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1、TheCrystalChemistrycftheRare-EarthSilicatesJ.FelscheInstitutfi~rKristallographiederETH,Ziirich,SwitzerlandTableotContents1.AbstractandIntroduction.......................................100/1012.StructuresContainingIsolated(SiO4)...............................1042.1.RE203"1SiO2Compoun
2、ds....................................1052.1.1.StructureTypeA,(La,...Tb)2(SiO4)O...................1062.1.2.StructureTypeB,(Dy...Lu)2(SiO4)O...................1092.2.OxyapatiteCompounds........................................1132.2.1.BinaryCompoundsRE9.33[~0.67(SiO4)602..............
3、..1142.2.2.Mixed-CationOxyapatites................................1212.3.Mixed-CationCompoundsREIV[1+(SiO4)........................1272.3.1.Compounds(Ce,...Nd)Na(SiO4).........................1282.3.2.Compounds(Nd....Ho)Na(SiO4)........................1302.3.3.Compounds(Er,...Lu)Na(S
4、iO4).........................1322.3.4.Stillwellite,CeB(SiO4)O.................................1342.4.REMgSilicateGarnets.......................................1362.5.CompoundsContainingDivalentRareEarths....................1372.5.1.DimorphicEu2(SiO4)..................................
5、..1372.5.2.Eu3(SiO4)O............................................1403.StructuresContainingIsolatedGroups(Si207),or(Si3010),+(SiO4)....1433.1.PolymorphieDisilicateCompounds1RE203-2Si02..............1443.1.1.StructureTypeA,(La,...Eu)2(Si~OT)....................1503.1.2.StructureTypeB,(
6、En....Er)4(Si3010)(SiO4)..............1563.1.3.StructureType,C,(Ho....Lu)2(Si~OT)...................1593.1.4.StructureTypeD,(Ho....Er)2(Si2OT)....................1613.1.5.StructureTypeE,(Eu....tto)2(Si~OT)...................1653.1.6.StructureTypeF/G,(La,...Sm)2(Si207)................
7、..1683.2.TernaryCompounds,Alk~RE(Si2OT)............................1723.2.1.StructureTypeA,K3Eu(Si2OT)...........................1723.2.2.StructureTypeB,Na3(Y,Er...Lu,Sc)(Si207)............1724.PolymorphismandStructuralData.................................1754.1.Configurationofthe(Si
8、O4)Tetrahedr
