2021-2022学年陕西省汉中市六校联考高一（下）期末化学试卷（附答案详解）

《2021-2022学年陕西省汉中市六校联考高一（下）期末化学试卷（附答案详解）》由会员上传分享，免费在线阅读，更多相关内容在教育资源-天天文库。

2021-2022
▷ḕ᪥ὶὃᓄᔁ1.ᓄஹᑗᐵ஺ᑡ!"#$%Ḅ'A.()*+,-.ᕡḄ0"␺2⇷4567B.8ᾦᙠ;Ḅ<ᓄ=ᵨ(?@ABCDEᑭᵨGHIJᳮLḂC.NE(ᵨOᑴCaO“2QRSᩭUVWXYZXSḄℍ⃔WD.᯼Ḅ^_`aᓄbᓄB᯼Ḅ.ᓄ5Sᓄ`aᱥᳮbᓄ2.dᑴ250mMḄNaCleSBᑡ#◤⌕ᵨᑮḄiᘤ'3.ᑡᱥklᨵn᩽ឋᐳrsḄtuᓄᔠᱥ'A.BaOH2B.CaClC.HOD.NaO22224.2022
ᓅxyᝍ{|ᵨ}~ᓄ╍CdTe
?ᵯᴻBᐸ?ᵯJᳮᙠᴻ⊤☢ấᓄ╍B|ᐸᐹᨵᐝᵯᣚ஺ᑡ!"$%Ḅ'A.112cd114cdB.ᔁ87eḄuᦪ128C.ᓄ╍'~ᨵᓄᔠᱥD.ᐁᓄ╍ᴻ?ᵯ*'ᓄᓄᵯ5.ᨵᒹ⁐B(lᨵNa2cqஹCaCGஹNaClஹCuSO4Ḅ~ᡈ¢~B£¤¥᪵§¨©᝞«Vজea@B®⁐¯°eS±ঝᔣজᡠeSµᐭ*¥·⏚⏚ᓄḄ4gN03eSBᨵ.¹5º»஺ᑣJ⁐½lᨵḄ'A.CaCl^NaCOB.CaC%ஹNaCl223C.CaCl,Na2c஺3ஹNaClD.NaCO,NaCl2236.ᑡᨵᐵNa2cO35NC1HCO3ឋkḄ!"$%Ḅ'A.NazCOs5NaHCO3ᙳ(ᵨa¿ᶭÁ⏚*ÂB.(ᵨµÃḄ0"◀ÅNa2c஺3ÆᨵḄNC1HCO3C.ÇᱥkḄ¥ḄNa2cO35NaHCqᑖ2*¥É⏚HIBÊ?஺“CO?Ḅk¥ᜧD.ᔣNazCOseS5NaHCO3eSᑖ2µᐭCaC%eSBÎ⁐º»7.ᑡᨵᐵnÏ`ÐᐸᓄᔠᱥḄ!"#$%Ḅ'

1A.®⁐ḄÔᓄÕ.¹⍗ᑮ×.{bØÙ⁐B.S02|⏚ឋ═⏚ßeSà⁐B¹á}5஺2ḄãäJឋC.æÔᓄấ'⏚ឋÔᓄᱥB#çè⏚HID.ê.)ᐭë⁐ìíeSBeSᐜbØïà⁐8.ᑡᱥkḄᑴᜓCDòᔠḄ'()NaOHC0ᨔ2A.õö÷TNaAlOzT4(஺B)3Tভ2஺3TõᰚᵯNaOHᰚᵯB.ᑴ£╅ý@TMg(0H)2TMgotMg$ᵯ%&C.N2+O2TNOTHNO3))*+Cl(1)ÿ2D.ỚTᔆf2(aq)Th(2)9.ᐵK2H3/06+9H/72K/+4/2+6H2஺&ᑡ()*+Ḅ-()A.K2H3஺6/01ᓄB.KI-1ᓄ5ᱥC.89ᑺ;1ᓄᑺḄᱥ<Ḅ=>?@71D.0ᡂ4zno஻2GHI9moiᵯM10.NG(g)+C0(g)=N0(g)+஺஺2(஺)ḄR=Sᓄ᝞UᡠW஺&ᑡ()*+Ḅ-()A.UXA-B@Z[\]B.^@ᔾ[C.`a1⊈஺c஺2(9)dlmoCO(g)ḄᓄghᔾᦈḄR=jdklᡂlmoNO(g)d(g)ḄᓄghᡠmZḄR=jdD.ᓣopq^Ḅᓄgr᳛tuvwx11.&ᑡ()t*+Ḅ-()A.yzᑖ|R}~Ḅᓄd⏚ឋo═⏚⁐ᐸ⁐9ᳮB.d᪀@ᱥ2⚓ᐳ20⚓

2C.p&ᵬ-u⁐ஹᕡḄᐹᨵ*☢᪀D.£¤d¥¦§ḄᑖM¨ᙳ@86«0஺5„¯°±²t@ᑖ³᪀12.y´ᙠᐝ᯿&/0¸¹ºᑮyḄ¹5ᱥᨬ½ᨵ¾A.10B.9C.8D.713.¿᯼ÁÂḄrq-ÃÄḄ7.5ÅᢙᰦឋÈÉÊ?o[ᦔ᳛o஺¿᯼Ḅ059ᳮ@C+”2஺¾஺"C஺+/஺ᓽ@ÏÐwÑÒᦪḄÔ&ᑡ()┯ÖḄ-¾A.12gl4cXᨵ?ᵯABCDEᵯAFᐸH⌕ᱯKLMNᵯOPQḄRS>?FᙠᵯA᜜UV⁚ᵯOPQFLXᢝᵯAᑁUᵯ᩽ᕜ]PQ^_Ḅ`a஺cC>?ᵯAd

