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1、PhysicalChemistryThirdEditionPhysicalChemistryThirdEditionRobertG.MortimerProfessorEmeritusRhodesCollegeMemphis,TennesseeAMSTERDAM•BOSTON•HEIDELBERG•LONDONNEWYORK•OXFORD•PARIS•SANDIEGOSANFRANCISCO•SINGAPORE•SYDNEY•TOKYOAcademicPressisanimprintofElsevierCoverDesign:EricDeCiccoCover
2、Image:©iStockphotoElsevierAcademicPress30CorporateDrive,Suite400,Burlington,MA01803,USA525BStreet,Suite1900,SanDiego,CA92101-4495,USA84Theobald’sRoad,LondonWC1X8RR,UKThisbookisprintedonacid-freepaper.∞Copyright©2008,ElsevierInc.Allrightsreserved.Nopartofthispublicationmaybereprod
3、ucedortransmittedinanyformorbyanymeans,electronicormechanical,includingphotocopy,recording,oranyinformationstorageandretrievalsystem,withoutpermissioninwritingfromthepublisher.PermissionsmaybesoughtdirectlyfromElsevier’sScience&TechnologyRightsDepartmentinOxford,UK:phone:(+44)1865
4、843830,fax:(+44)1865853333,E-mail:permissions@elsevier.co.uk.Youmayalsocompleteyourrequeston-lineviatheElsevierhomepage(http://elsevier.com),byselecting“CustomerSupport”andthen“ObtainingPermissions.”LibraryofCongressCatalog-in-PublishingDataMortimer,RobertG.Physicalchemistry/Rober
5、tG.Mortimer.–3rded.p.cm.Includesbibliographicalreferencesandindex.ISBN978-0-12-370617-1(hardcover:alk.paper)1.Chemistry,Physicalandtheoretical.I.Title.QD453.2.M672008541–dc222008007675BritishLibraryCataloguinginPublicationDataAcataloguerecordforthisbookisavailablefromtheBritishLib
6、raryISBN-13:978-0-12-370617-1ForinformationonallElsevierAcademicPresspublicationsvisitourWebsiteatwww.books.elsevier.comPrintedinCanada080910987654321Tomywife,Ann,andtomylatefather,WilliamE.Mortimer,whowasresponsibleformytakingmyfirstchemistrycourseContentsPeriodicTableInsidefrontc
7、overListofNumericalTablesinAppendixAInsidefrontcoverInformationTablesInsidebackcoverPrefacexvAcknowledgmentsxviiPart1ThermodynamicsandtheMacroscopicDescriptionofPhysicalSystems1Chapter1TheBehaviorofGasesandLiquids31.1Introduction41.2SystemsandStatesinPhysicalChemistry121.3RealGase
8、s211.4TheCoexistenceofPhasesandth
