2021年宁夏石嘴山市高考化学质检试卷（三）

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2021
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42
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ὶA.Nᵯ᩽□ᵯḄ᩽1y᩽

12B.C02ᰚᡂCO2'C2O52-3C.x᩽ᵯ᩽2C2O52-4e—4CO2t+O2tD.ᳮyᵯ᩽ᡂḄxᵯ᩽ᡂḄ!"Ḅ#$%3&4ூ()௃(&A.□ᵯḄP᩽+᩽N᩽᩽1ᵯ(x□᩽y▢᩽ᑣ□ᵯḄN᩽ᵯ(Ḅy᩽ᦑA+/0B.ᵫ2,C0202'ᡂCO32'C2O52ᓽC02ᰚᡂCO32'C2O52-,ᦑB+/0C.ᵫ2□᩽x᩽C2O525ᜫᵯ7ᡂC0202,ᵯ᩽2c2O52--45—4CO2t+02t.ᦑC+/0D.▢᩽ᵯ᩽(20325+45-C+3C)2□᩽2CO52'-4e'—4COt+O222t᪷:ᵯ7;ឤᨵ&C>02,ᑣyᵯ᩽ᡂḄxᵯ᩽ᡂḄ!"Ḅ#$%(ImolX12g/mol)&(ImolX32g/mol)=3&8,ᦑD┯@;ᦑ⌱&D஺Dஹ()⚪(ᐳ3I⚪Jᑖ0ᑖ)8.ṃ(Sb)NOᵨQRᔜTUVᑺஹ◌YஹZ[\ᐗ^_⚞abcṃ5dᩩ^fg⏚஺ijṃk(l⌕ᡂᑖSb2s3,noᨵAs2s5ஹPbSஹCuOSiO2_)pᧇᑴᜓbcṃᐸu5Tvwxy᝞஺⏚SbCI,l£MsbII1ᩚṃITf⏚?IIIA1z2&জ|}~l⌕oHC1SbC13,noSbC15ஹC11CI2ஹAsC13PbC12_ᩖ#஺ঝ25࠷K(CuS)=1.0X10-36,Ksp(PbS)=9.0X1029,sp)fᑡ⚪&(1)“⏚|”yuSbC15Sb2s3Rᱥuᨵ5T⁐\ᓫ#ᑣḄᓄy3sbe15+Sb2s3=3S+5sbe130(2)IḄᡂᑖSSiO2(ᓄ)஺(3)|}~uᐭ〉$SbḄḄSbC15npSbC13஺(4)2ᙠஹ¡¢£~uc(Cu2+)=0.008mol«L',c(Pb2+)=0.065mohLஹ¡yu¤᠒¦§Ḅ¨ᓄ©£~ᐜRḄCuS஺(ᓄ

13)«£~uc(Pb2+)=4.5X10-4mol.L'H't,£~uc(Cu2+)=5X10-12mol•L-*1«(5)“◀Ạ”yuᵨᑮḄNaH2P02£~ᕈËÌឋÎgNaOH£~ᑏ}NaHPO22£~uß7õöᵫᜧᑮIḄøùc(Na+)>c(H2PO/)>c(OHN>c(H+)஺(6)ᙠ“ᵯ(”yuiúឋᩞᧇᵯ᩽□᩽Ḅᵯ᩽2Cá-2e=C12t஺ூ()௃(&(1)“⏚|”yuSbC15Sb2s3ᡂ5T⁐\ᓫ#ᓽ¨ᓫ#᪷:p7;ឤýḄy&3sbe15+Sb2s3=3S+5sbe13,ᦑ)ᫀ&3sbe15+Sb2s3=3S+5sbe130(2)ᡂḄ¨ᓫ#SiOᙳg£Q⏚ᡠiIḄᡂᑖSSiO2,2ᦑᫀSSiO2(3)ᐭ〉SbḄḄḄSbCl5"#SbC13,ᓄ&'()3sbe15+2Sb=5SbC13,ᦑᫀSbC15"#SbC13:(4)0Ksp(CuS)=1.0X1036c(H2PO2)>c(OH)>c(H+),ᦑ)ᫀ&c(Na+)>c(H2PO2')>c(OH-)>c(H+)0(6)᪷:⚪×2□᩽Þß7ᜫàᵯ7ᡂÞ"ᵯ᩽&2Cá-2e'=C12t,ᦑ)ᫀ&2C1--2e=C12t»9.zD⏚5TDᐗË⏚åæç⁐èᨔ\ê£QëÙ᧕£QíÙî⏣஺ðñòióz⏣()pᧇᑴôzD⏚HOOC(CHJ4coOHḄðñxy᝞஺

