2020届高考化学模拟竞优卷（第四卷）

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᯿ᔠᡂ56ᑏ]CH3cH2OHஹCHMgBr[ᧇᑴᜓᑖᓄᔠᱥ2-ᵬK-Ḅᔠᡂ567&?ᑺ⌱C஺30.⏚═7MnSO஺Clr0⌕Ḅᓄᧇ;ᵨ,⌼¢ஹᓺ¤¥¦§஺r0¨═©7MnO">ª«Si஺?ᩖ3C®¯°©7±⌕ᡂᑖ[FeS?
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ZC[\]^_ᓄc.c.XYḄ/C[\]^_ᓄd.ᓫc]^ᑁefC-HhefH-0hᦪjklঞnoឤ./0.ᘤpqr!ItII,⊝]u!vQᜐ]".ᘤXYᑖ
P(X)^!{|Ḅᐵ'.টᙠo/0.ᘤᐙᐭ0.8molCOt0.2molCO2ᐭ|ḄFeO,pqr!I,ᙠR(lgKp=O),ᑣCOḄ⊝ᓄ᳛o(3)nᵨCuSO,ᑺ23ᓄL]"CuSO,COqr!rᡂCaS,ᑣ!ḄᓄL'o34.ᓄᜐᳮ'ᢣᙠ¡¢£¤ᐭ¥¦⊤¨ḄᓄL&ᜐᳮ¥©஺ªᓄᜐᳮḄᑴ¬ᐹᨵ¯°ḄὊ²ឋஹὊµ¶ឋஹὊ⇨ឋὊ¸ឋ஺¹ºᑡ¼⚪¾(1)HÀÁÂḄᓄᜐᳮ!6Fe(CO)3(NH)=2FeN+18COt+10NHf+3Ht஺32332জᐗÈCஹNஹOḄᵯÊឋᵫÌᑮᜧḄÎÏ;NH3᩽᧕Ó$ÔḄ¢Õ'oঝN%ᑖ£Ḅרᵯ£uØÙÚÛN¢£Ḅᩖᓄ'஺ঞÝÞßᵯ£Ḅàᑖ᪆Fe(CO)3(NH3)2ᑖ£âᙠḄᓄLhãÛ'ᐸ஺hᐔhḄᦪjæ஺(2)HÀFeNḄᨔèé᪀NaClkë,FeNᨔYḄFe¢£é᪀᝞:

14জHÀஹḄìᑮìíîᵯïDᑖð':^ïDL/(kJmoH)MkJ.mol1)ᐗÈN1402.32856.04578.1O1313.93388.35300.5ᐸஹḄhtLḄᜧÌòóôḄ¢Õ'஺ঝõöFe¢£ᕜøᨬúûlüïḄN¢£ᨵö஺ঞHÀFeNḄᨔèýᦪ'a=0.38nm,þḄ/gcm-3(ᑡCÿ
,ᦪḄ6.02X1023)஺35.ᨵᱥF(0)ᙠឋḄᶭᨵḼ"⌕Ḅ$ᵨ஺&'()*+,-✏/ᓄᔠᱥB234ᧇᑴᜓFḄ89:᝞<=>?@᮱CMOHhOB.Ann⌼DE.ETTl..Uiᔣ~~------------RCH஺+&CH?CHOLMNORCH=CCHOPQ=Ri(1)*+RᡂAḄ4Tᑭᵨ᳛100%,ᑣXX(Zᓄ[\)OF]^_`aḄbc.(2)E—FḄd$ef,BḄ᪀h\,iEḄbcᕸᖹ⏚OmIFḄbcX.(3)ᑏoDpNaOHMqd$Ḅᓄ[rs\=.(4)Eᨵtuvᑖx᪀yOzᔠ<ᑡᩩEḄvᑖx᪀yᨵuOᐸ᪶ᐳᨵ6ḄᱥḄ᪀h\஺জ`Rd$ஹd$Imolᱥᨬt4o4moiAgঝ⍗FeCbMqR⁐d$ঞᑖTᨵᵬ2O(ᨵ22

15(5))*+234ᧇOᔠᡂ89ᔠᡂ2-+⏚Oᑏoᔠᡂ89=(ᐸ¡ᑺ£⌱)஺36.¥ᩰ§¨*©ªᔠ«(II)X¬e^yOᙠᓄ&R®ᨵḼ"⌕Ḅ¯ᵨ஺Lᐸ°±^²³ᔾ^⛳,ᑴ¶᪵¸Oᙠ¹ឋ²y᛻O100g᪵¸OᵨWinkler»¼½᪵¸]^¾(ᔾᦈḄ^²Ḅ¾)OᡠᵨÁ°᝞:ᡠÂ(ᜳᢝÁ°ᶍÆ)஺PQWinkler»ÇÈḄÉᑖd$Ḅrs\᝞<=Mn2++2OH=Mn(OH)J(Ê⁐)22Mn(OH),+O=2MnO(OH),24Mn(OH)+O+2HO=4Mn(OH),222MnO(OH),+21-+4H+=Mn2++I+3HO222Mn(OH),+6H++2F=2Mn2++I+6HO22ËÌ<ᑡÍ⚪=(1)Á°ÏÐÑÒOᐭÔ¸Õ◤×ØḄÙ¯X஺(2)ᙠÚ100g᪵¸ÕOᐜÜᐭݾḄN?,ÚÒO⌕ÞßÜᐭNz஺ÚÒÞßÜN2ḄàḄX(3)Á°AtáᳫãḄ¯ᵨX,pᑖqäᧅæçOèᵨឤêëqäᧅḄÑᜐX.(4)d$¬íîïÒOᐭ50.0mLð¾Ḅñò⏚Oᐙᑖd$ÒOᨬÒôᔠMq30mL,ᵨ2.0molE1ḄNa2s2஺õ᪗÷Mqë½OᵨÆ50.0mLNa2s2O3᪗÷Mq஺(øᶍMqyùúᓄ)জ⌱ûḄᢣÂᑺbcOᑨþÿᑮ
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Ḅo4ঞ᪵Ḅ!mLgT(᪗$%&)஺37.)*+,!ᨬ.Ḅᐗ012ᐸᓄᔠᱥᙠ7ஹ79ᵨ;<஺(1)=᝱)?Ḅ@Aᵯ᣸DᐸᜐFᨬGHIḄᵯḄJK%᝱(L”NO”ᡈ"N”)ᨬGHIḄᵯ᣸D⍳SḄ?ᳮᡈUᑣ*

16V2X),*ᔠᡂZḄ?ᧇᙠ\.ឋ^_`COᓝᑖNefᙠghNeឋḄ?i*஺ᑏkCOḄᵯloCOn?᧕`pq?rᔠ7ᡂsᔠᱥtᑏkNiVCOX4Ḅx᪀l஺V3XNH3VZXஹN2H4VῃX*)ᐗ0Ḅ}~ᓄᱥᓄᱥ)?Ḅᩖᓄᑖஹ;N᩽᧕FH?i*V4X)ᓄVNaN3X}ᵨFḄᐰ,ᐸᨔx᪀᝞ᡠ஺NḄsᦪ஺¡¢£¤¥¦}ᦪḄ§NAᑣNaN3Ḅ¨©*g-cm3Vᑡk¯°X஺38.ᨵ³ᓄᔠᱥM*µᶭូឋ᷈Ḅᔠᡂ¹ᱥ஺ᑴᜓMḄᔠᡂ¼½᝞ᡠlPBr.IIÂÃlRCOOH—►R—c—BrRÄ=XV1XAḄᓄÇÈÉ*oV2XᵫA7ᡂBB7ᡂCḄËÌᑖ*V3XᵫC7ᡂDḄᓄÇ*.V4XᑏkEḄx᪀Ïl,X*EḄOᑖÒ᪀ÓÔXÕÖ×ᑡᩩÙ:জHÜ7ÝÞঝ⍗àFeC%äå⁐ঞᑖx᪀çènéx᪀஺

17êᔠ_ëᩩÙḄXᨵᐸ᪶íᐳïðñᨵ5óOᓄÇé᛻Ḅõ☢÷2l2l2l1l1Ḅx᪀Ï*.CH,UCHjøJ”IIIV5X᪷û⚪ýþÿᑏᵨCH3CHONHLCHTHᧇᑴᜓCNH—CH—ClhḄᔠᡂᐸᑺ⌱!.#ஹ%&⚪39.)*⏚,NaNO?!/012Ḅ3⌕ᡂᑖᙠ78ஹᵯ╄;<☢>ᵨ?@஺%&BCᩈEஹF*⏚ஹNaN023⌕ᧇᑴᜓ)*⏚,ḄIJ᝞LᡠN஺OᑖᜳᢝIJஹ#⚠STUVIJᙳXᶍZ!1!BIJḄ^ᵨ/«2!CIJ`3⌕a>ḄᓄcgCIJ`hᡂḄij◀NaNO?᜜mnohᡂpᓄce!qrshᩖu>᝞vᦋxyIJz«4!%&|}gᡭAIJ`ḄᜳᐭN?ḄḄ/஺5!%&`ᵨ15.6gNa?஺?a>hᡂNaNO?Ḅu8,!g,ᑣNab஺Ḅs᳛ᶇ#ᨵᦔᦪ!஺40.¡¢[CU(NH3)3CO]+ஹ[CU(NH)2]\[CU(NH)]12\NH3ஹCH3co0-ஹCO;§`¨ᦈ334Ḅ0ª«d᝞¬:过滤洗涤干燃⇧!

