湖南省益阳市2022-2023学年高三上学期9月质量检测化学试卷及答案

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0.50molI7'»Fᢝ67HI:ᘤḄ:J᡽ᜧᑮ.ᩭḄOPQRA⊝/CDAḄE7

20.30molU'oᑡᨵᐵᑨVWXḄA.x+yA.ᵯ/ᵯ᩽a
ᵯdḄW᩽ᐙᵯ/ᵯ᩽b□᩽B.ᵯ/᩽v
>LiC-xe=xLi++CxyyC.ᵯdᵯ/
>LiC+LiCoO=LiCoO+Cxylx22yD.ᵯᐙᵯ/┞c#ᵯdḄW᩽᩽ᡂᓄnᵯnḄ¡0ᓄ10.┡᮱¤"ḄCaSOyᐜᵨNa2c0?)*¦§Qᵨ¨©⏚ᡈ«⏚ᜐᳮ஺®>25࠷/4Ke
CaSO=9.2x10^,%
CaCO>=2.8xI
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.ᧇ=êðñ$òóô⌕öᵨḄ÷¶$⏣ᒹúíûü>ý4ü>CH=CH+C1+HO——>C1CHCHOH+HC12222220ýOü>2cleH2cH?OH+Ca(OH),——>2/\+CaCl,+2H,OHC-CH22O⊤CH-CH+Cl+Ca(OH),——>/\+CaCl+HO22222H2c-CH2Oᓄᵨ"#$ᓄᑺ&'()*+ᡂ2CH=CH,+O^->2/\,/ᑡ22H2c—CH2ᨵᐵ345┯7Ḅ9A.)<=>ᑖ@5Aᨵ5<"DE1<ᐔDB.CICH^CH/JHKᐭAgNOsPQ5RST⁐VWC.X=⏣4ḄZ@ᑭᵨ᳛25.4%,"$ᓄ4ḄZ@ᑭᵨ᳛100%D.AgḄ#ᵨ9abḄcᓄd&eᜧcᓄᑖ@Ḅgᑖᦪ&ijk᳛12./ᑡlᓄḄm@nop⊤qrḄ9A.ᵨH—2s⏚ᓄḄuvᮞxyQ5z{Ớ2f+HO=I+2OH222B.ᔣPQ5ᐭCO?CHO+HO+CO—>CHOH+HCO652265C.ᵨᔾᦈ5ḄSO?2NH.HO+SO=2NH+SO"+HO3222D.ᵨFeCL,PQῖ⇨⌚ᑴ#ᓺᑵᵯCu+Fe-=Cu2++Fe2+13.ẆCHiI¢X£ᵫ¥¦ᵨC1*⊤¨Ḅᨵ©ª«¬®¯஺±²CH.J¢C1*ᨵ4ᩩd

4Ḅ´&᝞¶ᡠ஺¶5TS⊤¹᝱&IM⊤5¼½஺/ᑡ345┯7Ḅ9TS1218.01200120//TS4\\I/128.69\\100//\\CHICI-+H*(2O80//°\''3´জUV240//.34.893%0/ÃᵨC1´ঝ)细、I--------ஹஹஹ\40.47混20‘᜛Ç57TÈÉQ´ঞ0\8.730.00\CHjC1+I´ট-80-80.22ᔊoA.ÏÐᩩÑ/&´জḄk᳛ᨬ᠒B.´টÔªÕÖC.´ঝ©Ø1+<21&=€!11+©9¥ᐗD.¹᝱5ᨬÝÞḄ9TS1,RᱥᨬÝÞḄ9´টḄ14.àáâᩞᧇÔªm@ᨔ½&ᐸᨔçè᪀᝞¶ᡠ஺/ᑡ34qrḄ9A.êáâᩞᧇḄᨬëᓄìpKNi^zB.NiïªᐗðᕜÇ⊤5ḄdsóC.ᨔç5SḄôïᦪ444?D.õêᨔ½Ḅö÷dg-cm-3,ᑣúûüýþÿᦪN=Aஹ⚪

