浙江省临海市白云2021-2022学年高考仿真模拟化学试卷含解析

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17A.᪷®\ᵬᡠ°©±²ᙠ40(TC,{|³4Ḅ´ᓄ᳛ᙠᔠ¶·¸2g/L,ᨬᜧA┯()B.\º⊤¼½³Ḅfj!ᙠᔠ¶·¸2g/L,ᨬ¾ᐸÀᔜ|ᔠ¶·¸,fj!ÂÃ2g/L,ḄnB┯()C.\ᵬ⊤°Äᨵᙠᔠ¶·¸2g/L,½³´ᓄ᳛ᨬᜧÅ\º⊤°ḄMÄᨵᙠᔠ¶·¸2g/L,½³´ᓄ᳛ᨬ¾©ÆÇ.Mᔠ¶·¸ÈᜧÉᓄᑺឋÈnC┯()D.\Ë⊤°ÌÍ1ᙠᔠ¶·¸2g/L,½³´ᓄ᳛ν³Ḅfj!ḄᓣnÅÐᜧÅ\Ñ⊤°ÌÍ2ᙠᔠ¶·¸2g/L,½³´ᓄ᳛ᙠ½³Ḅfj!20(TC,oÒÓnÔn0ÌÍ1,ᑴÕḄᔠ¶ḄÉᓄឋh²ÌÍ2i0ÌÍ1,D)ᦑᔠᳮ⌱⚗MD஺18ஹCூ᪆௃A.CO2ᙠ$Ḅ×!.ᜧسᙠ$Ḅ×!Óᜧ;NᐜÚᐭسÜᕈ>ឋᑭ0ᔾᦈ"_ḄCO2,ß<"_ḄNaHCCh,ᦑA┯()B.┵áâஹãâ$ᨵäḄåæ.çèéêᡈìᑴḄí!ÇÔîlïð,©hñò!⌼ᡂ(ôᡠ.◤⌕ïð┵áâᡈãâᦑB┯()C.⏚ឋn═⏚ö©÷ºø¢ᓄ6¢ᓄùú>ûᮞ©ᔾᦈ6¢ᓄùså³ᓽ©ÕþÿḄᵬᦑCD.ᐜ᠒!"#┵%&'⁐Ḅ)ᓄ+ᵨ"#Ḽ./Ḅ)ᓄᦑD┯12ᫀ⌱C஺ூ!௃⏚ឋ:═⏚<=>?@AᓄBCAᓄDEFᐭHIJKᮞᔾᦈCAᓄDOPQRᑮ◀ᩖḄVḄWXYZḄ᧕┯஺19ஹBூ᪆௃᪷^ᨵ`ᱥḄᑖcde,c4H8a2Ḅghᨵ`ᱥ,ijᨵCkᵬlḄmᑖn᪀ᐳᨵ4q,ᑖrXCH3CHCICHCICH3.CH3CCI2CH2CH3,(CH)2CClCHCk(CH)CHCHC12#32322ᫀ⌱B஺20ஹAூ᪆௃A.ᔣ1L0.5mol/Lt⏚=uᐭNH3vឋ(xᶍ=z)ᓄ)n(NHQ=n(C|)ᡠNH?kᦪB0.51,ᦑA

