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CETYLTRIMETHYLAMMONIUMBROMIDEACSSafetyDataSheetEmergencyTelephoneNumber:CHEMTREC1-800-424-9300ForInformationcall:DUDLEY732-886-3100DUDLEYCORPORATION125KenyonDriveLakewood,NewJersey08701EffectiveDate:May3,20121.PRODUCTIDENTIFICATION:Synonyms:Certrimoniumbromide;CTAB;Palmityltrimethylammoniumbromide;Hexadecyltrimethylammoniumbromide>CASNo.:57-09-0MolecularWeight:364.45ChemicalFormulas:C19H42NBr2.HAZARDIDENTIFICATIONEmergencyOverviewOSHAHAZARDSToxicbyingestion,IrritantGHSClassificationAcutetoxicity,Oral(Category4)Skinirritation(Category2)Seriouseyedamage(Category1)Specifictargetorgantoxicity–singleexpose(Category3)Acuteaquatictoxicity(Category1)GHSLabelelement,includingprecautionarystatementPictogramSignalwordDangerHazardsstatement(s)H302Harmfulifswallowed.H315Causesskinirritation.H318Causesseriouseyedamage.H335Maycauserespiratoryirritation.H400Verytoxictoaquaticlife.Precautionarystatement(s)P261Avoidbreathingdust/fume/gas/mist/vapours/spray.P273Avoidreleasetotheenvironment.P280Wearprotectivegloves/eyeprotection/faceprotection.P305+P351+P338IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontactlenses,ifpresentandeasytodo.Continuerinsing.HMISCLASSIFICATIONNFPARATINGHealthhazard:2Healthhazard:2Flammability:0Fire:0Physicalhazards:0ReactivtyHazard:0PotentialHealthEffectsInhalationMaybeharmfulifinhaled.Causesrespiratorytractirritation.Skin:Maybeharmfulifabsorbedthroughskid.Causesskinirritation.Eyes:Causeseyeirritation. Ingestion:Toxicifswallowed.3.COMPOSITION/INFORMATIONONINGREDIENTSSynonyms:Certrimoniumbromide;CTAB;Palmityltrimethylammoniumbromide;Hexadecyltrimethylammoniumbromide.CASNo.:57-09-0MolecularWeight:364.45ChemicalFormula:C19H42NBr4.FIRSTAIDMEASURES:Eyes:Immediatelyflusheyeswithplentyofwaterforatleast15minutes,occasionallyliftingtheupperandlowereyelids.Consultaphysician.Skin:Incaseofcontact,flushskinwithplentyofsoapandwaterwhileremovingcontaminatedclothesandshoes.Consultaphysician.Ingestion:Ifvictimisconsciousandalert,Rinsewithwater.DoNOTinducevomiting.NEVERgiveanythingbymouthtoanunconsciousperson.Consultaphysician.Inhalation:Removefromexposuretofreshairimmediately.Ifnotbreathing,giveartificialrespiration.Consultaphysician.NotestoPhysician:Treatsymptomaticallyandsupportively.5.FIREFIGHTINGMEASURES:GeneralInformation:Asinanyfire,wearaself-containedbreathingapparatusinpressure-demand,MSHA/NIOSHapprovedorequivalent,andfullprotectivegear.Duringafire,irritatingandhighlytoxicgasesmaybegeneratedbythermaldecompositionorcombustion,ExtinguishingMedia:Incaseoffireusewaterspraytocoolfireexposecontainers.Usewaterspray,drychemical,Carbondioxide,orappropriatefoam.Useagentmostappropriatetoextinguishfire.HazardouscombustionproductsHazardousdecompositionproductsformedunderfireconditions–Carbonoxides,nitrogenoxides(NOx),Hydrogenbromidegas.6.ACCIDENTALRELEASEMEASURES:GeneralInformation:UseproperpersonalprotectiveequipmentasindicatedinSection8.Spills/Leaks:Vacuumorsweepupmaterialandplaceintoasuitabledisposalcontainer.Cleanupspillsimmediately,observingprecautionsintheProtectiveEquipmentsection.Avoidgeneratingdustyconditions.Provideventilation.Placeunderaninertatmosphere.Donotletproductenterdrains.Dischargesintotheenvironmentmustbeavoided.7.HANDLINGANDSTORAGE:Handling:Washthoroughlyafterhandling.Usewithadequateventilation.Minimizedustgenerationandaccumulation..Avoidcontactwitheyes,skin,andclothing.Keepcontainertightlyclosed.Avoidingestionandinhalation.Storeprotectfromair.Handleunderinertatmosphere.Storage:Storeinatightlyclosedcontainer.Storeinacool,dry,well-ventilatedareaawayfromincompatiblesubstances.Donotexposetoair.Storeprotectedfrommoisture.Storeunderaninertatmosphere.8.EXPOSURECONTROLS,PERSONALPROTECTION:EngineeringControls:Facilitiesstoringorutilizingthismaterialshouldbeequippedwithaneyewashfacilityandsafetyshower.Useadequateventilationtokeepairborneconcentrationslow.ExposureLimitsChemicalNameACGIHNIOSHOSHA-FinalPEL’sCetylTrimethylAmmoniumBromideNonelistedNonelistedNonelistedOSHAVacatedPELs:CetylTrimethylAmmoniumBromide:NoOSHAVacatedPELsarelistedforthischemical. PersonalProtectiveEquipmentEyes:Wearappropriateprotectivefaceshield/eyeglassesorchemicalsafetygogglesasdescribedbyOSHA’seyeandfaceprotectionregulationsin29CFR1910.133orEuropeanStandardEN166.Skin:Wearappropriateprotectiveglovestopreventskinexposure.Clothing:Wearappropriateprotectiveclothingtopreventskinexposure.Respirators:FollowtheOSHArespiratorregulationsfoundin29CFR1910.134orEuropeanStandardEN149.AlwaysuseaNIOSHorEuropeanStandardEN149approvedrespiratorwhennecessaryorifirritationorothersymptomsareexperienced.9.PHYSICALANDCHEMICALPROPERTIES:PhysicalState:SolidAppearance:WhiteOdor:OdorlessFreezing/MeltingPoint:Meltingpoint/range:248-251˚C(478-484˚F)pH:5.0-7at36.4g/lat25˚C(77˚F)VaporPressure(mmHg):Notavailable.VaporDensity(Air=1):Notavailable.EvaporationRate:Notavailable.Viscosity:Notavailable.BoilingPoint:Notavailable.DecompositionTemperature:Notavailable.Solubility:36.4g/lat20˚C(68˚F)inwater.SpecificGravity/Density:NoDataavailableFlashPoint:244°C(471°F)–closedcup.Ignitiontemperature:nodataavailable.Auto-ignitiontemperature:nodataavailableLower/Upperexplosionlimit:nodataavailable10.STABILITYANDREACTIVITY:ChemicalStability:Stableatroomtemperatureinclosedcontainersundernormalstorageandhandlingconditions.ConditionstoAvoid:incompatiblematerials,dustgeneration,moisture,exposuretoair,excessheat,exposuretomoistairorwater.IncompatibilitieswithOtherMaterials:Air,moisture,strongoxidizingagents.HazardousDecompositionProducts:Nitrogenoxides,carbonoxides,irritatingandtoxicfumesandgases,hydrogenbromide.HazardousPolymerization:Hasnotbeenreported.11.TOXICOLOGICALINFORMATION:RTECS:CAS#57-09-0:BQ7875000LD50/LC50:CAS#57-09-0:Oral,rat:LD50=410mg/kgCarcinogenicity:CAS#57-09-0:NotlistedbyACGIH,IARC,NIOSH,NTP,orOSHA.Epidemiology:Noinformationfound.Teratogenicity:Noinformationfound.ReproductiveEffects:Noinformationfound.Neurotoxicity:Noinformationfound.Mutagenicity:Noinformationfound.OtherStudies:Nodataavailable.12.ECOLOGICALINFORMATION:EnvironmentalToxicity:Fish:LC50-Daniorerio(zebrafish)–0.3mg/l–96.0hDaphnia&otheraquaticinvertebrates:EC50-Daphniamagna(waterflea)–0.03mg/l-48h13.DISPOSALCONSIDERATIONS:Chemicalwastegeneratorsmustdeterminewhetheradiscardedchemicalisclassifiedasahazardous