18প¯°(1)“ᔿῃ”ḄḄ/(ᑏᩩᓽn);ᵫ¯°(II)nº»NH3H+Ḅ|ᔠo¼½CM+Ḅ(p“¿”ᡈ“Á)(2)¯°(1H)“”Ã,Na2sḄᵨ½ᳮÅᵨÆḄ/஺(3)¯°(IV)a>`ÇᓄsᱥmsᱥḄᱥuḄɽ஺(4)¯°(VI)Êha>hᡂËÌCu2(OH)3clḄÍÎḄᵯ᩽a>e;ÛUNaCIH2SO4ᙳnÒÓᵯã᳛ᵯ«ᦔ᳛ØÒÓḄ¨ᦈ᳛ä᛻æçὃ⇋êëḄ/(p“NaCI”ᡈ“H2soJ)஺41.ì⏚/íî⌕Ḅ01ᧇnᵨïᑴ⌼ñᧇஹòóஹôᧇஹõᵯö;஺¨÷¬ᑡù⚪(1)úûüýþÿ
Ḅᑴ⏚᝞“᮱(CuSO5HQ)4ᱥᡧᐸ!"#᮱ᓾ%&'…”"”+ᢣ,.ᑴ⏚ᳮ01ᡠ3⏚45Ḅ56ᑖᦪ9(Ꮇ;<=Ḅ>᝱<ᱥᐰA'BCDEᶇGHᦪIJK)஺(2)1746NOPQRST⌼VWXᩭᑴZ⏚஺.ᑴ⏚[\Ḅᐵ^+SOzḄ_ᓄabᑡde1.2NO(g)+O(g)NO(g)A/7|=-113.1kJmof22II.SO(g)+NO(g)SO,(g)+NO(g)AW=-41.8kJmof1II.III.222জᑣde2SO(g)+O(g)SO3(g)ḄAW=kJmoF122ঝᙠ460࠷vdeSO/஺+NQ(gSQ(g)+NO(g)Ḅw⊝yᦪK=85.0,ᙠ10.0Lឤ{|}{ᘤᐙᐭ0.10molSOஹ(IfimolNO,ஹ008molNO0.12molSC^g),vᖪQ=2,vOEj_______________Ớ(h“Vᡈ“=”)஺ঞᨵRὅp9WXᑴ⏚Ḅde[\9I.2NO+O=2NO22II.2SO,+3NO+HO=20NOSOOH+NO222III.20NOSOOH+HO=2HSO+NO+NO,,2224

19de92SO,+O+2HO=2H,SO224NOᙠdeḄᵨ+,ONOSO20H(⏚)ᐗḄᓄᔠ9.বᵯ᪆Na2sO,9ᧇᑴZH^SO"NaOH4Ḅ᝞ᡠ(BP9᩽)஺X9¡(h“□"ᡈ"▢")¤ᣚ□᩽Ḅᵯ᩽de¦9(4)ᙠIஹIIஹIH§¨{©ª«Ḅឤ{|}{ᘤᢥ⊤Ḅ6ᢗᐭdeᱥ¯°ᑴªeḄ±
=de2SO(g)+O,(g)SO,(g)AW<0.2{ᘤூ{ᘤn{ᘤinde±T400࠷400࠷500࠷deᱥᢗᐭ6n2molSOஹImolO4molSO32molSOஹ1molO2222w⊝vc(SC)3)qmolL1c2moiL1cmolL13ᱥ5Ḅw⊝Íᓄ᳛aa,SO2
«2ÏSO3
«3ÏSO2
ᑡ²³´µḄ+(h¶·)A.a(SO)>/(SC)2)B.c=2c;}22C.c<2CD.a(SO)+a(SO)<123233242.Ca(N0)29¸⁐ᨔ»᧕4½¾¿4½À⏣ᐹᨵÃÄḄ_ᓄឋÆᵨ¾ÇÈᓄÉÊᑺ2■ÑÒ┤ᑺÔ஺Õ᪥«RᑭᵨᦻÙḄÚᐺde“Ca(NO3)2+2CaFe2CU+4NO==3Ca(N0)22+2Fe2O3”ᑴᜓÝÞḄ⏚┛àá᝞ᡠ

20âãᑡä⚪Ï1çèéêᐭëìí◤ÊïḄð+஺Ï2çAᑴZNOḄᓄR\¦9.Ï3çB¾Ḅᵨ+÷CḄᵨ+.Ï4çàáúûᑮE4ᵫÿ⁐
⁐⍎UEḄ.MnO_,#$%MnOj,NO#)ᓄNO+,஺5,■0᎔ᔾ3045678Ḅ9:;.6,=>D@ḄABᓾ@DᑖFGᑮIJ⏚┛MN459:6◤⌕ḄQᴻSᘤ◀VW᜜$◤⌕.7,Z[CaNO,2_`ᩖbNOcḄbdᑖᦪᒹgḄhiᨵk2জmnagCaNO2,2_`pMqஹᵨNa2s஺4v┛cঝᵨxydNH4cl}~◀NOcNHc+NO,=NT+2H,O,c2ঞBᓾ@ᐭydVimLcimollNH,,FeSO,2MN⏚24NOc+3Fe2++4Ht==3Fe3++NO?+2H,O,cটᐭ〉d⏚ᢣᑺN-ᵬ⏚,ᵨc2moi1¢20207᪗¥MN¦[ydḄFe2+KzCr?஺#$%C/,,«¦[¬6®ὑKzCnCh᪗¥MNVzmL஺Z[_`NOcḄbdᑖᦪᑡ²³ᓽµ,c¶hiঝ·ᐙᑖ}~¹NOc◀ºᑣZGḄ¼½¾“Àᜧ”“À¢”ᡈ“Ä
’,஺43.PH?;ÇÈᩔÊᜐᳮ6ÍᵨḄÎÏᩔÊᑺcÐ᯼
ᣚ6_ḄP&Ô¹ÕᓄᑺÖ×Øῃ◀஺ÚÛÜᑡÝ⚪k1,PHஹßᐭNaClOMNῃ◀PH,6)ᓄ_ᱥ;áâg)⏚)ᓄᑺã$%ᑺḄᱥbḄdäå4k1,ᑣæg)⏚Ḅᓄç஺2,ÜᑡèÔᦪéP,ê,ᑖ¼᪀kᓄçèP—PH—HP—H0

21èÔ/(kJ-moó)213436322ᑣ4PH3(g)F\(g)+6H(g)AH=kJmol1cíîï6ð⊝ò2c(PH,)=0.25molL',c(Hj=c(R)=0.5mol-Löᑣð⊝ÍᦪK=஺(3)ᦻøù⍝“0.65CO(g)+Fe,O(g)+3PH,(g)=3FePO(s)+4.5H,O(g)+6.25C(s)”;û244üýÖḄþÿ
ᐸ⊝ᦪKpᑖ⊤Ḅ⊝ᦪ)ḄᦪḄᐵ᝞ঝIgKpᑡᵨᑖMCOJஹ!(PH,)ஹp(HQ)⊤Ḅ#$%&஺(4)
(CH)AUPH——>(CH,)AUPH+CHḄᔊ*᝞+332(I,-.:(CH)AUPH,—^.(CH,)AU+PH+(0
)333,1.:(CHஹ)3AU—2H6+CH3AU(᠒
),3.:CH,Au+PH,AuPH+,(0
)জ
Ḅ56ᱥᨵP9ஹ_஺ঝ,-.(;“-”“1”ᡈ“3”)
Ḅ?ᓄAᨬᜧ஺Pb2+,Cu2*(5)ᵨCiP+ஹPb2+EFῃ◀PH3Ḅ
:PH3+20Z^=H3PoᐸIᩩKFLMNOᙠNE40ḄQRᑖᦪஹPH,ḄSᓄᦔ᳛M5Ḅᐵ᝞ᡠ+2O'ḄQRᑖᦪᜧP&ḄSᓄᦔ᳛WḄXYZ(ᵨ[\ᳮ^_`a)஺44.₝⏚efᨔQ(FeCQrZHQ)ᙠhiḄNO0.22g/(100gi)ᙠjiḄNO0.026g/(100gi)ᐹᨵlmXឋoᵨp᯿Frsᑺ_஺uᓄv9wᑭᵨyfz{#᝞|}ᑴ

