Metal-Catalyzed Oxidations of C–H to C–N Bonds 英文书

Metal-Catalyzed Oxidations of C–H to C–N Bonds 英文书

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1、TopCurrChem(2010)292:347378DOI:10.1007/128_2009_19#Springer‐VerlagBerlinHeidelberg2009Publishedonline:16December2009Metal-CatalyzedOxidationsofC–HtoC–NBondsDavidN.ZalatanandJ.DuBoisAbstractThischapteroffersageneralreviewofselectivemethodsfortheoxida-tiveconversiono

2、fCHtoCNbonds.Specialfocushasbeengiventothemanydisparatecatalysttypesthatarecapableofpromotingthisuniquetransformation.KeywordsAminationlTransitionmetalcatalysislNitreneContents1Introduction............................................................................

3、.3472Background.............................................................................3483CopperCatalysis........................................................................3503.1NitrenoidReactions..........................................................

4、.....3503.2Non-NitrenoidAminationProcesses..............................................3544SilverandGoldCatalysis...............................................................3555RutheniumCatalysis..................................................................

5、..3576IronCatalysis...........................................................................3607ManganeseCatalysis....................................................................3628CobaltCatalysis..............................................................

6、...........3639RhodiumCatalysis......................................................................36410PalladiumCatalysis.....................................................................37011Miscellaneous......................................................

7、.....................37312Conclusions.............................................................................374References....................................................................................375D.N.ZalatanandJ.DuBois(*)DepartmentofChemistry,Stan

8、fordUniversity,Stanford,CA94305-5080,USAe-mail:jdubois@stanford.edu348D.N.ZalatanandJ.DuBois1IntroductionTothesyntheticchemist,Naturesexactingabi

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