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1、SurfaceChemistryOfSolidandLiquidInterfacesSurfaceChemistryOfSolidandLiquidInterfacesProfessorH.YıldırımErbilFacultyofEngineeringDepartmentofChemicalEngineeringGebzeInstituteofTechnologyTurkey©2006YıldırımErbilEditorialoffices:BlackwellPublishingLtd,9600GarsingtonRoad,OxfordOX
2、42DQ,UKTel:+44(0)1865776868BlackwellPublishingInc.,350MainStreet,Malden,MA02148-5020,USATel:+17813888250BlackwellPublishingAsiaPtyLtd,550SwanstonStreet,Carlton,Victoria3053,AustraliaTel:+61(0)383591011TherightoftheAuthortobeidentifiedastheAuthorofthisWorkhasbeenassertedinacco
3、rdancewiththeCopyright,DesignsandPatentsAct1988.Allrightsreserved.Nopartofthispublicationmaybereproduced,storedinaretrievalsystem,ortransmitted,inanyformorbyanymeans,electronic,mechanical,photocopying,recordingorotherwise,exceptaspermittedbytheUKCopyright,DesignsandPatentsAc
4、t1988,withoutthepriorpermissionofthepublisher.Firstpublished2006byBlackwellPublishingLtdISBN-10:1-4051-1968-3ISBN-13:978-1-4051-1968-9LibraryofCongressCataloging-in-PublicationDataAcataloguerecordforthistitleisavailablefromtheBritishLibrarySetin10on12ptMinionbySNPBest-setTyp
5、esetterLtd.,HongKongPrintedandboundinIndiabyReplikaPressPvtLtdThepublisher’spolicyistousepermanentpaperfrommillsthatoperateasustainableforestrypolicy,andwhichhasbeenmanufacturedfrompulpprocessedusingacid-freeandelementarychlorine-freepractices.Furthermore,thepublisherensures
6、thatthetextpaperandcoverboardusedhavemetacceptableenvironmentalaccreditationstandards.ForfurtherinformationonBlackwellPublishing,visitourwebsite:www.blackwellpublishing.comContentsPrefacexiPARTIPrinciplesChapter1–IntroductiontoSurfacesandInterfaces31.1DefinitionofaSurfaceanda
7、nInterface31.2LiquidsandLiquidSurfaces41.3SurfaceAreatoVolumeRatio51.4SolidsandSolidSurfaceRoughness61.5ChemicalHeterogeneityofSolidSurfaces7Chapter2–MolecularInteractions92.1IntramolecularForces:FormationofaMoleculebyChemicalBonding92.1.1Interatomicforces,bonds92.1.2Molecul
8、argeometry112.1.3Dipolemoments112.2IntermolecularForcesandPotentialEnergies