22ᜓ₝⏚efᨔQ஺ᑡ⚪:(1)ᘤaḄ,|}dḄpᵨZ«(2)◤yfzᙠ5%ḄNa2cO3NEjᯠᵨi¡SᑣNa2cO3NEḄpᵨZo(3)ᡭ¥K!Kᐵ¨K”-©M5ᐵ¨K+,ᡭ¥K2஺ᑴᜓ₝⏚efᨔQḄᓄvª*%v««*6¬ḄH?Ḅpᵨᨵஹ0(ᑏ2ᩩᓽo)(4)³c´ᑮḄ¶·◤ஹ¡¸Mᨬ¹⌱ᵨᑡ»ᑺḄ(;¼½)஺¾¶·Zᔲ¡SḄÀpZ஺a.Á⏚b.hic.ji(5)ᦻÄrFeGO!2HqÉjᑖOMÊQḄËÌÍÎᓄḄÏÐ᝞ᡠ஺ᑏjᑮ400࠷MFeCO-2HqÉjᑖOḄᓄvª*%஺2445.ÔÕᐸᓄᔠᱥᙠ×ØÙÚஹÛÚ¬6ᨵḼÝÞḄ
ᵨLMßZàᵨḄá⌕»ᑺ஺পKMnCUZlçᓄᑺᐸNEc(H+)=c(OH)ᑣ0.01mobL-1ḄHMnCUNEḄpH=o(2)MnSᵨì◀íîiḄPb?+_áðñòó:Pb2+(ô)+MnS(s)F^PbSGHMi^aq),øù«ᜐᳮḄic(Mn2+>lX10"ᑣc(Pb2+)=[
K(PbS)=8X10-28>Kp(MnS)=2spSX10l3]o(3)ᱥḄ!⌕#$ᐗ&'ᵨ)⏚═,-./01ᱥ2$3410%~15%஺9:ᔆᑭᵨ=ᦈḄ?@ABCᵯEᡂ)⏚BᨔH(MnSO^HzO)ḄMN᝞PQᡠST

23জMnSCMVWᨵḄᓄZ[\]ᨵ஺ঝ_`IIḄa⌕ᡂᑖ'_`Ic/d⁐ᓫg'“ij”lNVmᓄ2ᱥFe3+,ᑏopqrqḄstuNv:xrqVMnOḄyᓄ᳛{|}~Ḅᐵ᝞2PQᡠS'ᑣ〉Ḅ|}()஺a.40࠷b.60࠷c.8O࠷d.100࠷ঞ“┶”Vᨵ⁐ᕡḄHᡂ'iᨵMnCO36Mn(OH)25H2Oᡂ'ᑏopqrqḄᓄZuNv:஺46.cᝅᔠᡂ'ᔠᡂ:¡¢£¤\Ḅ|⛳¦⚪o᩽ᜧª«஺=¬Pᑡ¦⚪Tপ
Tজ1go¯ᐰ±²ᡂH2O(g)³oফkJḄµ$;ঝN2(g)+O2(g)=2NO(g)·H=+180.5kJ«mo¸;ঞ4NH3(g)+5O2(g)=4NO(g)+6H2O(g)·H=-906.2kJ•mol1,:ᔠᡂḄµᓄZuNv஺(2)qᵨᓄ¹±ᧇ(ᱯ¼᯼)ᑴᜓḄjᧇH2VWᨵᩖgÁ(a⌕ᡂᑖ¡CO?)ஹᩖg)(a⌕ᡂᑖ¡HS)O:ÃᵨÄÅῃ)ḄuÅ=ᦈ)'uÅᐜᵨÈÉ,-ᔾᦈH2S,1~yᓄ¡NaHS,ᯠÌᵨ2ÍÎ⏚Ï(NaVCh),-mᓄ)ᐗ&'1~yᓄ¡)ᓫg'ÐᡂᯖÎ⏚Ï(Na2V4஺9),ÄÅῃ)VÒḄmᓄijrqḄᓄZuNvrqVyÓ2X103moiᵯtÔ'ᳮÖ=ᦈ)kg஺(3):ᑭᵨNE¡jᧇᔠᡂ×&'ᐸjᳮ2NH3(g)+CO2(g)k^CO(NH2)2(D+HO(g)«জÙ02⌮rqḄÛ⊝Ýᦪ(K)ß|}(T)Ḅᐵ᝞PTT/࠷165175185195K111.974.150.634.8ᔠᡂ×&Ḅrq¡(“³µrq”ᡈ“ᔾµrq”)஺

24ঝᔠᡂ×&ḄjᧇVNH3ßCChḄᱥgḄ$~áâ¡Áá'0ᵨoãJ⊤S஺ᙠcæ|}ßn(CO)2çèP'QᵬVêë(“I”ᡈ“II”)⊤SḄÁá{CO2Ḅyᓄ᳛যḄᐵ'ᑨîᳮᵫ__________;ñò3=4Ô,NH3Ḅyᓄ᳛¡____________»«(C0)2(4)ᑭᵨᱯõḄᩞᧇ,÷lᵯᓄZÅø0ùᔠᡂ'᝞QúᡠSjᳮ0ᑭᵨN2ஹH2ஹCOஹûüᔠᡂ஺□᩽rqv'stþᣚ
Ḅ(ᓄ)஺47.⏚┞(LiFePOJ┞ᵯḄᵯ᩽ᩞᧇ஺ᐸ
!LiFePOḄ"#$%4᝞'ᡠ)*+ᓄ,-./ᑡ1⚪*(1)3456ᧇᙠ89:
Ḅ89;᳛=>?@AḄBCᨵ(ᑏFᩩᓽ>)஺(2)!$%
=IJজᒹMஹOஹPQ஺(3)ᙠRST
UᡂOIJWᡠᵨᑮḄấ⏚[\ᘤᨵ஺(4)ᑏF^_᮱
a89Ḅᓄb%c஺(5)d⁚LiH2PO,fgḄPH=>?hᑮijkḄᱥ=mnᔜkᱥḄᑖqᑖᦪ(s⊝WukᱥḄvwᓰᔜkᱥvwyzḄᑖᦪ){pHḄᐵ}᝞'ᡠ)஺জ3~h>ḄLiH,PO,,LiH,PC)4fgḄpH9ᑴᙠ

25ঝ᪷')=▢HPO*ḄᵯᦪK,Ḅᦪ3oঞLiH?PO,fgឋ=ᔣfg
ᐭḄCad,fg=fgᑣ⏚ឋ=6(ᵨb%c⊤))஺(6)⏚┞ᵯ893FePOj+LiLiFePOq,ᵯ
Ḅᵯ>L஺ᑏFᵯqᐙᵯᵯWḄ¡᩽89co¢ᵨᵯᵯ£⏚¤fg=¥▢᩽᪆F3.2g§¨¤W=ᵯ©ὑ┞Ḅ3஺

26«ὃ.ᫀ1..ᫀ*C᪆*2..ᫀ*B᪆*ᵫᓄ892NO+C>2=2NO2>n=2moiNOz1molO?Uᐰ89ᡂ2moiNO?,°ᵫ±²ᙠ892NO?Nq,,ᒕ´µ¶ᑖᦪ·±2=A┯¹;ᵨ»ឋᵯ᩽ᵯCuSO¼fg=ᐭ0.2molCMOHb½¾fg¿6=ÀÁᵯCuSOafg=ÂᵯÃ=▢᩽Äᡂ0.2molCuz0.2molH,ᡂ0.2molCuÅÆ0.4molᵯ=ᡂ0.2molH?ÇÅÆ0.4molᵯ=ᦑᵯ%
Å2ÆᵯḄᦪÉ30.8NAB¡Ê;Ë/ᵯ⛳zÍ[Ã=¥fgpHÎ7ᓣ5ᑮ13W=c(OH)=0.1molHfg¶ÐÑn=ÅÆᵯḄᱥḄÒÓÔÕ=C┯¹Ö1mol×ᾦ⏚ᵞÚÛᙠឋᩩÜ/aḂᓄ89=ÃÞß=ᡂ3mol×ᾦ⏚[z1molàá⏣/molàá⏣
kᨵ3mol-OH,D┯¹஺3..ᫀ*B᪆*X¨±Ûäᱥ=if±Ã=ᙠ⏚ឋᡈឋfg
ᙳ᧕aÃ89èé=AஹC⚗¡ÊÖᵫ±X
kᨵëì_᪀=ᦑîi>ï⏚ïÛḄj}ᱥ=B⚗┯¹ÖC4H9c0஺<>>(0.H7.{XḄᑖcñj=îXḄjᑖò᪀¶=D⚗¡Ê஺4..ᫀ:A᪆*X᩽3▢᩽=Y᩽3□᩽=□᩽ÄḄᵯõö÷▢᩽ÄḄ5=A⚗¡ÊÖᵯW=H+ᔣ▢᩽(X)Æø=X᩽ᕜúfgpHûü=B⚗┯¹Öᵫ'n=X᩽Äa89*Fe"+e-=Fe"ᵯ,C⚗┯¹Öᵯ8932Fe3++2Cr=2Fe2++CLT,D⚗┯¹஺5..ᫀ*A᪆*᪷⚪ýþÿaஹbஹcஹdCஹ0ஹNaஹALO2\Na\AḄ᪶᜜ᵯ᣸ᦪᜧA⚗Ḅឋ"#$B⚗┯&'ᓄ)Ḅ*ឋ"#'ᓄ+C⚗┯&COஹCO2ᙳᐳ.ᓄᔠᱥD⚗┯&஺6.4ᫀ6C7᪆69:;<=ᨵHCOஹHSOஹSO6?@ABᡂDEFGᮞIJKLḄMNA┯&H2c2஺4Oᵯ7PQᑏSTUVWXYZḄSTU[\2MnO+5HCO+6H+=2Mn2++10COt+8H2O,B┯&᪷^_`ab“deᩩWgh”jklNazSiChᐹ2242ᨵngḄoᵨjᵨo■rᑺCtᤍ“vw”V“vw”ᑁyBzᵯᓄ{|[}~᩽~᩽NaClIᡂḄNaCl:;\ᵯ7P:;᩽yBḄ|[\஺2+4+2H2஺=40,ᦑ“vw”yvḄ\~yBᔾῖ⇨D┯&஺

