The Virtue ofMichael-Type Addition Processes英文书

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1、TopOrganometChem(2006)19:115–148DOI10.1007/3418_007©Springer-VerlagBerlinHeidelberg2006Publishedonline:7April2006TheVirtueofMichael-TypeAdditionProcessesintheDesignofTransitionMetal-PromotedCyclizativeCascadeReactionsGenevièveBalme(
)·DidierBouyssi·NunoMonteiro

2、LaboratoiredeChimieOrganique,CNRSUMR5181,UniversitéClaudeBernardLyon1,43Bddu11novembre1918,69622VilleurbanneCedex,Francebalme@univ-lyon1.fr1Introduction...................................1162CycloadditionReactionsBasedonZwitterionicπ-AllylPdComplexes...1172.1Pd

3、-CatalyzedRingExpansionReactionsofVinylcyclopropanesandRelatedHeterocyclicSystems.......................1172.2CycloadditionReactionsInvolvingPd-TMMEquivalentsas1,3-Dipoles..1223SequentialMichaelAddition/Metal-PromotedNucleophileAdditiontoUnactivatedC–Cπ-Bonds..

4、.......................1253.1SequentialReactionsResultinginMonofunctionalizationoftheCarbon–CarbonMultipleBonds....................1263.2SequentialReactionsResultinginDifunctionalizationoftheUnsaturation.1314TandemConjugateAddition/Metal-CatalyzedIntramolecular

5、CouplingReaction.......................1375Metal-CatalyzedTandemConjugateAddition/ElectrophilicTrappingReactions..................1386ReactionsInvolvingaCouplingReactionandTerminatedbyaMichaelAddition....................1407Conclusion...........................

6、.........145References.......................................146AbstractCascadereactionsinvolvingatransitionmetal-promotedstepandaMichael-typeadditionprocesshaveemergedasapowerfultooltoconstructcyclicandpolycyclicstructures.Inthisreview,recentadvancesinthisfield

7、arepresented.Thefirstpartisre-latedtocycloadditionreactionsbasedonzwitterionicπ-allylPdcomplexes.ThesecondpartdealswithMichaelinitiatedmetal-catalyzedcyclofunctionalizationreactionsofun-activatedC–Cπ-bonds.PartsthreeandfourfeaturereactionswhereaninitialMichaelad

8、ditionreactionisfollowedbyeitheracouplingreactionoranelectrophilictrapping.PartfiveisdevotedtoMichaelterminatedreactions.KeywordsCyclization·Heterocycles·Michaeladdition·Tand