3e᝞gᡠiFᵯAjkCu+PbO+2HSO=CuS0+PbS0+2HO.ᑡ224442lmnoḄ()A.akn᩽Fbkr᩽B.sᵯAtuv.PbO2ᵯ᩽▬xPQḄpHyᜧC.b᩽Ḅᵯ᩽kCu-2e~=Cu2+D.ᵯ>ᵫb᩽>|F}~>ᔣa᩽17.Aᩭ;<Ḅ⌕ᓄtᧇFLᵨᩭ⊝BḄ;<ᓄt஺B1DḄᨵᱥFDLᵨᩭ◀ᨨᡈḄ஺Eᐹᨵ✏ᕡFFBC¡ᑖ¢ᓄᔠᱥFᑴᡂ¥Cᒹdᩞᧇ஺(1)4Ḅᵯ¢¨ko(2)ᑡᐵªB«¬Ḅ®¯noḄ(°±²)஺A.³ᙠQ☢µB.¶·ᰚᓄᡂᐝ¹ḄºᳫC.ᨵ-¼ᡂ(3)஺ᡠ½¾¿ḄÀÁk-FḄÂ᪀Ĩk஺(4)µÅজஹঝஹঞஹটËᨵÌÍḄÎE(°±²)஺a.&ÏAÐᡂc.ÐÑd.ᓄe.OÒ4⚓Fᐳ20⚓

4(5)ᑏ|B-CḄᓄÖ×ب஺(6)ᵨ"(J᪗ÚB(ᓽB¢k18஺)ᵨªẆÝB,DḄᳮ•ᑏ|½18஺ḄDᵨ18஺᪗ÚḄBᡂEḄᓄÖ×ب(àá18஺Ḅâe)஺18.®ᨵজ~ণåCᐗçFজ¢᪶᜜éᨵBᵯ¢êজঠìHíFîᐗçঠḄᯚ⁐kñ⁐êডঠìᕜóFîডḄ¢ᨬ᜜õᵯ¢ᦪ÷ঠ¥2Fᐸøᐗçᙠᕜó⊤Ḅâe᝞gᡠi஺úûᑡü⚪þ(1)ᐗçজ~ণFᨬ¡ÿᓄᱥᓄᱥḄឋᨬḄᐗᙠᕜ⊤Ḅ(2)ᐗজঞণᡂḄ(ᓄ)ᐸᵯ#o(3)ᐗঞটডঢ(#Ḅ)*ᵫᜧᑮ.Ḅ/0(ᵨᐗ23⊤4)஺(4)ᐗঞḄᨬ67ᓄᱥᓄᱥḄ89:;<=Ḅ>#?@______஺(5)WBCDᕜ;ঢEFGḄᐗ஺HIJKWLMNᐹᨵḄឋQB(RS)஺A.ᨬ6Tᓄᔠ7+6B.V᝱XᓄᱥY;ញ[C.ᨬ67ᓄᱥᓄᱥḄ⏚ឋY]⏚^D..஺2_ᐹᨵᓄឋ19.᝞aᡠ4Ḅc@Bdefgᑭᵨi□NḄẆlmn஺opqrcosᐝᓄuvᔠᡂwᧇḄc@yzosᐝᔠ{ᵨ஺(1)aᡠ᪀}ḄᱥQ~NḄi□NᨬᓄN஺(2)osᐝᔠ{ᵨḄ⌶*Bᙠᓄᑺ~ᐝ᯿ᩩC02~“2஺ᓄCHOH,=Ḅᓄ?@3ᓄᑺ205(g)+4%஺஺)2cH3஺g)+3஺2஺)஺[ᩩᙠ2Lᘤᑁ=Kn(CGOH)Ḅᓄ᝞⊤ᡠ4/min0123456n(^CHOH)/mol0.000.040.070.090.100.100.103জ0
3minᑁᵨC/O^S)Ḅ¡ᓄ⊤4Ḅ¢ᙳ=¤᳛moZ8•min-1o

5ঝᑡ⌱⚗Nª«=¬ᑮ¢⊝¯᝱ḄB(RS°)஺A²°ᑁ³ὑ27710%0(g)Ḅ°»ᡂ1¼஺£஺2(9)B.n(CW0W)n(0)=2332C.ᘤᑁÆᔠVÇḄQÈᢝLD.ᘤᑁÆᔠVÇḄ¢ᙳ²ᑖ#QÈᢝL(3)Ì=Ḅ=¤᳛ÍᜧMÎÏᑡÐÑḄ஺A.ÈᢝᘤÇÒLrᐭXVÌÔÍᜧB.ÕÖסC.Ø.ᘤÇÒÍᜧÔD.ÍᜧC&¡(4)ᵨosᐝᔠ{ᵨᑮḄᵬ⏣(C/0H)ஹV~8]⏚ᑴ{wᧇᵯárᐭᵬ⏣Ḅâᵯ᩽=஺ä³ὑ4.48l஺2(᪗è¯é)ᑣᵯëìmolᵯ#஺20.ᓄᐶð.ñ°ᵨaòólôḄឋQI⁵⏚ឋ6÷ø…⏚ú9:ûüB(1)᝞aA,þ₩
ᑮ⏚ឋ⏚⁐ᑖ(“ᨵ”ᡈ“ᨵ”)!"஺(2)᝞&B,)*ᐭᑮ,ᨵ-.Ḅ
ᐙᑖ1₩☟45ᑮḄ678(3):;<=>Ḅ?@AᳮᐶDEFGHIJᵨ᝞&L4MNOP:জL4IITU?@ḄᓄHWXY:2Fe+3Br=2FeBr]஺23ঝL4HI
ᑁḄaᵨ8஺bᘤMḄaᵨ8஺ঞf=gTUhi?@Ḅ678஺ট?@kl)L4HmnᓾᡭqK2,ᑭᵨtuv)L4IḄ.ᔾᐭL4IIxyaḄzḄ8஺ঠxOP|ᑮḄ8}~-Ḅᐹᨵa.]b..]c.ᵨ6⚓ᐳ20⚓