14r-^4MnOjr...Irlvt6,RXmin᣸T1ᔠUV.WᘤYZ[\জ“_ᓄ”(ᙠ(᝞c1ᡠd)e⚠ghijFkEḄl⌕no:OH—KOOCXCHz'COOK^H<0ঝqrstuFvᐵᱥyᙠzḄH{t|uᑡ~⚪ᱥy[⏚ᓄᓄ25࠷NH{t/g2.136.134.370࠷NH{t/g6837.848100࠷NH{t/g16039.556.3(1)c1ᓾz(“a”ᡈ"b”)ᐭ஺212/min3理ᐢ//min203040c2N/minqr[⏣uFHstNᓄ᝞c2,o⌱Ḅ[⏣5/min,⌱Ḅᳮᵫ_ᓄ(oᙠV50࠷stuijFFno¡ᘤᑁstᓣ¤F¥¦no஺(3)(§T1¨©(“¨©”ᡈ“ᓾ”)ª«¬Fª«¬Ḅ®¬tF¬Ḅ¯°¡᧕²³஺(´"®ᓽ¶)(4)(ᨬ¸´¹º»BCḄ'¼(½¾)஺A.ᵨÀ⏣º»B.ᵨ©zº»C.ᵨzº»(5)◀Â[⏚ᨔ°ÄᨵḄᓄᩖyÇÈḄÉÊ'¼ËÌᨔ஺(6)ÍÈ[⏚(M=146g/mol)᪵Ï0.2920g,ᵨÐÑÒḄ50.00mL©zH{Fᐭ2Ó⏙ÕTᢣdᑺFᵨ0.1500mo]I/iNaOHHØÙÚ®FijÛjÉÊÜÝÞÉ

15ʸFßὑNaOHḄÛᙳ°â20.00mL,ãä[⏚᪵ÏḄåt஺æç\[⏚èHᕈê⏚ឋìজØÚ®Ḅíîᐭᨬ¸--NaOHHFHᵫï⁐ñò⁐Fóôᑖõᑁqö⁐஺ঝ[⏚᪵ÏḄåt75%஺ூ{௃{ᵫc¶\FᓾzḄuùiᐭFᓽbᐭFa□Fᦑᫀ:bæ2
_ᓄ(oᙠV50࠷stuijFûnoü©noFᵫc¶\FFno¡ᘤᑁstᓣ¤,¥¦no,ýþstḄÿឋ50࠷,ᨬᵨ5/min,ᦑᫀ5ᓄᙠ50C!"ᘤᑁᓣ&'(!3
)*+1,ᑮMnO2.ᓄ/◀1ᩖ3■567⏚9᪆;*+1<=>?@>ḄBCD>>;ḄEF"᧕HIJᦑᫀ<=>>;ḄEF"᧕HI4
67⏚KLMN᧕L=N.O⏣ᑣᵨMNRSTUᦑCVᔠ⚪YA.BZ[\67⏚L]^ᜫᦑᫀC5
᪷a67⏚.bᓄcḄL]dḄeᓄfg◀167⏚ᨔFijᨵḄbᓄcᩖ3lḄmnopqrᨔᦑᫀqrᨔ6
জtuᵨvKL/+ᢣxᑺv⏦e⁐ḄpH}8~10,ᦑCḄᐭᨬNaOHL/L/ᵫ⁐e⁐ᑖᑁ⁐ᦑᫀL/ᵫ⁐e⁐ᑖᑁ⁐ঝᵫ67⏚cL/ᕈ⏚ឋuᵨv+ᢣxᑺ1mol67⏚jᨵ2moifὑ2moiNaOH,ᑣn67⏚=nNaOH
=Ax0.1500moPL_1X0.02L=1.522XlO^mol,ᑣ67⏚᪵ḄL5X1°molX*100%=75%,0.2920gᦑᫀ75%«10.¡D¢q⌕Ḅᓄ¤¥ᧇ஺