277.4ᫀ6C7᪆67⚪ᐵ1g+[Ḅᓄᡂ[Ḅc(H+)c(0H),¡ᣚ£¤:¦§<Ḅabcc(H+)/(mol'L1)IX1013ixio101XIO-7c(OH)/(mobL1)0.11XIO41XIO7c(NaOH)=0.1moPL1,ᦑº»I¼⊤'ᓄ)Ḅº»A⚗ᵫ⊤Àᦪ^¤B⚗b:;ᕈ⏚ឋÄIÅÆÇT<*ឋÈOc(OH)Èc(H+)ÉᜧC⚗┯&c[Ḅ:;ᕈ<ឋc(H+)=c(OH)=1X1O7mobL1,c(CD=c(CH,NH)=8X10-2mobL1,D⚗஺8.4ᫀ6D7᪆6K4[Fe(CN)](Ó⊈Õ)Ö×KCNᨵᒓ×A⚗┯&IXÙÚ|[Û'MÜ6XÝᵯWXᵨ#ᵯᘤßrB⚗┯&àáÇâãäPJឋåæAᜫèÙឋC⚗┯&éêë;᝱CO?î⁐:ᑺÖ×ð᧕òᾦᑖD⚗஺9.4ᫀ6B7᪆6XḄö᪀<=ᨵ$$øjùDúḄûüᓄ$:;ý⁐þY
Ḅᓄ⁐,A⌱⚗┯;XஹYḄᑖᙳ0HO,!ὅ#$ᑖ%᪀'()ᱥ+Ḅ,ḄXஹY-ᐰ/hi0(ὑ2,3$(B⌱⚗567᪷9:Ḅᡂ<ᱯ>(?@ABXᑖCᡠᨵ:?
ᐳG☢,C⌱⚗┯;YC?J:KLḄM:ᨵ8O121,D⌱⚗┯஺10.Vᫀ:CY᪆7a\]⁐^'(_ᓄᔠᱥ(ᦑacᓫ+defg᠒ij(?ᑴ⌼᯿no(ᦑcMg,ᓽZMg,YNauf^'ᓫ+(᪷9wCᔜᱥ+Ḅyᓄᐵ{(ᓽ“}~”ᱥ+?fCᓫ+(ᦑWC,XOuᓽyᓄᐵ{wCbCO?,dNa2co3,eO?,gMgO஺7O2->Na+>Mg2+,A⚗┯uឋ7C<0,B⚗┯uNaOHឋMg(OH%(C⚗56u0ஹNa?ᡂNa?஺ஹNaO,ὅ<(ὅ<ᐳ<(D⚗┯஺2211.Vᫀ7AY᪆7A᪗¡¢£(¤ᵬ¦ᕈ¨᝱(1ªCH3clᑖ4ªᐳ<(n(CHC1)=0.5mol,ᑣ3ᐳ<ᦪ´2NA(A⚗56uFed¶,·¸⏚ijºᡂFe(NO3)3,n(Fe)=0.5mohy»ᵯ1.5mol,B⚗┯u1molⅅ¾fYºᡂ1molℍ⃔¾1molÁ¾(C⚗┯uᵫSᐗÅÆឤ(S2'

28ஹHS-H2sᐳ0.1mol,D⚗┯஺12.Vᫀ7BY᪆7ÊËaCÌ⏀ÎÏ(ᦑÐ═⏚Ò
ᵨMnO,LÔ(A⚗56;ÊËb◀ᩖÊË(ÊËbj×Ê⛳NaCl(◀ÙHC1.B⚗┯;ÊËcCÚÛºijCl?+Na2s=2NaCI+SJ,Þn2ᓄឋCl>S,C⚗56uᨵß(NaOH?@ᔾᦈ■ãᐸåæç¨,D⚗56஺213.Vᫀ7DY᪆7èÊËéê᜜ìᵯíîï(ᵫᵯ
yðᓄñ
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ÛºḄᵯ᩽ij᝞£72cH4-4e-=C2H4+4H+72cH"2e=C2H6+2H+,CH+HO-6e=CO+6H+uCH+2HO-8e=CO+8H+,42422ºᡂC2H4ஹC2H6ஹCOஹCO?ᔜImolý(y»ᵯ20mo1,ºᡂH210mo1,D⚗56஺14.Vᫀ7CY᪆7ᔣH2ACìᐭNaOHý(c(HA)⌲
c(HA)ᜧᓽᜧ2C(HA)2(M)c(HAD
c(A=)ᜧ1g2
(N),A⚗┯#$c(A2-)E(c(H+)c(A2-).(.c(H+)c(A2-),|c(HA-).,...0vᵫKa2(H2A)=-----------1gKa2(H2A)=1g-----------------------=-pH-lg---;-=-3-1.3=-4.3,Ka2c(HA)c(HA)c(A2-)(HA)=5XIO?,B⚗┯#$:K$,2(HA)=5XIO-5,<=>?@AᦪKh(NaHA)=K/Ki22WaᜧNaHAHIᕈ⏚ឋc(H+)>c(OH),C⚗OP$ᙠaRSlgপU)=஺(ᔩ)=1.5,ᨵcC(HA)c(A2)2(HA)>c(A2')=c(HA),D⚗┯#஺215.ZᫀC@᪆”^_`ab……᧼efᮞ”hi“kl”ḄᡂᑖᩭqrsᱥfᡂḄᮞ“uv?wx”hiyᡂᑖ᧕Hr?“{ᑣ}~᝞k……⊟☢”hiyᡂᑖ⏗ᑺᡠ“kl”Ḅᨵᦔᡂᑖ⏚AOP$ᑁᒹklḄᑴᵨ⌶BOP$ᑴᒹ¡(¢£¡?)ஹ¥(¦§)ஹᰀf(᧼efᮞ)©ª«¬ᨵ®¯°ᨔªC┯#$⏚ᵨrᑭᵨ³ᐸ?@µlឋ⏚¶ᵨ⏗ᑺ·:ᐸ¶u¸☢¹ᨵº⏚»¼½ᡂCO2¾¿¿Àlឋ,DOP஺16.ZᫀC@᪆CH3cH=CH2?»¼½ᡂ(CH)2CHOH,Âᨵº»¼ḄÃᓄ᳛ƶÇᑮ100%,A⚗┯3#$:ÆÊ⍝HI¿ÌᦑÎÏÐNa+ᦪÑB⚗┯#$NO.CO2Ḅ᥅ÓÔÕᙳ44g•mol2ÚÛᑖÜᙳÝ3ÛvÜᦑ6.6gÞᔠ¾¿ḄᱥÔḄÕ0.15mol,ᡠÝvÜḄᱥÔḄÕ0.45mol,C⚗OP$1molà2ஹ1mol2H2ᙳÝᨵ2moiÔÜD⚗┯#஺17.Zᫀ:B

