江苏省南京市六校2022-2023学年高二上学期期初联合调研考试化学试卷(含详解)

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ᡭWpq*ᵨᢙ⏚D.FeCbᐹᨵIᓄឋ*ᵨᑺ4.¡ᕜᐗ¤WஹXஹYஹZḄ©ᦪ«¬ᜧ*Wᐗ¤Ḅᨬ᜜±ᵯᦪ@ᐸᵯ±ᦪḄ³´XḄµ¶@¡ᕜ·¸ᐗ¤8ᨬᜧḄ´Y@ᙢº8z!ᨬ»Ḅ¼½ᐗ¤´XnZ¾ᡂḄᓄᔠᱥḄᕈ8ឋ஺:ᑡ<=8*Y¿ộḄ@A.WḄ{¼½ឋdZḄ{¼½ឋB.ÁXᓫᢗᐭᑮCuSO48*6ᡂÅ`⁐ÆÇC.ÈÉᵨᵯÊᰚÌYIᓄᱥḄÍsÎϼ½YD.ZḄᨬ~IᓄᱥqᓄᱥHÐ⏚5.KMnCUஹNaClOᑖ×nØe⏚ÙᔠpqÚ6ᡂCL஺:ᑡᑴÝஹᓄCkஹßàᐸIᓄឋáâ

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5eᢝᐸhᩩjkl9/ᔠḄmCU2஺Ḅn᳛Ḅpq᝞sᡠO஺/ᔠuᜧ63.25mol-L”CU2஺Ḅn᳛wx9[Cu
NH3,y+Ḅzᓄ᳛{|ᜧ9}~Ḅ%.

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11ூ_ᫀ௃Dூb᪆௃ூdb௃A.ᓫḄᓄឋeACuᓄᡂ᝱A┯B.~eA<;⏚ᙠᩩ#Bᡂfᓄ~<⏚@BB┯C.O<;⏚◤⌕¡¢jAᡂfᓄ£Bᩩ@¤C┯D.fᓄ<¥Ḅ¦DBᡂQ(NHQ2SO3,D஺8.VB2so2(g)+O2(g)U2sCh(g)AH=-196.6kJ-mol"#ᑡ*+Ḅ,A.BḄAH<0,AS>0B.BḄÃ⊝>ᦪD⊤lK=cC2(SO)3CÈᵨiᓄᑺAᦋËBÌÍÎBḄÏᓄAD.Ðᜧ£ÒḄÓÔAÐᜧÏᓄᑖÕᑖᦪ¡ÖBḄ×᳛ூ_ᫀ௃Cூb᪆௃ூdb௃A.AH=-196.6kJmol'<0,Bᱥ£ḄÚ¥ÒᦪÛl3,ᡂᱥḄ£Ú¥Òᦪl2,ᑣBlÝÞBBḄAS<0,⌱⚗A┯c2(SOjB.B2S஺,(g)+஺,(g)U2S஺3(g)ḄÃ⊝>ᦪ⊤áâlK=0Iஹ/,ஹஹ⌱⚗B┯c-(SO)-c(O)22C.iᓄᑺAᦋËBÌÍÎBḄÏᓄAVBḄᯚËåæç⌱⚗cD.Ðᜧ£ÒÓÔDÈᓫè£éᑁÏᓄᑖÕᑖᦪÐëᨵᦔíîḄï᳛ÐᜧB×᳛¡Ö⌱⚗D┯_ᫀ⌱C஺9.ðᵯbòó┞ᵯõḄLiM%஺,Dú8ឋḄLi2co3ÛMnO,ᵯbüý᝞#(ᐸ
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12ᵯ+A.ᵯ᩽A/▢᩽123456B.ᵯ᩽BḄᵯ᩽1682H2O+Mn2+-2e=MnCC2+4H+C.ᵯEFGHIMi?+LMNᢝ!D.ᵯQRS⁚pH◀WMn?+XYᐭNa2cO3_`aLi2cO3ூdᫀ௃Cூ᪆௃ூh௃A.ᵫᵯijklᵯ᩽BmMn2+nᓄ/oMnCh,rᐗtᓄᔠvᓣxᜫᵯᑣᵯ᩽B/□᩽ᵯ᩽A/▢᩽aᵯ123456A|)}B.ᵫᵯijklᵯ᩽BmMi?+ᜫᵯnᓄ/oMnCh,ᵯ᩽56~/82H2஺+M+-2&=MnO+4H+,B|)}2C.ᵯ᩽A/▢᩽LiMmCMaᵯᵯ᩽56~/82LiMnO+6e+16H+=2Li++4Mn2++8HO,aᜫ242ᵯឤᵯ56/82LiMmO4+4H+=2Li++Mn2++3MnO2+2H2O,562ᡂoMn2+,Mi?+LMᜧC┯}D.ᵯ56/82LiMn2O4+4H=2Li++Mn2++3MnO2+2H2O,ᵯQRIS⁚pH═nᓄ/◀WᯠIXYᐭ⏚`a⏚┞D|)}dᫀ⌱C஺10.ᵨ¡CuஹCuOஹFezCh¦Cᑴᜓ©ªḄ«᝞k8“”G1256Ḅ¯~/Cu+4H++O}=CU2++2H2஺B.“SpH”GᵨCu2OHC2co3,²³CuO

