᐵò6óôᑖ᪆pÞßஹêëfõḄὃá6äᔠឋ÷ø6⚪]ùúKì஺18.ூRᫀ௃SO+SOj-+HO=2HSO32CaO+2SO+O=2CaS028ü222242co(g)+02(g)=2C02(g)/H=-566k/-moLý᩽4H++O+4e-=22H2஺-956.4ூ᪆௃!(l)Na2s஺390ᔾᦈSO2
ᡂ⏚ḄSO+SO+HO=2HS0g,22ᦑᫀSO+SOl-+HO=2HS0jQ22(2)“┛”ᓽ!ᮞ#$Ḅ᯼&'ᔠ)*$᯼&+ḄSQ,ᓄCaSCU)ᑣ!ᮞSO2,ᓄCasᑁ
Ḅᓄ02Ca஺+2SG+2=2CaS0,456ᳮᜐᳮIt$1.6%Ḅ᯼&9ᳮ:;<=>ᐭ@ᓄ┛ḄᱥBḄ4CDEF@ᓄḄᱥBḄCᐗHIឤKᑮn(CaO)=n(SO)=M:O=SOOmol,2BC=SOOmolx56g/mol=28000g—28kg,ᦑᫀ201஺+25஺2+஺2=2(?«5஺428+(3)জI-CaS0(s)+4co(g)UCaS(s)+4c஺2(஺)4Hl=-175.6k+-moL,4ᯏT/Hi<0,UVᦑᫀUVWঝYZ[\2moi]@ᓄ^#Imol@_ᡂ2molF@ᓄ^U`VC566kJ,5ḄVᓄ02co(9)+஺2(9)=2஺02(9)/"=-5660,a0b1,456ᳮc⏚ᵯeBfghiCO)ᧇᵯkᑣCOᵫm᩽oᐭoᐭ஺2Ḅ]᩽Ḅᵯ᩽4H++3+4e-=2“2஺ᦑᫀ:2co(g)+02(g)=2CO(g)AH=-566k/•mor1,m᩽W4H++O+4e-=22p16⚓ᐳ18⚓

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