29@᪆ᙠ50ã110࠷åæçèḄ<ÛévÜê<ÛëvÜìAhOP$ᵫ°᪀îï¶ÊXḄᑖÜïCioH^Br,ᑖÜᨵ3ÛÆ⛳¸ñòóᨵ4ÛÆ⛳¸ñᦑᐸôᑖõ᪀¿Æ¶Ýᨵòó,Bh┯#;Xᨵ3öᓄ÷ó᛻ÆôḄévÜᦑᐸ<ùìᱥᨵ3öChOP$ᵫæçèḄ°᪀¶Êæçèúᙠ4Ûûᐗó,DhOP஺18.Zᫀ:D@᪆19.ZᫀD@᪆ᵯ᩽ÿ▢᩽ᙠᵯὑᵨᵯ᩽A⚗┯᪷C/+ஹHg2+,ᦑᵯ"#▤%▢᩽Ḅᵯ᩽'()*Hg2++2e=HgஹCu2++2e==Cu,B⚗┯+,-.ᨵ01C/+ஹHg2+Ḅ2ᦑ301ᙠᵯ4▢᩽5ᡂᱥḄ82C⚗┯ḄC/+ஹHg2+ᙠ▢᩽:;᪆=□᩽Alᜫᵯ@5ᡂA13+,ABC▢᩽'((2HO+2e2==H2t+2OH)5ᡂḄOH-5ᡂᐹᨵᔾ▬GᵨḄAl(OH)3HIᔾ▬ḄJᱥK45ᡂḄH2ᡠM5ḄNOPQRᑮPTḄGᵨUVWXOḄYZᱥ[Tᑮ☢D⚗]0஺20._ᫀ:C᪆bᵯ@cd᪀fKḄg@;@hᦪjᜧlmjOg@lm:Cr>K*,Ano]0ᵯpᓄrstuCjvwKOH,Bno]0ᵬKH,ᡠᓄyzg@z{KOH,ᡠᓄyzg@zwᐳ}zCno┯;HQᑖ@ᙠz:HQ>HC1,Dno]0஺21._ᫀbB᪆b'(4st⏚ឋᵬ⁐3.1~4.4,⏦⁐8~10,A⚗┯astpOH=14-pH,BP-lgc(0H)=14-11.12=2.88,a=C(OH)/0.1mol-E1=10*188,ᑣIga--1.88,B⚗]0ᙠbᜐc(NH)=c(NHHO),32C(NH)C(OH)=vC⚗┯'(ḄᵯgWᜧ4C(NH-HO)V'IO-92632'(4ḄᵯgW¥ᑮᨬᜧ'(B§OD⚗┯஺22._ᫀbD᪆bt᝱©ᵨG᪶'(ᚮḄ¬®8A⚗]0NazFeCUᐹᨵ¯°ᓄឋᵨ±²ᵨḄ³ᐸ:;MᱥFe3+5ᡂḄ°ᓄµHI3ᔾ▬¶Tᩖ8ᵨ±²ᵨḄ¸ᓄ,B⚗]0;ℍ⃔⏀½¾〉2SO2,Rᑮᢙ°ᓄwᢙÁḄGᵨC⚗]0°ᓄ┛ᙠḄsWÃOÄÅᑴÇÈÉḄÊoËpPÌᐭᮞÏD⚗┯஺23._ᫀ:A᪆bÐÑNeஹNH3ᑖ@ᙳᨵ10Ñᵯ@᪗ÔZÕÖ2.24LPIO.lmoLA⚗]0KH+H2OKOH+H2t,1molKH×ᐰ'(4ÙÚÛImolᵯ@B⚗┯ᵞÝ3ÑÞImol

30ᵞÝᨵ5moic—HzC⚗┯stIåæD⚗┯஺24._ᫀbD0/\᪆bᵨAgGëᓄᑺ,íîw°Pï5'(2cH2=CH2+O23~>2H2(J-CH?,;@ᑭᵨ᳛100%,ᦑA]0;aḄᑖ@úC2H40,wíû(CH,CHO)Kᑖü᪀IᦑB]0íþ⏣
⏚ᙠᩩᓄ()ᡂᐗd,ᦑCdḄᑖ!"#C4H4O4,1mold,ᐰ./ὑ12#3mol,ᦑD┯6஺25.;ᫀ=C>᪆=@ᵯ>BCDECO2Fᓄ#HCOOH,GᐗHᓄᔠJKLMᑣC02@ᙠ▢᩽RSᵯ!ḄTUMᡠWSnᵯ᩽D▢᩽MᦑAPtᵯ᩽D□᩽M□᩽R1ᓄM□᩽RḄᵯ᩽"#2H2O-4e=O2t+4H+,□᩽RᡂḄH+bᵯ>cdHCOIH++HCO=CO2t+H2O,ᦑB▢᩽Ḅᵯ᩽"D2H2O+3CO2+2e-=HCOOH+2HCO,ghᣚj#□k!hᣚjMᵯ>lmnoM□᩽pḄK+rs□k!hᣚjtuᑮ▢᩽pMᦑwḼM▢᩽pKHCOyz{|MᦑC┯6,D஺326.;ᫀ=A>᪆=ᵫXḄ+1J□k!ᵯ!᪀bU!MX#ᐗH஺CH4ஹSiEᑖ!Ḅ᪀#☢MᵫU!ᦪ⌴MR#GᐗH஺ᵫGdXஹZᐗHḄ2#23=16MZ#ᐗHᡈ1ᐗHMᵫ2ḄU!ᦪᜧX,ᦑZ#ᐗH஺ᵫ¢£ME#¤¥¦cMF#¨¤⏚¥¦cMAl3++3A1O+6HO=4A1(OH)3IMY#¤ᐗH஺U!ª«=Na>Al>C,A⚗2⏚ឋ=H2sOOH2cCh>Al(OH)3MB⚗┯6Na+Al+2HO=NaAIO+222H2t,᝞µஹ¤¶ᱥḄ2¸ᔠMាº,ᐰ¦»MC⚗┯6¼ᓄ¤½¾ᵯMm¿Rᵯ>ᰚÁ1ᓄ¤ᑴᜓ¤MD⚗┯6஺27.;ᫀ=C>᪆=ÅÆÇedBÈÉᮞMᔾᦈÍdḄCO2ஹHO(g),ÏÐÍdḄCO2ஹHO(g)b22┞MA⚗┯6ᐜÓᐭÕÍM᣸×BCᑁÍMÙÚ.⏀ÜÝMB⚗┯6Þ⚪àMᐜ◀ChMÙ◀CO,ᨬÙÅÆMᵨy⏚ÅÆÕÍMC⚗COᙠäåæçḄèᴻÇêëᰦíMî᜜MCOFᓄᡂCO?MCO2b┞MD⚗┯6஺28.;ᫀ=(1)5s25P5(2)417=2(3)OCN,SCN-ஹN(òᑏôMᐸöᔠᳮ;ᫀø)

31HH—N-H—0(4)(5)HIOúû┵ý3;>᪆=(1)þÿᐗᵯᨬ᜜ᵯᦑᐸᵯ᣸5s25P5஺(2)⛳ᵯᦪ!3,$sp?ᩖᓄ஺)*ᨵ1-.ᵯᵯᦪ/!4,/$sp3ᩖᓄ஺1⍡3ᑖ56ᨵ9-89ᡂḄ9-C-H?/!@?஺(3)NODE!3ஹ16ᵯHIJᐸKᵯLḄMᨵOCN\SCN-ஹND஺(4)ᵫQRᔠT@ᵯMUNHVOH,ᦑNJRᑖ5Ḅ89ᡂ8?WXᓽ@9ᡂᐸZ᪀஺(5)U1஺6ᑏᡂ(HO)5lOHQᑏᡂ(H0)10,`abcᦪde⏚ឋdh஺2(6)ᵫᨔjZ᪀klm@nopqrsᔣḄỚᑖᑖv!Dw*x☢z{᜜☢zḄỚᑖ(4x1/2=2-)Dw⚔☢zḄỚᑖ(8xl/8+2xl/2=2)஺-ᨔj56ᨵ4-Ớᑖᑣ-ᨔjḄm=^g,-ᨔjḄLV=lO'cn?,ᦑᨔjḄm4x254_p=—=------------------------g-cm3Va-b-cx\O-3°xNA29.ᫀV(1)3,4-ab-1-⏚(2)bஹ?3(5)6D