16I.ªg298KஹlOlkPaᔠᡂ!Ḅ¶·eᓄ᝞¹1ᡠx(ad⊤x¿Àᓄᑺᔾ▬,!ᔊiÄÅᙳ¡᝱)஺(1)ÉᩩËN2(g)+3H2(g)U2NH3(g)AH=-92kJ/mol..(2)!ᔊiØᔠᡂ!᳛ḄÚ!Ḅ=ᓄÛoÜNad(g)+3Had(g)=NHad(g)+2Had(g)ÝH=+106kJ/mol஺(3)ᦋeᑡâᩩËã¶äᔠᡂ!᳛å¶æ&ç¡Ḅè⊝êᓄ᳛ḄD(ëìí)஺A.ᓣ&B.ïᜧ@ñC.ïäN2Ḅ·D.ôõᑖö¡II.¡+÷¥ᑺf◀1ø¡iḄçᓄᱥ஺ᐸi◀1NOḄ!¥ᳮ᝞4NH3(g)+6NO(g)=5N2(g)+6H2O(g)AH=-1980kJ/mol«(4)!᳛ÿ
ᙠ᝞ᐵ=1<©4(NH3)*C6(NO),v⌮=1;⌮©5(N2)•C6(HO)»kak⌮&'᳛)ᦪ+,-.
/0஺350࠷4+ᙠ2Lឤ7897ᘤ;+<2ᐭ0.9molNH(g)D1.2molNO(g)EFGH+Iᢝ.
KL+M⊝4NOḄPᓄ᳛3kx&50%,ᑣU.
V=0.25WX.
ᓣZ4+k[ᜧm]+k⌮[ᜧn]+ᑣmk⌮P2>P3yz{GH&|}ᑖᦪ[ᜧḄGH+lM⊝⌮+NOPᓄ᳛u.

