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1、ANINTRODUCTIONTOSURFACECHEMISTRYCAMBRIDGEUNIVERSITYPRESSLONDON:FetterLaneNEWTOEKTheMacmlllanCo.BOMBAY,CALCUTTAandMADBASMacmillanandCo.,Ltd.TORONTOTheMacmillanCo.ofCanada,Ltd.TOKYOMaruzen-Kabusliiki-KaishaAllrightsreservedANINTRODUCTIONTOSURFACECHEMISTRYByERICKEIGHTLEYRIDBALHUMPHREYOWENJONESLECT
2、URERINPHYSICALCHEMISTRYCAMBRIDGEUNIVERSITYCAMBRIDGEATTHEUNIVERSITYPRESS1926WiltThounotopethehearttoknowWhatrainbowsteachandsunsets;ahow?EMERSON.^^c^^INGREATBBITAINPREFACEByProfessorF.G.DONNANimportanceofanaccuratestudyoftheactions,equilibria,THEandstructureswhichoccurat.theinterfacesbetweenhomo
3、-geneousphasesofmatteriswidelyrecognisedatthepresenttime.Thusaknowledgeofthesemattersisrequiredforaproperunder-standingofadsorption,theformationandstabilityofdisperseormicro-heterogeneoussystems(colloidsolsandgels),catalysis,enzymeactions,etc.,whilsttheprogressofresearchshowsmoreandmoreclearlyt
4、hatthephenomenaoflife,i.e.thebehaviourofcellsandtissues,areintimatelyconcernedwiththeactionsoccurringatsurfaces,andthattheeffectsproducedbydrugs,disinfectants,andothersubstanceswhichprofoundlyaffecttheoperationofcellsandmicro-organismsarelargelyduetosurfaceactions.Fromthegeneralstatisticalandth
5、ermodynamicpointofview,thescientifictheoryofsurfacephenomenawasplacedonasatisfactorybasisbytheresearchesofJ.WillardGibbs,SirJ.J.Thomson,andJ.I),vanderWaals.Incomparativelyrecenttimesthe^morein-timatemolecularstudyofthestructuresandkineticsofsurfaceshasadvancedveryrapidly,thanks,moreespeciallyto
6、thepioneerworkofLordEayleigh,Andre".Marcelin,SirW.B.HardyandIrvingLangmuir.OurknowledgeofthissubjecthasbeengreatlyincreasedduringthelastfewyearsbytheexcellentworkofN.AdamandofE.K.Rideal.Thecombinedeffectoftheseresearcheshasbeen"torevealtheexistenceofanewlyrecognisedso-calledtwo"dimensionalmolec
7、ularworld,thedynamicsofwhichisanalogoustothatoftheordinary"threedimensional"molecularworldof"homogeneousphasesinbulk,whilstthestructureofthissurfaceworld"presentsnewphenomenaofmolecularorientationofthehighestimportancefortheunders