6ᑺ]d.10%ḄNaOH]e..஺Ḅya:஺21.¡¢@ᵨ£¤¥¦§¨⚞ª§¨«¬ᵨ®ᑡ°±W²ᑴᜓẄFeSO¶7H20W²ᑭᵨ·¸¹º»⌕ᡂᑖ:CuFeSz
ᑴh¾X᝞&ᡠÀ஺Cuso►CiiSC%HQ4ÁÂ2ÃÁ2f᪻CuFeS2ᑺbÅÆÇᑖ□ÉÊËÌᓄᱥÎYÏÐÑḄpH᝞®⊤:ÓÔÉFe2+Fe3+Cu2+qÕÏÐḄpH6.31.55.2ÏÐÖᐰḄpH8.32.86.7:;1
yaTU?@CuFeS+O+H20CuS0+FeSO
+W022S442432ØÙÚÙÚx?@WXYÛᵨᓫÝ᫑²᪗àᵯâãḄWᔣ¦ᦪzo2
æ⁚pHḄᨬéë:஺3
ᑺaḄᓄHY:஺W²ᑭᵨ§¨ìíîᑴh¾X᝞&ᡠÀ஺〉ðNa2c஺3〉ðñò⏚§¨ìíîA?@I»õöA?@flAùú.nᓾஹkᨔஹᨵýþ~
f
TஹfẆIn4
I◤⌕ᵨᑮḄᴻᘤᨵo5
!"#CO$ᑨ&I'ᔲ)*+#,-'
ᑏ/ஹ01234஺6
6789:;FeS04-7%஺Ḅ<=>a.?@3.72gẆ9:+AB+ᙠ250mLD=E;7DFb.=@25.00GH6IJ┵LE;Fc.MᵨN⏚⏚ᓄḄO.Olnwl"TKMTI஺4AIQᐭ┵LE;ST+ាVWᐰSTYZὑKMnO,AIḄ\]^20mL஺জc;`aSTḄbc,de^஺ঝ᪵:;FeS%•7H2஺Ḅh=ᑖᦪ^
3klmᑮ0.01%
஺

7nᫀpB᪆1.ூnᫀ௃DூB᪆௃B>4⇷vḄᡂᑖ^xyh+z{Ḅᡂᑖ^|}~+⇷vᨵᯖḄᕡ+z{ᨵḄᕡ+!"ᕡḄ,-␺⇷vpz{+ᦑAmFB.ᾦJ+ᙠḄᓄᵨ!`aBSTaᡂᵞpᾦ⏚+ᾦ⏚!ᵨJᑴ⌼Ḃ+ᦑBmFC.ℍ⃔'¡¢£¤+ᐹᨵ¦§¨ឋ+ª«¬ᑴ(0")2®¯IaᡂẈ±⁐ḄC%஺+01³´+µ¶·!ᵨJ#¸¹+ᦑCmFD.᯼Ḅᓄ'Ḅ᯼»«¼STaᡂ᯼+᯼ḄIᓄ'M᯼ᙠᓄᵨaᡂI\½ᧇ+᝞ᵬ⏣Â+ᑣ᯼Ḅ)ÄஹᓄpIᓄÅJᓄ¶Æᓄ+ᦑD┯ÈFᦑ⌱>D஺A.⇷vḄᡂᑖ^xyh+ᨵᯖḄᕡFB.ᾦᙠḄᓄᵨ!`aBSTaᡂᵞpᾦ⏚FC.ℍ⃔<ᨵ¤£+ª«¬ᑴᙊ(஺+)2®¯ISTaᡂẈ±⁐ḄÌᓄÍÎFD.ᨵ¬ᱥhaᡂḄ'ᓄ¶Æᓄ+Ðᨵ¬ᱥhaᡂḄ'ᱥᳮÆᓄ஺Ò⚪ὃÕÖᱥh×ᡂஹឋhpTᵨÂØÙ+ÚÛᱥhḄ×ᡂ2ឋhஹ`aḄSTஹ␺,-ᓽ!Bn+ÝÞὃÕ¶aḄᑖ᪆ªßpàᵨªß+á⚪ᨵᑭJãä¶aåVḄæ¶~ä+çèéᐵ£ẠØÙḄ]ì+⚪íîïðᜧ.2.ூnᫀ௃BூB᪆௃B>ᵨᡲóᜩõ?=öᓄ÷\+ᙠøùᙠAB+úᵨᴻûᤅý+ᵨᴻûþÿ
ᑮ250mLஹᴻ
ᐭᔣ1
2cmᦋᵨᜮ!"#☢%&ᑗ(ᑴ*+,ᵨḄ.ᘤᨵ1ᡲ3ᜩ5ஹ6ᓇஹஹᴻஹ250mLஹᜮ!89:,ᵨᑮ;ᧅᦑ⌱1Boᵨ?@NaCl(ᑴ2507n஻7no஻LḄNaClAḄBCD1EFஹGஹAHஹ
ஹஹIஹ᤯ᒴ8᪷M(ᑴḄBC⌱N,ᵨḄ.ᘤ⌱O9◤⌕Ḅ.ᘤᓽS஺U⚪ὃXY(ᑴZIᱥ\Ḅ]ḄA(ᑴ^_.ᘤḄ⌱N᪷Mᱥ\Ḅ]I`aᳮH(ᑴcᳮ⚪de9ᜧgᙠὃXijklẠnoḄpqrs஺3.ூwᫀ௃DூH᪆௃H14{|ᓄ~~{|᪷ᙠஹ஺-Hcᙠ᩽ឋᦑA┯B.ᓄ┛┛ᙠᦑB┯8⚓ᐳ20⚓