17手率5^100尔80£X'百60*40。之20•ஹ/jj_0~~_1~MXJ1MO(TL5IO.N(+2!"+C3«(NH)X(6)Iᢝ.
KL+ᙠឤ7897ᘤ;ᢥhiᐙᐭNH3(g)DNO(g)EFGH+ᑮM⊝4H2O(g)Ḅ}ᑖᦪজ(H2O)f(N0)ḄLᓄ᝞n3ᡠp,Xh/NO)n(NH)n(NH)33-24+ᑮM⊝4(p(H2O){AஹBஹC;ḄCo(_“A”ஹ"B”ᡈ"C”)ூ௃1.(1)ᵫᔠᡂgLᓄnᔠᡂlmolNH3(g)¡¢46kJg+ᑣ¤ᩩ¦,N2(g)+3H2(g)=2NH3(g)Z\H=-2X46kJ/mol=-92kJ/moLᦑᫀ&-92kJ/molW(2)®ᩩ¦+¯ᓄ°ᜧ+GH'᳛°᠒+²iGH'᳛Ḅh³&GH'᳛ᨬ᠒Ḅh³+ᓽ¯ᓄᨬᜧḄh³+zUGHᔊ·;²iᔠᡂGH'᳛Ḅh³GHḄ¸ᓄ¹º·»&Nad(g)+3Had(g)=NHad(g)+2Had(g)½H=+106kJ/mol,ᦑᫀ&Nad(g)+3Had(g)=NHad(g)+2Had(g)½H=+106kJ/molW(3)A.ᵫ(1)ᔠᡂGH&¡¸GH+ᓣZ.
+GH'᳛[ᜧ+¾M⊝⌮ᔣÀ+Á|ḄM⊝Pᓄ᳛ÂÃ+ᦑA┯ÅWB.[ᜧlm+GH'᳛[ᜧ+ᔠᡂM⊝ᔣÀ+Á|ḄM⊝Pᓄ᳛[ᜧ+ᦑBÆWC.[N2Ḅg+N2Ḅ
[ᜧ+GH'᳛[ᜧ+¾N2ḄM⊝Pᓄ᳛ÂÃ+ᦑC┯Å;D.È4ᑖÉ|M⊝ᔣÀ+Á|ḄM⊝Pᓄ᳛[ᜧ+ÁGHᱥ
u+GH'᳛u+ᦑD┯ÅWᦑᫀ&BII.(4)ÌÍλ4NH3(g)+6NO(g)=5N2(g)+6H2O(g)Ïd(mol/L)0.450.600Lᓄ(mol/L)0.20.30.250.3M⊝(mol/L)0.250.30.250.3

18M⊝4+ViE=v⌮+ᓽkiEC4(NH3)-C6(NO)=k⌮(N2)*c6(H2O),ᑣᓰᓛ=k⌮(No)X(HoO)n9r5nn6------2---------2_=0.25XQ.3=025W.
ᓣZ+M⊝4NH3(g)+6NO(g)C4(NH)X6(N0)0.254X0.363C5N2(g)+6H2O(g)⌮ᔣÀ+ÖM⊝×vP2>P3,ᦑᫀ&P1>P2>P3;GH&|}ᑖᦪ[ᜧḄGH+lM⊝⌮+NOPᓄ᳛uW(6)ᐸàᩩ¦KL+n(N0)[ᜧ,áÜn(NH3)KL+n(NO)[ᜧ+M⊝ᔣn(NH)3À+M⊝4};nâ[ᜧ+n(H2O)[ᜧ+¾᪷äåæᱯᑡyᳮn(H2O)[ᜧê
uÜ[ᜧê
+zUë(H2O)u+&n;C+ᦑᫀ&C«ஹூᓄ¹-⌱î3ᱥÛï᪀jឋÛ௃11.ᓴóᐗõ{ö⌕Ḅøùúᐗõ+ᵨ⌶ýþ஺ÿ
ᑡ⚪(1)
ᑡᔠᓴᐗᐸᓄᔠᱥḄឋ᪶ᵯ₹ᦪḄᓄ!Ḅ"a஺(2)'᝱)*+,-ᨵᓫᵯ+Ḅ0⍝234562஺(3)8ᐗ9:Ḅ-;⏚HBrO4⏚ឋBHBrO3⏚ឋC(D“C”ᡈ“H”)I*J"HBrCU,MN';OI⏚ឋC஺(4)ᓄᔠᱥI3ASF64U+ᓄᔠᱥIᐸ,□U+(13+),X*+ḄᩖᓄZ[4sp3ᩖᓄ஺^ᨔ`,a-ᨵḄᓄbcde4(D⌱⚗hi)஺

