浙江省丽水2022年高考仿真卷化学试卷含解析

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20GH⚪Jᫀ:24ஹ_ஹ()CHCOOHWX©1^Na2cO3OONa+2NaHC033vX)Na3mol4nmolூ2᪆௃᪷⚪ᔜᱥᓄᐵ᪷mᩰ⏚Ḅ᪀:;ᵬZᙠᓄᑺḄᩩQRḄWXRᡂACH3COOHCOONacbAQRᓄTRᡂB1ClBQRឋm2CVoNa»C⏚ᓄmᩰ⏚mᩰ⏚Z"⏚QRWXTRᡂ¡ᓛ᪍NM,ᑣMCH3COOH,¡ᓛ᪍QRWXTRᡂ¤¥*(CH3)2COHCNQRm2D(CH3)2COHCOOH,Dᙠ¦§⏚¨ᵨQRª«TRᡂECH=C(CH)COOH,EQR¬TRᡂF23FZ¡ᓛ᪍TRᡂ®¯¡ᓛ᪍°±²ᡭ´J⚪;ூ12௃᪷⚪ᔜᱥᓄᐵ᪷mᩰ⏚Ḅ᪀:;ᵬZᙠᓄᑺḄᩩQRḄWXRᡂACH3COOHCOONaC¶C1BQRឋm2CCbAQRᓄTRᡂBONaC⏚ᓄmᩰ⏚mᩰ⏚Z"⏚QRWXTRᡂ¡ᓛ᪍NM,ᑣMCH3COOH,¡ᓛ᪍QRWXTRᡂ¤¥*(CHGCOHCNQRm2D(CHSCOHCOOH,Dᙠ¦§⏚¨ᵨQRª«TRᡂECH=C(CH)COOH,EQR¬TRᡂF23COOH(1)TজḄᩩSB(}clᱥ¸B^ᨵḄ?@A¹SºN,ᦑJᫀL_N(2)᪷☢Ḅᑖ᪆:;MḄ᪀89CH3COOH

21(3)TঞḄu¼WXTDᙠ¦§⏚¨ᵨQRª«T½:S`N_o¾QRWXTRᡂ*ᡠTটḄpÁnᱥḄ᪀89(4)mᩰ⏚ZÂNa2CO3gh@QRTḄᓄÃcd9Ä^°"+2NaCOp"+2NaHCO,:23(5)᪷¡ᓛ᪍Ḅ᪀89:;Imol¡ᓛ᪍ᨬʪὑNaOHḄᱥ¸ḄÂ3mol,®¯Ìᦔ¡ᓛ᪍Imol®¯Ìᦔ¡ᓛ᪍ZNaOHghᐙᑖTᨬʪὑNaOHḄᱥ¸ḄÂ4nmoLூÎÏ௃G⚪ὃÑᨵᱥḄÒÓZᔠᡂ᪷¡ᓛ᪍ZÌᦔ®¯¡ᓛ᪍Ḅᑖ9ÒÓFḄ᪀S2⚪ḄᐵEÔÕTḄᑭᵨ⏚ᓄ×-CNAᓄ-COOH,◤⌕ÃR᪷ᓄᐵᑨÓÔÛÃRḄÜÃ@Ýஹᳮ2@Ýஹᑖ᪆ßà@Ýஹ;áâã@ÝḄὃÑ஺25ஹMnO2+4H++2a>Mnr+Cht+2HOHC1ChWäÂmåæç,2¬ᐭé⏚eNêé⏚nRë⁐ìíqrᨵiî=ïðñ:;m^H*ஹcr,ᓽZmTRᡂóH+Ncr,Ḅᓄᔠôïõôö÷ᑮ-1ôùᯠ⌕ᨵᐗüᓄᔠôᓣþHÿᨬᓣᨵᐸᐗᓄᔠḄᓣᐗᓣᑮ+1஺⏚ឋឋᐭ!"#$%&⁐()c(C12)*+,-./ᐭ012Ḅ⛳ᓄ4"#"#5678⁐()9:Ḅᐭ;<ᡂ>C12,ᓽ@!ḄABC⌮ABEᜧ9:GHI⊝ᔣABᱥMᔣNOPC12EQᡠSᕈU68⁐ூW᪆௃(1)Z[ᓄ═G]⏚ᙠ_ᩩabAB<ᡂ@ஹᓄ═!d(2)জG]⏚᧕ᢵhᑴjḄ@kᨵᓄlmnᓄlopqr⏚l4AB<ᡂZ[ᓄrWsdmn@ᓄlᙠ⛳t]!u"Wឋv⌱x◀ᩖM{dঝ}~@q!ABḄᱥᐹᨵឋB✌ᐜ᣸◀@Ḅ◤⌕}dঞmn9:opq9:AB<ᡂᓄ⁐⁐"⏚Ḅឋ}9:Ḅᙠd᪷nᐗᓄᔠḄᓣ,ᩭᑨvḄdট¡Ḅ}¢£¤¥}¦§ᑮ}U¨q}IஹIIu©ª()!ᐹᨵឋ⏚ឋd(3)mn@"#!«ᑖq!AB<ᡂᓄl⏚ᙠCL+H2O0IT+Cr+HCK),mnᓄI⊝NO®ᑖ᪆W¯஺