8C.ᑖH-஺cᙠ᩽ឋᦑC┯D.*|ᓄ*|᪷ᙠஹ஺-஺cᙠ᩽ឋᐳᦑDᦑ⌱1D஺Zᩭᐗ᧕¢ᡂஹ¤¥ᐗ᧕¢ᡂ᩽ឋᐳ9¤ᐗ᧕¢ᡂ᩽ឋᐳIA¦Hᐗ◀᜜©ஹIIA¦VIA¦ஹVIIA¦ᐗ᧕¢ᡂª᪷⏚᪷ᙠ¬ᨵḄᓄᔠᱥ®ᓄᔠᱥᓄᔠᱥS¯¬ᨵᐳ.U⚪ὃXᓄiஹᓄᔠᱥᐵ±²³ὃXlUᭆµ¶ᱥ\ᙠ·¸_·¸¹ᵨºᓽSHw»¼*|ᓄᵯaḄ¾ᑏ.4.ூwᫀ௃AூH᪆௃H1A௃*cd%114cd®╍ᐗḄ9¤cÂD¤ÃᦑAB.ᦪ=\ᦪ-\ᦪ=128-52=76,ᦑB┯C.Æᓄ╍9¬Çᐗ®Z¥ÈÉᓄᔠᱥᦑC┯D.ÊËᵯᴻ¯ᐝ¯ᓄDᵯ¯ᦑD┯ᦑ⌱1AoA.¤Ã®¤¥ᐗ¢ᡂḄ9¤ḄckÍ®cB.ᦪ=\ᦪ-\ᦪC.¬ᨵÇᐗḄᓄᔠᱥDᨵÉᱥ◀ÎÇḄ|ᓄᱥஹÇ⏚ஹÇ⏚Ï8D.ÐM¯ᓄ¢aHw஺U⚪®ᱥ\Ñ᪀ḄÓᔠὃ⚪^_¤Ô¢@ஹcÑ᪀8no◤⌕ijᐹᨵÖ×ḄlUØ⚪de9ᜧ஺5.ூwᫀ௃DூH᪆௃H1জÚÛ?@ÜÝ"#AHÞÈ⁐à¶AZI9¬ÈCuSO,NazCq%CaC%¬ᨵZ¥ᡈâ9ᙠ4ঝᔣজᡠÞAᐭ*å⏚⏚ᓄḄ4gN03Aᨵæ@çèéj¬ᨵNaClஹNaCO,9¬ᨵCaC%ᑣcë⁐ìíZI¬ᨵḄ®NaCkNaCO,ᦑD2323ᦑ⌱1D஺জÚÛ᪵ïAÝÞÈ⁐ðñAZI9¬ÈC1ZSO4,Na2c஺3%CaC%¬ᨵZ¥ᡈâ9ᙠঝᔣজᡠÞAᐭ*å⏚⏚ᓄḄ4gN03Aᨵæ@çèéj¬ᨵNaQஹNaCO,Mòówᑨõ஺23U⚪®Z⍝ᱥ\Ḅ÷ønoḄὃX⚪ὃXijᑖ᪆Hùú⚪Ḅ¯º»¼ᱥ\Ḅឋ\®ᐵe8஺

96.ூwᫀ௃BூH᪆௃H14Ç⏚ûឋüý9¯ᵨÝþᶭ⏚ᦑA┯B.Na//C03᧕ᑖ஺2஺஺3ᑣᵨḄ◀Na2c஺3ᨵḄNaHC03ᦑB!C.᪷#$%ឤ'(ᱥ*Ḅ+ḄNa2c஺3,NaHCOsᑖ-.+Ḅ/⏚0123CO?Ḅ+4᪵ᦑC┯D.NazCq67,NaHC"67ᑖ-ᐭCaCJ679ὅ;3<ᑖ013ᡂ$⏚┛?@Aὅ01BCDᦑD┯ᦑ⌱FBoA.$⏚GHឋJKB.NaHCO?᧕ᑖ஺2஺஺3C.᪷#$%ឤᑖ᪆MD.Na2c஺367,NaHC0367ᑖ-ᐭ679ὅ23N⁐?@AὅBCD஺P⚪ὃS$⏚G,$⏚TGឋ*ḄUJVW⚣ὃYZ[\ὅḄ6ឋஹ^_ឋஹ.⏚ஹHḄ01VMḄᐵabcᑖ᪆dḄὃSeᔠឋJK⚪ghiᜧ஺7.ூMᫀ௃Cூ᪆௃F4ᵫpNO.4013ᡂNO2,ᡠrB⁐Ḅ4sᓄuv⍗ᑮyvz{V|}⁐ᦑA!B.S4ᐹᨵឋ⏚ឋW═⏚67⁐ᦑB!FC.\sᓄấ⏚ឋsᓄᱥ.HF01ᦑC┯D.v6p3ᡂ/⏚,⏚/⏚ᐹᨵ⏚ឋ⏚ᐹᨵNឋvᐭ⁐6767ᐜ{|A⁐ᦑD!ᦑ⌱FCoA.NO.஺2013ᡂNO2(B.S&.⏚ឋW╍⏚67;3sᓄ01C.\sᓄấ.HF01D.v6p3ᡂ/⏚,⏚/⏚ᐹᨵ⏚ឋ⏚ᐹᨵNឋ஺P⚪ὃSᐸᓄᔠᱥḄឋ*bcὃS3Ạ'Ḅ[⚪hi(஺8.ூMᫀ௃ANaOH
C0ᰀᨔ2ூ᪆௃F4¡ᑴ£F£¤¥TNaAl()2T4(஺“)3-42஺3ߟ£ᰚᵯ«ᔠ¡32¬▭ᦑA!ᮞ⏚ᨔB.®¯╅F®-Mg(0H)2-MgCJ-MgCl2•HCIᰚᵯ6H2஺TMgCl-Mg,ᦑB┯²2³10⚓ᐳ20⚓

10pt1C.¡¶32HNO3-N/+஺2TNOTN()2tHNO3,ᦑC┯C)D)*+Cl(1)·2D.®¸¯ỚF®¸T®¸ᮞT»ᔆ½7T/2(aq)TᦑD┯(2)EFᦑ⌱FA஺A.NaOH676£¤¥ஹ½¾ᑮMMZ026767ᐭCO2v013ᡂᒹ(஺“V?@ᰀÂ4(0")3¾ᑮ2஺3ᵯ42஺3ஹÄᨔᰚǾᑮA1(B.®ᐭTsᓄ┛╅ÈÉÊᓄVMg(0H)2?@½Aᐭ/⏚6ᙠHC1vÌÍ;67¾ᑮMgC%ᵯ᩽ᰚÇMgC%¾ᑮ╅C.¡¶ÏᵨÐᓄsᓄÑv32HNO3-NGÐᓄsᓄ3ᡂNO,sᓄNO3ᡂNaNO?.013ᡂHNO3(D.®¸¯ỚÒᐜÓ®¸6ÔÕ¾ᑮ»Ö½7ᐭvsᓄỚÈÉ3ᡂỚᓫ*⃓ÕஹÍÙ¾ᑮ஺஺P⚪ὃSÚÛஹ®¯Ớஹ¡32Ü⏚(ᓄ32ᳮÌÒZ[ᱥ*ឋ*ஹ;3Ḅ01ஹᑴᜓᳮVMᐵaßà[£ḄÚÛᳮbcὃS3Ḅᑖ᪆.áᵨd⚪ghi(஺9.ூMᫀ௃Cூ᪆௃Fâ01Iᐗäᓄᔠåᵫ+7åஹ-1å{V஺åᑣK2H3஺6VsᓄᑺஹçᑖHIVᑺÊèᵯÉᦪV7,A.sᓄᑺ;301ஹᑺ;3sᓄ01///஺6;301ஹHI;3sᓄ01ᦑA┯B.KIësᓄ2ᱥì2ᱥ.ësᓄ2ᱥì2ᱥᦑB┯C.K2H3஺6VsᓄᑺஹçᑖH1Vᑺ01ᨵWḄᓺïᑺᡠrᑺ,sᓄᑺḄᱥ*Ḅ+ðUV7-1,ᦑC!D.â01ÊèᵯÉᦪV7,ᓽ3ᡂ4mo஻2òÊèᵯÉ7mol,ᦑD┯ᦑ⌱FCoâ01Iᐗäᓄᔠåᵫ+7åஹ-1å{V0åᑣK2H3஺6VsᓄᑺஹçᑖHIVᑺÊèᵯÉᦪV7,A•sᓄᑺ;301ஹᑺ;3sᓄ01B.KIësᓄ2ᱥì2ᱥC./G%/%VsᓄᑺஹçᑖHIVᑺD.â01ÊèᵯÉᦪV7oP⚪ὃSsᓄ01bcὃSẠ'Ḅ[,ᮣõáᵨdö!ᐗäᓄᔠå{ᓄஹPᭆøᑁúP⚪ᐵaßàFçᑖHIïᑺ⚪ghiᜧ஺10.ூMᫀ௃C

