山东济宁市兖州区2022-2023学年化学高三上期中调研试题（含解析）

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2022-2023
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ᡂᡂD,ᑣDḄ᪀CH3CHOHCOOH,D
HBr!Ḅ"#ᡂE,ᑣEḄ᪀CMCHBrCOOH஺Dᑖ%&'(2ᑖ%DᡂG,ᑣ()II᪷*GḄᑖ%GḄ᪀"+—-.<ீ(*1ᑖ᪆345(>-<1—CM—()ூ⚪89:௃(1)ᵫHḄ᪀(Hᑖ%Ci஺=஺5(2)BḄ᪀CH3coeOOH,ᡠ?@ABCஹE5(3)?FGCOOCH3BḄCḄHᑖI᪀JᐳᨵH3COOCCH2cH2cH2COOCH3ஹH2COOCCH(CH3)CH2coOCH3ஹCH3CH3cH2cH(COOCH3)2ஹCH3OOC-C-COOCH3ᐳM4N5ᐸ&᪶QᐳRSᕈU2GᔾᦈXḄHᑖI᪀JḄ2H3CH3᪀CH3OOC—2—COOCH3;CH3(4)ᵫ!Yᑖ᪆BᡂᡂDoD"#ᡂEo()II(5)G?Zᐗ\Ḅᓄᔠᱥ(ᑏ`ᐸ᪀'H3rL.()—1X-CH—II3()H,O(6)᪷*b!ᑖ᪆EfFḄᓄcdefCHjCHBrCOOH+ZNaOHfCHCH(OH)COONa+NaBr+H2O»3AA25ஹA2NHCl+Ca(OH)=:CaCh+2NH3t+2HOBCCu+2112so4(g)=C11SO4+SO2T+2H2OAD422BA&ᡂḄNOjkl\᛻(ᡂnHopḄq⏚rBdᫀ◤⌕Ḅq⏚vwூᑖ᪆௃পy*ᱥz᝱ᩩ}ᑖ᪆ᑨᑴᜓJḄ(Aᔠ(Jᓄᓄ┛ᡂ5(2)gNaOHJᡂ(Bᔠ5᩽᧕(ᜐᳮ⌕ᵨ■᎔ᔾ;(3)⏚g¡(¢⏚r(ᡠbᓽ¤r¥p(⏚¦A§ᐰ(©g⏚rªᑮCuSO,ᡠb¬ᒕ¯Ḅ⏚(A¬⏚᪷°%(◤⌕¬ᒕ¯&?H+4(4)᪷*⌱²dᫀḄy*³⁐ᓄµᳮᩭ·4¸⚪஺ூ⚪89:௃(DAᔠ(ᵨNH4aCa(OH)2ᩭᑴ"(ᱥJJᑴᜓ

19JḄ(⌱ᵨᜧº»ᑴᜓ(⌱ᑣAᵨJᓄ¼ᓄ┛ᡂ(Ḅᓄcde:AA2NH4Cl+Ca(OH)2=CaCL+2NH3T+2H2O,ᦑ4ᫀfA2NHCl+Ca(OH)=CaCl+2NHT+2H2O4223(2)জNaOH¿`p(ᦑÀ¤Ḅ:ÁÂ(ÃÄ⍎`(Æᵯ:oÈᙠᵯ°Ê⊝fNH3+H2OWNH3H2OWNH4++OH-ᐭᓄÍ(᪷gÎᜧ(Ê⊝ÏÐ(⍎`(Bᔠ(ÑᵨgNaOHJᩭᑴ"⌱ᵨB,ᦑ4ᫀfBঝ᩽᧕(ᜐᳮ⌕ᵨ■᎔ᔾ(ᦑ4ᫀfCA(3)জrÔg⏚ḄᓄcdeCu+2H2s04(g)=CUSO4+SO2T+2H2O,ᦑ4ᫀfCu+2H2so4(g)A=CuSO+SO2t+2H2O4ঝ⏚g¡(¢⏚r(ᡠbᓽ¤r¥p(⏚¦A§ᐰ(©g⏚rªᑮCuSO,ᡠb¬ᒕ¯Ḅ⏚(A¬⏚᪷°%(◤⌕¬ᒕ¯&?H+,H+Fe¿`(NaHCOs4ªᑮÕᓄÖ(ᦑ4ᫀfAD(4)⌱²dᫀ⌕ὃ⇋ᔲÚᨵÛJklÜ(dᫀᔲ(ᔲÝᐰ(Þ3ᔲᓫ(ᔲ⁚áâµᧇ(dᫀAḄᡂᱥjkl\᛻(äåᑴ"nHopḄq⏚r(dᫀBæὑḄµᧇᨬw(q⏚&Ḅq⏚᪷ᐰéêᓄᡂq⏚r(ᦑ4ᫀfBA&ᡂḄNOjkl\᛻(ᡂnHopḄq⏚rBdᫀ◤⌕Ḅq⏚vw஺26ஹ