13C.“
”c(Cu2+)-c2(OH)

14ூ?<௃A.BCDᜧᵯGHGIBCᜧᵯGJCKᑣMὅᵯGJCKᦑA┯QB.NaClO*"ᐹᨵWXឋZ[ᵨpH]ᐸpH,ᦑB┯Q`C.aឋᩩcdA1ஹg⏚᪷GIj,kᓄmn,ᡂopᑣḄ⁐⁐ᦑCqrD.ᐭ⛳&MnSCh*"᝞uvQc>Ksp,ᑣ,ᡂ/0Z[z{*C|ᜧK,ᦑD┯Qᦑ⌱`Co12.dᑡqrḄA.□᩽▢᩽B.ᙢd⍝ᵨᙽ+⍝Ḅῖ⇨C.ᵯq᩽ᵯ᩽J`PbO+4H++SO-+2e=PbSO4+2HO22D.§¨§©dªk«ᧇᵯᵯJ#®ὑ1L2LH2,±²ᵯIḄᦪ´602x1023ூ9ᫀ௃Cூ<᪆௃ூ?<௃A.¸¹ºᵯ<□᩽▢᩽ᵯ<"»GI¼*"ᦑA┯QB.ᙢd⍝ᵨᙽ᪀ᡂᵯ¾᩽ᙽq᩽⍝Ḅῖ⇨¿᳛ÁᦑB┯QC.ᵯq᩽ÂkᓄÃᵯI,ᡂÄ⏚ᵯ᩽J`PbO+4H++SO^+2e=PbSO4+2HO,ᦑC22qrD.§¨§©dpÆ᥅ÈÆ|ZÉÊ22.4L/mol,11.2LÍpḄᱥÏḄÐZ[ᢥÒᦪÓÔÕÖ×ᦑD┯Qᦑ⌱C஺13.ÙdᑡÚÛÜÝ₝⏚ßH2c2஺4àḄឋÏ஺ÚÛÚÛâ&ãä1å¨dᵨpHÖ]ÃO.lmoVLH2c2O4*"ḄpHç1.3å¨dᔣ25.00mL0.1mol/LH2c2஺4*"#⌲ëᐭO.lmol/LNaOH*"Ã2ᑮdíëîïdᑡᨵᐵqrḄ