320KMnOCH,CH,OH4CHJCHJOH—p-CHjCOOH-34᳘*CH—C—OCHjCH,3DCHjMgBrỏ⏚¡ᓄᑺCH-cCH-A-322)H*,HO2CH,£~ECH—C-J?2CH(6)3¤᪆V¦1
ᓄᔠᱥ¨Ḅ©ª3,4.ab-1-⏚ফ᪷WBḄZ᪀@nᓄᔠᱥB5®¯°Ḅ©ªbஹ?஺¦4
E-FḄ±²³´!µᓄ±²ᡈs·±²஺¦5
¸ᔠᩩºḄEḄrᑖ»᪀Lᨵ᝞x6p:0HCH2cH3CHOHCILOH230.ᫀV¦1
¾ᜧᧇ⊤☢ஹ±²ᱥÃᔠᙳᒴ¦2ÆÂMnO,Çᓄ@ÈឋḄMnSO43
ÉÊËஹÌᓾZᨔDÎÏA56ÐḄMnSOÑ,@ᵨÓ“Õs”×ÓḄÈᑺØÙᧇḄᑭᵨ᳛4
SiO,+2OH=SiOD+H,ODFeODấ⏚Ý23¦5ÆVOVVCVVOVDKNH,HO
AVH,CO,
K^HCOÆb2al23¤᪆V¦1
᪷WÞnßà@n“ᳫâ”ḄãḄ!¾ᜧᧇ⊤☢ஹ±²ᱥÃᔠᙳᒴ஺¦2
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í“îïa”ðñᑮïóA¦6FeO,SiO
ôõḄÈÏ,öÈÏ◤íÉÊ422ËÌᓾZᨔðE¯îïñᑮᨔL஺ÎÏA56ÐMnSO,@ᵨÓ“Õs”×ÓḄÈᑺØ4ÙᧇḄᑭᵨ᳛øØÙMnSO4HOḄ£᳛஺¦4
“ùÕ”æNaOHJSiO?±²éᡂNa?SiO32JHQ,MúûSiO?+2OHzSiOj+H2஺஺¦5
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33COjᐸᵯ!:V0VVCVVV0V஺ᵫmþ@n,ÿ
(H2co3)Ḅᦪ107ஹ(H2co3)Ḅᦪ10"ஹKb(NH3H2஺)Ḅᦪ10"ᦑK(NH,HO)>/C(H,CO,)>K(HCO,)b2ala2231.%ᫀ'(1)Is22s22P63s23P63d64s2ᡈ[Ar]3d64s:45᝱Ḅᵯ89:ᑮ<᝱=>?@A(2)জO>N>C>H>FeEN>O>Cঝsp?ஹsp'ঞNEFe(3)জᐳLMN᪆'(1)FeP826QᐗSᐸ᪶᜜ᵯ8᣸XYIs22s22P63s23P63dzs2(ᡈ[Ar]3d64s?)Eᵯ8[45᝱9:ᑮ<᝱=>?@A\ᐝḄ^Y>?஺(2)জ_`a
bcᐗSḄᵯdឋfgbcᐗSḄhiᕜk[lᑮmᵯdឋ⌲opqᦑᵯdឋ'O>N>C>H>Fe஺NḄ᪶᜜ᵯ8᣸XYIs22s22P3,ᓽᐸps⍝ᨵ3vᵯ8ᜐxyᐙ{|᝱}~ᦑNḄᵯAᜧx0஺ঝMḄNsp^ᩖᓄvMᙳᓫMḄNᩖᓄ஺ঞᵫ⊈Ḅ᪀YNFe^ᡂ2vM஺(3)জFeஹBrᵯdឋx1.7,ᦑᐳLM஺ঝᵫFeBr?ᨔ¡᪀Fe¢£¤ᨬ¦Ḅ4x)16Brᨵ8vEᵫFeBr2ᨔ¡1vᨔ¡©4vFeBr2,ᦑ1vᨔ¡Ḅªm=——gᦑᐸ¯°864.3Nj32.%ᫀ'(1)C6H(5)9E(toOH

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᪷·⚪ḄÄÅঞḄÆÇÈÉYN%COOH|^jj+HO—^2^~ÆÇÊËÌÍÆÇ஺4
ᵫ⚪EḄ᪀YEḄᑖ8YC13H1Q2N஺5
A5ÏÐÑÆÇÒÓ©ᨵÔ<⍗FeCLÖ×ØÙ⁐ÒÓ©ᨵÛÜ<஺Ý´Þ¸ᨵßv0ÌÍ<=ÌÍ<ᑖàH³:³á³áH,ᐳᨵâஹãஹä3å᪀´Þ¸ᨵvÌÍ<=ÌÍ<ßvÜ<ævÔ<,ᵨ“éêë”ᐜîßvÜ<ḄïðêñÔ<Ḅ0HOH0Hঝᐭজজóজঞ'জYজ-0H,ᦑᐳᨵ9å᪀஺ᐸ᪶ôᐳõö÷ïᨵ6å᪀:øùú¤ú☢üf1'1'2'2Ḅiᑖý᪀þHOHIl\JY°ÿ6
ᵫ⚪Ḅᔠᡂ,ᨵᓄᔠᱥHḄᔠᡂ:33.ᫀ(1)জHஹHIFeO34ঝH+3AH,.+3AH+4AH134(2)জIIஹIIIঝaঞp(CHj=p(CO)pYHq)

35ট37.5%67(3)CuSO+4CO=CaS+4CO42/᪆(1)জ23ᘤBᩭḄ7ᨵCO/UHzO,ᑣ=>?@ABḄCᓄᱥDCOEH?23஺ঝᵫHIJKLI+3x(III+III)+4xIVEPt#C(s)+O(g)==CO(g)«22(2)জnEIHḄIgKpZ[\ᓣ@^_ᜧaᔾc23஺ঝdὅᙳ>g23h᳛aa⚗┯l23mnopḄᑖrᦪtuab⚗gwᵫx23mnopyz{|}ᓄae⚗gwdὅ23ᔣta4moic-Hᓽὑ4moi0-Hᓽὑ2molH?O,d⚗gw஺ঞᵫ⚪-ᵯ◤ᓲ1Lp(CH)=p(CO).p2(HO)42:PCOট23ḄCOxmol,ᑣFeO(s)+CO(g)jFe(s)+CO(g)2/mol0.80.2ᓄ/molxx¡⊝/mol0.8-x0.2+x0.2+x=K=1,x=0.3ᑣCOḄᓄ᳛03moix100%=37.5%.0.8-x00.8molV(3)CuSO£+6AḄS¥¦§|ᡂCaS,ᑣCOCḄᓄᔠAᓣ@|ᡂCO?a¨¡ᓽ஺34.ᫀপজC᩽ឋᑖra±NH3DH2O²³᧕µᡂ¶;ঝ☢pµ;sp3ঞ(᩽ឋ)ᐳAஹ¨¹;73(2)জºOḄAᵯr»᪀>2PaNḄAᵯr»᪀>2Panὅ½J»᪀aᜫ¿ᵯrÀaᦑOḄhÃxNḄÄÅÆᜫ¿1ÇᵯrnO+ḄAᵯr»᪀>2P3ஹN+ḄAᵯr»᪀>2P2,mὅ½J»᪀aᜫ¿ᵯrÀ(ᡈᐸÊᔠᳮÌÍ)ঝ6;ঞ-------Î-------Ï(0.38X10'7)X6.02X1023/᪆(1)জᐗÑCஹNஹOḄᵯÒឋDÓÔÕឋÖ×aᦑᵫÃᑮᜧḄÙÚCsp3஺ঞᙠFe(CO)3(NH)2ᑖr3COᡈNEçèᵯrÞDFe§rçèḄéê⍝µᡂ¨¹aNH.3ᑖrN-H>ᐳAa^CìOᨵ2ÇnE1Ç஺aᦑFe(CO)3(NH3)2ᑖr஺D”Ḅᦪî146,ᓽ73஺(2)জºOḄAᵯr»᪀>2P",NḄAᵯr»᪀>2P3,nὅᜐxñᐙóô᝱aᜫ¿ᵯrÀaᦑOḄLÃxNḄLÄÅÆᜫ¿1ÇᵯrnO+ḄAᵯr»᪀>2P3ஹN+ḄAᵯr»᪀>2P2,mὅᜐxñᐙóô᝱aᜫ¿ᵯrÀaᦑOḄkᜧxNḄ12஺ঝøFeNḄᨔpḄFe§rḄ᣸ᑡå☢üýᨬÿᚮ
FeNḄᨔNaClᨔᦑFeᕜᨬḄNᨵ6஺ঞ

