返回
Kinetics of methanol to olefins over AlPO4-bound ZSM-5 extrudates in a two-stage unit with dimethyl ether pre-reactor

Kinetics of methanol to olefins over AlPO4-bound ZSM-5 extrudates in a two-stage unit with dimethyl ether pre-reactor

ID：37945257

大小：530.91 KB

页数：10页

时间：2019-06-03

Kinetics of methanol to olefins over AlPO4-bound ZSM-5 extrudates in a two-stage unit with dimethyl ether pre-reactor_第1页
Kinetics of methanol to olefins over AlPO4-bound ZSM-5 extrudates in a two-stage unit with dimethyl ether pre-reactor_第2页
Kinetics of methanol to olefins over AlPO4-bound ZSM-5 extrudates in a two-stage unit with dimethyl ether pre-reactor_第3页
Kinetics of methanol to olefins over AlPO4-bound ZSM-5 extrudates in a two-stage unit with dimethyl ether pre-reactor_第4页
Kinetics of methanol to olefins over AlPO4-bound ZSM-5 extrudates in a two-stage unit with dimethyl ether pre-reactor_第5页
资源描述：

《Kinetics of methanol to olefins over AlPO4-bound ZSM-5 extrudates in a two-stage unit with dimethyl ether pre-reactor》由会员上传分享，免费在线阅读，更多相关内容在行业资料-天天文库。

1、MicroporousandMesoporousMaterials164(2012)172–181ContentslistsavailableatSciVerseScienceDirectMicroporousandMesoporousMaterialsjournalhomepage:www.elsevier.com/locate/micromesoKineticsofmethanoltoolefinsoverAlPO4-boundZSM-5extrudatesinatwo-stageunitwithdimethyletherpre-reactorMarkusMenges

2、,BettinaKraushaar-Czarnetzki⇑InstituteofChemicalProcessEngineeringCVT,KarlsruheInstituteofTechnology,Kaiserstrasse12,D-76128Karlsruhe,GermanyarticleinfoabstractArticlehistory:Thefixed-bedconversionofmethanoltoolefinswasinvestigatedinatwo-stageseries-flowunit.ThefirstAvailableonline14July2012

3、reactorwithc-Al2O3catalystconvertedmostofthemethanoltodimethyletherandwatervapor(DMEpre-reactor).ThesecondreactorproducedhydrocarbonsandcontainedanextrudedcatalystconsistingofKeywords:H-ZSM-5(Si/Al=250)embeddedinanovelmacroporousmatrixofAlPO4withtridymitestructure.Pro-Methanoltoolefins(MT

4、O)cessingexperimentswerecarriedoutoverawiderangeofconversionsatreactiontemperaturesfromKinetics400°Cto450°C,andundervariationofthemethanolconcentrationsinthefeedbetween10%and34%Co-feeding(v/v).Additionalco-feedingexperimentswithethene,propeneoriso-butene,respectively,deliveredExtrudedZSM

5、-5insightsintosecondaryreactions.TheexperimentaldatawereusedtodevelopakineticmodelbasedMacroporousAlPO4-matrixonlumpswhichdescribeswelltheMTOreactionsatconditionsclosetoindustrialpractice.Ó2012ElsevierInc.Allrightsreserved.1.IntroductionrousAlPO4bindermatrixenhancestheinternalmasstranspo

6、rt,whichcouldimprovetheyieldoftheintermediateproducts.InTheconversionofmethanoltoolefins(MTO)representsameth-additionwiththeuseofapre-reactorfortheconversionofmeth-odofproducingtheimportantbasechemicalsethyleneandpro-anoltodimethylether(DME),thecatalystlifetimecanbeim-pylenefromcarbonreso

7、urcesotherthancrudeoil,suchasproved.ThepreparationandcharacterizationofAlPO4/ZSM-5naturalgas,coalorbiomass.Sincedecadeslargeresearcheffortsextrudateshasbeenpublishedearlier[5,6].havebeentakenfortheoptimizationofthereactiontoboth,ole-KineticmodelingoftheMTO-processhasbeent

当前文档最多预览五页，下载文档查看全文

此文档下载收益归作者所有

当前文档最多预览五页，下载文档查看全文
温馨提示：
1. 部分包含数学公式或PPT动画的文件，查看预览时可能会显示错乱或异常，文件下载后无此问题，请放心下载。
2. 本文档由用户上传，版权归属用户，天天文库负责整理代发布。如果您对本文档版权有争议请及时联系客服。
3. 下载前请仔细阅读文档内容，确认文档内容符合您的需求后进行下载，若出现内容与标题不符可向本站投诉处理。
4. 下载文档时可能由于网络波动等原因无法下载或下载错误，付费完成后未能成功下载的用户请联系客服处理。