15ëî&┵ñòó⌕ᵨõö"÷B.0.1mol-L-1H2c2O4*"#øᙠc(H^)>2c(CO^)+c(HCO)22C.aஹbஹcúnḄ*"#ûḄᵯGJC`c>b>aD.V(NaOH)=25.00mLmnᡠÃ*"#`c(CO-)2C(CO)+222C(HC2஺)BC.apH=7,Ḅᵯᜐ!ᵯ"᝱($%&)b'()ᨵNa2c2஺4,(Ḅ,-Ḅᵯ.ᑮ01c'ᨵ2᜜ḄNaOH,ᐸᵯ5ḄOH-67ᢓᑴḄᵯᡠ:;"᝱<Ḅᵯ=>?@b>a>c,C┯BD.C"᝱<'(?NaHCzCU,᪷E(FGឤᐵJᨵc(H+)+c(HCO)=c(OH-)+c(CO^),pH<7,c(H+)>c(OH),ᡠᨵaC2஺K)>c(H2c2O4),D2242┯B஺14.CO2LᓄNOPᔠᡂSᵬ⏙ᐸV='W⌕YZ<ᑡ\?ᨵ\?IKCO2(g)+H2(g)^=iCO(g)+H2O(g)AH=+41.2kJ-mor'\?IIK2CO(g)+6H(g)UCH30cH3(g)+3H2O(g)AH=-122.5kJmol122ᙠឤ^ஹCO2`H2ḄabcdeḄᩩg<CO2h⊝jᓄ᳛`h⊝CH30cH3Ḅ⌱mឋ(CH30cH3Ḅ⌱m2xCHQC&Ḅᱥ(Ḅc_ឋ=\?ḄrḄᱥ(ḄcXM%)vw>Ḅxᓄ᝞zᡠ{஺

16100%、把融、烟假郴W叔<ᑡ|}Ḅ@A.200~360࠷ᑁJ'W⌕YZ\?HB.276࠷\?IஹII'N\?ḄCO2Ḅᱥ(Ḅc12K13C.b⊤h⊝CH30cH3Ḅ⌱mឋxᓄD.CH3OCH3⌱mឋ◤ẆYwᩩg<\?IILᓄឋḄLᓄᑺூᫀ௃Dூ,᪆௃ூᑖ᪆௃\?Iᔾ\?nᐸᩩgᓣw>h⊝Iᔣ¡¢h⊝n⌮ᔣ¡¢CH30cH3(g)⌱mឋ¤a⊤{CH30cH3Ḅ⌱mឋvw>Ḅxᓄb⊤{CChh⊝jᓄ᳛vw>Ḅxᓄ஺ூ¥,௃A.200~360࠷ᑁCOzh⊝jᓄ᳛ᐜ¤§ᓣᙠ¤▤©W⌕YZ\?H,ᙠᓣ▤©W⌕YZ\?I,A┯BB.276࠷CH30cH3Ḅ⌱mឋ48%,\?ªḄ«ὑImolCCh,ᑣZᡂCH30cH3Ḅᱥ(Ḅc0.24moLᑣ\?H'N\?ḄCO?Ḅᱥ(Ḅc0.48mol,\?I'N\?ḄCO2Ḅᱥ(Ḅclmol-0.48mol=0.52mol,ᦑIஹII'N\?ḄCChḄᱥ(Ḅc=0.52:0.48=13:12,B┯BC.ᵫᑖ᪆P°b⊤{CO2h⊝jᓄ᳛vw>Ḅxᓄc┯BD.CH30cH3⌱mឋ±◤ᢓᑴ\?I,01\?H,ᵫ\?Iᔾ\?Hw²³´ᦑ◤ẆYwᩩg<\?nLᓄឋḄLᓄᑺDᫀ⌱D஺Sஹµ⌱m⚪Kᐳ4⚪ᐳ58ᑖ15.ᵨ¹º»(W⌕¼CuSஹFeO)ᑴᜓCsOḄd¾¿=᝞