18B.ᔣjᨵFeLḄ=uᐭ〉IQQᐜAᓄỚcᨵFeLḄᱥḄI+ᨵ1molFe"AᓄᵯcḄᱥḄIᦑB┯1C.᪗hCᵬX22.4LCᵬḄᱥḄI+XImol,ᦑC┯1D.ᵨឋᵯ᩽ᵯCuSO,=▢᩽ᐜZᡂᓫZᡂQ᪗▢᩽Zᡂ22.4LQḄᵯcᦪᜧ2NA,ᦑD┯1஺2ᫀ⌱A஺21ஹAூ᪆௃SO2ᙠ᩽ᜫᵯcZᡂSO4%ᡠPtlᵯ᩽B᩽Pt2ᵯ᩽B᩽஺ூ௃A.Ptlᵯ᩽CAᓄAᓄᡂ⏚ᜫᵯc¡ZAᓄ¢£B᩽ᵯ᩽¤¥dB¦SO2+2HO-2e=SO42+4H+,ᦑ2A┯1B.§ᵯ¨Ḅ©ᳮBCAᓄ«AQḄ¢£ᓽ2so2+C>2+2H2O=2H2so4,ᡠᵯ®¥¯ὑḄSO2O2Ḅz±²B21,ᦑBC.cᓽcᵯ□cᔣ᩽Ptlᵯ᩽B᩽Pt2ᵯ᩽B᩽ᑣ§ᵯ¨ᵯcµPtlᵯ᩽¶®ᑁᵯ¸ᑮPt2ᵯ᩽ᦑCD.CAᓄ-ºQc»ᣚ½¾ᧇᵯ¨ᔾᦈÀºQḄCAᓄÁᑮÀÂÃḄÄᵨÅᱥᨵ⏚ÆÇ¡ᵯÈÀᑴ⏚ஹ¡ᵯஹÂÃÊËÌḄÍᔠᦑDᦑ2ᫀBA.22ஹAூ᪆௃A.ÏᐭÐᙽÒ᩽᩽¢£BZn-2e=Zn2+,A⚗┯1B.Ô¤ÕBÖᱨ□᩽Ḅ▢᩽ÃØÕᓽÖᱨÒ᩽ḄÐᙽÃØÒ᩽ḄÙᦑᵨ╅ᔠÜᩭÞßÐᙽB⚗C.ᵫáOᕈãJឋä¡ZᔾAῖ⇨ᦑ᩽¢£B2H2O+Ch+4e-=4OH-,C⚗D.èÃؤÕX᪀ᡂÀ©ᵯ¨ÖᱨÀÐᙽÃØÙᦑBÖᱨ□᩽Ḅ▢᩽ÃØÕD⚗2ᫀ⌱A஺Cஹé⌱ê⚪(ᐳ84ᑖ)H23ஹb&Na+b4KCIO3KC1+3KC1OAIH3HNH2AlH3+6HO=2Al(OH)+6Ht4232

19ூ᪆௃1.(1)᪷^mᕜíᐗïឋ⌴)ñòó2ফõÊᕜíḄᐗïö᜜øᵯcᦪX8#(3)ù⏚X⏚ឋúûᑺᐹᨵþAᓄឋ+úûJឋQஹÿឋP2O5⏚ឋᓄᱥᓄឋᑺឋ(4)᪷⚪⏚ᓄ᪷ᓄᔠ!"ᓄᑨ$%&'⏚ᨬ)᪷ᓄᔠ!ᓣ+,-./ᓽH.ᵬ2345ᐰᑖ89:ᑮ&'<ᕜ>ᐗ@ḄBCᓫEFH2,GHᵬBCIᓄᱥᵬJKLMNOPH2,QRSOP&'T⁐VWᱥT⁐VWXYNaOHXZGH[ᨵ]ᐗ@ᓄᔠᱥ^ᙠ`ᓄᑺaᙠbᑖ8:ᑮcF%&'ᓫEdᑣ^BC᝱Iᓄᱥdᙠ᪗hi᝱bḄjk1.25g/L,ᑣᓫEdḄ᥅mEnM=1.25g/Lx22.4L/mol=28g/mol,do^p஺ூ௃(1)a.Qᕜ>Ḅᐗ@rsᑮtuvwxyz{BCᐗ@|ᡂḄ□uvwBCᐗ@|ᡂ▢uvw{᝞r(Na+)Ḅᐗ@rsᑮtBCឋzBCឋᦑbc.Qᕜ>Ḅᐗ@rsᑮtᨬ!ᓄᱥMḄKᓄᱥឋz⏚ឋᦑc┯d.ᓫEḄᰚᓣ᝞Ḅᰚ╅Ḅᰚᦑd┯஺⌱b஺(2)ᕜ>Ḅᐗ@y᜜ᵯuᦪ8,ᨬ᜜ᵯuᦪJy᜜ᵯuᦪ,QḄᐗ@pᐗ@BCឋᓫ□uḄᓄឋᡠᕜ>ᐗ@ᓄឋᨬḄᓫ□uNa+#(3)⏚⏚ឋᑺᐹᨵᓄឋᵨ⏚NH3ஹHI#P2O5⏚ឋᓄᱥᓄឋᑺNH3#ᡠᵨ⏚ᵨP2O5ḄHL⌱b#(4)¢2`ᓄᑺ400CRᑖ89Pᡂ£'ᐸ¥&'⏚%&'Ḅ▢□u¦ᦪ11,ᑣ⏚KCLKC1¥ᐗ@ᓄᔠ!-1,GH⏚¥ᐗ@ᓄᔠ!+ᑣ%&'[⏚¥ᐗ@ᓄᔠ!§ᓣᵫY⏚¥ᐗ@ᓄᔠ!+5,ᑣᐗ@ᓄᔠ!ᓣ9©ᓄᡂ⏚᪷ᓄSLM¥ᓄᔠ!ᓣ+,-400"C./LMª4KC1O3=KC1+3KC1O4«Hম᪷¬ᑖ᪆ᵬ]ḄIᓄᱥA1+3!ஹH-1!ᓄ®¯AIM#^ppḄᵯu¯HdNdH஺(6)AIH3JKLMPᡂIᓄ]FILMḄᓄ®°±¯2A1H3+6H2O=2A1(OH)3+6H2b(7)A1H3¥[-1!H,NH3¥[+1!H,²PᓄSLMOPH2஺

