江苏省2022-2023学年高三上学期暑期作业检测化学试卷及答案

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13Kb?&=(஺+(+)ᓽc(o/r)=Kb?4i(+^=?H)?,56,AABC1daB.2./☟¡PḄ¢£¤RNaHCQ¥aBa(OH)2./(ᡂBaCz஺¥᪷2Q8¦⊝c(Ba2+)c(COa)=Ksp(BaCO),BAB;224C.3+ᑮḄQR᝞ª«ᐭḄHC1Ḅ¬!ᐸ®¯°±O.lmol/L,ᑣ`!c(Na+)C஺ᙠÇÈᨵÉᱥRCÊËsG,HÊËAG,ÌᙠᓄᔠᱥRᐳᵨᵯ#ÏÐÑᔣC,ÌᵯsឋC>H஺ÒᵯsឋO>C>H஺AAB஺B.ᙠÓRÔCuSO4,ᵫÓp(᝞Õ./Cu2++2NH,Hq=Cu(OH)2J+2NHCCU(OH)+4NH,.HO=CU(NH,+2OH-+4HO,fÖ+ᑮ×⁐ÙÚ஺B┯஺222C.[RCu(OH)2ᓄᡂCU2஺ᐗ¿ᓄᔠGH+2ÛÜᑮ+1,p(wj./஺CAB஺D.Þ2ᑖßàáâ⁐ᙊäåᦪl+8x=2åç⁐ᙊäåᦪ4å஺23àáâ⁐ᙊäè⊤OO2-,ç⁐ᙊäè⊤Cu+஺4åCu+ᑖêë4ᩩÏíîḄ¢!ᜐᡈÕ,ᜐÒò"Cu+ᨬôḄCP-ᨵ2å(1åᙠ⚔ä1åᙠö)ᓽ÷ëᦪ2஺DAB஺ø¢ᡠù/⌱B஺14.Dூ78௃A.ᵫúàá600࠷Eᵬ⏣ᓄ᳛55%ஹᵬÿḄ⌱ឋ60%,ᑣ5minᑁImolx55%x60%ᡂᵬḄᙳ᳛HCHO)=2L-0033molL'min1,ᦑA┯5minB.ᵫ600Cᵬ⏣Ḅᓄ᳛ᜧஹᵬḄ⌱ឋ!"#$700஺(2'ᔊ)iiiḄ*+),ᜧ-.'/ᑁ*+ᔊ)0Ḅ᳛12*+ᔊ)3Ḅ᳛ᦑB┯C.4*+5667ᜧḄᔾ9*+ᜧ:;⊝ᔣ⌮*+?ᔣ@AᵬḄB᳛!"ᦑC┯D.CᵨEᓄᑺ!"*+ḄGᓄHᑣCᵨI⏚KL*+EᓄᑺḄ*+ᔊ)iḄGᓄH12

