名校卷北京市某中学2022-2023学年高三上学期检测化学试卷(含详解)

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24饱浓和NaHCOs氨NaCl氨水盐1CC2|᝞UḄbᐭ,水¡¢£5¤ᵨ¥ᓄ¢£Ḅ¦§⛳z+©ª2«ᡂNaHCOsḄ®¯°ḄᓄP±>.HO⛳z+©ª23¯°²ᡂ³FUᑁḄµᔠᱥᜐᳮNᑮ¹QNaHCOszº»জ½¹QNaHCOsᐙᑖ¿ÀÁ«ḄÂQᐜÄÅÆVÇÈ⏚ÊÄÅÆVNa2஺ËNa2஺2Ì0.14g,ᑣ¹QNaHCO,ḄV>g஺ঝFNaHCOszNaOḄ¹Qµᔠᱥ£Ï`ÐÑᘤ5¿Àᑮ250࠷¤ᐸᐙᑖ¯°Õᢝ250࠷஺22E¯°ᱥ×⏚ØÙzÅÚᓄÙḄᱥḄVÛÜᐙᑖ¯°³ÝNÞß¹Qᨵàáᱥᡂdá>amol,ãdá>bmol,äa>b,ᑣå¹Q5ÅÚᓄÙḄᱥḄV>஺4ᙠæᑴ⛳z穪5¿ᐭ×⏚Ø╆Lᑴᜓ%éᡭNaHCOs,ëìíᓄ╆>îᧇᡈdñëx>kyíᓄò஺º%éᡭ³ó»ëìíᓄôᨵàáPuজÄᐭ+õᓾஹ¿ç©Åºঝ÷Ä+,õᓾஹ¿ç©Åº஺½àáPuḄøùúûḄ§஺A.জ᪆Ḅíᓄ╄xaÿB.ঝ᪆Ḅᓄ╄C.জᵨD.ঝḄᵨ5ᓄᐭ"#$%ᢚNH4HCO3ᨔ-./010.800molNH3Ḅ#789:54.0g,ᔣ>7ᐭᓄ?@ABᐰ.D.Eᑮ31.2g,ᑣNH4HCO3ḄJ᳛:%o6NOJP⏚R$Sᔲ1ᨵᓄRḄVWS஺ூYᫀ௃1\ᓄ]^_`ᜧb☢d.⛳f"g#hCO2ᐙᑖb.@Aᐙᑖ2CO+NH,+NaCl+HO=NaHCO,+NHC1224

25a+b(3)জ.0.84ঝ.-----(4)AD2(5)92%(6)tu9᪵Pwxy$.zᐭ{9|}⏚.~zᐭ}⏚7.ᑮJ⁐,᪵P$1ᨵᓄRூ᪆௃ூᑖ᪆௃"#$zᐭᓄREᑮ⛳f"g#.ᐭ{9ᓄ᪆⏚Rᨔ-.DEᑮ⏚Rᨔ-zᑖEᑮJP⏚R.Eᑮ-:ᓄDEᑮ~zᐭᓄR᪆JPᓄ.7⌕:g#஺ூ1௃CO2᝞U¢yḄb£¤ᐭ.>]^$ᵨ\ᓄ]^Ḅ¥¦S\ᓄ]^_`ᜧb☢d.⛳f"g#hCO2ᐙᑖb.@Aᐙᑖூ2௃⛳f"g#hᓄ@Aᡂ⏚Rfᓄ╆.@AḄᓄ©Vª«:CO+NH+NaCl+HO=NaHCO>L+NHCI23234ூ3௃জImolCChh{9Na?஺?@A.ᨬ²Na?஺³`´Ḅ89µ¶wImolCOḄ89.Ꮇ¸¹-NaHCO?Ḅ89:xg,ᑡ᝞¼ᐵ¾«:2NaHCOÀCO-NaO~CO2222x84282x8428Âij-----=——Ex=0.84gxg0.14gxg0.14gঝzÅ@AÆ2NaHCOANa2co3+CO2T+H2O,ÉÊÅ@AÆ2Na2C)2+2CO2=2Na2co3+O2ஹ32Na2O+2HO=4NaOH+O2TCO+2NaOH=NaCO3+HO,_ÌÍDᓄRᐜhᓄ@A.ᯠÊ~h22222#@A.EDᓄRh⏚R@AḄÐVª«Æ2NaHCO3+2Na2Ch=2Na2co3+O2f+2NaOH,ᡈ4NaHCCh+2Na2O2=4Na2co3+O2T+2H2஺Ó.n(NaHCO)Æn(NaO)=1Æ1,ᡠE¹-:Na2co3ஹ322NaOH,Ön(Na2cO3)=n(NaOH)n(NaHCCh)Æn(NaO)<1Æ1,ᡠE¹-:Na2co3ஹNaOH22ØÙ@AḄNazCh,Ön(Na2co3)=n(NaOH)n(NaHCO)Æn(NaO)>2Æ1,ᡠE¹-:322Na2c஺3Iln322(NaOH)ÛÜᑖ᪆0.@AÊ$¹-Ḅᡂᑖ:Na2co3ஹNaOH,ÖNa2cO3:amol,NaOH:bmol,᪷Þᐗàáឤ0.n(NaHCCh)=n(Na2co3)=amoL᪷ÞRãäáឤ.2n(NazCh)+n(NaHCCh)

