2021-2022学年河北省邢台市高三（上）入学化学试卷（附答案详解）

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2021-2022
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13D.|ᑖ~~஺8⚪ὃ=jᦪḄᨵᐵwxὃ=ᑖ᪆ஹᑨBwx~iᐗᓄᔠᱥឋAஹᑖ᪀ஹᱥAḄWᔜᱥᳮḄᐵT8⚪ᐵ,BTQ᧕┯!⚪gKLMᜧ஺9.ூQᫀ௃AூT᪆௃T4ᙠWC0¡34qᡂ¢¡ᓄ◀¤ᩖAᦑAhiB.¢¡ᓄo0⛳m§o⏚¨©2&M34,ªᔾᦈ¡ᓄo,`ᱥA◀¤ᦑB┯C.NO05ஹo⏚ᙳM34ª¢¡ᓄ0534`ᱥA◀¤ᦑC┯D.¯°⏚ឋ#═⏚²¡ᓄqᡂ¢¡ᓄ³ᐭµᩖA4⌱¶5ஹ·ᦑD┯ᦑ⌱AoA.ᙠWC0¡34qᡂ¢¡ᓄB.¢¡ᓄo0⛳m§o⏚¨©2&M34C.NO05ஹo⏚ᙳM34D.¯°⏚ឋ#═⏚²¡ᓄqᡂ¢¡ᓄ஺8⚪ὃ=¸ᔠᱥᑖ¹º#ὃj»⚪J¼½ᱥAḄឋA¾¿ஹpqḄ34TQḄᐵᑖ᪆0ÀÁ~Ḅὃ=ÂÃᐗᓄᔠᱥGHḄ4ᵨ⚪gKLMᜧ஺10.ூQᫀ௃BDூT᪆௃TᵫÅÆᑖ᪆GWஹXஹYஹZᑖÇHஹCஹNஹS,A.ÈᕜÊᐗW:ËÌᦪ=`ᨬ᜜Ðᵯᦪ=ᨬ#hÑÒ¡ஹÓ◀᜜Ôᡠ/ᨬ#hÑZ>Y>X>W,ᦑA┯B.ᵫWஹXஹYÕᐗ~Öᡂ×Õᓄᔠᱥ᝞?FÙÚÛWḄHaᑮḄÝᑡᨵßᱥ-ᦑBhiC.YḄᨬ#Ñ¡ᓄᱥà4Ḅ5ᓄᱥá⏚âᐸä¡ᓄᱥà4Ḅ5ᓄᱥ~å⏚æ᝞§⏚ᦑC┯D.SCN-/ᵨᩭèÁFe3+,éê2&ᔲ⊈í⁐ᦑDhiᦑ⌱BD஺WஹXஹYஹZ`ÌᦪïðñᜧḄÈᕜÊ:ËᐗᵫXஹYஹZᙠᐗᕜÊ⊤WḄóàôõGXஹYôö¢ᕜÊZôöᕜÊjklᵫWஹXஹYஹZ÷ᡂḄj»ḄᓫAWùᨵúÕ'GWHஹXCஹYNஹZS,/ûᩭTQ஺8⚪ὃ=ôõஹ᪀0ឋA⚪gKLMᜧiᐗḄôõஹᓫAḄü᝱ᩭýᐗTQḄᐵᑖ᪆04ᵨ~Ḅὃ=ÂÃᐗᓄᔠᱥGHḄ4ᵨ஺11.ூQᫀ௃DூT᪆௃T4ᵫ᪀GNḄᑖ஺6/0஺7"ᦑAhiB.McþFNcþFmÿ
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+)-c(OH-)=O.lmol/L+c(MOH)+2c(A2~)-C(HA),ᡠ.ÂᙠC(H+)>C(HA)-c(A2-)-c(MOH)-c(OH-)=O.lmol-22L,ᦑDᦑ⌱2AD,A.ᵯs«⊝Hᦪ®ᜧ
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ᑣᨵ2c(4+)+2c(HA')=22c(O/T)+2c(MOH)+3c(᮱-)+c{HA-)+c{HA),᪷ᱥᧇ½ឤg.᮱á)+2c(HA-)+C(HA)=02moi/L஺2@⚪ὃCÌᵯO?Ḅᵯs
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Ḅc(Fe஺?-)<10-5mol/L,ᑣÜÝc(Ca2+)>mol/L=4.5x

