聚芳亚胺酰胺缩聚工艺条件探索.pdf

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1、2015年3月化学研究141第26卷第2期CHEMICALRESEARCHhttp：／／hxya．cbpt．cnki．netResearchonp0lyc0ndensati0nprocessofpoly(aryliminoamide)sJIAOYa，ZHANGLinh。LINRunxiong(1．ResearchCenterofLaserFusion，ChinaAcademyofEngineeringPhysics，Mianyang621900，Sichuan，Chi口2．EngineeringResearchC

2、enterofHighPerformancePolymerandMoldingTechnologyofMinistryofEducationQingdaoUniversityofScienceandTechnology，Qingdao266042，Shandong，China)Abstract：Poly(ary1iminoamide)s(PAIs)canbeconsideredasnovelhighperformancepolv—mers．Theeffectsofprocessconditions，suchass

3、peciesofhalogenmonomers，solvents。con—centrationofthemonomer，reactiontemperatures，thequantityandspeciesofcatalyticsys—tern，onPAIs’relativemolecularweightandtheirdistribution。wereinvestigatedinthispa—per，andtheoptimumconditionsforobtainingPAIswithhighrelativemo

4、lecularweightbypal—ladium—catalyzedC—Ncross—couplingpolycondensationreactionwerealsoinnestigated．Itpro—videsatheoreticalfoundationforfurthermodificationandapplicationofthesepolymers．Keywords：poly(aryliminoamide)s；relativemolecularweight；palladium—catalyzedCLC

5、number：O633．4Documentcode：AArticleID：1008—1011(2015)02～0141—07聚芳亚胺酰胺缩聚工艺条件探索焦娅，张林，林润雄。(1．中国工程物理研究院激光聚变研究中心，四川绵阳621900；2．青岛科技大学高性能聚合物及成型技术教育部工程技术研究中心，山东青岛266042)摘要：聚芳亚胺酰胺(PAIs)是一种新型高性能聚合物．本文作者讨论了卤素单体种类、溶剂、单体浓度、反应温度、催化体系及其添加量等工艺条件对PAls相对分子质量和相对分子质量分布的影响，得到了钯催化C

6、—N偶联缩聚反应制备高相对分子质量PAls的最佳条件，为该类聚合物的进一步拓展和应用提供了参考．关键词：聚芳亚胺酰胺；相对分子质量；钯催化Polyaramide(PARA)，consistingofamidemakeithardtodissolveincommonorganicsol—groupsandaromaticrings，isasignificanthighvents．Itssofteningandmeltingtemperatureareperformancepolymermateria1．Therig

7、idityframe～extremelyhigh，whichmakeitverydifficulttobeworkandintensiveintermolecularhydrogen—bondprocessed[一．Wehavesynthesizedtwonovelinteractionofthepolymermakeitpossesssuperiorheat—resistantpolymers—poly(arylimino—amide)sthermalstabilityandmechanicalproperty

8、[卜．Atviapalladium——catalyzedC·。Ncrosscouplingreactionthesametime，thestructura1featuresofPARAofP—pheny1enediamine，4，4r_diaminodiphenyletherand1，4-bis一(4bromobenzoy1)benzene．Theintro—Reeeiv