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-+H2O⏚JKᵨᑮḄᨵᐵᦪM᝞G⊤:ᱥPQᑖSPTUV/(g/crrP)WX/࠷[\ឋ⏚1121.204228᧕\⏣460.78978᧕\⏚1400.926195`\abc840.78080.7`\defᙠ⚠ijklᐭ5.6g⏚ஹnT⏣ஹo[ᑺapcஹqTIᓄᑺrstWuvwlx⚠ij67yVz110࠷,{|4}~lxrᤅ67ᓾyIᓄᑺrWu᎔ᐭᑖᧅkᐜᵨ5%NaHCO3\kឋᵨ[ᑖᙠᨵklᐭqT[MgSOa,☟<ᱏᦈ195࠷Ḅᑖᑮ¡¢Ḅ⏚4.7g஺{£Gᑡ¥⚪f(1)DᘤaḄ¦§¨஺Dᘤb©cQªᙠ«k¬Ḅ®X¨஺(2)67k¯Kᵨ[w°±vwlxḄ²³¨஺বஹᑖ9klᐭ5%NaHCCh\ḄµḄ¨o(4)ᙠᨵklᐭqT[MgSOḄµḄ¨¶SO=Ḅ·¸¹᪀z»஺4(5)ᙠ«k⏚Ḅ¼᳛¨(¾¿0.1%)஺Áஹ²ᳮÃᔠ⚪16.ÄÅᩭᡃÈᙠ7É᎛ËᓄÌkÍÎ℉ᡂᦔÑᔣÈ▭ÔÕÖ×2030Åᜮ“ÚÛÜ”,2060Å“Úkr”஺³ßCO2àᓄzá▬lãᓄä$ᡂzåä*ẆçḄè⌕ê⚪஺

6ÌëìᙠCu-ZnOIᓄGᑭᵨCO?îï᝞G67iᩭï¼ᵬ⏣ñ~òᨵ67iiîï஺67ifCO(g)+3H(g)^CHOH(g)+HO(g)AH1=-50.0kJmoó223267iifCO(g)+H(g)^CO(g)+HO(g)AH,=+41.1kJ-mor'222প67CO(g)+2H,(g)BCHQH(g)ḄAH=kJ.r'஺mo(2)ឤyGCO?rH?ᙠឤöU÷öᘤîï67iஹii,GᑡK⊤øìù67bÛᑮú⊝ü᝱Ḅᨵ(þ᪗)஺A.ImolH-HᡂImolO-Hn(CHQH)_]B.n(CO)2C.ᔠḄᙳᑖD.ᔠḄ(3)ᩩᢥ᯿n(CO2)"n(Hj=l:3ᢗᧇCO?Ḅ⊝'ᓄ᳛᝞+ᡠ-஺জPHP2,P3ᵫᜧᑮ2Ḅ345஺6Pi789:570࠷<=>Ḽ78ᓣ9CO?⊝'ᓄ᳛AᜧḄBC5஺ঝ+EFM(500,60),GP60.2MPa,CHQHḄ⌱Iឋ6|(⌱Iឋ"ᡂCHQHᡠMὑḄCO2ᓰᐰQ'ᓄḄCO2ḄR)஺ᑣT78UViḄ⊝WᦪKp=(MPaY(ᑖ=[xᱥḄᑖᦪ)஺II.ᵯᓄ_`aBbcᓄdᑴfg(4)ᙠ⏚ឋjkElᐭbcᓄdᵨoឋᵯ᩽qrᵯstᑴufgᐸBᳮ᝞+ᡠ-▢᩽ᵯ᩽UVy6Tz{E|ᵨḄ5(}“▢"ᡈ"□")ᣚ஺