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Ạ⚪ᐵ᦮஺15.ூᫀ௃OxFeSz+4H++᜜=2++Fe2++2S+2H2஺ᚮ"#$%&'()*ᓄ,-#./01⁐34ᑣ6ᨵFe2+,89ᑣ:6Fe2+1.01.5CUsFeCuS+HO+2H+=Cu2++2HO+SBX100%222ூ᪆௃<(1)=ᱥᚮ"?@ABC#8DEFGHᜧ8Dᱥ9JḄLM☢OPᓄQ8DR᳛(Tᦑᫀ<V(2)=ᱥᚮ"?@WX▤ZḄ8DCuFeS?C“9J\=]ᓄ^_8D=ᡂC/+ஹFe2+bS,᪷d]ᓄ^_8Dᓄᔠfᓣhiឤஹᵯ₹iឤmniឤGo8DḄpqr@sC஻FeS2+4H++஺2=Cu2++Fe2++2S+2HO,tuAᔲ6ᨵFe2+Ḅr2wᚮ"#$%&'()xᓄ,-#./01⁐34ᑣ6ᨵFe2+,89ᑣ:6y2+,ᦑᫀ

18¤¥ᨔnᑖᦪ¨"ª°¬°)=®x100%,,mgmᦑᫀ<¯®x100%஺m°±²³´?Ẇ¶·ᙠ¸=ᱥ¹ᵨºEFᚮ"»=ᱥᚮ"PᵨḄ]ᓄ¼)½ᩚ¿(7./À¿)ᙠpHl.O6.0ÂᑁGÄᢝÆឋÇÈFe3+ᙠpH1.5É\=34»Êᚮ"?@ÄᢝpHᙠ1.01.5,PCnFeS2CËÌ\=]ᓄ^_8D=ᡂÍஹ)Íஹ½ᓫnᯠ·ᔣᚮ"#(ᐭ^_ᑺFe3+^_Ç+ÓᓄCuS,ᯠ·?ᑮFeS04-#bCuSBÔᔣCuS(ᐭ]ᓄᑺbÕ½⏚CuSÓᓄᯠ·ᑖÖ×FeSQ-#ஹCuS/-#Øᑮ¤¥ஹÙ¥Ê(1)(6)*(7)᪷d]ᓄ^_8DᓄᔠfᓣhiឤGoὅᐵs5FeS04KMnQ"'?@ὑ"(KMn஺஺=cmol-L^xVx10_3L=10-3cVmol,ÚτÛ(FeS஺஺=n(FeSO•47H2஺)=5x10~3cVmol,m(FeS0-7HO)=nM,¤Ẅᨔnᑖᦪ42Ý⚪Þ?¤ßb1ßḄᑴᜓá@ὃãäᱥnᑴᜓrᫀḄåærw⚪çèὃéê⚪ëìí
ᱥnᑴᜓrᫀḄåæ_ᑣîïᑖ᪆ᑴᜓá@/ᱥnḄᑴᜓ_ᳮÊñ⚪Ḅᐵ%⚪ᨵᑭ$ØèQ=Ḅᑖ᪆ஹᳮómᓄQôuó%⚪Ḅõᔠឋö஺16.ூᫀ௃+19.80.167.7%0.8pBD÷0+4H++4e-=2HO1IE22ூ᪆௃<পùoH2s(g)+|O2(g)=H2Oa)+SO2(g)A"i=-562.6/c/-nioL,“2(஺)bS(s)Ḅúûü஺H)ᑖÖ-285.8•mor1.-296.6fc/•moL,জH2s(g)+|0(5)="2஺஺)+5஺2(஺)ÿ%=-562.6fc/-mor1,ঝভ+R2S)="2஺(஺2H=-285.8k*-mol-1,ঞS(s)+O(^)=SO(g)SW=-296.6k/•mor1,2223জ-ঝ-ঞᑮS(g)UH2(g)+S(s)S%=(-562.6/c/-mo/-1)-(285.8©•moL)—(ߟ296.6/c7-7nol-=4-19.8/cJ-mol-1,ᦑᫀ+19.8*(2)3mo%S!"ᐙᐭ"%2LḄឤ()*(ᘤ,-H2sভ=/X+S(g),lOmin./ᑮᓄ12⊝4(ᘤ,5ᔠ!"789pkPa,:5ᔠ!",;"2sḄᱥ>Ḅ?@A21,BᔠCDEᑡEGᑖIH2sᱥ>Ḅ?x,H2s(g)=H2(g)+S(g)JK?(mo2)300Lᓄ?(niol)xx%2⊝?(?no2)3-xxxx(3-%)=21,x—2mol,2mo2জ0lOminᑁ(ᘤ,ᡂ;ভ)ḄP᳛=RS*=஺Z1UV,L•min-1,ᦑᫀO.lmo!•LT1-min-1*ঝ"2sḄZᓄ᳛=|x100%«67.7%,

