资源描述:
《材料化学全英文课件PPT课件》由会员上传分享,免费在线阅读,更多相关内容在教育资源-天天文库。
1、材料科学基础FundamentalofMaterialsScienceProf:TianMinBoTel:62795426,62772851E-mail:tmb@mail.tsinghua.edu.cnDepartmentofMaterialScienceandEngineeringTsinghuaUniversity.Beijing100084Lessonfive2.5IndicesofCrystalPlanesandDirections2.5.1What’scrystalplanesanddirections?Theatomicplanesanddirectionspassingthr
2、oughthecrystalarecalledCrystalPlanesandCrystalDirectionsrespectively.1.Stepstodeterminatetheplaneindices:Establishasetofcoordinateaxes.Findtheinterceptsoftheplanestobeindexedona,bandcaxes(x,y,z).2.5.2PlaneindicesacbxyzTakethereciprocalsoftheintercepts1/x,1/y,1/z.Clearfractionsbutdonotreducetol
3、owestintegers.Enclosetheminparentheses,(hkl)Example:1/2,1,2/32,1,3/2(423)Planeindicesreferredtothreeaxesa,bandcarealsocalledMillerIndices.SeveralimportantaspectsoftheMillerindicesforplanesshouldbenoted:Planesandtheirnegativesareidentical.Therefore,.Insomesituation,planesandtheirmultiplesarenoti
4、dentical.Incubicsystems,adirectionthathasthesameindicesasaplaneisperpendiculartothatplane.Total:12Total:4×3!=243.5.3Directionindices1.DerivationforthecrystallographicdirectionAsthefirstabove,settheoriginonthedirectiontobeindexed.Findthecoordinatesofanotherpointonthedirectioninquestions.Reducetoth
5、reesmallestintegers:u,v,w.Encloseinsquarebrackets[uvw].2.Theimportantdirectionincubiccrystals:<100>:crystalaxes<110>:facediagonal<111>:bodydiagonal<112>:apicestooppositeface-centers3.Familyofdirectionsconsistsofcrystallographicallyequivalentdirections,denoted2.6HexagonalAxesforHexagonalCrysta
6、ls2.6.1Whychoosefour-axissystem?Fourindiceshasbeendevisedforhexagonalunitcellsbecauseoftheuniquesymmetryofthesystem.acb2.6.2Planeindices(hkil)Itcanbeproved:i≡-(h+k)Sofouraxisofplaneindicescanbededuceddirectly.Importantplanes:a1a2a3c2.6.3Directionindices[uvtw]Tomaketheindicesunique,anadditionalcond
7、itionisimposed.----Lett=-(u+v)ImportantdirectionsForexample:three-axis:four-axis:,,areallallowed,butnotunique.TransformationofindicesTransformationof3to4indices,orviceversa.Supposewehaveavector,whose3indices[UVW]