7ஹ⚪17.ᦈᧇᨵᦔsஹ᛻¡¢⚪஺£¤¥¦§ᓄᑺᧇ(©⌕¦CoஹFe,a¦ᨵ°ḄCoOஹFeOஹFeQ,ஹCaOஹSi஺?)ᑴᜓcᓄ(CO2O3)Ḅº᝞+ᡠ-:জNaClOjk@Na2CO3Na2CO3(NH4)2C2O4Coo23ÁÂ"i.ÃÄᐹᨵÆḄᓄ_ឋÇii.cᓄឋCo">C1CT஺Êᑡ¢⚪"প⏚Í=“ÎÏ”Ḅ©⌕ᡂᑖᨵÑ(}ᓄ_y)஺(2)“◀Ä”ᐜÔᐭNaClOjk©⌕UVḄÕy6,ÖÔᐭNa2c0,jkÙ⁚pH62.5~3.0,ᡂÞßÄàáâ஺(3)ã᝱BḄᵯ᣸æy6஺(4)(NH)CaENBḄᩖᓄè⍝êë6஺(NHjCzOM◀ïᐗñ᜜ᐸóᐗñḄô£ᵯᵫᜧᑮ2Ḅ346»(5)ᡠuC஺஺tᵨ:ᔠᡂö⏚஺£¤ö⏚Ḅᨔøù᪀᝞+ᡠ-TûÕᨔøüᦪ6apm,þC஺ᕜ
ḄOᐳᨵ஺NAᦪḄ⏚ᨔḄg•cm"(ᑡ'()*)஺

8,ஹᨵ./0⚪18.ᵨ6ᑴ⌼◚:;<Ḅ=>?ᑖAᩞᧇFḄᔠᡂGH᝞J:ᐸMDḄOPQH2ḄTQ43,ᑖAMCஹHஹ஺ḄYAᦪZ2[3[1,D᪶]ᐳ^_`ᨵ3abḄc⛳ef⏚஺(1)AḄhi,DḄj᪀l*.(2)EMnop>qḄhio(3)A-BḄuvwx஺(4)ᑏ'E-FuvḄᓄ{|}*______o(5)DḄᑖ᪀MᔠJᑡᩩḄᨵ஺i.>uv>Ḅᓄ⁐஺(6)[MḄc⛳eHCNᡂuvᡂn(-CN)Ḅᱥ¡¢£ᡂf⏚஺¤?ᑖAᓄᔠᱥMḄj᪀l*᝞¦ᡠ¨©ᑏ'ᵨAe2-ªᯋYᧇᑴᜓ?ᑖAᓄᔠᱥMḄᓫ®ḄᔠᡂGH(¯.°ᑺ²⌱)஺CHCH33-fCH-C^COOCHCH23M

9

10¶ὃ¸ᫀ[1.Cூ»௃A.“¾ᘤÀ6ÁÂMᓽᡂÄ⁐Å“ḄƾÇ⏚ÄḄÈᣚuvAcᔠ⚪ÊB.jᨔËÌÍÎÏ6?ᑖAᓄᔠᱥᔠᡂjᨔËÌÍÎḄÆÐÑuvBcᔠ⚪ÒC.ÓÔᓣÖᔾᦈÙÚᕜḄÜPÝÞßÜPMḄOP⍗áᓄ:ᡂ᝱ãᨵäᱥ¡ᡂÏ6ᱥᳮæᓄCᔠ⚪ÒD.çoè⏚Qé᛻ëìíîஹᩔð⊤òóoᓄឋᓄ{æᓄDcᔠ⚪Òᦑ⌱C஺2.Dூ»௃A.ö÷øùÎúᯠü⁚TþÑᔠcÅÿ
ᑖᡠᑖ᪀AB.◌Ḅ⌕ᧇ◤⌕ᵨ"ᮞ"BC.$%&'Ḅᘤ)*ấ⏚-.ᡠ)*/01234)ᩞᧇCD.ₐ789ᨵḄₐᓫ<=ᑖ>CI5HHO6?,9ᨵ@ᐗBḄᓄᔠᱥᡠ)*ᨵ2ᓄᔠᱥDᦑ⌱D஺3.BூJK௃A.CO28CMONOPᡂRSᐸU᪀>0=C=0,AB.V᪷XY⌕ZᵯḄᑖ\]^⊤`aᩭᦑcᓄ╄Ḅᵯ>᝞fᡠ`Hgᔣ[B┯j;.H]C.NH38ḄNlᵨsp3ᩖᓄVSEPRnop☢oᐸ89ᨵrsᵯC;3s3pD.t᝱vᨬ᜜yᨵ6zᵯᐸ{yᵯ|⍝⊤`>|rni|IAIAI-D;Iᦑᫀ⌱B஺4.CூJK௃A.*aA┯jB.᩽᧕*■᎔ᔾ᎔Ḅᧅ☢
B┯j

