物理化学(应化专业)教学大纲_New

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1、物理化学（1）双语一、课程基本要求通过本门课程的学习，学生应比较牢固地掌握物理化学基本概念及计算方法，同时还应得到一般科学方法的训练和逻辑思维能力的培养。这种训练和培养应贯穿在课程教学的整个过程中，使学生体会和掌握怎样由实验结果出发进行归纳和演绎，或由假设和模型上升为理论，并结合具体条件应用理论解决实际问题的方法。二、课程内容、学时分配Chapter0IntroductiontoPhysicalChemistry(0.5academichours)Teachingstrategies:lecturesChapter1ThePropertiesofGas

2、es(3.5academichours)Teachingstrategies:lecturesandtutorialsMatter^sphasesBasicConceptsofEquilibriumTheConceptofPerfectGasRealgasesTheprincipleofcorrespondingstatesChapter2TheFirstLaw:TheConcepts(6academichours)Teachingstrategies:lecturesandtutorialsBasicconceptsandspecialtermsTh

3、efirstlawEnthalpyHeattransactionAdiabaticchangesofi.gApplicationsofFirstLawThermochemistryStandardenthalpychangesThetemperaturedependenceofreactionenthalpiesChapter3TheFirstLaw:theMachinery(5academichours)Teachingstrategies:lecturesandtutorialsThermodynamicpropertiesreconsiderat

4、ionTheJoule-ThomsoneffectGeneralizationmethodinrealgasescalculationChapter4TheSecondLaw:Theconcepts(6academichours)Teachingstrategies:lecturesandtutorialsCarnotCycleTheCommonFeaturesofSpontaneousChangesThesecondlawClausiusstatementSecondLawofthermodynamicsEntropyThethirdlawHelmh

5、oltzandGibbsenergiesGibbsenergyGCalculationof?Aand?GGibbsenergyinchemicalreactionsChapter5Thesecondlaw:themachinery(5academichours)Teachingstrategies:lecturesandtutorialsFundamentalequationsFundamentalequationsofthermodynamicsandMaxwellrelationsMaxwellrelationsanddeductionsoffun

6、damentalequationsApplicationsoffundamentalequationsChapter6Physicaltransformationofpuresubstances(8academichours)Teachingstrategies:lecturesandtutorialsSomeSpecialTermsSometypicalphasediagramsChemicalpotentialandcriterionofphaseequilibriumThermodynamicdescriptionsofphasetransiti

7、onTypicalphasediagraminordinarycasesTheeffectofappliedpressureonvaporpressureVaporPressureEstimationTheEhrenfestClassificationofPhaseTransitionThephysicalliquidsurfaceSurfaceTensionFundamentalequationswithsurfaceworkForcebalanceincurvedsurfacesWettingCapillaryactionVaporpressure

8、ofcurvedsurfaceMetastablestateandnewphaseproduc