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1、第24卷第3期高校化学工程学报No.3Vol.242010年6月JournalofChemicalEngineeringofChineseUniversitiesJune2010文章编号：1003-9015(2010)03-0382-06聚酰亚胺中空纤维气体分离膜的物理老化现象1,22222212丁晓莉,曹义鸣,赵红永,介兴明,王丽娜,刘丹丹,张玉忠,袁权(1.天津工业大学材料科学与工程学院中空纤维膜材料与膜过程省部共建国家重点实验室培育基地,天津300160;2.中国科学院大连化学物理研究所大连洁净能源国家实验室,辽宁大连116023)®摘要：以聚酰亚胺6F
2、DA-mPDA为原料制备了单层非对称中空纤维膜，以聚酰亚胺Matrimid5218为分离层材料制备了双层非对称中空纤维膜，膜的致密层厚度为0.09~0.21μm。测试了中空纤维膜的O2、N2、CH4和CO2等气体渗透性能随时间的变化，研究了中空纤维膜物理老化现象。结果表明，随着老化的进行，气体渗透速率逐渐减小，分离系数逐渐变大，直至平衡。以自由体积扩散机理为基础，针对非对称中空纤维膜具有超薄皮层的特点，建立描述物理老化过程的数学模型。结果表明，该模型与实验结果相吻合，表明自由体积扩散机理可用来描述具有超薄皮层的中空纤维膜的物理老化现象。关键词：聚酰亚胺；中空纤
3、维膜；物理老化；自由体积中图分类号：TQ028.8；TB383文献标识码：AThePhysicalAgingPhenomenonofPolyimideHollowFiberMembranesforGasSeparation1,222222DINGXiao-li,CAOYi-ming,ZHAOHong-yong,JIEXing-ming,WANGLi-na,LIUDan-dan,12ZHANGYu-zhong,YUANQuan(1.StateKeyLaboratoryBreedingBaseofHollowFiberMembraneMaterialandMemb
4、raneProcesses,SchoolofMaterialScienceandEngineering,TianjinPolytechnicUniversity,Tianjin300160,China;2.DalianNationalLaboratoryforCleanEnergy,DalianInstituteofChemicalPhysics,ChineseAcademyofScience,Dalian116023,China)Abstract:Thesingle-layerasymmetrichollowfibermembranesmadefrompol
5、yimide-6FDA-mPDAandthe⑧dual-layerasymmetrichollowfibermembraneswiththeselectivitylayermadefrompolyimide-Matrimid5218werepreparedwiththethicknessrangeof0.09~0.21µm.Thephysicalagingphenomenonofthepreparedasymmetrichollowfibermembraneswasstudied,andthegaspermeabilityvaryingwithtimeforg
6、asesofO2,N2,CH4andCO2weretested.Experimentalresultsshowthat,duringphysicalaging,thegaspermeancedecreaseandtheselectivitiesincrease,whilefinallybothcometoastateofequilibrium.Accordingtothecharacteristicofultra-thindenseskins,amathematicalmodelbasedonthefreevolumediffusionmechanismwas
7、developedtodescribethephysicalagingofthehollowfibermembranes.Theresultsshowthat,accordingtothemodeldeveloped,theresultscalculatedagreewellwiththeexperimentalresults.Itindicatesthatthefreevolumediffusionmechanismcanbeusedtodescribethephysicalagingphenomenonofthehollowfibermembraneswi
8、thultra-thindensesk