26=2n(Na2co3)+n(NaOH),ᓽ2n(NazCh)+amol=2amol+bmol,ᦑn(NazCh)=-------mol2ூ4௃$1ᨵᓄ╄.ᐭ".çᓾஹzg.ᨵᑭw"ᓄêḄ᪆..DÊ$1ᨵ".ëìᵨ.ÉঝḄᵨYᫀ⌱ADூ5௃>"#Bᐰ@A◤ᐭ0.8mo1CC>2,DEᑮm(NH4HC03)=54.0g+0.8moiX44gmoH-31.2g=58g,᪷Þ58gãäáឤ.ᳮðÜAEᑮm(NH4HCO>0.8molX79g•mol-'=63.2g,ᑣNH4HCO3ḄJ᳛:77^363.2gX100%=92%;ூ6௃⌕NO⏚R$Sᔲ1ᨵᓄR◤⌕ᐜ᣸◀⏚Róô.t᪵Pwxy$.zᐭ{9Ḅ|}⏚.~zᐭ}⏚7.SᔲJ⁐ᦑõÆtu9᪵Pwxy$.zᐭ{9|}⏚.~zᐭ}⏚7.ᑮJ⁐.᪵P$1ᨵᓄR஺18./0ö÷ø_ᔠᡂ$₝ûḄüឋᡂᑖPsoralidin,ᔠᡂþÿ᝞
H+iiRiCOOR?+RQH—+ROH2(1)AᨵḄ஺(2)CḄ᪀o

27(3)D—EḄ.(4)FḄᨵA.ᡂB.!C."#D.$%,'(FeCL,)*+,⁐Ḅᨵ.஺R2R2W«JḄR2R2(7)G—HḄ/ᑖ12஺ᑏ4KஹMஹHḄ᪀Gூ7ᫀ௃(1);#<=>?HCOH3co3(3)+C2H5OHஹ▲ஹ+H20HOOCC2H5OOC(5)19(6)@A(7)HOH0ூC᪆௃0Hூᑖ᪆௃ᔠDḄ᪀,GBnHFᡂAAGCFWHH3coH3coFᡂB,BIJᡂC.CGMgஹCChஹQCO2cH3HCO3K<⏚ᓄᡂD,DGN⏣PᓄᡂE,EGCHOOC25OCH3HCO3H,CO,CHFᡂF,FRSᩩU
VᓄG,G⏚ᓄWᡂHHCO3