19a.klcb.nocc.᩽ឋcd.M᩽ឋcs5uᵫwஹ;ஹỚzᐗ᪀ᡂḄᨔ`ᨔ}~᪀᝞1ᡠ஺ᑣ^ᨔ`Ḅᓄb[4KIO3,ᨔ},lK+Ḅ0Ḅᦪ412os6uᨵ“◍”ḄNaClᨔ`ᵯIᐸ~᪀᝞2ᡠ஺ᨵ4
ᨵ“◍”ḄNaClᨔ`ᵯI"J4Na+ᵫ3CᡂḄᨬz2¡¢s᝞3ᡠuI£¤ᑮ¦§l¨⌼ᡂḄ஺ª«¬Z`®a=282pm,²+³´rsNa.u=115pm,rsO'u=167pm,·¸ᑁᑗᙊ³´rᑁḄ¼½ᑨ¿^À"ᔲ!ᑁÂ-65pmVI15pm,^À"┯ÆḄ஺sÇ«᝞p1.4,ÈÉ1.7uூË௃Ëslua.ᓴᐗᐗMnoឋÍCᐸᵯÎឋÍᜧIᓴᐗMnoឋḼ*+ÑᦪÒᜧ¨ÒᜧIᡠÓᵯÎឋḼ*+ÑᦪÒᜧ¨ÒᜧIᦑa!Õb.ᓴᐗÖᓄᱥ×Ḽ*+ÑᦪÒᜧ¨ÒᜧIØ-ᨵÖcḄᓴᓄÖ×ᨬIHF,ÙᙠÖcIᡠÓ×ᨬIᦑb┯Æc.ᓴᐗᓫḄᰚḼ*+ÑᦪÒᜧ¨ÒᜧIᦑc┯ÆÕᦑᫀ4aÕs2uÝ*+᪶᜜ᵯ+Ḅ᣸à[4Is22s2P5,ᐸ,-ᨵᓫᵯ+Ḅ0⍝42P0⍝Iᐸ234562Iᦑᫀ4562Õs3u8ᐗ9:Ḅ-;⏚HBrO4âHBrO3Ḅã[4sOHumBrOn,åὅ4sOHuBrO3,çὅ4sOHuBrO2,n¼ÍᜧI⏚ឋÍCIᡠÓHBrO4⏚ឋBHBrO3⏚ឋCIᦑᫀ4CÕHBrO4,MN';OI⏚ឋCÕs4u13+,XI*+Ḅ஺cᦪ42,èᵯ+9ᦪ42,ᑣéêᵯ+9ᦪ42+2=4,ᡠÓ,XI*+ḄᩖᓄZ[4sp3ᩖᓄI^ᓄᔠᱥ4U+ᓄᔠᱥI-ᨵU+cI□U+,-ᨵ

20I-IM᩽ឋᐳécI▢U+4klU+I-ᨵklcIíoî᩽ឋcIa-nocIᡠÓbᔠ⚪ïIᦑᫀ4Sp3ᩖᓄÕb;(5)ᵫ1«Iᨔ},-ᨵK+Ḅᦪ48XA=1,-ᨵ஺*+Ḅᦪ46x2=823,-ᨵI*+Ḅᦪ4I,ᡠÓ^ᨔ`Ḅᓄb[4KI03,,ñK+Ḅ஺Ḅᦪ43,᪷óᙳõ*ᑣI⚔K+÷8ᨔ}ᐳᨵIᡠÓK+Ḅ஺Ḅᦪ48X3øù=12,2ᦑᫀ4KI03;12Õ(6)^z2¡¢4úz2ID(CL-CL)=(2)2+(ᒹ)2=Js282u2τs282u2Pm=197.4pm,[rCu+rg
]cos30°=ADsC1-Cl
HP[167pm+rsᑁýxY^=197.4pm,Ëþrsᑁÿ65Pm<115pm,
NaClᨔᵯᵫNa*2ᑮ⌼ᡂḄᔠNaClᨔ᪀Ḅ┯!Ḅ,ᦑ$ᫀ&'r(«)^65pm<115pm,)┯!Ḅ஺+ஹூᓄ/-⌱253ᨵ5ᓄ/6Ạ௃12.9:ᱥ<=(H)Ḅᔠᡂ@A᝞஺OOCCHjCXX'CH,ZCOOHCH,COOHCl?/ᐝ᯿pNaOHH
AH2,CஹCOOH:C,HQC.HQᓄᑺঝH.DCᖝஹ⃎⏚CHCI,BC╨/H,CH,CTbCOOCHjCHCHCOOCH,“22IUC-CHCHCl:CHQH#$⏚GOCH^CH,OilH'জJKLMNOPQR6STUVW᝞XY'OHIR-CHOH--R—CHO+H2OঝR—CHO+Rτ—CFbCHOHZᗚ'☩^R—CH-CH—R1+H2O+CO2t_$ᑡa⚪'(1)AḄᓄ/cd&eᵬ6ghᡈ4-ᵬ6ghH<ᡠklmḄcd&noஹp6஺