17ÀÁ⏚ஹMnOÃஹNHHCO,ᔠᨴÅ24¹º»d►⏚Æd►ÇpH——►◀═——►ËÌd*Cu,OᓝττSFe(OH),MnCO,N,(1)“⏚Æ”'CuSYZ\?ḄᓄÑÒ=o(2)“ÇpH”§pHÓ4,CFe3+ᱥ(ḄcÔ>஺[K[Fe(OH)]=lxlO-38]sp3(3)“◀Õ”ḄFÒ=.(4)“ËÌ”×◤ØeºÃF[Cu(NH3)4]2+ḄÔ>ᩭeᔠÚḄᵨc஺20.0mL◀ÛMn?+ḄºÃ100mLÜcÝ'NÀÞßà>ácâ25.00mLÀÞ§Ḅ┵äÝ'åN3moi2sCMßpH3~4,NᐭVcKIç஺èéᢣ{ᑺZᡂḄỚᵨO.lOOOmolLNa3s2O3᪗áåeßí(\?2Cu2++4r=2CuI+h,L+2S2O=2r+S4OK),îï2~3ðhᙳ«ὑNa2s2O3᪗á22.00mL஺òóºÃḄᱥ(ḄcÔ>(ᑏ5òóV=)(5)õᢝᐸᩩg÷xᔠῃÔ>CsOḄù᳛Ḅúû᝞zᡠ{஺ᔠῃÔ>ᜧ3.25mol.L”CsOḄù᳛<¤[Cu(NH3)4]2+Ḅjᓄ᳛ýþᜧP²ḄÌÿூᫀ௃1CuS+MnO+2HSO=CUSO+MnSO22444+S+2H2O(2)lxlO-8molL-'(3)Mn2++NHHO+HCO=MnCO3j,+NH4+HO322(4)0.4400mol-L”(5)C112ON2H4H2Oᡂᓫூ᪆௃ூᑖ᪆௃ᐭ⏚ᓄ"#ᓄ$ᓄ"%&ᓄ'(&ᡂ)*ஹ,╎)*ᓫ#ᓄ./$⏚'(&ᡂ./)*#0ᓄᡂ/)*#12⁚pH◀5/)*#ᯠ789:⏚;╆◀5╎)*#ᨬ719ᔠ?)*@ᑮB஺ூDE1F௃ᓄᨵឋ#ᓄ"ᨵᓄឋ#Iὅᙠ⏚ឋᩩMN%&ᓄ'(#OP@ᜫᵯ*Sឤ*Sឤ#'(ᓄUVWXYZCuS+MnO2+2H2SO4=CuSO+MnSO4+S+2HO42o

18ixlO-14ூDE2F௃K[Fe(OH)]=c(Fe3+)-c3(OH)=1x1038,pH=4,ᑣc(OH)=----------=1x1010mol/L,sp3lxKT4c(Fe")=τ=lx10_8mol/L஺I7(1x10*3ூDE3F௃ᵨ89:⏚;^◀5")*Ḅ)*VWXYZMn2++NH3-HO+HCO=MnCO4+NH+HO»22ூDE4F௃2CU2+~I-2s2஺:2ᵫ⚪cᡠe'(f@ᐵhXZ22
i@n=0.0020mol,ᑣ20.0mLn0.1000mol/Lx0.02L◀5M/+Ḅ8klm8)*[Cu
NH34p+ḄᱥḄoY0.0020molx4=0.0080mol,pqY:().()()8()mol=0.40(X)mol/L஺0.02LூDE5F௃9ᔠῗqᜧt3.25mol.LTu#9ᔠvᓄᡂwx#8)*Y#y@[Cu
NH34BḄzᓄ᳛|}ᜧ#CU20ḄB᳛N~஺16.᯼xḄNOxஹSO2ᜐᳮ7fᔾᦈ#ᵯᓄUᙠᐵᨵ⌕(ᵨ஺1x⌕ᡂᑖYNOஹSO2,fᵯ◀5#ᐸᳮ᝞ᡠ•▢᩽Ḅᵯ᩽'(XY.2x⌕ᡂᑖYNO?ஹSO2,fᐭNaOHklNO2ᐰzᓄYNO»1JNO2ஹSO2$NaOH'(Ḅ)*VWXY஺3ᵯf◀59Ḅ8w#ᵨ¡¢ᵯ᩽ᵯ£pqḄ
NHD2SO4$NaClḄ⏚ឋ¤ᔠklᩭ¦§¨஺জᵯu#□᩽Ḅᵯ᩽'(XY஺ᵯWkl«¬pqpH8w5◀®᳛$¯ὑᜐᳮ£o8w±ὑḄᵯ¯Ḅ²³ᐵh᝞1

