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ID:51992433
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页数:31页
时间:2020-03-27
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1、Unit1UnitOperationsArp26th,2011Ying,Xiaoguanglesson1ClassificationofUnitOperationsFluidflowThisconcernstheprinciplesthatdeterminetheflowortransportationofanyfluidfromonepointtoanother.HeattransferThisunitoperationdealswiththeprinciplesthatgovernaccumula
2、tionandtransferofheatandenergyfromoneplacetoanother.EvaporationThisisaspecialcaseofheattransfer,whichdealswiththeevaporationofavolatilesolventsuchaswaterfromanonvolatilesolutesuchassaltoranyothermaterialinsolution.DryingInthisoperationvolatileliquids,usu
3、allywater,areremovedfromsolidmaterialsDistillationThisisanoperationwherebycomponentsofaliquidmixtureareseparatedbyboilingbecauseoftheirdifferencesinvaporpressure.AbsorptionInthisprocessacomponentisremovedfromagasstreambytreatmentwithaliquid.Membranesepar
4、ationThisprocessinvolvesthediffusionofasolutefromaliquidorgasthroughasemipermeablemembranebarriertoanotherfluid.Liquid-liquidextractionInthiscaseasoluteinaliquidsolutionisremovedbycontactingwithanotherliquidsolventwhichisrelativelyimmiscible(不混溶的)withthe
5、solution.Liquid-solidleaching(浸提)Thisinvolvestreatingafinelydividedsolidwithaliquidthatdissolvesoutandremovesasolutecontainedinthesolid.CrystallizationThisconcernstheremovalofasolutesuchasasaltfromasolutionbyprecipitating(沉淀)thesolutefromthesolution.Mech
6、anicalphysicalseparationTheseinvolvesseparationofsolids,liquids,orgasesbymechanicalmeans,suchasfiltration,settling,andsizereduction,whichareoftenclassifiedasseparateunitoperations.Lesson2FractionaldistillationFractionaldistillationistheseparationofamixtu
7、reofcompoundsbytheirboilingpoint,byheatingtohighenoughtemperatures.FractionalDistillationinaLaboratoryApparatusconicalflask1.Theapparatusisassembledasinthediagram.Themixtureisputintotheroundbottomedflaskalongwithafewantibumpinggranules(沸石),andthefraction
8、atingcolumnisfittedintothetop.2.Asthemixtureboils,vaporrisesupthecolumn.Thevaporcondensesontheglassplatformsinsidethecolumn,andrunsbackdownintotheliquidbelow,refluxingdistillate.3.Onlythemostvolatileofthevaporsstaysingaseo
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