14CH30H(g)UHCH0(g)+H2(g)ḄGᓄHᦑD3Xᦑ⌱D஺riYZ15.(l)4Fe[CrO],+7O+8NaCO,—2Fe,O+8NaCrO+8CO,222324(2)lmZnᓄḄo6Ẇqஹo6rs't0ᤅvw(3)xᨬz{|}~2ᐭBaCl?~B⁐ᑣCr(OHb|}(4)FeS+3Ci-Oj+7HO=FeOOH+3Cr(OH),+SO^+4OH0.1FeSᓄᡂ⏚2ூᑖ᪆௃⌕ᡂᑖ¡Fe(CrCh)2,£¤ᨵAI2O3wᩖ©ᐭI⏚Kஹªᐭn5ᙠmZᩩ®Fe(CrO2)2ᓄNa2c04°FezCh,AI2O3ᓄNaAlCh,o6ᱥ©¤ᨵNazCrCU°lFeO,NaAlO,rNazCrCUஹNaAlCh³ஹFezCh2r´µ◀·FezCh,µ~〉¹232⏚ᡂºnᓄ»◀»¤Na2CrO4Ḅ~¼´ᜐᳮᡂCr(0H)3,Cr(0H)3¿ÀᡂCnCh஺(1)“mZnᓄ”´)Fe(CrO2)2°Na2co3ஹO2*+ᡂNazCrCUஹFezCh°ÅnᓄI*+ḄᓄÆ?ÇZ)È4Fe[CrO2௃2+7O2+8Na2co3=2FeO3+8NaCrO4+8CO222(2)lo6ÉᓾஹẆqËrsxẆqÌᜧÍÎ☢7Ðrs᳛ÑmᐗÓḄsÔ᳛(3)ᨬz{|}~¤SOÕ,#$|}4ÖסÕxᨬz{|}~2ᐭBaCL~B⁐ᑣCr(0H)3|}(4)জFeSᜐᳮÚrḄÛÜ?)ÈÕFeS+3CrOÕ+7HO=FeOOH+3Cr(OH)+SO^'+4OH஺CrᐗÓᓄᔠ23ßᵫ+6!"+3,ImolNazCrCU@3molᵯÜ10LḄ“Úr”¤ᨵNazCrCUḄᱥ©Ḅ¹¡3.00x1Olol-x]0L=0.300mol,ᑣ@ᵯÜḄᱥ©Ḅ¹¡0.300molx3=0.900molFeSFeᐗÓᓄᔠßᵫ+2ᓣm+3ஹSᐗÓᓄᔠßᵫ-2ᓣm+6,ImolFeS@9molᵯÜ,᪷çèᜫᵯÜêឤnᓄFeSO.lOOmolঝATBo6©¹ìí¡FeSᙠî59'ïn5nᓄᓄᡂ⏚஺16.(l)sp\sp5(2)£ì*+

15OCH20cH3Br,বCH30cHூᑖ᪆௃A-B,óxô*+-OHïClxôBTC,óxô*+-Clï-0CH3xôCTD,óxô*+õöḄHï-CH20cH3xôDTE,óxô*+÷ÅøõöḄHï-CH3xôE—F,ó£ì*+-COOCH2cH3ᓄᡂù-CH2OH,ᨬúèᑮBᱥ஺(1)AᑖÜḄnìÜüᙠᓫþ°þᐸᩖᓄ⍝ᑖsp3ஹsp\(2)EFḄ᪀ᓽ-C00CH3ᓄᡂ-CH2OH,஺(3)OCH20cH3cᨵ!-OH,"#$%&'()*+ᦑ-.ᱥCHOCHOX>^XCOOCH332(4)CḄ012ᑖ3᪀4567ᓄ89:();⁐ᓽ=ᨵ>?@ABឋDᐰFGH⏚ᓄᡠK.ᱥᑖLᙳ=21N2ᓄOP᛻ḄLRLFGSHT)ᡂ-0H,V@FGSHWT)ᡂ-0H,ᓽFGSHTᙠYPZ[ᐭ2!-0H,ᙠ]!-0HḄᑖ^_`21N2ᓄOP᛻ḄLFGS(5)aE-Fbᑮd(V@ᓄᡂ⏣,ᑣ-COOCH2cH3ᓄᡂ-CH20Hh6HC1[ᐭC1Lᓽ)ᡂ-CH20,h6MgᙠiF&⏣Ḅᩩkl)ᡂ-CH2Mge1,hᔠno#oh6pjCH2cH20HHCOOHᙠ⏚ឋᩩklᓽKᑮᨬHḄrHCOOH#ᵫCH30Hᓄᑴ

