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1、GModelJPPS-739;No.ofPages68ARTICLEINPRESSProgressinPolymerSciencexxx(2012)xxx–xxxContentslistsavailableatSciVerseScienceDirectProgressinPolymerSciencejournalhomepage:www.elsevier.com/locate/ppolysciAdvancedpolyimidematerials:Syntheses,physicalpropertie
2、sandapplicationsDer-Janga,∗bacLiaw,Kung-LiWang,Ying-ChiHuang,Kueir-RarnLee,Juin-YihcdLai,Chang-SikHaaDepartmentofChemicalEngineering,NationalTaiwanUniversityofScienceandTechnology,Taipei10607,TaiwanbDepartmentofChemicalEngineeringandBiotechnology,Natio
3、nalTaipeiUniversityofTechnology,Taipei10608,TaiwancR&DCenterforMembraneTechnology,DepartmentofChemicalEngineering,ChungYuanUniversity,Chung-Li32023,TaiwandDepartmentofPolymerScienceandEngineering,PusanNationalUniversity,Busan609-735,RepublicofKoreaarti
4、cleinfoabstractArticlehistory:Polyimidesrankamongthemostheat-resistantpolymersandarewidelyusedinhighReceived25May2011temperatureplastics,adhesives,dielectrics,photoresists,nonlinearopticalmaterials,Receivedinrevisedform16February2012membranematerialsfo
5、rseparation,andLangmuir–Blodgett(LB)films,amongothers.Addi-Accepted24February2012tionally,polyimidesareusedinadiverserangeofapplications,includingthefieldsofAvailableonlinexxxaerospace,defense,andopto-electronics;theyarealsousedinliquidcrystalalignments,
6、composites,electroluminescentdevices,electrochromicmaterials,polymerelectrolytefuelKeywords:cells,Polyimidepolymermemories,fiberoptics,etc.Polyimidesderivedfrommonomerswithnon-coplanarSynthesis(kink,spiro,andcardostructures),cyclicaliphatic,bulky,fluorin
7、ated,hetero,carbazole,perylene,chiral,non-linearopticalandunsymmetricalstructureshavebeenPhysicalpropertiesApplicationsdescribed.Thesynthesesofvariousmonomers,includingdiaminesanddianhydridesthathavebeenusedtomakenovelpolyimideswithuniqueproperties,are
8、reportedinthisreview.Polyimides,withtailoredfunctionalgroupsanddendriticstructureshaveallowedresearcherstotunethepropertiesandapplicationsofthisimportantfamilyofhigh-temperaturepolymers.Thesynthesis,physicalpropertiesandapplicationsofad