ᑴªë⏚(3ᓄᑺí᠒ïð⏚ஹCᵨñò&2Fe(NO3)3+3KClO+10KOH=2K2FeOi+6KNO+3KCl+5HOFe(OH)3KFeOiSiO2+2OH=SiO32+HO3222ூ4ᫀ:᪆௃᪷*óô(Aᑭᵨö⏚
ð⏚ᑴCh,CL&ᨵᢵ`ḄᩭḄHC1J(ᡠbB&⛳ùðḄ3ᵨ◀ûCL&ḄHCLC&Ch
KOHᑴªKC10,D3ᵨᜐᳮüýḄCl.2(1)C&ᵨ
ᓄᑴªë⏚(3ᓄᑺ஺ᦑ4ᫀf
ᑴªë⏚(3ᓄᑺ5(2)CLKOHᙠ'þÿ
ᡂKC103,ᑴKC10
ᙠ0࠷5࠷,C
ᙠ᠒⏚᠒ᡂḄ᳛஺ᦑᫀ!"᠒⏚ஹCᵨ%(3)&Fe(N03”⛳()*᠒ᑮKC10⛳()*ᓽ-ᑴ"FeOi,(FeOiᑣ!/ᓄ1ᱥKC10345KC1,
678!"2Fe(NOs)3+3KC10+10K0H=2KFe0i+6KN0+3KCl+5H0232ᦑᫀ!"2Fe(NO3)3+3KC10+10KOH=2K2FeOi+6KN03+3KCl+5HQ(1)&9:;ḄKzFeOi<1=)>?Ḅ3moi/LKOH)*ᵫ>Fe(0H)3A)>)>ᡠCD9EᵨṺGHᧅJK-LᑮḄMNFe(0H)3,O1«^01-ᙠK*஺&K*>ᔣK*ᐭ⛳(ḄKOH)*⚪STU

20AFeOiW)>XKOH)*ᡠC᪆ZLFeO1ᨔNᑣD\EᵨṺGHᧅJKL]I^_FeOiᨔN%`aHᧅᡂᑖ!SiO?,᧕dKOH
ef678!"SiO+2OH-=SiO2'+HO»232ᦑᫀ!"Fe(OH)3oKzFeOuSi02+20H=Si02'+H0«32ூhi௃k⚪l⌕ὃopqᑴᜓ6ᫀஹ/ᓄ45
678ḄsᑏஹᱥuḄᑖevwxᔠឋ{|஺}⚪~✌ᐜ⌕pqSḄU᧽pq5ᳮᑖ᪆pq⚪ᡠḄTU}⚪஺27ஹ2Al+2NaOH+2H2O=2NaAlO2+3H2T97mLEDG╅ஹd⏚
ᡂN┵N|ᜧACDᑖ*HᧅᑁN|d┵ᑁN|¡ᡭ£ᑖ*Hᧅ¤¥~⏚¦§ᑭ©ᐭ┵Ḅ⏚Nª¡>ᐭᑖ*HᧅḄNNª«O¬◀ᵫ>ᐭ⏚®¯Ḅ°Nª±²VI-V2ூᫀ}᪆௃6ᫀ9"প.d°/ᓄµ)*
ᡂ⏚µd°
678!"2Al+2NaOH+2H2O=2NaAlO2+3H2Tᦑᫀ!2Al+2NaOH+2H2O=2NaAKh+3H2Tফ.·╅!3%~¸¹Ḅ·;ᨬ5.4gᔠ¸Ḅu;!5.4gx(l-3%)=5.4x97%g,»(J2A1+2NaOH+2H2O=2NaAlO+3H2T254g2mol5.4gx97%gVxl0-3Lx2.0moVLL54g:(5.4gx97%g)=2mol:(Vx10-3Lx2.0mol/L),}LV=97,NaOH)*ḄNª97mL╅½¾▬Ḽ⏚µ¡ᱥuÁÂÃÄMN¾ÅÆÇ:╅Ḅu;ᜧ╅Ḅu;ᑖᦪ%ᦑᫀ!97mL%6ᫀ\"ব.জ.ᔠ¸d⏚
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ᡂN┵N|ᜧ%ঞ.
