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1、ExperimentalStudyofEvaporationP.C.Wayner,Jr.intheContactLineRegionofaC.Y.Tung1ThinFilmofHexaneM.TirumalaThetransportprocessesinthecontactlineregion(junctionofevaporatingthinliquidfilm,vapor,andsubstrate)ofstationarysteady-stateevaporatingthinfilmsJ.H.Yang2ofhe
2、xanewithvariousbulkcompositionswerestudiedexperimentally.Thesub•stratetemperaturedistributionandliquidfilmthicknessprofileweremeasured,DepartmentofChemicalEngineeringanalyzed,andcomparedwithpreviousresultsonothersystems.TheresultsandEnvironmentalEngineering,de
3、monstratethatsmallchangesinthebulkcompositionsignificantlyaltertheRensselaerPolytechnicInstitute,characteristicsofthetransportprocessesinthecontactlineregion.ThecurvatureTroy,N.Y.12181gradientattheliquid-vaporinterfaceisastrongfunctionofevaporationrateandcompo
4、sition.Concentrationandtemperaturegradientsgiveinterfacialshearstressesandflowpatternsthatenhancecontactlinestability.1IntroductionInarecentsetofpublications,theuseofascanningevaporatingethanolmeniscusthathadafiniteapparentanglemicrophotometertodeterminethehea
5、ttransfercharac•werepresentedin[3,5].Inthiscase,theanalysesindicatedteristicsofastationaryevaporatingfilminthefilmthicknessthatthemaximumcurvaturewaslocatedatthecontactlinerange5<10"5mwasdescribed[1,2].Decaneandamixtureandthatfluidflowstowardsthecontactlineasa
6、resultofaof98percentdecaneplus2percenttetradecanebyweightwerecurvaturegradient.SystemIIrepresentsarelativelypurediscussed.Hereinexperimentalresultsobtainedusingevaporatingthinfilm,whichhasanapparentisothermalresearchgradehexane,technicalgradehexane,andamixture
7、contactangleequaltozero(spreadingsystem).Theorywouldof98percenthexaneplus2percentoctanearepresentedandindicatethatthemaximumcurvatureshouldoccuratafilmcomparedwithourpreviousresults.Theexperimentalresultsthicknessoftheorderof10~7—10-8m,theregionwheredemonstrat
8、ethatsignificantdifferencesinthetransportcapillarityanddisjoiningpressureareapproximatelyequal.characteristicsresultfromsmallchangesinthebulkcom•However,theexperimentalresultsindic