19ᦑᫀ67.7%*ঞ\]^_2⊝`᝱_!"7ᱥ>Ḅ?=3mol+%=5mo/,p(WS)=pxp(W)=2222p(S)=pXI"\]^_Ḅᓄ12⊝bᦪKp=de=0.8p,ᦑᫀ0.8p*ট4ᓫghᑁiὑcrnioZH2s(g)"kᡂamol/S)"lᔣnopqrs/ᑮ2⊝`᝱ᦑA┯uvB.w.!"ᱥ>Ḅ?xᜧ!">?pL5ᔠ!"Ḅ2ᙳ᥅|>?p}Lᓄqrs/ᑮ2⊝`᝱ᦑBl~vC.w.!">?"%pL5ᔠ!"Ḅ)^KpLᓄpqrs/ᑮ2⊝`᝱ᦑC┯uvD.w.!"ᱥ>Ḅ?xᜧ(ᘤᑁ!"Ḅ89pLqrs/ᑮ2⊝`᝱ᦑDl~vᦑᫀBD*(3)জa᩽dᓄᜫᵯᡂᓫ>-ᓄᑣa᩽ᦑᫀvঝᵯ᩽bl᩽-஺2+4H++4e-=2%஺ᦑᫀO+4H++4e-=2HO?22ঞ17gH2sᱥ>Ḅ?=ᗩ=0.56஺1,Ogmol/SᜫImolᵯḄImoLᦑ17gH2sᨵ>nᐭl᩽ᦑᫀ1*l஺(1)/S(g)+|஺2(஺)=஺஺)+5஺2(9)S%=-562.6kJ-mol-1,(9)S(s)Ḅ¡¢£(”)ᑖ¥285.80•moLஹ-296.6/c/-mo/-1,জ/S®)+1஺2(g)=“2஺(஺+5஺2(஺)I%=-562.6kJ-mol-1,ঝ/ভ+§(9)=஺஺)“2=-285.8/c/mo/-1,ঞS(s)+஺2(஺)=SO?®)S/=-296.60•moL,জ-ঝ-ঞᑮH2s(g)="2(g)+s(s)Svn(2)জ0lOminᑁ(ᘤ,ᡂ”2(g)ḄP᳛=;vSiঝH2sḄZᓄ᳛=¨|*100%*ঞ\]^_Ḅᓄ12⊝bᦪKp=©M©ª©©টᑮ/2⊝`᝱l⌮P᳛¨2⊝ᔜᱥ>Ḅ¯^ஹ°ᑖ±?pL²³ᵫ:µḄ¶?p-Lᓄᵫ:noᑨ¸v(3)2H2s(9)+஺2(9)=52(5)+2”2஺¹᩽H2sᜫᵯ-ᓄl᩽஺2ᵯ-Bᔠᵯºឤᵨ஺¼⚪ὃ¿Àᓄ12⊝ÁÂÃÄᓄ12⊝ஹ£ᓄ1ÅÆEḄÇᑏஹᵯᓄ1ᳮᵨ¨ÊË⚪ÌÍ^,¨ÎÏᓄ1ᳮÐẠÊᐵÓÔÕBᔠ⚪ÌÖ×20⚓ᐳ24⚓

