资源描述:
《紫外光谱分析-英文课件.ppt》由会员上传分享,免费在线阅读,更多相关内容在教育资源-天天文库。
1、Ultraviolet/VisibleSpectroscopyFifthgroupSpeaker:GaoXianzheUVradiationistheelectromagneticradiationofawavelengthshorterthanthatofvisiblelight,butlongerthanthatofx-rays.ThetypicalrangeofUVwavelengthis10-400nm.UVRadiationIndailylife,varioussolutionsarepresentedwithdifferentcolors,becauseitisrelate
2、dtotheselectiveabsorptionoflight.Whenabeamoflightismadeupofasolutionbyacertainproportion,somewave-lengthsoflightareabsorbedbythesolution,whiletheotherwavelengthsoflightarenotabsorbedthroughthesolution.Whenthelightisvisiblethroughthelightpacketcontainingthevisiblewavelengthrange,itcanbeseenbytheh
3、umaneye,thecolorofthesolutionisdeterminedbythewavelengthofthelight.UVAbsorptionUV/VisSpectroscopyDefinition:It’stheanalysismethodswithanalysis,determinationandinferenceofmaterialcomposition,contentandstructurebyusingtheuv-visspectraandthedegreeofabsorptionwhichproducedbymaterialmolecules,orionso
4、ntheabsorptionofultravioletandvisiblelight.Features:Highsensitivity,highaccuracy,goodselectivity,easytooperate,fastanalysisspeed,wideapplicationrange.AbsorptionCurveUsingdifferentwavelengthsoflightthroughasolutionofconstantconcentrationandthicknesstomeasuretheabsorptiondegreebytestingoneachwavel
5、engthlight(absorbance),andthenmakethewavelengthastheabscissaandtheabsorbanceastheordinatetomapacurve.Thematerialabsorptioncapacityofdifferentwavelengthcanbedescribedbythecurve,calledabsorptioncurveorabsorptionspectra.Thesameconcentrationofthesolutionundertesthasdifferentabsorbancetodifferentwave
6、lengthsoflight.Forthesametestsolution,thegreatertheconcentration,thegreatertheabsorbance.Forthesamematerial,nomatterwhattheconcentrationis,thewavelengthconnectedwiththemaximumabsorptionpeak(themaximumabsorptionwavelengthλmax)isthesame,andtheshapeofthecurveisalsothesame.Accordingtotheanalysisofab
7、sorptioncurve:Lambert-BeerLawResearchshows,theabsorptiondegreeofcolorsolutiontomonochromaticlightisrelatedtotheconcentrationofsolutionandthethicknessofliquidlayer.ThisisthefamousLambert-Beerlaw,itisthebasisofcoloranalysis.Wh