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¨ᐸÏᦪÐXᜧᑣZAlRஹYᑖ×±PᡂR+ஹY+,¨RḄÏᦪ*B,YḄÏᦪᙠBMA1NOᦑRLi,YNaWMBஹAIᑖ×᪀ᡂàá▢XãBW4å•MãAIWç,¨WḄÏᦪÐBᑣWHéÈᡠêWH,RLi,XB,YNa,ZAl,ᵬNaBH4,ìLiAlH4஺ூJK௃A.ᵫᑖ᪆îïWH,RLi,YNa,ðὅᙳó*ᐗBᕜõ⊤8IAöAB.ᵫᑖ᪆îïWH,ᵬNaBELi,ìLiAlM,àáᱥ8Hùú-1{BC.ᵫᑖ᪆îïYNa,ZAl,AlḄ34)ឋÐNaýᡠA1Ḅᵯþឋᜧ*Na,CD.ᵫᑖ᪆îïZA1,ᐸᨬÿ
ᓄᱥḄᓄᱥA1(OH)3,ឋ
ᓄᱥ⏚D┯!"ᦑ⌱D஺6.Aூ*+௃A.᪷./012ᙠ4জ67PdCkFஹH2?@PdஹHCkCF,A@ḄBCDE7PdC14G2-+H2-Pd+2HCl+2chAMN"B.᪷.PC127PdCLFᐜS?@Pd,ᡂUᦪWXYZᩭPd\]ᓄE7PdChOzFᡂUᦪW\_`B┯!"aᓄᑺC.c./01H202ᙠ7PdC14?dᵨf@ᡂH2O2,BCD2H+O2=^=HO2,i@ᡂ221molH2O2ḄPCl]mᵯopᦪE2mol,C┯!"D.᪷.PC127PdCL?ᐜH2?@Pd,PdᨬZ\]ᓄE7PdCLF7PdClF-ᐜrὑZ@ᡂtZḄuvwᡠ7PdCLPyḄaᓄᑺD┯!"ᦑᔠᳮ⌱⚗Ao7.Cூ*+௃A.3.6g2ḄᱥḄuE0mol,ᨵḄloḄᱥḄuEO.lmolxl0x2=2mol,ᦪWE2NA,AMN;