20Úᑖ᪆஺17.ூᫀ௃àr|3s64s2F>N>C>H>H/ᑖh±ᨵÓsp3ÓஹᐳèÓégÓ21ᨔ",Ḅëᕈᕜîឋᨵð᣸ᑡCuCI◤Xi஺?௃ூI᪆௃I(1)ùeḄ᪶ᵯ₹ᦪ26,Ð᝱FeḄ᪶᜜ᵯ᣸ÿ
[Ar]3s64s2,ᦑᫀ
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F>N>C>H?(3□*ᑖ,-ᨵ/012HFḄ3456ᦑᫀ
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4,@ᵨsp3ᩖᓄ8ᔠᱥ;-ᨵE0ஹᐳ=0H8I0ᦑᫀ
sp3E0ஹᐳ=0H8I0(5)᪷LᙳNᳮ☢QRSᨔU;-ᨵḄVḄWᦪ
;x6+8x=4,]QRS2o;-ᨵḄVḄWᦪ
9x8+1=2,Oᦑᫀ
21(6)b
ᓫᨔ]ᑁᔜWSᔣg᣸ᑡjkl⌼ᡂ,oᔠplbq⊤stᔜᔣuឋbvᐸbxᨔ];Ḅyᕈᕜឋᨵ᣸ᑡ{ᨵ|WI}⚔4WI}☢Q;x6+8x==4,ᨵWI}ᑁᐸWᦪ
4,ᡠᨔ]Ḅᓄ
CuCl,ᐸjkp=£=?=6X1021g.c-3,ᦑᫀ
ᨔ];Ḅyᕈᕜឋᨵ᣸ᑡCuCIX102௃஺a3NA(l»eḄ᪶ᵯ₹ᦪ
26,᝱FeḄ᪶᜜ᵯ᣸ᔠᑭᳮH¢ᱯ¤ᑣ(2)ᕜᐗḄᦪᜧᵯ!ឋ#(3)HFᑖ,-ᨵ/012HFḄ346}{ᓄ/(4)8ᔠᱥᑖ;<@ᵨsp3ᩖᓄ8ᔠᱥ;-ᨵE0ஹᐳ=0H8I0(5)☢QRSᨔU;-ᨵḄVḄWᦪ
;x6+8x=4,]QRS;-ᨵḄV2oḄWᦪ
8+1=2(6)b
ᓫᨔ]ᑁᔜWSᔣg᣸ᑡjkl⌼ᡂ,oᔠplbq⊤stᔜᔣuឋbvᐸbxᨔ];Ḅyᕈᕜឋᨵ᣸ᑡ{ᨵ|WI}⚔4WI}☢Q;x6+8x=4,ᨵWI}ᑁᐸWᦪ
4,ᡠᨔ]Ḅᓄ
28CuCI,ᐸjkp=¦⚪ὃ©ᱥªo᪀Hឋª
6⚣ὃ4®ᨔU¯°ஹ᪶᜜ᵯ᣸±²³4´µὃ©Ạ²³Ḅᳮ·Hᮣ¹ºᵨஹ»,¼½¾p®¯°¾p¿4xᨔU¯°²

21⍝ᨔUjk¯°SÁ⚪¿k;±஺18.ூᫀ௃C7Hg{ஹÄÅᓄÆÇ(ÈÉÆÇ)⏚ஹËÌ1ூ·᪆௃·(1)ᵫᑖ᪆ϲᱥªAḄᑖ
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Brô22⚓ᐳ24⚓

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23COOCH,ᵬ⏣*+,-./+ᡂDE஺G⚪ὃJᨵKᱥḄLMN#OPQ᪀RឋஹᨵK./STஹ▲ᑴᩩXYᑖZ᪀[\ᑏ^_ᨵKᓄ`aẠḄcᔠὃJᐙᑖᑭᵨᨵKᱥḄ᪀hiᑖ᪆EklḄὃJ`+ᑖ᪆LᳮPnop^஺q24⚓ᐳ24⚓