Chapter 29-Recent Advances in the Hydrosilylation and Related Reactions (p 1687-1792)

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1、TheChemistryofOrganicSiliconCompounds.Volume2EditedbyZviRappoportandYitzhakApeloigCopyright¶1998JohnWiley&Sons,Ltd.ISBN:0-471-96757-2CHAPTER29RecentadvancesinthehydrosilylationandrelatedreactionsIWAOOJIMA,ZHAOYANGLIandJIAWANGZHUDepartmentofChemistry,StateUniversityofNewYorkatStonyBrook

2、,StonyBrook,NewYork11794-3400,USAI.INTRODUCTION....................................1688II.HYDROSILYLATIONOFALKENES......................1688A.SimpleandFunctionalizedAlkenes......................16881.ByGroupVIIItransitionmetalcatalysts.................16882.Bymetallicandcolloidalmetalc

3、atalysts.................16933.ByGroupIVmetallocenes,lanthanidesandothermetalcatalysts......................................16974.Byimmobilizedcatalysts...........................17015.Byradicalinitiators..............................1703B.MechanismoftheAlkeneHydrosilylation...........

4、.......1704C.IntramolecularHydrosilylationofAlkenes..................1710D.OtherReactionsAssociatedwithAlkeneHydrosilylation........1714III.HYDROSILYLATIONOFALKYNES......................1716A.SimpleAlkynes...................................17171.Byplatinumcatalysts.....................

5、........17172.Byrhodiumcatalysts..............................17183.Byiridium,ruthenium,osmiumandothercatalysts..........17204.Byradicalinitiators..............................1722B.MechanismoftheStereoselectiveHydrosilylationof1-Alkynes....1723C.IntramolecularHydrosilylationofAlkynes.

6、.................1725D.Bis-TMS-ethyneandBis-TMS-butadiyne..................1725E.FunctionalizedAlkynes..............................1727F.OtherReactionsAssociatedwithAlkyneHydrosilylation........1732IV.HYDROSILYLATIONOFCARBONYLANDRELATEDCOMPOUNDS......................................17

7、33V.ASYMMETRICHYDROSILYLATION......................174316871688IwaoOjima,ZhaoyangLiandJiawangZhuA.OfProchiralKetones,IminesandImineN-Oxides............1743B.OfAlkenesand1,3-Dienes............................1752C.IntramolecularReactions.............................1756VI.SYNTHESESOFS