2024ஹ()HCOOHIIIICH,HCH2coOHBCCOXIICIICOOC'H,A+3Na()HCII2COOHNIL('HC'IIC()()Na2H.NCOOXa+C,H()I13NaOOC4-ILOonOHHCNIHH.()HCHO-------->CH,CN—CFLCOOHXIINH3('ll('OOHRfᩩhூ8᪆௃ᓄᔠᱥA¶✏¸ᓄᔠᱥᓽA¥[ᨵ¹º᪷AḄᑖu¯»A²P¼½LMA¥[ᨵ¾¿᪶ÁᐳÃIÄᨵ5'Qᓄ®º᛻ḄIu᪷¹dp⏚ᵬÆAḄÇ᪀¯2cHO,᪷ঝÊËBOH0HO_CH^HCN᪷ঞÊËCḄÇ᪀¯ḄÇ᪀¯^Q^-CHICHCOOH
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21()IK,OOHIIIICHOC-NCHCHCOOH,Öᑖ᪆஺6ூ×8௃oHCOOIIIIII(1)᪷¬Üᑖ᪆FḄÇ᪀¯(H()C—NCHCHCOOH.6(2)Aஹ᪷AḄÇ᪀¯A¥[ᨵÝÞ¾¿ᦑA┯Bஹ᪷BḄÇ᪀¯Ð¿ᡠßàuḄ,áḄÑÒ¬ᨵH,ᓽ²PâãLMᦑBCஹC¥[ᨵ¹º²P2ᡂLMᦑCGäDஹᓄᔠᱥD¥[ààåæᡈèæ²P2éLMᦑD┯êᫀ⌱BC#(3)᪷ìíîïḄÇ᪀¯Imolìíîï¥[ᨵImolð¿ஹImolÆ¿ஹImolñæòÖImolìíîïᨬóâIINC()NHCHC()()CII(ὑ3moiNaOH,ᐸᓄ®°±¯τ+3NaOHCOOHNH.A6+CHX)H+H2OII-.NCOONaNaOOC(4)ᨵ'Qᓄ®º᛻ḄIuGHüÇ᪀ᨵýᱥþ¥ឋ,ᨵýᱥ¥[ᢈஹ-NH2ஹ᪷DḄ᪀,ᑖ᪀ᨵNth,ᔠ⌕ᑖ᪀(5)⏚Ḅ᪀H2NCH2COOH,ᧇᵬ"#᪗%ᱥ⏚'()*+,ᵬ"ᐜ.HCN/0(ᡂ230ᡂHOCHzCN,ᙠ⏚560ᡂHOCH2coOH,ᯠ8ᙠ9ᩩ;<.NH3/0HzNCH2coOH,