12B.22gḄᱥḄuE0.5mol,ᓫUᙳEUUlᨵ1U1ᐔUᑣᨵUᦪWE0.5X6NA=3NA,BMN"C.⏚᪷o+ᦪWXᦑILlmoLbḄNaHCC)3lᨵHCO"ḄᦪWNA,C┯!"D.hnolKMnO,¡¢EMn"¤]mḄᵯoᐵ¦EKMnO,~5¨~Mn",ᑣ]mᵯoᦪWE5NA,DMN"ᦑ⌱Co8.Dூᑖ᪆௃ᵫ⚪®¯°1±⊝¤³´AḄµ¶E0.50molூT,¸ᢝº¶vw»¼ᘤḄ¼¾᡽ᜧᑮ¢ᩭḄÂÃÄű⊝¤³´AḄµ¶E0.30moLU,ÇÈXÉʱ⊝⌮ᔣmÍ.Îᑖ᪆+⚪஺ூ*+௃A.ᵫᑖ᪆1XÉʱ⊝⌮ᔣmÍᦑ⌮EÏÐо_ᜧḄBᔣᓽx+y>z,A┯!"B.ᵫᑖ᪆1±⊝ᔣ⌮BᔣmÍB┯!"C.ᵫᑖ᪆1±⊝⌮ᔣmÍᦑBḄ]ᓄ᳛XC┯!"D.ᵫᑖ᪆1±⊝⌮ᔣmÍᦑCḄоᑖᦪXDMN"ᦑÕᫀE2D஺9.Aூᑖ᪆௃᪷./l¯°1Øᵯ¤□oLi+ᔣᵯ᩽amÍᑣᵯ᩽aEM᩽ᑣᵯ᩽bEÜ᩽iᐙᵯ¤ᵯ᩽bE▢᩽ᵯ+¤Li+ᔣ▢᩽mÍ஺ூ*+௃A.᪷./l¯°1Øᵯ¤□oLi+ᔣᵯ᩽amÍᑣᵯ᩽aEM᩽ᑣᵯ᩽bEÜ᩽iᐙᵯ¤ᵯ᩽bE▢᩽⌱⚗A┯!"B.Øᵯ¤ᵯ᩽bEÜ᩽Ü᩽ßLixCyᜫᵯo?@Li+Cy,ᵯ᩽DELixCy-xe-=xLi++Cy,⌱⚗BMN"C.ᵯâØᵯ¤M᩽DELiirCoO2+xe-+xLi+=LiCoO2,äᔠ⌱⚗B1pE2LiC+Li,.CoO=LiCoO+C,⌱⚗CMN"xyx22yD.᪷./l¯°1Øᵯᐙᵯ¤┞oæçᵯâḄM᩽Ü᩽èéêᡂᓄëᵯḄìí]ᓄ⌱⚗DMN"Õᫀ⌱A஺

1310.Bூᑖ᪆௃᪷.⚪î1(CaSO)=c(Ca2+)xc(SOt)=9.2x106,4K(CaCO)=c(Ca2+)xc(CO;")=2.8xl0-9,.Î+⚪஺sp4ூ*+௃A.ó/1iCa2+ìô¤x,Nø⊤CaCChḄúû+±⊝üýMø⊤CaSOX|<24Ḅúû+±⊝üýᦑAMN"9?xIO'6-2B.X1X2ḄCa2+µ¶þ4xl(rmol-L-',x=-~^-=2.3xl0,24xl0D.@⏚B$%CD┡᮱GHḄJᳮCaSO4(s)+CO(aq)=CaCO3(s)+SOj(P)'ᦑD=>ᦑ⌱Bo11.BCூST௃A.ᓫXᙳZ0X'[X&\ᨵ1^_X1^ᐔX'a^bcᑖe&\ᨵ5^஺Xg1^ᐔX'A=>B.C1CH2cH20HZhᵯTi'jkᵯlmnle'ᦑoᐭAgNO,$%&jrst⁐vw'B┯C.ᵫyz{.|'n}b⏣ḄJeᑭᵨ᳛Z100%=53.8%ᓄ&z{ᱥJeᐰᑮsᡂᱥi&'ᑭᵨ᳛Z100%,c┯D.ᓄᑺᦋz{ᔊ'z{Ḅᓄ'ᜧᓄᑖeḄᑖᦪ'z{᳛'D=>ᦑ⌱BC஺12.BCூST௃A.⏚ឋ$%&Ḅle¡9{Z2¢+£஺2+211*=12+2£0,ᦑA┯B.᪷)⏚ឋ@⏚ᜧ¤¥¦ᜧ¤@⏚§᪷'ᦑᔣ¥¦B$%&ᐭ©ªCO?Ḅlez{ZCH,0+HO+CO,——>C6H50H+HCO,ᦑB=>62c.ᵨª®Gᔾᦈ±²³´&Ḅso,le9Z2NH,-H2O+SO2=2NH;+SO-+HO'ᦑc=>;22