21(2)DḄ᪀qr&,G-HḄXYst&uvXY஺(3)E-FḄᓄ/XYwxr&H0-<^>-CH=CHCOOH+Hyz╋2cH2co0H1--°(4)XGḄJᑖ}᪀ᑏᑡᩩḄXḄ᪀qrCH,CH,CHCOOHIIO—CHCOOH22CILஹCH,(ᑏ9ᓽ)oজK⏚XYWᡂᓄK3ঝFeC13VW⁐XY3ঞgNḄuv6S+QgNḄvᱥᨵ9஺CH,CT!Cl:(5)᯿Nᔠᡂ@AᵫCH3COOHᑴᜓḄᔠᡂ@A_CH,CHCl;0NQ-CH2CH0CH3coOH-CH-CH=CH¡ᓄᑺ22"------------A'-=-------------------7ᖅஹg¤*஺(¦5§ᑺ¨⌱)ூ©$௃©'(1)AḄᓄ/cd&eᵬ6ghᡈ4-ᵬ6ghH<ᡠklmḄcd&⏚oஹp6ᦑ$ᫀ&'eᵬ6ghᡈ4-ᵬ6gh3noஹp63(2)DḄ᪀qr&H°ߟd-CH°,G-HḄXYst&uvXYᦑ$ᫀ&';uvXY3,ஹHO-<^r-^-CH=CHCOOH«HO-CH2cH2coOH(3)EḄ᪀qr&J/F&J/z,,E®VWᡂXYWᡂF,E-FḄᓄ/XYwxr&

22HO-^^-CH=CHCOOH+Hyz╋HO-^^-CH2cH2C00H2-A-*…gHO-eX>-CH=CHCOOH„yzmHO-¯'ு-CH2cH2co0Hᦑ$ᫀ&'\=/+H,ᵪᔈ´.A(4)XGḄJᑖ}᪀X¶ᔠᑡᩩ'জK⏚XYWᡂᓄK·¸kᨵ-COOH3ঝFeC13VW⁐XY·¸kᨵhR63ঞgNḄuv6S+QgNḄvᱥᨵ9,·¸gNᨵ9LMCH,CH,1JHO--CHCOOHHO஽2/CHCOOH2¶ᔠᩩḄ᪀qrᨵCH,ஹCH,CHjCH,1-^O^-CHCOOH2HO-CHCOOHHO2ᦑ$ᫀ&'CH,ஹCH,.(fH—CHᔢ+fH—CHᔢCILCHChᓰ(5ᓰᑴᜓ^^,Vᵫ(5)ᵫCH3C00HClhCHCU▬-CH=CH2VW½XY¾ᑮoVW©XYWᡂg¿ng¿È-CH2-CH=CH2,ᐸᔠᡂ@A&n¿⏚VWÀÁঝḄXYWᡂ-CH2-CH=CH2¡ᓄᑺ3AZÊஹg¤’ᓝÄÅᔢCHஹᦑ$ᫀ&

23CIUCHCh^>-CHCHOCH,COOH^>-CH-CH=CH$ᓄᑺN4)H#222'():+,'A(fH-CHᔢ