几种基于蒽醌受体分子合成及性质的研究

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1、单位代码10445学号2007020835分类号O621.3硕士学位论文论文题目几种基于蒽醌的受体分子的合成及性质研究学科专业名称有机化学申请人姓名陈岳峰导师姓名郭佃顺教授论文提交时间2010年4月18日独创声明本人声明所呈交的学位论文是本人在导师指导下进行的研究工作及取得的研究成果。据我所知，除了文中特别加以标注和致谢的地方外，论文中不包含其他人已经发表或撰写过的研究成果，也不包含为获得（注：如没有其他需要特别声明的，本栏可空）或其他教育机构的学位或证书使用过的材料。与我一同工作的同志对本研究所做的任何贡献均已

2、在论文中作了明确的说明并表示谢意。学位论文作者签名：导师签字：学位论文版权使用授权书本学位论文作者完全了解学校有关保留、使用学位论文的规定，有权保留并向国家有关部门或机构送交论文的复印件和磁盘，允许论文被查阅和借阅。本人授权学校可以将学位论文的全部或部分内容编入有关数据库进行检索，可以采用影印、缩印或扫描等复制手段保存、汇编学位论文。（保密的学位论文在解密后适用本授权书）学位论文作者签名：导师签字：签字日期：年月日签字日期：年月日目录中文摘要····································

3、·····················································I英文摘要······················································································III第一章前言·················································································1第二章三唑桥联二茂铁蒽醌开链冠醚受体的合成、表征及

4、性质研究·················································21第一节结果与讨论·······························································21第二节实验部分···································································47第三章新型三唑桥联吡啶蒽醌受体的合成、表征与性质研究·····························

5、·······················54第一节结果与讨论·······························································54第二节实验部分···································································70结论···················································································

6、·········76致谢····························································································77附录I作者在攻读硕士学位期间发表论文·······························78附录II目标受体的NMR图谱···················································79山东师范大学硕士毕业论文几种基于蒽醌的受体分子的合成及性质研究摘要蒽

7、醌衍生物是构建具有特定功能的超分子受体的优秀结构平台，在超分子化学研究领域具有广阔和潜在的应用前景。特别是基于蒽醌衍生物的光、电活性受体的研究对生命科学、材料科学和环境科学的发展具有重要的意义，在分子识别、分子探针、分子器件、化学传感、疾病检测与诊断以及人工模拟酶等领域具有广阔的应用价值。为此，本论文开展了基于蒽醌分子受体的设计、合成和表征，并系统研究了它们的识别功能，取得了一定的研究成果。主要内容如下：1.综述了近年来基于蒽醌衍生物受体的设计、合成及在超分子识别传感等方面的研究进展。2.本论文共设计、合成了两个

8、系列，7种未见文献报道的蒽醌衍生物，其结113构经IR、HNMR、CNMR、MS和元素分析所表征。3.以蒽醌结构为平台，通过具有高产率的click反应将二茂铁和吡啶基团引入蒽醌，设计、合成了7种以1,2,3-三唑环为桥联基团的二茂铁蒽醌、吡啶蒽醌受体5a-c和R1-R4。4.利用循环伏安、荧光和紫外滴定技术系统研究了新型三唑桥联二茂铁蒽醌受体分子的识别性质。研究发现5a-