36ᙠFeNḄᨔ"#Fe$Nᙳ&4ᡠ)*+&4x70------7-------cm(0.38x107)x6.02xIO2335.9ᫀ;<1=Ch;<@=ABஹDB<2=DᓄFGᡈIJFGKClᕸᖹ⏚ODᐭQ〉SᩩU+5NaOH----------+2NaCl+3H2஺(3)(4)3K<5CH=CH>CHCHO-^£HO..„-HCH=CHCHO223>C3QMᑴcYZ[\]>CHஹCH=CHCOOH_᪆;ᵫCḄb᪀deஹFGfghiAஹB#ᙳkᨵlBmbᔠOoAḄqᓄᐵsiAtOlBt2uQ~CHO,ᵫCqᓄ&DḄFGᩩUiD&'uO-CH=CHC00H,ᵫEḄᑖeஹFḄb᪀e}FGᩩUiEHO=C-CH=CHCOOH,ᵫEஹFḄᐵsiYtO⏥ᵫDḄiFḄ&ᕸᖹ⏚OD஺<4=ᵫঝiᑖ#kᨵᨵABKᵫজ}ᑖ#ᦪiᑖ#kᨵQQCHOOCHCHOஹQHCOOQᨵ2;QOHஹCHO,ᨵ3ḄᐵsᦑᐳCHOOCHᨵ3ᑖ᪀ᐸ#᪶ᐳᨵ6¡Ḅᱥ£Ḅb᪀de&CHO<5=Ooᐜ¥ᓄ&OlOlmqᓄ&2-¦olᨬ§ᓄ&᪗©ᱥ஺36.9ᫀ;<1=ª«¬*ឋ<2=¯°£±ᴻ³#´µ¶Ḅᐰ¸¹ᐭA#ºO,¥»ᐰᔾᦈ<3=¾ᜧFGᱥḄÀ☢
º¥ᐙᑖᔾᦈKÃ⊝ÅÆᨵᑭÈÉÊ⏚Ëᐭ<4=জÌÍKÎÏÐ⁐ÒÓÔᑖÕᑁឮØ⁐ঝ2s2஺K+I,=SO^+2r<3=564_᪆;<1=¬Þ§ßᐭàáâ◤äåḄæçtª«¬*ឋ஺<2=ßè§éêëN2ḄḄt¯°£±ᴻ³#´µ¶Ḅᐰ¸¹ᐭA#ºO?¥»ᐰᔾᦈ஺

37(3)¬A#íîᳫðḄçᵨt¾ᜧFGᱥḄÀ☢
º¥ᐙᑖᔾᦈ஺ºᵨឤÅËÏóᧅõ)Ã⊝ÅÆᨵᑭÈÉÊ⏚Ëᐭ஺(4)জ⌱÷Ḅᢣùᑺ&ÌÍ.ᑨüýᑮËÿ
Ḅ⁐ᑖᑁឮ⁐஺ঝᱥNa2sc>6(Ḅ)*+,-2SQ0+l2=SQ4+2r஺ঞ730mL4=ᔠ?(᪵ABḄCDEFX஺ᵫ⚪JKL+,-M2SQ0+I=S.Q0+2r,QRᐵT-42O~2I~4SO0',x=22.4x2.0x0.05x0L=0.56L=560mL஺Z=ᔠ300mL,ᑣ100g᪵AB2225600mL,ᦑ(᪵AB_C`5600mL/100g=56mLg-1.37.dᫀ4(1)2s22P30ij0kᱯmᑣ(2)nὅpqᵯ*EᐹᨵiuḄᓄwxᱯy04CQO400n(4C()tCIII0(3)sp30sp30N2H4}HaOᑖ*~ᡂxḄᦪNH3Ḅ(4)60—-----------᪆4(1)᝱*Ḅᨬ᜜ᨵ5ᵯ*ᑣᐸᵯ*᣸-2s22P3,ᐸᨬḄᵯ*᝱ijḄᓫᵯ*ᨬᵯ*Ḅ᣸⍳kᱯmᑣ(ᵯ*᣸ᙠjḄj⍝¢᝱*BḄᵯ*Z£¤ᐜᓫ¦ᓰ¨⍝©᝱ij)஺(2)N2}CO*ᦪijᵯ*Zᦪiqpqᵯ*EᐹᨵiuḄᓄwxᱯyª«ឋ®¯ᙠiuឋ஺COḄᵯ*-}N2Ḅᵯ*-iu:CQO4஺±ᐗ³Ḅᵯ´ឋCᐗ³Ḅᵯ´ឋµᦑNi(CO)4BC*᧕JR¸?ᵯ*}¹º*xᔠᑣNi(CO)4Ḅ»᪀-O=C-0஺tcIII0(3)NH3(½)ஹN2H4(¿0ᑖ*B*Ḅᵯ*?ᦪᙳ4,ᩖᓄ+-ᙳsp30NH3ÂN2H4ÃÄᑖÅ}Æᑖ*~ᡂxN2H4}H2Oᑖ*~ᡂxḄᦪNH3ḄᦑN2H4ÂÆÄÇÈÉp஺(4)ᵫÊᓄËᨔÍ»᪀ÎÃL)N0ᨬÏḄᨵ6Na+,ᦑN0ḄÐÑᦪ64ᨔE»᪀B_ᨵ3

38NaᓱÂ3N~,ᦑᨔEḄÓÔp=m/V=-------=9,+14x3x3V&Õ/Ö,᮱஺438.dᫀ4Ø1
2-ÙÚÛØᡈa-ᵬÙÞÛßØ2
àᡂ0áâᡈÆCOOH+0?ãb1CH3HO+2OHCOOHCHO0160HOCHKHO1^CHQOH—>CHjC-CH—CNH-CH—CH,3(5)ØᐸäᔠᳮdᫀæÃß᪆:ᨵçèéêëÃÄìÙíî£áâᑣêï£2-ÙÚÛ;æÃÄìᵬîáâᐸêï£a-ᵬÙÞÛ஺CH32
᪷¨BḄᑖ*-ÃLAòᡂB£74CHBḄ±±óx}BqḄàᡂ0᪷¨BḄᑖ*-MBòᡂCḄᩩõ“NaOH”ÃL(Br÷øáâḄ஺

39CH3COOHC—CH,OH(3)CḄ»᪀ù-J°”᪷¨(ḄᩩõÃLDCOOHIüᓄᑺC-CH3+H02OH(Ḅᓄw+,-(4)ᵫG⌮ÿ
IE஺“''X“⍗FeCl,⁐”XᦑᔠᩩḄᱥ"#$%&'()*+,ᑖ./(i)12'(/3CHOஹ3OHஹ-CH=CH,ᐳ1078(ii)92'(/3OHஹ-CH=CHCHOᡈ3OHஹ2CHC)CH=CCHO,ᔜ37ᐳ67஺ᦑᔠᩩḄXᨵ167஺ᐸ?@ᨵHO2Ḅ᪶BᐳCDEFG57HIᓄK%᛻ḄD஺39.Nᫀ/(1)ᔾᦈARS?ᢵUḄV⏚XYZ[HNO3ᡂNO,]^ARS?ᡂḄNO?_ᓄNO2NO+NaO=2NaNO,(2)22(3)Na2CO3ஹNaOHᙠBRSbCRScdef32gᨵhiᮞḄklm(4)nRSᑁpᶇḄrsᓄᱥtuvDRSXᐸᐙᑖᔾᦈxyz{|}(5)65.2%~᪆/(1)ᵫ⚪
BRSḄᵨᔾᦈ#ARS?ᢵUḄV⏚XYZ[HNOஹᡂNO,]^ARSᡂḄ_ᓄNO஺(2)ᵫ⚪ᑖ᪆
CRS?Ḅ⌕ᱥNObNa?஺ஹᑣḄᓄK2NO+NaO=2NaNO222

40(3)ARS?ᨵsᓄ}+ᐭcRSᨵᡠCRS?ᡂNa2cO3bNaOH,xyᩖ"ᙠBRSbCRScdef32gᨵhiᮞḄklmᩭ◀ªbsᓄ஺(4)rsᓄᱥᨵ¬ᜧ}z{ᱥ®ᐭNzḄ°ḄnRSᑁpᶇḄrsᓄᱥtuvRSXᐸᐙᑖᔾᦈxyz{|}஺(5)²ᳮ´&ᡂNW஺¶Ḅ"·x2NO+NaO=2NaNO2227869x215.6gx7869x2”----=----,x=27.6gᑣᨵ15.6gx100%®65.2%ᑣNaNOḄ᳛=27.6g஺240.Nᫀ/(1)^Cu(I)sᓄCu(II)ஹ^COsᓄ]CO2ᔿUஹᔿUÈÉḄNH3Ê;Ì(2)XCM+ÎÏÐÑᐰÓÔpᶇ᳛(3)3/2(4)2[Cu(NH)4]2++C1-+5H++3HO=CU(OH)3c4+8NH/;6(ᡈ5.565)322(5)[Cu(NH)4Ù++2e-=Cu+4NH38H2sO43~᪆/(1)YÜÝ?ᨵCu(I)ஹCu(II),ᵨÞ|}ᔿῃ02^Cu(I)sᓄ8ᵫ⍎UḄ}CChbNH3,COâãsᓄNH3?ḄÈÉÜᵫᔿῃḄäåæçᑖãè஺ᵫ[Cu(NH)]2++4H+=CU2++4NH8,NH3é᧕ZH+ëᔠ஺34(2)ᵫCM+(ì)+S2-(ag)CuS(s),eᜧc(S2-),ÓÔ?pᶇḄc(Cu2+)஺(3)ᵫî?Ḅïð3CUS+8HNC)3=3CU(NO)+2NOf+3SI+4HO,sᓄᱥ322S,òᱥNO஺(5)ófNaCI,▢᩽&ᵫ[Cu(NH)4öᑮᵯù᪆UY/3ICu(NH)4/++2e=Cu+4NH3ófNaCl□᩽Ḅᵯ᩽2Cý-2e-=Cbt
⏚⁚3pH,□᩽Ḅ2H2O+4e=4H++O2f,CI2⌼ᡂ!ᡈᜐᳮ%&'()ᩖ஺41..ᫀ0(1)SOKSO?6789ᡂḄ⏚:);57.6%(2)জ-196.7ঝ1.6;>ঞFᓄᑺ;+3(3)▢;2HO-4e=4H"+OT22(4)AD

