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《基于1,5,9-三硒杂[9]二茂铁环蕃的一维链状汞(Ⅱ)配位聚合物的合成与晶体结构.pdf》由会员上传分享,免费在线阅读,更多相关内容在行业资料-天天文库。
1、第26卷第2期无机化学学报CHINESEJOURNALOFINORGANICCHEMISTRYVol_26No.22010年2月339.342《研究简报i(!!!!!;基于1,5,9.三硒杂[9]二茂铁环蕃的一维链状汞(Ⅱ)配位聚合物的合成与晶体结构顾诚云景苏杨波魏烨张文吉玮(南京工业大学理学院.南京210009)(南京大学配位化学重点实验室.南京210008)关键词:汞(Ⅱ);1,5,9三硒杂[9]二茂铁环蕃;配位聚合物中图分类号:0613.52;0614.243;0614.81+1文献标识码:A文章编号:1001—4861(2010)0
2、2.0339—04SynthesisandCrystallographicStudyof1DMercury(if)CoordinationPolymerof1,5,9-Triselena[9]ferrocenophaneGUCheng。YunJINGSu,。YANGBoWEIYeZHANGWenJIWei1(SchoolofScience,NanjingUniversityofTechnology,Nanjing210009)(2StateKeyLaborator,ofCoordinationChemistry,NanjingUnivers
3、ity,N&njg210008)Abstract:Amercury(1I)coordinat/onP。lymerwith1,5,9一trise1ena[9]ferrocenophane(L),[HgI2L.0.5c4H40.0.5CH3OH],hasbeensynthesizedandcharacterized.TheXraycrysta1structureshowsthatbridgingbytheligandLcausesc0mpoundt。form。ne_dimens1‘。na1chaln.Thehalf-waVepotential0
4、f1,1一ferrocenylenegroupismorenegativethanthat。fthe“free”ligand,whichrevealsnothrough-sPaceinteracti。nHg⋯Feinthec。。rdinati。np。1ymers.CCDC:742585.Keywords:Mercury(H);1,5,9一Triselena[9]ferrocenophane;coordinationpo1ymerMetalcoordinationpolymershaveattractedc0nsi.istry,especia
5、llywiththepost—transitionmetals[s].Wederableattentionsduetotheirpotentialapplicationsinarenowpromptingthestudyofthemetalcoordinationmanyfields,suchascatalysis,molecularadsorpti0n.polymersincorporatingpolyselenaferrocenophanes.magnetism,nonlinearoptics。luminescenceandmole.M
6、ercurycomplexeshavebeenthefoeuSofmanvcularadsorption【1J.Thefe~ocenylcompoundshavebeenrecentstudies[91.Toinvestigatetheinfluenceoftheextensivelyincorporatedintotheframeworks。whichnatureofmultidentatepolyselenaferrocenophaneligandsprovideagoodopportunityofpreparingnewfunctio
7、nalontheconstructionofmereury(1I)polymers.theeonfor—materialswithuniquefeatures.Uptonow.almosta110fmationallyflexibletridentateligand1,5,9一triselena[9】thosestudiesuseferrocenylligandswithharddon0rferrocenophane(L)wasfirstemployed.Inthepresentatoms,O[andNAssofterdonorligand
8、s,p0lysele—communication,wereportthecrystalstructurealongnaferrocenophanesareexpectedtoha
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