11ூ᪆௃F44û᝱Ḅ+ýpBû᝱ᑣþATBVᔾ
ᦑA┯B.NOz(g)CO(g)ḄᜧNO(g)COz(g)ḄᦑB┯C.ᵫB"=ᱥḄ-ᡂᱥḄ0,!"#lmoWO2(g)lm஻C0(g)Ḅᓄ%ᔾᦈḄ()ᡂlmoWO(g)Imo*஺2(g)Ḅᓄ%ᡠ-ḄᦑC./D.ᓣ123Ḅᓄ%4᳛67ᦑD┯ᦑ⌱9CoA.A:᝱Ḅ<B:᝱ᑣ>?4tBᔾ
B.ᱥḄᜧᡂᱥḄḄC.AH=ᱥḄ-ᡂᱥḄD.ᓣ123ᓄ%4᳛@ᜧ஺A⚪C⌕ὃFᓄ%?ḄGᓄᒹIḄJKஹMᔾḄᑨ"1⚣ὃP⚪QR3Sᜧ஺11.ூVᫀ௃AூY᪆௃Y94[\M]^6ᡂ[\_⏚ឋ1b⏚cdefᓄᑣdeg⁐ḄiᳮSkᦑA┯B.lmnmᙳmpq᪀stukvᱥᦑB./C.ᵬm?Csp3ᩖᓄyCizS{|}ᵯz.☢q᪀y2ᵬm⁐ஹᕡḄᦑC./D.Ḅᑖzᙳ(஺6“10஺5”ᔠ3nSkSukᑖ᪀ᦑD./ᦑ⌱9A஺A.[\M]^6ᡂ[\_⏚ឋ1⏚cdefᓄB.lmnmᙳmpC.ᵬm?Csp3ᩖᓄyCizS{|}ᵯzD.Ḅᑖzᙳ(஺6“[0஺5”ᔠ3nSk஺A⚪ὃFᨵᱥḄq᪀Mឋ1⚣ὃPᨵᱥḄq᪀ஹkvᱥkᑖ᪀Ḅᑨ"YVḄᐵ¡ᑖ᪆Mᵨ£ḄὃF¤¥⌱⚗DYVḄ᧕┯P⚪QR3Sᜧ஺12.ூVᫀ௃BூY᪆௃ூᑖ᪆௃A⚪ὃF¨kᑖ᪀ᦪQḄªK⚪QR3Sᜧ¤¥«kᑖ᪀ḄᭆªK®¯°/ªKᨵᱥᑖz±ᦔ³izḄ®¯YVA⚪Ḅᐵ஺´12⚓ᐳ20⚓

12ூYV௃ஹ[m?ᡠᨵ³iz·±ᦔᑣᐸ¹º»ᱥ¼ᨵ1½¹º»ᱥᨵ2¾¹º»ᱥᨵ2¹º»ᱥᨵ2¿M½Àº»ᱥÁᦪskÂùº»ᱥᨵ1¿Mĺ»ᱥÁᦪskÂŹº»ᱥ1ᡠÆᐳᨵ9ᦑ⌱B஺13.ூVᫀ௃AூY᪆௃Y9412914c?{ᨵzᦪÇஹÈ/771஺/=MÆᦑA┯B.᪗Ë:Ì22.4LḄÍ᯼ᡠ{izÁᦪÏJx2xM/7nd=2ᑘᦑB./C.l8gÍÑÒᐰÔÕᵯzᦪÖX2x^/mo,=2MᦑC./D.28gCOC2H4×ᔠᙠÙᑖzÁᦪ¥xN/mol=N,ᦑD./AAᦑ⌱9AoAÁ14c?{ᨵ6ÁzB.CO³ᙳÚizᑖzC.஺+”2஺¿஺Â"CO+/?1molÍÔÕ2moiᵯzD.qᔠÜ71=zJK஺A⚪ὃFÝÞ6ßàᦪḄᨵᐵJKᑨ"⚪QR3?±ÝÞ6ßàᦪ1ὃḄ“P”ãὃF¨%}ᱥḄஹäzᦪஹஹå±MÝÞ6ßàᦪᐵvḄᳮYæçÆèéêë3Ḅᓄ%ìᑁî«ïÆᱥḄ?ðḄᔜᓄ%MÝÞ6ßàᦪḄᐵvY⚪Ḅᐵ஺14.ூVᫀ௃CூY᪆௃Y9᪷óᑖ᪆çWOᐗZPᐗXMgᐗYA1ᐗAA1Ḅizõᦪ13,öᐗᕜø⊤Ḅ´¾ᕜø´EL4úᦑA./B.Cúᐗkᕜøûüᔣþÿ
ឋ⌲ᑮ
ឋ⌲ᑣZFPGḄ
ឋ஺ᦑBC.YḄᨬ!ᓄᱥ$%Ḅ&ᓄᱥ'(!ᓄ)*&ᔠ,'-./01(!ᓄ)ᦑC┯3D.XḄᓫ5'
Mg,WḄᓫ5'!6Mg/78!69:!ᓄ;<=%ᦑD>ᦑ⌱C»@ABᕜDᐗFḄ஻ᑣW'0ᐗFZ'PᐗF>XஹYḄᓄᔠᑖT'+2ᵬஹ+3QY>P,ᑣX'MgᐗFY'A1ᐗFVWᑖ᪆1Y஺Z⚪ὃ]