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21ঝ.:ÑḄ0óᙠ½6ôEãḄNªᦪõö²!Ç:Ḅ°ḄNªᦈø°â:Ñᑁ*☢½ᓣãᦪú,ᡠCÇ:°ḄNª!VLV2,ᦑᫀ!VLV2஺28ஹ+3ZnFeO4+8H+=Zn2++2Fe3++4HO\/ᓄấ(ᡈSiOz)Ôᜧ⏚ḄXᡈ〉ÿᓣ
ᡈ22ᯏṺ⚩ᜧᡈᤅᩭ᳛H2O2+2Fe2++2H+=2Fe3++2HO⁚ḄpH,Fe?+!2ᓄ#$%&ூ⚪)*+௃(1)᪷.Ḅᓄᔠ0#+20ஹ2ᐗ4Ḅᓄᔠ0#-2056ᔠᓄᔠᱥᔜᐗ49ᦪ;#0,ᑣZnFezCh=FeḄᓄᔠ0#+30>?@ZnFe2O4AB⏚5ᑣ⏚DEZnFezOaF⏚GᡂIஹJI;K5ḄLMNOP#QZnFeO4+8H+=Zn2++2Fe3++4HOᵫBS2ᓄấUBV⏚5ᦑ⏚DXYZḄᡂᑖ\⌕^SiCh:(2)_ᜧ22ᱥḄ`ஹᓣ
ஹ_ᜧᱥab☢defg᳛5ᡠgfgiᵨ_ᜧV⏚Ḅ`ᡈ〉lᓣ
ᡈᯏṺ⚩ᜧᡈᤅᩭ᳛>(3)m2Kᐹᨵ2ᓄឋ5AqrJLM2ᓄ#JLM5ḄLMNOP#QH2O2+2Fe2++2H+=2Fe3++2HOstguᑖ᪆f@5X#ZnOᐸxᵨ#⁚ḄpH,Fe3+2!ᓄ#$%>(4)ᯏṺ=yᨵCuO,BV⏚X5V⏚&ᙠ{ᓄH=|ᐭḄ~5ᑮḄY^&஺29ஹ-122.6kJ/molAC>20O.lSmol-L-1-min-'KA=K>KIḄAHCO,ᓣ
5CBCO2!ᓄ#CH30HḄ⊝!ᓄ᳛BD<ூ⚪)*+௃(D᪷.5AH3=2AHMH2=-122.6kJ/mol(2)I
CO(g)+3H(g)CHOH(g)+H2O(g),223Aஹ^dḄ5ᙠឤᩩ5ḼḄ5Ḅ5ᡠglḄUE5Iᑮ⊝᝱5A>Bஹᙠឤᩩ5¡Ḅᔜ¢ᑖe^5ᑣḄ£¤;d¥¦U5ᡠg§ᔠḄ¨©ᢝU5UAIᑮ⊝᝱5B┯¬>Cஹ®E᎛eᨵKᑖM°±2NA²H-O³5´ᑖMGᡂ3NA²H-H³5l´ᑖMµEGᡂ;°±3NA²H-H³E5Iᑮ⊝᝱5C>Dஹ=5CH30H;H2OḄ`¶¥¦©ᢝU5ᑣ⌱⚗UAIᑮ⊝᝱5D┯¬>ᦑ⌱AC[c(CHqH)]2_042Mt-c(CHOCH).c(HO)-1.8xl.8=0.049V¼;332ᵫBᔣNᔣº»5¾H2O¿À!ᓄxmoIL-i,ᑣᨵ

22CH30cH3+HOÁS2CHOH23112x1.81.80.4yXX2xz1.8+x1.8+x0.4+2xᑣᨵQ■-[0'4+2x1--=0.25,+x=0.2,ᑣCH30HḄdᑖᦪ#Qa4+2xC)2xl00%=20%(1.8-x)(l.8-x)1.8+1.8+0.4(4)HI#Q2cO2(g)+6H2(g)kiCH30cHKg)+3H2O(g),᪷.⚪Ä5ᢗᧇ¶n(H2):n(CC>2)=12moi:6mol=2,᪷.ÇÈf@CChḄ⊝!ᓄ᳛#60%,ᓽAMCChA6moiX60%=3.6moL᪷.NOPf@QAn(CH30cH3)=L8moLc,1.8molÊ!Iv(CH30cH3)=---------------=2Lx5minO.lSmol-L^min1ᵫBA;CḄ̵5¡KÍ;ᨵᐵ5ᡠgK,\=Kc;Ï#HI^ÐÑ5Ti-Tz,CO2Ḅ⊝!ᓄ᳛5tO^ᓣtO5ᑣKA>KB;ᡠgᨵKA=KC>KB;(5)^ÐÑ5ᓣ
5⊝ᔣ⌮Nᔣº»5CO2Ḅ!ᓄ᳛>Ó⌱ÔឋᩭÕ5ÖᓄᑺCZ(Zr-l)TḄᦔÙÚÛ5ÓÜ᳛ᩭÕ5230࠷Eᵬ⏣ḄÜ᳛ÚÛ5ᦑ⌱BD(6)ßàÇÈḄXáâ5ḼḄᓣ
5CChḄ`_ᜧ5^Ï#=NH4HCO3ᑖ+Ḅ¤ãᩭãä5ᑣᑖ+^ᔾÑ5ᡠg(NHQzCChᣓçCChḄ^ÐÑ5ᓽAH<0஺