14D.FeJ$%ῖ⇨⌚º»ᑴ½ᓺᑵᵯÀ»Ḅle¡9ZCu+2Fe3+=Cu2++2Fe2+,ᦑD┯;ᦑ⌱BC„13.CDூST௃A.ÃÄᩩÆÇ'ÀÈজḄᓄᨬᜧ'z{᳛ᨬ᠒'A=>B.ÀÈটḄsᡂᱥyªÍ¤z{ᱥyª'ΤÏÐz{'B=>C.Ñᐗz{Óᢣz{ᱥaÕÖ×ᓄZrᱥḄz{'ØÙ&.ÚÛm'ÀÈঝ&Ýᙠ&ßrᱥ,ᑣCHI+cr=CH+IC1jÓÑᐗz{'C┯;3D.ã᝱&TS1Ḅªᨬæ'çèឋᨬé'D┯ᦑ⌱CD஺14.ACூST௃A.ᨔë&KJeí¤⚔ïgðᑁ'a^ᨔë&JeᦪòZ8X+1=2NiJeí¤ᨔëO☢ô'a^ᨔë&JeᦪòZ8x3=4SJeí¤ᨔëõôgðᑁ'a^ᨔë&JeᦪòZ8X+2=4ᦑö÷øᩞᧇḄᨬúᓄû9ZKNi2s஻A=>B.╅Z28þᐗÿ
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15ᡂ⏚°±Ḅ@’³᪷ª᳛´▭=ᘤ@¶X஺஺·«¬஺ᳮ¯@(1)᪷ª¸`ᘤaᳫ\]^_;`ᘤbgcl¹ᐸ»¼ᙠ´¾bcᢝeᧅghiᘤᑁjkl&meᧅᑁnoᙠ¿ÀÁÂÃᵨspᑭrs;(2)hi◤vwḄ}L110࠷,ÄtḄż100C,tuvwxbyᑮhiᡠ◤Ḅ}L110C,ÆÇ⌕ÈᵨÉuvwḄÊ(3)hi⌮hi,hiᱥxbᐰËᓄ"¢ᡂᱥ஺ᵫÍ⏚Ḅ⏚ឋ¹Ï⏚Ḅ⏚ឋkÆÇᙠÐÑஹᑖnÒvᐭ5%NaHCChÔnḄ:ḄgᒕḄ⏚hiyᑮ◀ᒕḄÕhiḄ⏚Ḅ:Ḅ(4)ÖtMgS04ᐹᨵᔾtឋᙠᨵÙvᐭÚ@ÖtMgSCUḄ:Ḅ◀ᨵᱥḄtᑖsoḄÛSÜÝÞÙᵯÝàᦪ4+\—=4,ÖáàᵯÝᦑSOḄâ᪀ä5☢o\(5)5.6g5.6g⏚Ḅᱥ?Ḅ@஻(⏚)=112g/mol=005mo1,ᐸᳮ¯+hiᑴç⏚°±Ḅ?@47gè⏚°±Ḅ?@)=0஺5molxl40g/mol=7.0g,´▭@4.7g,ᦑᐸ᳛〈x100%=67.1%஺16.(1)-91.1(2)CD(3)P>P>P,hiiêwhihiiiᔾwhi}L570cëìhiËᓄ᳛í⌕32ᵫhiiiîï37.5(4)2CO+12H++12e-=CH=CH,+4HO□222ூñ᪆௃(1)ᵫòóïôhii-hiiiõhiCO(g)+2H2(g)=CHQH(g),ᑣhiḄᰚ÷"AH=

