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1、Issue5,Volume7,2013229OptimizationofelectrochemicaloxidationofglycerolforglycericacidproductionJuanCarlosBeltrán-Prieto,RomanSlavík,andKarelKolomazník.ThemostimportantindustrialusesofglycerolareinfoodAbstract—Theanodicoxidationofglycerolusingplatinumandbeverage,personalandoralcare,andtobacco[
2、4].electrodesinalkalinesolutionwasstudiedtooptimizetheproductionGlycerolanditsderivativescanbeblendedwithgasoline[5].ofglycericacidusingcentralcompositedesign.TheparametersEtherificationofglycerolproducebranchedoxygencontainingunderstudywereconcentrationofoxidantreagent,stirringspeedandtemper
3、atureofreaction.Selectivitytodesiredproductandoverallcomponents,withpropertiesforuseasafuelorsolvent[6].conversionofglycerolwereconsideredastheresponsevariables.InGlycerolisusedintheproductionofchemicalsandfuelsordertoperformtheelectrochemicaloxidation,cyclicvoltammetryincludinghydrogen[7].Pu
4、reglycerineiswidelyusedinandmultiplepulseamperometrytechniqueswereusedtostudythepharmaceuticalformulationsandcanbeobtainedfromeffectofpotentialvariation,thereactionorderforglycerolandsaponificationreactionsofsoapproduction,microbialoxidantreagent,adtoperformtheoxidationatcontrolledpotential.f
5、ermentation,petrochemicalfeedstockandtransesterificationKeywords—glyceroloxidation,centralcompositedesign,cyclicreactionofbiodieselproduction.Duetoitsproperties,itisvoltammetry,optimizationalsousedforimprovingsmoothness,providinglubrication,andashumectants.Itisusedincoughsyrups,elixirs,expect
6、orants,ointments,plasticizersformedicine,capsules,I.INTRODUCTIONearinfectionmedicines,andasacarrierforantibioticsandHEgrowthofworldbiodieselproductionhascausedaantiseptics[3].Tsurplusofglycerol,whichisgeneratedasabyproductofGlycerolisalsoanimportantintermediateofglucoseandtheprocess.Thisnonto
7、xicandbiodegradablerenewablefuelislipidmetabolismbyvirtueofitsabilitytosupportconstitutedbymono-alkylestersoflong-chainfattyacidsglycogenesisinvarioussystems,aswellasservingasaderivedfromvegetableoilsoranimalfats[1,2].Extensiveprecursorforthe