22onOHHCNHCHO-------►CHCN----------►CHC()()H2ᓽᔠᡂ?@NILNHI3(H('OOH-fᩩhூBC௃E⚪ḄGBᑖ᪀ḄHᑏ3JᔠḄᩩ;ᐭLᑨNOᨵPQRᡈ᪀᝞E⚪⌕ᨵUᱥឋᨵUᱥWXஹNH2ஹᓽNYOZᔠᡂNO2,ᨵUᱥᨵ[\Wᓄ^_᛻Ḅa,bcde᪀ᓽf_3ᨵ[*ᵬJgᑨNO᪀஺25ஹHNO3AgNChi⏚⏚ᓄḄ2mL0.1mol/LAgNO3Ḅ56pH=2
23j᳛lmᡈ23ḄnᓄQoᜧqNOj+4Fe+10H+=NH++4Fe2++3HO(ᐭrsti⏚(uvwᐰy5z{ᔣᡠ~56(ᐭt⏚42%0⁐WQFe2+Qi⏚ᓄᡈᓄூz᪆௃1
FesQ.i⏚230ᡂi⏚ᡈFe.i⏚230ᡂi⏚2
জ(i⏚⏚ᓄḄ2mLO.lmol/LAgNChḄ56pH=2
dঝ1ᑮ⁐.23j᳛lmᨵᐵঞ/0NO3-+4Fe+10H+=NH4++4Fe2++3H2O,ὑa,pH'ᜧট¢56ᐜ£ᡂ¤¥⁐g8⌲§ᕈ©ª⁐«᦮*¢®NO%0ᑣNth-N±ᓄNH4+#3
Ag5²i⏚W5²⏚4
³´µ¶56(KSCN5656£·¸³´,³´¹᩽«,Qi⏚ᡈᓄ஺ூ»z௃1
¼O½¾¿Fe?+QFe.HNO3ᡈAgNCh23Ḅ%ᱥ2
জ2ᡠᵨḄᑺi⏚⏚ᓄḄZmLO.lmol/LAgNChḄ56pH=2
,.1dঝÃᧇÄÅ¿ÆÇ<0.1molLÈḄAgNCh56ÉvFeᓄFe2+.«1ᑮ⁐ḄÊQ23j᳛lmᡈ23ḄnᓄQoᜧঞ23ὑa,pH£ᜧᑣpHËÌᘤÎ~ḄqÅqটÎ~2ᨵNHJ0ᡂᑣ2/023Ḅ,Ï¢NO+4Fe+10H+=NH4++4Fe2++3HO323
Ïᫀ¿ÑOÒsÓ⁐wÔÕ8(ᐭrsti⏚(uvwᐰy5z{ᔣᡠ~56(ᐭt⏚%0⁐Öᡈ(ᐭrs⏚ᨵÓ⁐wᒕØÙÚcÓ⁐wᨵAg#

23(4)iᫀdRklmno

24ÛÜḄÝÞe-c—d—g-h—b—a—f,ᦑàᫀ¿e#g#h#b#a#f஺(3)᪷á⚪~OᑺXâã⏚ᦑàᫀ¿âã⏚஺(4)᪷(2)~ᑮäåæçᮞḄᵨéê■ìíîïᐭäåðᦑàᫀ¿éê■ìíîïᐭäåð஺(5)+⏒ò(COCL)óBô[òᵬõ᧕ᢵ/ÊøäåðùíúᔠᱥḄᵨ■ì[òᵬõᢵ/û+⏒ò6ᓄüýᳫÿḄ
ᵨᜧᱥḄ☢᳛ᦑᫀ■ᵬᢵ!"⏒$ᓄ&ᜧᱥḄ☢᳛஺II(6)"⏒()*ᵨ+,-ᔾᦈ0ᡂ234ᓄ56Ḅᓄ789:COC12+4NHyHO=CO(NH2)+2NHCI224+4HO,2COOHcoa6+cod6+CO2+HC1121g140.5gxg562g121gxg=140.5g562g;┵@PCbஹPBr,NF3ஹNCbBᵯDEFGHIḄJ᝱LMᑮF3OHIḄJ᝱PQR᝱ST*ᐝḄ@:VWHXNiḄYDZ[F\]^ᵯDᦪ`FabcdFeC5.36x1()32>^a2cNAூ᪆௃(1)R᝱fYD᪶᜜ᨵ28jᵯD᪷l᪀⌼YᳮpᑏNiYDḄᵯD᣸s:tuᩞᧇxᡠzᐗ3KஹCaஹNiஹFeஹAs,|}ᐗ3ḄR᝱YDx~ᡂᵯDᦪᑖ1ஹ0ஹ2ஹ4ஹ3#ফDzᨵFe,C,N,04ᐗ3bcC,NO,YD⍝tᵯDᜐᐰஹᐰஹZSFᔠCஹNOḄᵯD᣸s:ᑖ᪆;&(3)জ᪷lVSEPRᳮᑨAs(V-Ḅ᪀BᵯDᢣYDᦪ]ᵯDᦪ(ḄঝᵯDEGH᝱LMᑮOH᝱S⌕VWHX&(4)bcᨔᰚ¥¦ḄGObcdḄe§ᨵᐵbcdḄe§]^ᵯDᦪ`4bcYDḄZ[ᨵᐵ&

