反应型阻燃剂的合成与真丝上的应用

《反应型阻燃剂的合成与真丝上的应用》由会员上传分享，免费在线阅读，更多相关内容在学术论文-天天文库。

1、浙江理工大学硕士学位论文反应型阻燃剂的合成及真丝上的应用AbstractSilkisallkindofelegantanddecorativefabric．However,duetoitscombustibility,flameretardantfinishingisverynecessarytomeetthehigh-endmarket[]demandfordecorativesecurity．Currently,afterflameretardantfinishing，it’Softendifficulttobalancethecontrad

2、ictionbetweenhandle—feelingoffinishedfabricanditswashability．Inresponsetotheseproblems，wesynthesizedtwotypesofreactiveflameretardantwhichcouldbegraftedwithsilkfabric；then，thechemicalbondingreactionbetweentheflameretardantandsilkfiberswasverified；atlast，thephysicalanddyeingpro

3、pertiesofthefinishedsilkfabricwereinvestigated．Therearetwokindsofsyntheticproduct．Oneischloro—S—triazinephosphorusflameretardantsK—P1．Cyanuricchlorideanddiethyl0aydroxymethyl)phosphonatewerechosedaslawmaterialsandanhydrouspotassiumcarbonateasacid—bindingagent．Inthissynthesisr

4、eaction，diethyl(hydroxymethyl)phosphonatewascontinuousfeedingandreactiontemperaturewascontrolledstepbystep．Theotheroneisvinylphosphateesterflameretardants：Bytwosteps，phosphorusoxychloridehadcondensationreactionswithhydroxyethylacrylateandmethanol(orethan01)separatelywithtriet

5、hylamineasacid-bindingagent．ThenhydrophilicflameretardantP2andhydrophobicP3wereobtained．Furthermore，IRspectroscopyandNuclearMagneticResonancespectroscopywereusedtoconfu'methatthetwotypesofflameretardantshadthetargetchemicalstructure．Bywayofpaddingmethod，silkfabricwastreatedwi

6、thchloro—s—triazinephosphorusflameretardant．Thebond—formingreactionbetweenK—P1andsilkfabricwasverifiedbyIRspectroscopy；thelimitingoxygenindex(LOI)offinishedsilkcouldbeimproved．toamaximumof29％withincreasingconcentrationofK—P1andsilkfabrichadflameresistance．’TheLOIvalueoffinish

7、edfabricwoulddroptoaround26％after30and50timeswashingrespectively．Inthispaper,researchfocusedonthegraftco-polymerizationofvinylphosphatewithsilk；flameretardant[]structurewasdemonstrated；flameretardantdosage,initiatorconcentration,pH，andreactiontemperatureandotherprocessfactors

8、werediscussed；aftersilkwasgraftedwithflameretardant，therelationshipb