19」Q・口(Tr鹭0.353(.S6/热£m(4鹿0.25·2ᡠ஺尔¸Cs-嗨¹(.2。崛0.1523(X)4XX)5(X)fXX)7(M)4681()12ClpJµ/(mg-L')«º?pH12ঝ1¾Cl-pqÂuஹ2¾«¬pHÅᑮ12u#8w5◀®᳛ƯὑÇḄÈf¯;ƾC1-pqÂÇu#Ê@klḄNOpqÂÇ#f¯ḄÈ_______o4vN2H஺ᧇᵯÑÒZvᧇᵯÑA᩽%&Ḅᵯ᩽'(YZ஺ூᫀ௃(1)জ.NO+5e-+6H+=NHZ+H2஺(2).(NH)SO^H2SO442422NO2+SO2+4OH-2NO-+S0j+2HO23জ.2Cß-2e-=Cl2fঝ.□᩽f¯OHáᵯ#B&ᜧox#±ὑᵯ¯ঞ.CßpqÂÇu#B&ḄCbᡈHC1OÂå#æNHZᓄYNO4NH-4e-+40H-N2+4HO242ூ᪆௃ூDE1F௃çèéYᵯÑ#▢᩽êᵯëḄì᩽#ᵫfí▢᩽NO@ᵯ*&ᡂNHZ,▢᩽ᵯ᩽'(XYN0+5e+6H+=NHZ+H2O,□᩽SO2ᜫᵯ*#□᩽ᵯ᩽'(XYZS0"2e-+2H2O=SO+4H+,BᱥYNH^SCUஹH2so4ூDE2F௃ᵫ⚪íN02ஹSO2ᐭNaOHklNO2ᐰzᓄYNOZ,Nᐗô,᝱ᵫ+4,~ᑮ+3,#ᦑSᐗô,᝱◤ᓣÇᓽᵫS02&ᡂS0;#1᪷P@ᜫᵯ*SឤᐗôSឤûüᓽf@2NO2+SO2+4OH-=2NOZ+SOZ-+2HO2ூDE3F௃জᵨ¡¢ᵯ᩽ᵯ£pqḄNHQ2SO4$NaClḄ⏚ឋ¤ᔠkl#□᩽%&ᓄ'(#Crᜫᵯᡂᵯ᩽2C-2e=C12f;

20ঝCl-ᡈpHᜧ□᩽!"#OH-$ᵯ%ᜧ&'(ὑᵯ"ᡠ+,-.◀0᳛2"ὑ34cr3%ḄC126ᡈHC1O789NH'ᓄNO44ூ<=4>?௃ABᧇᵯDEA᩽F᩽GᜫᵯḄᵯ᩽N2H4-4e+4OH=N2+4H2O஺17.+IJK6L⌕ᡂᑖ#FeS2,OP&AbChஹSiChRFesCUSᧇᑴᜓV⏚J
FePOQ஺61X⏚Y஺9Z[&ᯏ]^ḄIJK_`aᐭᑮd⚠fEឤh50i60࠷ak6lmnoXpqrstᧅv᠒raZ[ḄxI⏚ᐙᑖqz஺h{|q3ḄS}#
2~S஺ᔣzsEaᐭ~SJ_ᐙᑖᤅsEFM+ᐰ~S஺Fe3+ᐰ~SḄ#,~SḄ63◀஺ᔣ~S^ḄsEaᐭFeO{ᤅAF+ᐰᓄA1
OHX3,qzFeSCUs஺aᐭFeO^GḄ(4)ᑴᜓFePC)4,SᳮFe(SO)3+2NaHPO4=2FePOX+2NaSO4+H2SO4,ḄFePCU⁐24242{pH¡V⏚JḄ¢£᝞oᡠ¥஺pH¦3^JḄ᳛§¨ᐰ2VḄ᳛ᓾᙠ«¬Ḅ!"S}#
5ᑮḄFePO®¯⊡ᐙ᦮+◀^ḄFeSCUsᑴᜓFePO4Ḅᫀ³Z[&◀^ḄFeSO4s,´µᑮFePCU஺6!⌱ᵨḄ¸ᑺ1molL“Na2HPO4s
pH¦10ஹ3%º஺2sஹBaCLsXூ»ᫀ௃61¼½Fe3+¾?ᡂFe
OHX3,¿ᜫJᐗÁ62জ.³PÄsŸÆErᐭPÄKSCNsÇs{ÈÉ⁐ᑣFe3,ᐰ~Sঝ.2Fe3++Fe=3Fe2+
32A13+4-3FeO+3HO=2A1
OH+3Fe2+23
4pHᜧÅ2.5^FePO8ᓄFe
OHË$PO443