25(5)জ᪷NiḄᨔᚮNbdᕈABCABC……5☢bᨬᚮNঝᵫᨔ@᪀@ᔠᙳ,fg%ᨔᨵḄNi^As%ᦪ¢£ᨔḄop᪷ᨔ6¤=ᨔop+ᨔ6Nfg஺ூ¨©௃প¬᝱®᪶᜜ᨵ28%ᵯNiḄᵯ᣸³dz[AiJ3d84s2,´µᩞᧇᡠᐗ]zKஹCaஹNiஹFeஹAs,»ᐗ]Ḅ¬᝱¼ᡂ½ᵯᦪᑖ¾51ஹ0ஹ2ஹ4ஹ3,¼ᡂ½ᵯᦪᨬBḄ5Fe,ᦑ*ᫀz{3d84s2#Fe#ফÀÁᨵFe,C,N,04Âᐗ]ÃzCஹN|O,Ä⍝´ᵯᜐÇᐰÉஹᐰÊஹËÉÌÍΣÏ2PÄ⍝´ḄᵯzËᐙÉѽΣÒ᧕ᜫÔᵯᡠUCஹNஹO:Âᐗ]ÕÖᵯÁᨬᜧḄ5Nᐗ][Fe(CN)6aᨵ6%À×Ø6%C:N,"#஺Ø|ᐔØḄᦪÚÛz(6+6)6x2=11,ᦑ*ᫀz{N#11#বজ½ÇAsCh%᪷VSEPRᳮAVP=BP+LP=3+”"3+3=%ᑣAsC^•Ḅ6᪀áz:â┵äåᵯ652ᢣçᦪÑèéᵯçᦪSÑèḄêë|AsCh"ìzåᵯ6Ḅᑖᨵ{PCh,PB0NF3ஹNCbåᦑ*ᫀz{:â┵äPCbஹPBnஹNF3ஹNCbåঝᵯíî᝱ïðᑮ9᝱Ì⌕ñòpᡠUᯚ⁐HIᳮ5õ?᝱ḄᵯípÍîḄÄ⍝ïðᑮpÍ9ḄÄ⍝ÌUÖ£ö÷(T!ᐝúû)ᐝḄädñòpᦑ*ᫀz{ᵯíÍîýḄõ?᝱ïðᑮÍ9ýḄõ?᝱þÿ᝱ᐝḄ(4)NiḄᵯᦪᦑNiḄᰚ!"#!ᙳ%CaḄ&ᦑ'ᫀ)*NiḄᵯᦪ(5)জ᪷-╋Ḅᚮ0123NiḄᨔ5ᚮ06ᕈ8ABCABC……9:;<☢>?6ᨬAᚮ0A⌱⚗TᳫᑣWᨔ5IJ3)C,ᦑ'ᫀ)*C#ঝᵫᨔ5Z᪀M\Ni]Rᨔ5Ḅ⚔!"4ᩩ`abFᨔ5KcᨵNiᦪ=8x1+4xe=2,As]Rᨔ5ᑁh8459+752ccᨵ2FAsᨔ5j=2x—g,ᨔ5Ḅk0V=axlO_10cmxaxlO_10cmxsm6O°xcxlO'10cm=—-----xlO'30cm3,NA9c59+752x---------g5.36x10325.36x1()32NAᦑᨔ5ḄAlp=g»cm'3,ᦑ'ᫀ):^a2cNq??ஹnoACNA2ூ!s௃u⚪Ḅ᧕┯!"y!)(5)ঝKᨔ5Ḅz{⌕}~ᨔ5Ḅ☢<<⌕}~☢☢0Ḅz{6஺

26H0ᓄᑺH2-OH29ஹஹᡂHH22H-OHH2-OH2CH-CH=CH-CHO>CH=CH-CH-CHO>OCHJCH^HJO322CH=C-CHOn2HQ/«ᓄᑺCu/OjCu(OH)?CHj-CHzOH►CHjCHQHCHjCHO►CHjCOOH.CHJCOOCHJCHJ------------------᯿-----------ᯠ------------------+ᦈ⏚/ூ%᪆௃⚪ᑖ᪆*1᪷-BஹDḄZ᪀MSCḄZ᪀€OOH¢£¤¥£ᡂPTT,PTTḄZ᪀<¦§¨”ᔢ஺«᪆*1
BḄZ᪀CH2=CH-CH-CHO>2CH=C-CHO25
CH=CH)À⌕ᧇᑴᜓÄ⏚ÄÆÄÇ¡±¢£ᡂ£ᡂÄ⏣Ä⏣ÉÊᓄ)ÄÄÊᓄ)Ä⏚,22Ä⏚¡Ä⏣¢£Æᓄ£ᡂÄ⏚ÄÆᔠᡂÌÍ):HXWItMWOtfl,Oha/JHCHFUO.CHfCHjOH.CH|040*CHiCOOH,CHiCOOOiKHi0

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