金属片上制备纳米微米晶薄膜

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1、中国石油大学（华东）硕士学位论文金属片上制备纳米（微米）晶薄膜姓名：王研申请学位级别：硕士专业：化学工程指导教师：陈宏刚;李建强20081001PreparationofNano一(Micro一)CrystalThinFilmsonMetaJSubstrateWangYan(ChemicalEngineering)DirectedbyProf．ChenHonggangAbstractInthisdissertation，inorganicnano一(micro一)crysta／thinfilmsw

2、erepreparedonself-sourcemetalfoilsubstratethroughhydrothermalmethod．Aluminumhydroxideisexcellentinorganicfiller／flameretardantandrawmaterialformakingA1203．Nano．A1203iswidelyusedincatalystsupport，ICchipsetc．ZnSehasgoodprojectiveperformance，whichisthebe

3、stmaterialformakingphotocell，BluesemiconductorlaserandLED，madeofZnSe，arewidelyavailableforspecialapplications。1．Thinfilmsofconstructedwithaluminumhydroxidenanosheetswerepreparedonaluminumfoil．XRDresultsshowedthatthesamplesweremainly6．AIOOH．Thefilmswer

4、ebuiltupwithaluminumhydroxidenano—sheets，whichhavethicknessofabout30hm．1engthof300—400rlnq，andwidthof100．200nm．Theinfluenceofvariousexperimentalparametersonthemorphologyofaluminumhydroxidellano-sheetshasbeeninvestigated，includingtheconcentrationofhexa

5、methylenetetramine(HMT)，theadditionofsurfactantCTAB，theratioofN，N-dimethylformamide．(DMF)towaterinthesolvent，andthereactiontime。Thealuminumhydroxidenano．sheetsbecamethinnerwhentheconcentrationofDMFwasincreased，andaluminumhydroxideflower-likenano．sheet

6、sassemblieswouldappearonAIfoilathigherconcentrationofHMT．Aluminumhydroxidenano-platesorllano—sheetswouldbecomethickerwhenCTABwasaddedinthesystem．2．ZnSemicrocrystalthinfilmsweresynthesizedonzincfoilthroughhydrothermalmethod．Theexperimentalresultsshowed

7、thatrodlikemicrocrystalswereobtainedinthemixedsolventofEGandwater(1：l，v／v)．WhennoEGwasaddedinthesolvent，ZnSenanopartMesweredepositedonZnfoil．TheZnSenanoparticleswouldaggregateintohollowspheresinthepresenceofhigherconcentrationofCTAB．Thesampleswerechar

8、acterizedusingXRDandSEM．Keywords：nano(micro)crystal，thinfilms，aluminumhydroxide，ZnSe，关于学位论文的独创性声明本人郑重声明：所呈交的论文是本人在指导教师指导下独立进行研究工作所取得的成果，论文中有关资料和数据是实事求是的。尽我所知，除文中已经加以标注和致谢外，本论文不包含其他人已经发表或撰写的研究成果，也不包含本人或他人为获得中国石油大学(华东)或其它教育机构的学位或学历证书而使用过的材料。与我一同