21(5)aᐭÎ&Ḅ3%Ñ'¾sᐙᑖFeSChsᐰ'ᓄFe2(SO4)3s×ᤅ×91moÚᓃNazHPOasv᠒aᐭᑮFe2(SC>4)3sEsḄpH¦2.5,qzãäᨬ^ZæãäsaᐭBaCl2séêëூ?᪆௃ூ<=1>?௃IJK_ᯏ]^J'ᓄ+3í9ᐭxI⏚8ᡂFe%zsE□#îJஹஹJïJ"¾?¾?#ᔾkᓣ3hòóJ¾?ᡂô'ᓄJ⌼ᡂJᐗÁ¿ᜫ஺ூ<=2>?௃Fe3+ᐰ~S³PÄsŸÆErᐭPÄKSCNsÇs{ÈÉ⁐ᑣFe3+ᐰ~S஺~SḄ2Fe3++Fe=3Fe2+oூ<=3>?௃¾?ᡂô'ᓄRôa'ᓄîJòóḄ¾?ᐸ2Al3++3FeO+3H2O=2Al(OH)3+3Fe2+஺ூ<=4>?௃ᵫ⚪ûüpHᜧÅ2.5^FePO48ᓄFe(OH)3Ë$PO4஺ூ<=5>?௃aᐭÎ&Ḅ3%Ñ'¾sᐙᑖFeSChsᐰ'ᓄFe2(SO4)3s×ᤅ×91moH/NazHPOasv᠒aᐭᑮFe2(SC>4)3sEsḄpH¦2.5,qzãäᨬ^ZæãäsaᐭBaCLséêë18.ᨵᦔ◀ᜧḄNOஹḄ᛻Ḅ⌕⚪஺(1)জ2co(g)+O2(g)=2CO2(g)(AHi=-566.0kJmol-'ঝN2(g)+2Ch(g82N0a(g)(AH=+64kJ-mol-'2;<2NO(g)+4CO(g)=N(g)+4CO2(g)AH=஺22;3(2)?⏚╆╅(MgNHaPOQFGHI◀ḄJ(NH(NH3)஺KLMNOJᜐᳮ1LḄNOJS(T⌕UNH(),WXᤅZᘤ\]^_;<`ab25࠷஺ᐜefᐭMgChNa2Hpe)4jk]ᵨNaOHm⁚;

22100(80)树健60小联40(3)(NZVD/BC(CuPd)/BCὶᔠ¡ᵨI◀喊2007.58.08.59.09.510;

23⊤☢âãᓄᱥḄäᡂ]åIáæ☄èéḄ;<¸ឋêë]ìí;<Ḅíîூï᪆௃ூñò1óï௃2জ-ঝI;<2NO(g)+4CO(g)=N(g)+4CO(g),ᑣAH=2AHi-AH2=2x(-566.0kJ-mol-,)-(+64kJ-mol1)=-22231196kJ-moH஺ூñò2óï௃জᔣNOJSfᐭMgCbNazHPChjk~ᡂ?⏚ö╅FG]÷;<ḄbMg2++OH+NH+HPO=MgNH4Po41+à0(ঝ᝞1ᡠ]pH7.59.0Ḅ]JḄ◀᳛f]ÐḼpHḄᜧ]HPO¼ᓄbc(PO)}aᜧ]Ò~ᡂFGḄ;<Ó᳛fÔ]J◀᳛f஺ூñò3óï௃জ᝞2ᡠ]NO3ᙠ⊤☢ᑮᵯزbNO2,NO?Øᔾ▬ᙠCuPd⊤☢Ḅ¸ឋHÚÛ²bN2ᡈNH(ঝ᝞3ᡠ]Á200minᑁ]pH=9.88ÃḄ◀᳛ÄÅXpH=4.05Ã]ᐸIÇḄ⏚ឋÜÝ]FeÜ᧕ᜫᵯ]NO(Ü᧕ᑮᵯز(⏚ឋÜÝ]H+}aᜧ]Iá®⊤☢âãᓄᱥḄäᡂ]åIáæ☄èéḄ;<¸ឋêë]ìí;<Ḅíî஺