13ghᑖ᪆8%ᵨ/jḄὃ]klm`ឋnoḄ%ᵨ⚪pqr.ᜧ஺15.ூYᫀ௃Bூ1᪆௃14Fe8xy⏚=%:ᡂ(6|᣸~ᑁ6ᐵa,|y⏚8NaOH0=%M|ᑴᜓ(!ᓄᦑAB.ᓄ8(!ᓄ┛ᨵ&:ᡂ%ᶍᔣ■:ᡂḄ&᎔ᦑB┯ஹ>C.ᐝ᯿ᵬ869:¡=%¢£&¤¥ᓣ*§|¨©ᦑc>D.Mªr«Ḅ&¬ᳫᙠ¯°±²Ḅ³ᜐµ¶µ&·~ᑖ°ᔠᳮᦑD>ᦑ⌱BoAFe8xy⏚=%:ᡂ(6|᣸~ᑁ6ᐵa,|y⏚8NaOH0=%>B.ᓄ᪶8(!ᓄ┛ᨵ&:ᡂ>C.ᐝ᯿ᵬ869:¡=%>D.ᑖ°ºªr«»¼½ᑖḄªrµ¶µ&·~஺Z⚪ὃ]ᓄ¾¿ÀÁᫀḄÂ'⚣ὃÄÅÆᱥ5Ḅឋ5ஹᱥ5Ḅᑴᜓஹ=%8ÇÈஹÉᔠᱥḄᑖÊËÌஹ¿Àᢈ/'1YḄᐵeghᑖ᪆8¿À/jḄὃ]kl¿ÀḄÂឋᑖ᪆⚪pqr.ᜧ஺16.ூYᫀ௃ACூ1᪆௃14ᵫÏᑖ᪆|naᵯ᩽'Ò᩽bᵯ᩽'᩽ᦑA┯3>B.bᵯ᩽'᩽᩽=%'PbG+4H++SO%-+2e-=PbSO4+2“2஺=%Óὑ(ÊGPh஺2ᵯ᩽▬Ö0ḄpHᜧᦑB>C.aᵯ᩽'Ò᩽bᵯ᩽'᩽᩽=%×'Ph஺Ø+4H++S஺Ù+2e-=PbSO4+2H2஺Ò᩽=%×'Ca-2e-=CM+,ᦑC┯3>D.aᵯ᩽'Ò᩽bᵯ᩽'᩽ᵯᵫb᩽~Û¥Üᔣa᩽ᦑD>ᦑ⌱ACoᵯÝÞ=%'Ca+PbO4-2HS0=CuS0+PbS0+2HO,ß9:ᜫᵯGḄ!ᓄ=224442%:ᡂC“2+,ᑣaᵯ᩽'Ò᩽bᵯ᩽'᩽Ò᩽=%×'C⇟-2e-=Ci?+,᩽PbOz9:ãᵯGḄ;<=%:ᡂPbSO”᩽=%×'PbG+4"++S«-+2e-=PbSO+2HO,äWᑖ᪆1Y஺42Z⚪ὃ]<ᵯÝåæ<ᳮÅÆᵯ᩽Ḅᑨcஹᵯ᩽9:Ḅ=%ᓽ|1Ykl^ᔠᵯ15Ḅ⏚-ឋéᑏᵯ᩽=%×⚪pqr.ᜧ஺ë14⚓ᐳ20⚓

14HH17.ூYᫀ௃••••Cïð-—e2CHCHOH4-32Cu0T2cH3CH஺+2HO2ò2oII......................18cc„ó?C%—C-^9õöᡭ°~C2H5-CH-c—18o—CF32IIIIூ1᪆௃1(1)ᵫVᑖ᪆|nA'C“2=஺“2ᵯG×'HCCHHHᦑYᫀ':HCCH(2)B'CH3cH2஺A.ú⏣Ḅürýᑣýþᙠ☢
ᦑA┯;B.⏣᠒
ᰚᡂᳫ
ᦑB┯C.⏣ᡂ
ᡠᨵᡂ
ᦑC;ᦑᫀ!C(বDKCH3coOH,D"#$%&'()*
FḄ,᪀./01CHLC12
ᦑᫀ!)*-CH~—(4)45জஹঝஹঞஹটᑖ<(=ᡂஹ>ᓄஹ@ᓄᡈBCஹ=D
ᡠEᨵFGḄHI
ᦑᫀ!e((5)8-C(⏣ḄJᓄ>ᓄ
KL/2cH3cH2஺"+஺2Ḇ2CHCHO+2HO,32Rᦑᫀ!2cH3cH20H+4”2CHCHO+2HOO32R(6)S18஺Ḅ⏚1ᵨ18஺᪗WḄ⏣ᙠ0Yᩩ[\Ḅᓄ]KL/!OCH3+Hj-18o-C,H0^4CH-C—,8O—CH,+HO5322ᦑᫀ!oII......................18cC„`Ỿ?CH3-9HtUh°~C2H5'QCIL_C_18o_CH+HO3252A(ᩭdefḄg⌕ᨵiᓄjkᧇ
mᱥopᵨᩭ⊝r0stuefᓄj\vHw
ᡠA(C//2=C“2,E(ᐹᨵy✏ᕡḄᨵiᱥ
E(@
⏚⏣ᡂ@
ᑣBD0}(⏚0}(⏣
Dpᵨᩭ◀ᨨᡈH"ḄH
ᑣB(CH3cH2஺D(CHCOOH,ᑣECH3coOCH2cH3(Jᓄᑺஹ=ᩩ[
CH3cH2஺>3>ᓄᡂCC/CH஺
AᡂF,F(0}Dᱥ
ᑣF0sLeὡ2஺7⚪ὃᨵiᱥ
⚣ὃ
g]Ḅᑖ᪆$Ḅὃ
FGஹ⏣ஹ)