16Kᐸwx᝞lz17.(1)[Ar]3d5[Cu(NH)+2OH'=CuO^NH,T+HO■|᎔ᔾ342(2)ᤅᐭ〉LOmolCH2s0&ᐙᑖ9GᯠH⌲ᐭl.Omol.L'NaOH⁚pHᙠ3.24.7SᯠHw(3)96%ூG᪆௃(1)জFe26ᐗᐸ᪶᜜ᵯL᣸^[Ar]3d64s2,ᑣFeOFe(HI)Ḅ᪶᜜ᵯL᣸^[Ar]3d5A23_Aঝᵨ⇨:ᑴᜓCuOḄ¢L£x[CU(NH3)4]2++2OH=CUO1+4NH3T+H2OAঞ¥.)NH3,NH3᩽᧕9¨Fᦑ©ªXḄ«ᵨ■|᎔ᔾ஺(2)$ᯏwḄ®¯°᮱²ᧇᑴᜓCUSO#5H2Oᨔ4µ#$ᐜᵨH2so49G᮱²,Kᑮ=Fe2(SC)4)3ஹCuSOḄ9:hᵨNaOH9:⁚9:pH·3.2~4.7,¸Fe(SO)3ᓄFe(OH)¹ºw4243Hh»wH¼½«#KᑮCuSO#5H2Oᨔ4ᐹ4Ḅ¿À£ᫀ*0ÂᯏwḄ®¯°᮱²ᤅᐭ〉LOmolLÃH2sCUᐙᑖ9GᯠH⌲ᐭl.Omol-L-1NaOH⁚pHᙠ3.24.7SᯠHwஹÄÅÆஹÇᓾᨔஹwஹÉÊKᑮCuSO#5Hqᨔ4஺(3)¿ÀwxËÌḄ¢L£x2Cu2++4r=2CuI+I,2s+L=S&+21AᑣᨵCu2+~S,O^,2ᓽ஻(CuSO#5H2O)="(Cu2+)=0.1000molL/x23.04xl0-3L=2.304xl0-3mol,w(CuSO-5HO)=422.304x10-3molx250g/mol=0.576g,ᑣCuSO-5HO᪵ÏḄÐÑxlOO%=96%420.6000go18.(l)0.8mol(2)1058CKOH%6OH)ᡂ#9¨FḄ[Cr(OH)Jᡈer஺Ó(3)ÔᑖNOAÕN2ᡈNO⍎×F4ØÙÚÛ8ஹ®ÜÌF9:ÝᡂᵯÞß◀NOAḄá᳛NOAKᑮØÙÚÛ8ᜫḄᵯLᓄNOA,NOAᙠØÙÚÛ8ᡈ®⊤☢KᑮᵯLᓄNHz

17ூG᪆௃(1)FeCL+2NaBH4+6H2O=Fe+2B(OH)3+2NaCl+7H2T8ᐗᓄᔠÛùúBᐗᓄᔠÛ+3ÛNû,ᐗᓄᔠÛ-1Ûᓣý0Û+1Ûùúᑮ0ÛᔠᵯLÿឤ
ᑮᦪ8mol,5.6gFeḄᱥḄn=q=J'?O.lmol,ᑣᵯ"ᦪ0.8mol,ᦑ%ᫀ'0.8mol(M56g/mol(2)জ᪷0123⍝pH=0.78c(HCrO)=c(HCrO)K,>஺@:,=B)=.)=CpH=6.5244,8c(CrO»(HCrO)=஺(ᵪ)=10GᑣH=ᔁ=JCy-H-V—jIUঝCr(OH)3RSឋᱥUVWXYZ[Ḅ\]᪷^"_`abcᡂeCr(OH)41fg◀iᦑ%ᫀ'Cr(OH)jOHabcᡂUYklḄeCr(OH)Jᡈer஺?(3(3)জᵨqrstuvwlx[ḄNO',NO(UVgFevwN2ᡈὅRNOf⍎|lxYZ[Ḅ}~ᦑ%ᫀ'NO,UVgFevwN2ᡈὅRNOf⍎|lx'ঝ8,Fe-Cu-lYZ᪀ᡂwᵯuḄab᳛,᪷013
ᑮNOᓄNH(3Ḅᳮ'qrstuvwlx[ḄNO(,NO(gFevwNO',NO?ᙠqrstuᡈCu⊤☢
ᑮᵯ"ᓄNH(,ᦑ%ᫀ'8Fe-Cu-lYZ᪀ᡂwᵯuvwlx[ḄNOஹḄ᳛(qrstuvwlx[ḄNO3,NO(gFevwNO஺NO'ᙠqrstuᡈCU⊤☢
ᑮᵯ"ᓄNH'஺