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1、InternationalReviewsinPhysicalChemistryISSN:0144-235X(Print)1366-591X(Online)Journalhomepage:http://www.tandfonline.com/loi/trpc20Metalextractiontoionicliquids:therelationshipbetweenstructure,mechanismandapplicationCamielH.C.Janssen,NormaA.Macías-Ruvalcaba,MarthaAguilar-Martínez&Ma
2、rkN.KobrakTocitethisarticle:CamielH.C.Janssen,NormaA.Macías-Ruvalcaba,MarthaAguilar-Martínez&MarkN.Kobrak(2015)Metalextractiontoionicliquids:therelationshipbetweenstructure,mechanismandapplication,InternationalReviewsinPhysicalChemistry,34:4,591-622,DOI:10.1080/0144235X.2015.108821
3、7Tolinktothisarticle:http://dx.doi.org/10.1080/0144235X.2015.1088217Publishedonline:02Nov2015.SubmityourarticletothisjournalArticleviews:299ViewrelatedarticlesViewCrossmarkdataCitingarticles:7ViewcitingarticlesFullTerms&Conditionsofaccessandusecanbefoundathttp://www.tandfonline.com
4、/action/journalInformation?journalCode=trpc20Downloadby:[HongKongPolytechnicUniversity]Date:17January2017,At:18:58InternationalReviewsinPhysicalChemistry,2015Vol.34,No.4,591–622,http://dx.doi.org/10.1080/0144235X.2015.1088217Metalextractiontoionicliquids:therelationshipbetweenstruc
5、ture,mechanismandapplicationaaaCamielH.C.Janssen,NormaA.Macías-Ruvalcaba,MarthaAguilar-Martínezandb,cMarkN.Kobrak*aFacultaddeQuímica,UniversidadNacionalAutónomadeMéxico.CiudadUniversitaria,C.P.b04510MéxicoD.F.,México;DepartmentofChemistry,BrooklynCollegeoftheCityUniversitycofNewYor
6、k,2900BedfordAve.,Brooklyn,NY11210,USA;DepartmentofChemistry,GraduateCenteroftheCityUniversityofNewYork,365FifthAve.,NewYork,NY10016,USA(Received17July2015;finalversionreceived26August2015)Ionicliquids(ILs)haverecentlyemergedasanextremelypromisingmediumfortheextractionofmetalsfromaq
7、ueousphases.ILsaresaltsthatareliquidatroomtem-perature,andhavephysicalandchemicalpropertiesthatmakethempotentiallyvalu-ablereplacementsfororganicmolecularsolvents.However,thatsameioniccharactergivesrisetoextractionmechanismsthathavenoanalogueinmolecularliquids.Whilemetalsgenerallye
8、xistinhydrophobicneutralco