41O᪆0(1)CuSO5HOQRSTCuSO5HOACuSO+5H,0,CuSOACuO+SO(g),SO,4242443UVWXYᡈ⍗78XY:ᨬ\XᱥUSO3+5HQ^_\UH2so+4`0,abc4dᑖᦪU:-----------------xl00%~57.6%1x98+4x18(2)জᵫijkl2X(11)+(I)W2somg)+O(g)(SO3)n=2o+p1ঝ2£(r)±565=0012x0.008=16,Qv(⌮)஺ঞNO|}tuC(SO)+C(NO)0.010X0.00622ᡂḄNO2~ᓄSO2tuḄU2SO2+O2+2H2O=2H2SO4NOFᓄᑺᵨ;ONOSQOH}⏚"ON”+1H,S~-2ᦑNU+3ᡈStuHIᑨ஺(3)SO;ᔣ□᩽□᩽XḄH+(2HQ+4,=4H~+0?T)ᔣ▢᩽ᦑXU▢ᣚᙠ᪷IJḄXᑮ⏚஺(4)ᵫaᘤIஹaᘤIII¢ᙳU2moiSO?ஹImolvtu¤Rtu¥¦§¨©ᓄ᳛§«aᘤHIḄ¥¦aᘤI¨ᦑ©ᓄ᳛«A⚗v;aᘤH¢d}¢®4moiSOz+ZmolOz¯ᦔḄ±4moiSOz+Zmo஺²ᑖ³´aµKḄaᘤ¶ᙳU2molSO>ImolO,,·aᘤ¸¹⊝®c(SC>3)=qᯠ\±³aᘤᔠ½¾¿UV,ᵫ¹⊝ᔣ2vtuÀᔣᦑ2>2qB⚗┯Â;ὃ⇋aᘤIஹaᘤHIÅᨵ¥¦Ç´¥¦¨SO,Ȧ«ᓽ032c,>2c3,C⚗┯Â;aᘤII
¢®4moiSOz+ZmolO2(¯ᦔ¹⊝)¸¹⊝®SO?Ḅ©ᓄ᳛Uᒹ(SO?)a(SO)+«(SO)=l,aᘤHḄ¾Ìᜧ2342a(SO)>6Z,(SO),ᵫA⚗"(SO?)>4(SO2)ᦑ%(SO?)ு4(SO?)ுa4SC>2)ᦑ422a(SO,)+<2,(SO,)<1,D⚗v஺242..ᫀ0(1)ÏÐÑÒÓឋ(2)3Cu+8HNCh==3Cu(NO)+2NOt+4HO322(3)Õ◀×WḄNCh;ØÙNO(½◀×ᐸḄ⏚ឋW)(4)NO+3MnO;+2HO==NO;+4H++3MnO0ᡈNO+23MnO*+4OH==NO,+3MnOj+2H2O(5)ᐜᰐÝ⏀ßàáâãᐭNOåDḄVW^ᓾå¥(6)çᧅஹéᴻë;-(c,V,-6CK)X103X622(7)................-....................xlOO%;ìᜧaO᪆0(1)ÑÒíîï6Ñᐭðñ◤xyḄóÏÐÑÒÓឋ஺(2)ÑÒAᑴõNOḄᓄöÀ÷mU3CU+8HNO3==3CU(NO)+2NOt+4HO«322

42(3)øùú⍎üḄWý⌕NO,ᐭ◀NO2(3NO+HO==2HNO+NO),NOᜫᯠᮞ"#$◀%&ḄHNCh*+,223-ḄNO஺(4)MnO34567MnO3,NO48ᓄ7NO3,ᑣ;<Ḅ=>?@A7NO+3Mn°3+2HO==N0J+4H++3MnO^ᡈNO+3Mn0GH+4OH==NO3+3MnO^+2HO»22(5)7■LKMnCUOP᎔ᔾᐭ;

43(4)জᵫø;<(CHjAuPH,——>(CHJAUPH3+C2H6j◀;<ᱥwᱥᐸúᙳ7Tüᱥ஺ঝТ;ᑁ@0Ab,ᐭc4224224224(4)c0DᨬE
FGHIJKLᐭBaCbMNO₩᝞RSᨵT⁐VWXY,[\VW]GH^'
(5)FeCO-2HO=FeO+COT+COT+2HO24222_᪆%(1)bᘤaḄdefឤ,-.ᧅ஺=>dḄgᵨi1■k@Mᐭ=>c஺(2)Na2c஺3Ḅgᵨi◀3456⊤☢Ḅ9:஺(3)l5mno᧕qᓄᑴᜓtuᙠwx᛻MNFez{|⏚ᑴᜓ|⏚l5ᑭᵨYᡂḄ᣸=>Ḅ@᜜ᑭᵨYᡂḄb,ᜧA|⏚l5,ᐭ⚠஺ᙠ⚠FeSO₝⏚Y%4
FeSO+HCO+2HO=FeCO-2HOJ+HSO4224224224(4)᪷₝⏚l5ᨔᙠ_⌱MNGH஺VWGH^'ᑣᨬE
FGHH2so,ᦑgf:DᨬE
FGHIJKLᐭBaCl2MNO₩᝞4RSᨵT⁐VWXY[\VW]GH^'஺(5)3.60gFeC2O2HQḄᱥḄf0.02mol,¡ᑖ_tu5ᐗ£¤ᑣB¥¦1.44g§f0.02molFeO,¨©Lᑮ400CH«FeCO-2HO¡ᑖ_Ḅᓄ¬u®242Af:FeCO-2HO=FeO+COT+CO,T+2HO242245.)ᫀ%(1)2(2)4X10-21moPL-1(3)জmn°ஹ(᩽ឋ)ᐳµ°ঝFe(OH)30MnO+4H++2Fe2+=2FeJ++Mn2++2HO;c;22ঞ7Na2co3+7MnSO4+1lHO=MnCO3»6Mn(OH),5HOt+7Na2so4+6CO2tᡈ2227CO0+7SO%+1lH2O=MnCCh6Mn(OH)2,5¹0I+6CO2t_᪆%(1)ᵫ⚪¼ᩩ¾KMnO4i¿⏚¿ÀÁᦑHMnO4i¿⏚0.01molLÂḄHMnC)4ḄpH=2஺

44(2)K=c(Mn")=&?(MnS),ÃᐭÄᐵᦪEÆ<஺(pb?+)X1021mobL'c=4c(Pb")K*(PbS)(3)জMnSChimnᓄᔠᱥᨵmn°SO%ᨵ᩽ឋᐳµ°஺ঝᵫÈÉHÊᡂḄᩩ¾ᐸÌ⌕ᡂᑖiFe(OH)3஺ᵫÎuÏMnChqFe2+ÐÑfMn?+,Fe?+ᑣqᓄfFe3+,Ḅmnu®fMnCh+4H++2Fe2+=2Fe3++Mn2++2HO«ᵫÏÓÔÕᑮ80࠷EMnO2Ḅ×ᓄ᳛ØÙ2Sᨵ¤ᓄᦑÔÚᑴᙠ80࠷ÛÜfÝ஺ঞ᧕ÞßYᡂḄiCO2,ᦑᐜᑏ?NH3Ḅ(ᓄ᳛<@ಗx100%=32%஺4mol(4)᪷C5ᳮEḄF2ᱥ8/ᑏ2HḄᓄIJKL<2N2+3H2+3CO+3H2O=3CC>2+4NH»M᩽

45ᓭ7-4
2LiHPO+FeO,+C===2LiFePO+COT+2HO242425
@4~5.5@IO-133
3Ca2++2HPO^=CaPO
+2H+3426
FePO+Li++e=LiFePOU0.7g44᪆h1᪷C᳛Ḅ>/0<+5ᧇᙠḄ᳛/Ḅᨵij⏚┞mnᐭ«9¬ᦑ¬®(ᓄ<"¯ᓄj°±¯ᓄj᪷CᜫᵯR²ឤஹ5R²ឤ67F¢´µ/2ᓄIJKL