waste.USEPAguidelinesfortheclassificationdeterminationarelistedin40CFRParts261.3.Additionally,wastegeneratorsmustconsultstateandlocalhazardouswasteregulationstoensurecompleteandaccurateclassification.RCRAP-Series:Nonelisted.RCRAU-Series:Nonelisted.14.TRANSPORTINFORMATION:DOT:(US)Notdangerousgoods.IMDG:UN3077,ENVIRONMENTALLYHAZARDOUSSUBSTANCES,SOLID,N.O.S.,(Cetrimoniumbromide),9,PGIII,MarinePollutant.IATA:UN3077,Environmentallyhazardoussubstance,solid,n.o.s.(Cetrimoniumbromide),9,PGIII15.REGULATORYINFORMATION:USFEDERAL:TSCA:CAS#57-09-0islistedontheTSCAinventory.Health&SafetyReportingListNoneofthechemicalsareontheHealth&SafetyReportingList.ChemicalTestRules:NoneofthechemicalsinthisproductareunderaChemicalTestRule.Section12b:NoneofthechemicalsarelistedunderTSCASection12b.TSCASignificantNewUseRule:NoneofthechemicalsinthismaterialhaveaSNURunderTSCA.SARACodesCAS#57-09-0:acute,chronicCERCLAHazardousSubstancesandcorrespondingRQsNoneofthechemicalsinthismaterialhaveanRQ.SARASection302ExtremelyHazardousSubstances:NoneofthechemicalsinthisproducthaveaTPQ.Section311/312:AcuteHealthhazard.Section313:NochemicalsarereportableunderSection313.CleanAirActThismaterialdoesnotcontainanyhazardousairpollutants.ThismaterialdoesnotcontainanyClass1Ozonedepletors.ThismaterialdoesnotcontainanyClass2Ozonedepletors.CleanWaterActNoneofthechemicalsinthisproductarelistedasHazardousSubstancesundertheCWA.NoneofthechemicalsinthisproductarelistedasPriorityPollutantsundertheCWA.NoneofthechemicalsinthisproductarelistedasToxicPollutantsundertheCWA.OSHA:Toxicbyingestion,Irritant.STATECAS#57-09-0canbefoundonthefollowingstaterighttoknowlists:NJ&CaliforniaCalifornia–thisproductdoesnotcontainanychemicalsknowntoStateofCAtocausecancer,birthdefects,oranyotherreproductiveharm.16.DISCLAIMERINFORMATION:******************************************************************************************************************************************************DUDLEYCORPORATIONprovidestheinformationhereiningoodfaithbutmakesnorepresentationastoitscomprehensivenessoraccuracy.Thisdocumentisintendedonlyasaguidetotheappropriateprecautionaryhandlingofthematerialbyaproperlytrainedpersonusingthis.Individualsreceivingtheinformationmustexercisetheirindependentjudgmentindeterminingitsappropriatenessforaparticularpurpose.DUDLEYCORPORATIONmakesnorepresentationsorwarranties,eitherexpressedorimplied,includingwithoutlimitationandwarrantiesofmerchantability,fitnessforaparticularpurposewithrespecttotheinformationsetforthhereinortotheproducttowhichtheinformationrefers.Accordingly,DUDLEYCORPORATIONwillnotberesponsiblefordamagesresultingfromtheuseoforrelianceuponthisinformation. ******************************************************************************************************************************************************