15⏚Ḅឋo1ᓄ
⚪*Ạឋ
¡¢£*Ạ¤¥ḄᳮI§¨஺H+18.ூᫀ௃®¯ᕜ±®@4³NHClPH!N!H+
!CI!-S2->N3->F->4HAl3+3CU+8H++2N0?=3Cu2+2N0T+4HOBD2ூI᪆௃I!ᵫᑖ᪆p¤
জHஹঝCஹঞNஹটFஹঠNaஹডAlஹঢSஹণC1(1)ᐗÈজ
ণ"
ᨬÊ>ᓄᱥ£HᓄᱥḄËឋᨬḄᐗÈNa,ᙠᕜ±⊤"ḄÎÏ®¯ᕜ±®%4³
ᦑᫀ!®¯ᕜ±®%4³H+(2)ᐗÈজঞণÐᡂḄÑN/a
ᐸᵯÕ/H!N!HÖ-!CI!Ö'.HH+ᦑᫀ!NHQH!N!H!ci!Ö'H(3)ᵯÕÝ,᪀ÞßḄàÕ
᪶ᵯ₹ᦪäᜧ
àÕæçä
èàÕḄᵯÕÝäéàÕæçäᜧ
ᦑàÕæç52->/V3->F->43+,ᦑᫀ!S2->N3->F->Al3+O(4)ᐗÈঞḄᨬÊ>ᓄᱥ£HᓄᱥHNO3,îï⏚ðñ1ḄàÕKL/3Cu+8H++2N03=3Cu2+2N01+4H0,2ᦑᫀ!3Cu+8H++2N0S=3Cu2+2N0T+4/஺(5)AW(®ôᕜ±1ঢ(õ)ßö³ḄᐗÈ
ᑣWSe,ᜐVIA³
ᑣSeḄᨬᓄᔠÊ+6,ᦑAB.ßö³d4èüýþឋÿ
ᓄᱥឋ
ᓽឋSeV/^S
ᦑB┯C.ឋ
ᐸᨬ#$%⏚Ḅ⏚ឋ
ᦑ/Se/Ḅ⏚ឋ()⏚
ᦑC*+D.SeO2/Se+4$
ᜐ3/4$᝱
6ᐹᨵᓄឋ9ᐹᨵ:;ឋ
ᦑD┯
ᦑ<ᫀ>BD»@ᨵজ
ণCDᐗF
জ;G᪶᜜JᨵKLᵯG
ᑣজHᐗFজPঠ
RᐗFঠḄᯚ⁐U⁐
ᑣঠNaᐗFডPঠᕜZ
RডḄ;Gᨬ᜜[ᵯGᦪ(ঠ]2L
ᑣড;Gᨬ᜜[ᵯG^3,ᦑডA1ᵫᐸdᐗFᙠᕜZ⊤/Ḅgh
ijঝCஹঞNஹটFஹঢSஹণC1஺r⚪ὃuᐗFᕜZ⊤PᐗFᕜZv
wxyzᐗFᙠᕜZ⊤/gh
w{|}ᐗFᕜZvPᐗFᓄᔠᱥj
⚪ᜧ
ᙠὃuẠjḄ|}஺16⚓
ᐳ20⚓

1619.ூ<ᫀ௃0.01540஺஺஺“3஺”-6e-+”2஺=C஺2T+6H+0.8ூ᪆௃>(1)ᵫij
□✌ᐜ¡ᓄᓄ
¢ᧇ¢¤¥¦/§ᑖᓄ¡ᓄ
ᦑ<ᫀ>Ano.Q9mol-o(2)জ0
3minᑁª«¬/C/OH)=®¯°±¯=0.015nio//(Z,-min),ᦑ<ᫀ>0.015(ঝ4²³4ᑁ
´ὑ2m0
“2஺(஺)Ḅ³
ᡂ1᪷஺º஺2(஺)»¼*⌮«¬¾᳛²
«¬ÀᑮÂ⊝Ä᝱
ᦑA*+>B.n(CHO/7)-n(O)=2-3³
ª«¬KÀᑮÂ⊝Ä᝱
P«¬ÅÆᱥÇḄÈÉ32¡ᓄ᳛ᨵᐵ
ᦑB┯>C.«¬ËÌÇÈÍឤ
ÏᔠÐÑḄÇÈÒ
KÓÔ
»¼«¬ÀᑮÂ⊝Ä᝱
ᦑC┯D.ª«¬ÐÑᑖGᦪÕḄ«¬
ᵫÇÈÍឤvij
«¬ËÌÐÑḄÇÈÔ
ÏᔠÐÑḄÂᙳ²ᑖGÇÈ×ᜧ
ØᘤᑁÏᔠÐÑḄÂᙳ²ᑖGÇÈÚᢝÔ»¼*⌮«¬¾᳛²Ü
«¬ÝÀᑮÂ⊝
ᦑD*+ᦑ<ᫀ>AD((3)4ØᘤÑÞÔßᐭ×ᜧáâ
ᔜäᑖåÔ
ᑣ«¬¾᳛Ô
ᦑA┯B.æçè
«¬¾᳛Õ
ᦑB┯C.éÕØᘤÑÞ
áâ×ᜧ
«¬¾᳛×ᜧ
ᦑC*+D.×ᜧCO2å
«¬ᱥå×ᜧ
«¬¾᳛×ᜧ
ᦑD*+ᦑ<ᫀ>CD((4)¢ᧇᵯê/ßᐭ¢ᧇḄᵯ᩽ì᩽
ᑣª¢ᧇᵯê/ßᐭ¢ᧇᵬ⏣Ḅᵯ᩽«¬^CHOH-6e-+HO=COT+6H+,ßᐭᓄᑺÐḄᵯ᩽*᩽
⏚ឋᩩñ*᩽322ÐòᵯGÉóôG«¬ᡂõ
*᩽«¬^஺2+4H++4e-=2“2஺
ö´ὑ4.48L஺2(᪗øÄ)
ÐḄᱥÇḄÈ22ù“=0.2mo1,ᑣᵯú/¡ûḄᵯG0.2molx4=0.8mol,ᦑ<ᫀ>+ü2஺=C஺2T+6"+;O.80(1)᪷j
□¡ᓄᓄ
¢ᧇ¢¤ýþÈAn(2)@0
3minᑁª«¬/"(C/OH)=®ঝi⌮«¬ÀᑮÂ⊝Ä᝱³
*⌮«¬¾᳛²Ü
«¬ÑÿᔜᱥḄᱥḄஹᱥḄஹᑖᵫḄᑡᱥᳮ(3)ᓣஹᜧஹᜧ!ᜧ"#$᳛&'()ᘤ)+,-ᐭ/ᨵ1234"#$᳛&5ᑖ᪆(4)7ᧇᵯ:-ᐭ7ᧇḄᵯ᩽<=᩽&-ᐭ>ᓄᑺḄᵯ᩽1HᵯIJKLI"#MᡂO஺