22ூ°W௃(1)Z[ᓄ═G]⏚ᙠ_ᩩabAB<ᡂ@ஹᓄ═!9:M±²:´µ_MnO2+4Ht+2Cl^=:Mn2+Cht+2HO2(2)জG]⏚᧕ᢵhᑴjḄ@kᨵᓄlmnᓄlopqr⏚l4AB<ᡂZ[ᓄr¶·ᨵ&⁐@¸<,!ឋ}⌼ᡂ᡾d@ᙠ⛳t]!u"WHᜧᓄl᧕"!ᡠSCSᵨ½ᨵ⛳t]!Ḅ¾@¿◀Àᓄldᦑ¯ᫀ.ÃHC1.⛳t]!ঝ}I
ÅᨵÆᐜ~)Ḅ@&ឋᑣo~)@q!ABḄᱥᔲᐹᨵឋÃᦑ¯ᫀ.ÃC12ঞ9:opq9:AB<ᡂᓄ⁐⁐"⏚ᡠS}9:ᙠḄM{ÃjÉÊ!ËÌuᐭ⏚Í⏚Îᨵ⁐<()ᨵᙠdÏ}CÐ!ukH*ஹcr,ᓽ@q!AB<ᡂ>H*cr,ḄᓄᔠÏ/,-ᑮ-1Ñᯠ⌕ᨵᐗᓄᔠᓣHÓᨬᓣᨵᐸᐗᓄᔠḄᓣᐗᓣᑮ+1dট¡Ḅ}¢£¤¥}¦§ᑮ}U¨q}Iஹnu©ª()!ᐹᨵឋ⏚ឋᦑ¯ᫀ.Ã⏚ឋឋd(3)@"#!«ᑖq!AB<ᡂᓄl⏚ᙠCL+FhO^^H++Cr+HCK),ᐭ!"#$%&⁐,()C(C12)*+,-./ᐭ012Ḅ⛳ᓄ4"#"#5678⁐()9:Ḅᐭ;<ᡂ>CL,ᓽ@!ḄABC⌮ABEᜧ9:GHI⊝ᔣABᱥMᔣNOPCLEQᡠSᕈU68⁐஺ூÔÕ௃@Ö×ᐹᨵឋq!AB<ᡂḄ⏚ᐹᨵឋ!ḄᡂᑖᨵÃ@⏚!l9:9:⏚᪷9:l[᪷9:஺26ஹI⊝@ØSÙᐵÛÜÝᜳßᙊáâ¿ᑁ@Øäᜧ■æçèéḄ#1ᐭêëÌu(íî@ï)ñᘤᵬᜐõ#&ö÷#1ঝজঞd,-øᬀöᙠ!uḄ"WHᨵᑭᑖû◀ÀøᬀöuḄ!ᡈRjCOOCH,CWpHRCOOCH+3NaOH—»AR<,N«+CHOII353.6g/L(IூW᪆௃ᙠA¢£u_

23⏚415678#ᵨ15⃓ᐸ<ᨵḄᬀᐭ=⏚>◀@⏚)ABḄᨬDEFᑮᬀ஺᪷JᬀḄK⌕ᡂᑖN'ᾦPQNaOHRSTUVWᾦX⏚>Yᵞ[BḄNaOHᵨHCI\]᪷J⏚^Y\]_`ᐸ<ᨵḄᬀḄaB4FᬀᾦḄYᵞÂRJCOOCHJCHQHRSḄᓄÄÅÆÇ+3N^>H—♦5RC(M>N»+<'HOHÈ1ম᪷JHCl+NaOH=NaCl+HO,ᡠun(NaOH)(*>=n(HCl)=0.1mol/Lx0.020Lx_200mL.=0.016mol,ᑣᾦRSḄ2a25.00mLᱥaḄBḄᱥaḄBÈ0.5mol/Lx0.08L-0.016mol=0.024mol,᪷JᬀNaOHRSḄᱥaḄBḄᱥaḄBᐵÌÍᐸ<ᨵḄᬀḄᱥaḄBn(ᾦ)=1n(NaOH)=-x().024mol=0.008mol,ᐸaBm(33ᾦ)=0.008molx884g/mol=7.072g,Î!|Âᬀ<ᨵᾦ7.072g+0.02L=353.6g/L஺ூÑÒ௃Ó⚪ὃÖ×ᓄĶ·ØÓ¨©ḄÍÙÚÛ¨©ª«ஹ
Ý_ḄÞḄஹ⏚^Y\]Ûᱥa?@ABᡂ.Ḅ9:#Ḅ;<62.00g,9:=;<62.00g,>?ABC01ᓄ3ḄDᑮC஺Ḅ;CoGHᱥ;Ḅ,᪷>CoஹHஹCᐗMNឤ@PᩭRS'43⏚6ḄᓄT4