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ᡂH,_`C7஺HOூab1cC௃AᨵḄd#?஺ூab2cC௃CḄ᪀ூab3cC௃H3c0ஹ/^0CH3H38VDGN⏣PᓄᡂEITᓄgTT+C2H5OHC2Hᨵhiஹj?ஹkklmeP?eḄᨵᡂஹ"#஺ூab5cC௃0H0Ḅnᑖo᪀peqCersᨵP?,(FeCh)*+,⁐ersᨵ=>?etᨵ-OHOHஹ-00CCH3?vewᙠxyz3.etᨵ-OHஹ-CH2OOCH?v:wᙠxyz3.᪀etᨵ-OHஹ-C00CH3?vᨵxyz3.etwᙠ-OHஹ-OOCHஹ-CH31.?veᨵ10.eᑣᐳᨵ3+3+3+10=19.஺ூab6cC௃\=^—»Psoralidin+JḄ#ᳮ:᪷_H+RR2R/\+R/\]ᓄ./R\+/L\/JCH2=CHCH3,@A஺R1R2R1R2R1R1R2R2ூab7cC௃

2919.IJজᓄᙠ⏚ឋᩩU
ᓄCuO+2H+=Cu+Cu2++H0ঝWḄ22Ḅᓄᱥ஺ᓄgaRᓄGḄᓄᱥe᝞ᑖᜳᢝ2¡¢veᐜᡭ¡Aᑖ*¥ᧅ§¨e/R©ªe«¬Dᜐ⏀¯°eজ±᪵³´ḄµḄ¶etCuᐙᑖe¸veঝ
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”Ḅ,Ḅ-஺./τஹn12HNO3ᓄcuḄ789᳛;HNO3ᓄc<஺23u=5?@ABCDᱏ'ᐭEᨵGHNO3ḄLMNO2PQRSᨵTU☢VQ⁐ᕈW⁐஺XᔠZ./ᑖ᪆ᑨ^_78᠒Ḅ`a◀cd⏚fgTஹ78hgijk789᳛᜜m)no⌕`a-o=6?sᱥCuOvCu?஺Ḅxᔠᱥyxᔠᱥ5.92g}~Gd⏚78ᡂ448mL᪗NOᑣCuOvCjOḄᱥḄ;஺ூᫀ௃=1?জ.⊝ᑖᧅᑁ᜜ᑭঝ.Cu+4H++2NO=CU2++2NO2T+2H2O=2?জ.C¦(Ḅ§᣸§■ª3}Cu78jk./X«ঝ.জ=3?¬=4?জ.NaNChঝ.HNO2®ᐰᑖ°=5?Gd⏚±²CNO3ᓄNO2,´±²µNth}·ᡂHNChḄ78=6?2¸3ூ°᪆௃ூᑖ᪆௃¹⚪»¼½NOvCu78Ḅ3ᓄᱥ⚪ᩞ¿À./¼½./¦(AᑴᜓNOḄ¦(2µḄ78¸Cu+4HNO3=fÄCu=NCh?2+2NO2f+2H20,¦(BᑴᜓNOḄ¦(µḄ78¸3NO+HO=2HNO+NO,¦(CÈÉNOḄ¦(DNO}Cuµ78Ḅ¦(EᦈÍÎÏḄ223NO,¿ÀÐᜐᳮ■ªÓÔÕ᛻×Øᑖ᪆°⚪஺ூTÙ1Ú°௃জᵫ./¦(ÜÝÞ¦(AE'DßaMḄàᵨ-ᑖᧅḄOâvãäåæḄçè²éᑭঝ_¦(-Dvfd⏚78ᦑµ78ḄëìíîCu+4H++2N0=Cu2++2NChT+2H2O,ᦑᫀ¸⊝ᑖᧅᑁ᜜ᑭCu+4H++2N0=Cu2++2NO2T+2H2OூTÙ2Ú°௃ᵫï§Ḅ3ð²}Cu78ᡂCuO,È᡾òó./ᦑ./NOᐜᡭNAᑖᧅö÷ø)ùúûüDᜐ⏀þÿ
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