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1、第22卷第2/3期化学进展Vol.22No.2/32010年3月PROGRESSINCHEMISTRYMar.,20103两亲性杯芳烃的超分子自组装33梁清官冰江明(聚合物分子工程教育部重点实验室复旦大学高分子科学系上海200433)摘要本文综述了两亲性杯芳烃分子在不同维数下组装研究的进展,主要包括零维组装(囊泡、胶束、树枝状分子和分子箱)、一维组装(纳米管,纳米线及纤维)和二维组装(LB膜、超薄分离膜及界面组装);探讨了不同维数下组装体的形成机理和驱动力,主要包括氢键作用、金属配位作用、静电作用、包结络合作用以及疏水相互作用;控制和调节不同维数下组装体的转
2、变,有助于组装体材料在许多方面的应用。关键词杯芳烃自组装维数纳米尺度中图分类号:O62511文献标识码:A文章编号:10052281X(2010)02/320388212SupramolecularSelf2AssemblyofAmphiphilicCalixarenes33LiangQingGuanBingJiangMing(TheKeyLaboratoryofMolecularEngineeringofPolymers,MinistryofEducation,DepartmentofMacromolecularScience,FudanUniversit
3、y,Shanghai200433,China)AbstractRecentprogressinself2assemblyofcalixarenederivativesindifferentdimensionshasbeenreviewed.Itmainlyincludeszerodimensionassemblyleadingtocapsules,micelles,dendrimersandmolecularboxes,onedimensionassemblytonanofibers,nanotubesandtwodimensionassemblytoult
4、ra2thinmembranesandassembliesoninterfaces,etc.Themechanismsanddrivingforces,whichincludehydrogenbonding,metal2ligand,electrostatic,host2guestandhydrophobicinteractions,fortheassemblyandthetransitionsbetweenassemblieswithdifferentdimensionshavebeendiscussed.Thetransitionscanbecontro
5、lledinordertomeettherequirementsinvariesapplicationsoftheassembledmaterials.Keywordscalixarene;self2assembly;dimension;nanoscaleguestinteractionContents313Onedimensionassemblybasedonotherinterac21Introductiontions2Zerodimensionassemblyofcalixarenederivatives4Twodimensionassemblyofc
6、alixarenederivatives211Theassemblybasedonhydrogenbondinginter2411Membraneassemblybasedonelectrostaticinter2actionaction212Theassemblybasedonmetal2ligandinteraction412Interfaceassemblybasedonhost2guestinterac2213Theassemblybasedonhydrophobicinteractiontion3Onedimensionassemblyofcali
7、xarenederivatives412Interfaceassemblybasedonotherinteractions311Nanofibersformedbymetal2ligandinteraction5Thetransitionsamongdifferentdimensionassem2312Supramolecularpolymersformedbyhost2bliesofcalixarenederivatives收稿:2009年8月,收修改稿:2009年9月3国家自然科学基金项目(No.20774021,20834004)资助33Corresp
8、ondingauthore2mail:mjiang@