16AHi+AH=-50.0kJ-mol-'-41.1kJ-mol'=-91.1kJmol-1஺2(2)A.øùúImolH-Hûü¢ᡂImolO-Hûxbýþ5⌮hiÿ᳛
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ᦑnᫀ*piDVWiiDᔾWYZ\h570࠷`2Lᓄ᳛b⌕ᵫiirsঝtaujvᐭḄᓄḄᱥ"Ḅ#*Imol,ᑣx+*3mol,MyjᓄḄ⊝Lᓄ᳛*60%,ᑣLᓄḄᓄ*0.6mol,ᵬ⏣Ḅ⌱zឋ*pᑣ|ᡂᵬ⏣Ḅᓄ*6moix=0.4moLᙠi~6jὑx+L2mol,|ᡂḄᵬ⏣+ᙳ*0.4mol,iiLᓄḄᓄ*0.2mol,6jὑx+0.2mol,|ᡂḄCO+ᙳ*0.2mol,ᡠ⊝jᓄ*1mol-0.4mol-0.2mol=0.4mol>x+*3mol-l.2mol-0.2mol=1.6mob+*0.4mol+0.2mol=0.6mol,+,ᱥ"Ḅ#*0.4mol+1.6mol+0.6mol+0.2mol+0.2mol=3.2mol,ᑣᓄḄᑖ>*—X0.2MPa=0.025MPa,x+Ḅᑖ>*&x0.2MPa=0.10MPa,ᵬ⏣Ḅᑖ>*0ᨣ43.23.23.0.025x0.0375xO.2MPa=O.O25MPa,+Ḅᑖ>*xO.2MPa=O.O375MPa,50.025x(0.10)3=37.5(MPa)4(4)ᐭᓄ|ᡂᐗḄᓄᔠfg|ᵯḄ▢᩽|ḄD,

17ᡠ▢᩽ᵯ᩽*p2CO+12e+12H+=CH=CH2+4HOpᙠ□᩽ᵯ£Ḅ0¥ᜫ§ᵯ.|ᡂ222+6j|ᡂH+,▢᩽◤⌕H+,ᡠH+©ªᔣ«JKᑣ¬®~¯ᵨḄD□£.°ᣚ²஺17.(1)SiOCaSO24(2)2Fe2++C1CT+2H+=2Fe"+Cr+H,O(3)[Ar]3d74s2(ᡈIs22s22P63s23P63dzs?)ভsp3ᩖᓄN>O>C59+48+16x3,…155ম12=ÓÔ(ᡈ᧡Öூᑖ᪆௃ÚÛÜᓄᑺÞᧇvᐭàá⏚ᓄấஹá⏚┛åæhᦑçᑮḄèé*SiO2CaSOêèëÚᨵFe2+ஹFe3\C?Ḅ34ABCD2Fe2++CIO+2H+=2Fe3++CH+H2O(3)27JᐗLM᝱O4Ḅᵯ4᣸RC[Ar]3d74s[ᡈIs22s22P63s23P63d74sঝ)(4)(NH)CO4`NO4ᕜbcᡂ4d஺f,NO4ᩖᓄh⍝jksp37mᕜnoḼO4qᦪsᜧ422umᵯ3vsᜧNḄ2Ph⍝wᐙyz{|᝱umᵯ3vᜧ27ᕜn}~ᐗLᦑumᵯ3vᵫᜧᑮḄqN>O>C(5)⚔ḄC஺ὃC஺ᡠᙠ☢ḄX)☢~Ḅ஺ᨵ4d`ᙠxzyz☢ᡠC஺~Ḅ0Ḅdᦪ12᪷ᨔmdᨔ`ᨵC஺Ḅᦪ8xD=1dᨵTiḄᦪ1dᨵOḄᦪO1(59+48+16x3)grn6x^=3dᨔḄ§¨——-——ᨔ«¬(apm)3=(axl0“஺cm)3,ᨔ«¯°?=

