Chapter 17-Recent Advances in the Chemistry of Silicon-Heteroatom Multiple Bonds (p 1063-1103)外文

《Chapter 17-Recent Advances in the Chemistry of Silicon-Heteroatom Multiple Bonds (p 1063-1103)外文》由会员上传分享，免费在线阅读，更多相关内容在学术论文-天天文库。

1、TheChemistryofOrganicSiliconCompounds.Volume2EditedbyZviRappoportandYitzhakApeloigCopyright¶1998JohnWiley&Sons,Ltd.ISBN:0-471-96757-2CHAPTER17RecentadvancesinthechemistryofsiliconheteroatommultiplebondsNORIHIROTOKITOHandRENJIOKAZAKIDepartmentofChemistry,GraduateSchoolofScien

2、ce,TheUniversityofTokyo,7-3-1Hongo,Bunkyo-ku,Tokyo113,JapanFax:C81-3-5800-6899I.INTRODUCTION....................................1064A.MultipleBondstoSilicon............................1064B.TheoreticalCalculations..............................10651.Silanonesandsilanethiones.

3、........................10652.Otherdoublebondstosilicon........................10673.Miscellaneous..................................1067II.DOUBLEBONDSBETWEENSILICONANDGROUP16ELEMENTS........................................1068A.Introduction...................................

4、...1068B.SiliconOxygenDoubleBonds(Silanones).................10681.Formationfromhydrosilanes........................10682.Formationfromcyclicsilylethers.....................10693.Formationfromallyloxysilanederivatives................10714.Formationfromsilanolderivatives.....

5、................10745.Formationfromsilylenes...........................10756.Formationfromsilenesandsiliconheteroatomdouble-bondcompounds.....................................1080C.SiliconSulfurDoubleBonds(Silanethiones)................10831.Formationfromhydrosilanes.........

6、................10842.Formationfromdiaminosilanes........................10863.Formationfromsilylenes............................10864.Formationfromsilicon-containingcyclicpolysulfides.........10905.Formationfromadisilene...........................10946.Formationfromthioketen

7、es..........................10957.MatrixisolationofSiS2,Cl(H)SiDSandCl2SiDS..........109610631064NorihiroTokitohandRenjiOkazakiD.SiliconSeleniumandSiliconTelluriumDoubleBonds(SilaneselonesandSilanetellones).................................10971.Transientsilaneselones........

8、.....................10972.Silaneselonederivedfromsilicocene...............