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1、Thisarticlewasdownloadedby:[YaleUniversity]On:04January2012,At:17:53Publisher:Taylor&FrancisInformaLtdRegisteredinEnglandandWalesRegisteredNumber:1072954Registeredoffice:MortimerHouse,37-41MortimerStreet,LondonW1T3JH,UKCommentsonInorganicChemistryPublicationde
2、tails,includinginstructionsforauthorsandsubscriptioninformation:http://www.tandfonline.com/loi/gcic20ARationalApproachtoSolidStateSynthesis—TheZintlConceptaSusanM.KauzlarichaDepartmentofChemistry,UniversityofCalifornia,Davis,California,95616Availableonline:23O
3、ct2006Tocitethisarticle:SusanM.Kauzlarich(1990):ARationalApproachtoSolidStateSynthesis—TheZintlConcept,CommentsonInorganicChemistry,10:2-3,75-88Tolinktothisarticle:http://dx.doi.org/10.1080/02603599008050859PLEASESCROLLDOWNFORARTICLEFulltermsandconditionsofuse
4、:http://www.tandfonline.com/page/terms-and-conditionsThisarticlemaybeusedforresearch,teaching,andprivatestudypurposes.Anysubstantialorsystematicreproduction,redistribution,reselling,loan,sub-licensing,systematicsupply,ordistributioninanyformtoanyoneisexpressly
5、forbidden.Thepublisherdoesnotgiveanywarrantyexpressorimpliedormakeanyrepresentationthatthecontentswillbecompleteoraccurateoruptodate.Theaccuracyofanyinstructions,formulae,anddrugdosesshouldbeindependentlyverifiedwithprimarysources.Thepublishershallnotbeliablef
6、oranyloss,actions,claims,proceedings,demand,orcostsordamageswhatsoeverorhowsoevercausedarisingdirectlyorindirectlyinconnectionwithorarisingoutoftheuseofthismaterial.ARationalApproachtoSolidStateSynthesis-TheZintlConceptSUSANM.KAUZLARICHDeparrmenrofChemisrn.Uni
7、versiryofCalifornia,Davis,California95616Thereareawidevarietyofternalycompounds,A,M,X,.whereA=alkalioralkalineearthmetal.M=semimetalormaingroupelementandX=pnictide.thathavebeensynthesized.ForexamplethecompoundsBa,AlSb,.Ca,AISb,,Ca,AI,Sb,andCa,,AISb,,havebeensy
8、nthesizedandtheirstrucfurescanbeunder-stoodviatheZintlformalismwhichcanbesimplystatedastheoctetruleforallatoms.ThestructurescanbegenerallyformulatedasA'+[(MX)-]sothattheanionicunit