18(59+48+16x3±59+48+16x3..155------²~~a3xlO-3,,N(ᡈa3xlO-3°N\?/cmTA(axlO'°cm)3AµCH=C—COOH218.(1)¶·CH3(2)¸MஹºM(3)&ᡂ>?CHCH33(4)nCH=C_>-fCH-C^22COOCHCHOHCOOCHCHOH2222(5)5CNCOOHHCNHO,H+2HC-C=C-CH--------►HC-CH=C-CH--------►HC-CH=C-CH-|…µ333333»ᓄᑺA¾¿⏚ஹÀ0,»ᓄᑺCH=CH-----►CHCHOHJ2232(6)Áஹ&ÂCHCH33CH=CICOOCH2CH3ூᑖ᪆௃DḄÅÆÇH2Ḅ}ǯ°43,ᑣ}Çᑖ4§¨43X2=86,ᑖ4`CஹHஹOḄO4dᦪÉ2D3D1,ᑣᨬÊCC2H30,Ëᑖ4C(C2H3O%,ᑣ43n=86,n=2,D᪶ÍᐳÏÐCH=C—COOH2Ñᨵ3ÒÓḄÔ⛳Ö⏚ᵫ×ØÀDḄÙ᪀ÊCI஺ᵫEᑖ4`ḄÛO4ᦪCH3Üᵨ⌮ßàá{AஹBஹCᑖ4`âᨵ2dÛO4ãD⏥ᡠACH2=CH2,BCHCH33BrCHCHBr,CHOCH2cH2OH,åæØÀEC%=C,FçCF^—Cè22COOCHCHOHCOOCHCHOH2222(1)CH=C—COOH2ᵫᑖ᪆ACH2=CH2,ᑣé궷DḄÙ᪀ÊC~IoëᫀD¶·;CH3CH=C—COOH2cH3C3IC—,îvïḄéê¸MஹºM஺ëᫀD¸MஹºM:COOCHKHQH

19(3)CH2=CH2+Bn-BrCH2cH2Br,>?jk&ᡂ>?஺ëᫀD&ᡂ>?;CH3I)->F(-fCH-C^),ñ&ò>?ᓄóABCDn2COOCH2cH20HCOOCHCHOH22CCI3CHI33CHCC2•{ᩩöIëᫀ:ICOOCH2cH20HCOOCHCHOHC00CH2cH20H22CH3I——ã_>-fCH-C^2COOCH2cH20H(5)CH=C—COOH2ø~IyùᩩöD“i.vñûü>?ii.výþḄÿᓄ⁐”ḄᑖCH3᪀ᨵஹᑣ᪀CH2=CHCOOCH3ஹCH3coOCH=CH2ஹHCOOCH2cH=CH2ஹHCOOCH=CHCH3ஹHCOOC(CH)=CH,ᡠᑖ᪀ᐳᨵ5#஺%ᫀ'325((6)CHCHCHCH3333ᵫMḄ᪀ᓝCH—f+,-.ᐸᓫCH=f,1ᵨ⌮45ᔠᡂ8ḄCOOCH2cH3COOCH2cH3CHCH33ᱥ:CH3cH20H;CH=C<=>?@ᡂAᡂCHCHOH,2-CD>HCN@ᡂE?32ICOOHCHCH33FAᡂ1H=1GHIJᵨA;2-CDKᧇᑴᜓOᑖPᓄᔠᱥMḄᓫḄᔠᡂQRI..COOH

20CNCOOH+HCNIHO,HHC-CH=C-CH2HC-C=C-CH-------->--------►HC-CH=C-CH-|333333'TᓄᑺVZ[⏚ஹVᓃ0,TᓄᑺCH=CH--CH-3-cH-2OHY22Vஹ@X%ᫀ:CH=CCOOCH2cH3CNCOOH+HCNHO,HHC-C=C-CH---►HC-CH=C-CH-2--►HC-CH=C-CH-333333TᓄᑺVZ[⏚ஹVHQ,TᓄᑺCH=CH------------►CHCHOH-2232Vஹ@XCHCH33CH=CICOOCH2cH3ூ_`௃ᔠᡂᨵbᱥcd1ᵨ⌮45஺