17R⚪ὃUᓄVW⊝ஹYᵯ:Yᳮ&Z[ὃU\Ạ^_Ḅ`aJᮣc#ᵨ&efᓄV"#$᳛ghijஹᓄVW⊝k᝱ᑨnijஹYᵯ:YᳮopR⚪ᐵr&'(stᨵ"#uvᦋḄᱥᳮx`aW⊝k᝱ᑨn᪗z&⚪{|ᜧ஺20.ூ~ᫀ௃ᨵ2ᑖ&Gᕈ⁐&F⁐Br◀ᓄK12Ḅ1■᎔ᔾHI⏚ᑁ⁐◀HBr12&⍎¡1bdecaூp᪆௃ps(1)££¤r¥⏚ឋ¦⏚§>ᓄ&¨©ªᐭᑮ¬ᨵ⏚ឋ®⏚§Ḅ¯°&±₩&⏚ឋ═⏚§´⁐&µe©ᑖIᨵ££¤r&ᦑ~ᫀᓄ&¨©ªᐭᑮ¬ᨵ⏚ឋö⏚§Ḅ¯°&±₩&⏚ឋ═⏚§´⁐&µe©ᑖIᨵ££¤r(2)©Ḅ·¸O¹&¨©ªᐭᑮ¬ᨵßOḄ¯°&ᓫ¿©&ᐙᑖ±₩v☟&ÂÃÄᑮḄÅo2ᑖ&Gᕈ⁐&F⁐(3)জII©ÇᙠᓄÊËᓄÌᵨF"#Mᡂ©J½ᓄKঝHI{Ḅoᵨ⏚ÕÖHBr×ᙠ&¯°ᑁ©ḄÌᵨo◀ᓄK12Ḅ÷18⚓&ᐳ20⚓

18ú1ÜᘤMḄÌᵨo■Ý᎔ᔾঞ©ÇÙMàá"#MᡂHBr,IIIHBrJ⏚"#Mᡂᓄ⁐ট"#ãäv&¨IIåæᓾv&ᡭéKzᑭᵨë¨IḄOᔾᐭII;ঠHᑮḄïß©&ᨵ©ஹßᩖ&ÂᐜOòஹóªᐭNaOH◀Èᓫ&ᑖ,ᑭᵨõḄijᑖL©J©஺R⚪ὃU©Ḅᑴᜓ&Z[ὃUVMÿᔠᑖ᪆Ḅ⚪஺68E21.ூᫀ௃2.8
4CuFeS-17O-2HSO4=4Ci]SOr2Fe2(SO4)3+2H2O2225.2HSOஹᧅஹᴻ!"ᨬ$%&'()*+,-BaCG.)/2401⁐345ᡂᑣ89:'(;</ᨵ1⁐345ᡂᑣ89>'(;

19ᦑᫀL@ஹᧅஹᴻ[(5)FI$^ᑮ'(;<ᦑᫀL@!"ᨬ$%&'()*+,-BaC%.)/01⁐345ᡂᑣ89:'(;<@/ᨵ1⁐345ᡂᑣ89>'(;<[(6)জFcC⏚¢£¤X═⏚¦5§ᓄ¨©IJ5ᡂ┶«a¤£«a5IJḄ«aMNOLMnOj(+5Fe2++8H+=Mn2++5Fe3++4H0,2ᦑᫀL@MnO^+5Fe2++8H+=Mn2++5Fe3++4HO(2ঝ᪷|ᵯaឤ}^ᐵ°O@5Fe2+-MnO^,3.72g±²K³´ᨵn(Fe2+)=5x0.01mol/LX0.02LXµ¶=O.OlmoZ,FeSO-7H2஺Ḅ¸"ᑖᦪLº»¼½ಗx4100%=74.735,ᦑᫀL@74.73%஺Mi%@CuFeS2ABC⏚ஹ4ᙠFᵨHIJK5CuS/ஹFe(SO),ᯠ$243◀Z.ឋᩖ¸-ᐭFeḄ§ᓄᱥu⁚.)1ḄpHÂ2.8
5.2,yFe3+lᓄLFe(OH)334ᐭ2,.)´ᨵCuSO,ᯠ$Ã.)ÄஹÅÆÇᓾÉᨔ^ᑮCuSO-5HO22ᡂᑖxFe(OH)3,ᯠ$-ᐭC⏚IJK5Fe2(S04”ᔣ.)42-ᐭ"¨©£*2஺஺4)3˨©VLFeS5,Ã)ÄÅÆஹÇᓾÉᨔ^ᑮ±Ì[MiÍ@ÎÏУÑ⊤☢ᨵÓÔ-ᐭ〉"NazC".)Z◀ÓÔ'(^ᑮ<ḄУÑ-ᐭ〉"BC⏚IJ5ᡂC⏚¢£Ö×^ᑮ<ḄC⏚¢£.)%ØÇᓾஹÉᨔஹஹ'(^ᑮ±Ù஺Ú⚪ὃÜᱥ¸ḄᑴᜓLX⚣ὃßàáᱥ¸Ḅឋ¸ஹᑴᜓ©ᳮஹãäḄFᵨஹᢈL?ᐵæçèᑖ᪆AḄὃÜ⚪wéᜧ஺ë20⚓ᐳ20⚓