24(5)VᨵC஺(A10)2ḄXᴻZᵨ\]^_`abᐗMḄᯚ⁐9:eXᴻC0CI2,ᔣst$ᐭu1.CoC()3,3u1.ᐹᨵw1ᓄឋyz{|H1ᓄ<{|H|H9:}~4<2Fe2++H2t>2+2H+=2Fe3++2H2O,$ᐭC0CO3,⁚stḄpH7.6,Fe(OH)3ஹAl(OH)3ᡂᯠ=pggCoஹHஹCᐗMNឤ@Px;y;z=0.015mol;0.02molx2;0.02mol=2;4;2,ᦑ120gAnol'43⏚6ḄᓄT4

25ট\2³¼st½¾s;Ḅ\\}<¿/ஹᓾᨔpg஺ூ᪆௃ᔠAᑮḄ9:ᩩÂ@PAÃÄḄHÅBr¾ÆᔠBḄᑖH4CḄ᪀@RÈAÃÄḄÉÊË()ÎÏGHžÆDᑮB,ᡠBḄ᪀Ð4<ÑÒBCḄ᪀@RÈBᑮCḄ9:ÓÔ⚪¶ᡠÖ×ØজᔠDḄ᪀ÙEḄᑖH4@PEAḄ᪀Ð4@PAḄᑖH4ᑖ᪆ÑÒBCḄ᪀@RÈBᑮCḄ9:ÓÔ<¾Æ9(;9:(2)ᵫDḄ᪀@PDVᨵÉÊÜÝÜÝÞ3⏚ß9:Ḅᱥ;ḄàÒ<2:1,DÞ3⏚ß9:Ḅ}~4<(4)á⚪â@ᑨäåᨵF᪀æᙠÉÊçឋ3GHe3GHèᨵÃÄஹÏGHஹᵬÝஹÜÝDÈéᫀ:(5)ì✏îᓄᔠᱥMÞAï<ðᑖñ᪀´Myòó9:ôõMᨵÉCHO᪀ö÷ᩩÂḄMḄ᪀ᐳᨵ14ù¿ÃÄᨵÉʾÆÝúᨵ2ù¾ÆÝ<ÉCH2cH2CHOᡈÉCH(CH3)CHOÃÄᨵüʾÆÝúᨵ6ù¾

26ÆÝýᔠ<ÉC%ஹÉCH2CH0ᡈÉCH2cH3ஹ—CHOÃÄᨵ²Ê¾ÆÝúᨵ6ù¾ÆÝ<ÉCH3ஹ—CH.3-CHO,ᐳᨵ14ùᐸ᪶ᐳᨵ4ᓄ᛻Ḅ☢6:2:1:1Ḅ᪀ᨵ,◤⌕⏚!"#$%&'᪷)*+ঝ-.//01-234═⏚67ᓄᡂ9:;<ᓴ>?-2"#@A%&#ᡂ//01;ᡠ2ᵫ1-DEF!GᧇᔠᡂJ᪗LᱥḄᔠᡂNOCHCHCHBrN><)HA»CHiCH»CHKMnO)-CHC(XHICH,CKt<>H29ஹSrS0“+4C4QSrS+4cot1.2X10-10niol*L-lOIFR7ᓄ┞ḄTUVᢓᑴYᵨ;0[\]^ᜧ;`a7ᓄ╄cd᪆f■iQ]jka7ᓄl᪆f<⌼ᡂnᜫCa(0H)zஹMg(0H)jQᨔ22Fe"+H2s=2Fe"+SI+2H*Fe"—e-=Fe"ூU᪆௃(1)᪷OPQRS◞UVWᯏYZSrSO4[\]^(ᡂSrS,_Z`ᡂ6ᓄ]bcḄᓄdefg;SrSO+4ChiSrS+4COT(2)জ95cZjḄk^=1.0xl0-,2,pH12,c(H4w+)=1012mol/L,Kw12in-10Xc(OH)=c(“+)=lmol/L,c(Mg2+)=m@r=ᓃᑈ6=1.2x10"஺molL"ঝOHqrsᓄ┲7Ḅu%vᢓᑴyᵨOH-{|}ᜧ~sᓄ┲᪆sᓄ┡Ḅ᳛(3)“}”ḄḄ■i|sᓄ᪆⌼ᡂᜫ“”Ḅ⌕ᡂᑖᙠឋᩩᩭḄMg(OH)2!¢uᱥCa(OH)(4)¤}¥Ḅ¦Q§ᑮSr(OH)2©Ḅª«iᨔஹ}ஹ2®ஹ¯°(5)“ῃ”e²;ᵨFeCbu¦ᔾᦈ⏚¶`ḄW·¸~ᓄᓫ¹ᔾᦈZḄᓄᱥSºᵨ»¼ᵯ᩽ᵯ%ᔾᦈ¦ᵯ%}f~¾ᓄ¿¸ᓄ¾ᓄ¸ᦑᵯ%¥<ᙠ“ῃ”QÀÁᑭᵨḄᱥ¹FeCh»