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TheMSDSformatadherestoU.S.standardsandregulatoryrequirementsandmaynotmeetregulatoryrequirementsinothercountries.MSDS规格遵照美国标准及规范要求,但并不一定符合其他国家的规范要求。Thisinformationisbasedupontechnicalinformationbelievedtobereliable.Itissubjecttorevisionasadditionalknowledgeandexperiencearegained.此资料依据被认为是可靠的技术资料汇编而成,但可随新的知识及经验的增长而随时修订。AMMONIUMMOLYBDATE钼酸铵CF0236Revised16-OCT-1999Printed17-MAY-2000CF02361999年10月16日修订2000年5月17日印制CHEMICALPRODUCT/COMPANYIDENTIFICATION化学品/公司识别MaterialIdentification产品识别CorporateMSDSNumber:DU006246DSPCMSDSNo.:A13CASNumber:13106-76-8Formula:N2H8MO04MolecularWeight:196.04协会MSDS编号:DU006246CAS号:13106-76-8分子式:N2H8MO04分子量:196.04TradenamesandSynonyms商品名及别名AMMONIUMPARAMOLYBDATEDIAMMONIUMMOLYBDATE仲钼酸铵 钼酸二铵CompanyIdentification公司识别MANUFACTURER/DISTRIBUTORBAKER;FISHER;KODAK;EMSCIENCE;ACROSORGANICS生产商/分销商BAKER公司;FISHER公司;KODAK;EMSCIENCE公司;ACROS公司;ORGANICS公司;PHONENUMBERSTransportEmergency:CHEMTREC:1-800-424-9300MedicalEmergency:1-800-441-3637电话号码运输应急:CHEMTREC:1-800-424-9300医疗应急:1-800-441-3637COMPOSITION/INFORMATIONONINGREDIENTS组成/组份资料Components成份MaterialCASNumber%AMMONIUMMOLYBDATE13106-76-899-100ORAMMONIUMMOLYBDATE,TETRAHYDRATE12027-67-799-100ORAMMONIUMPARA-MOLYBDATETETRAHYDRATE12054-85-299-100材料CAS号%钼酸铵13106-76-899-100或钼酸铵·四水合物12027-67-799-100或:仲钼酸铵四水合物12054-85-299-100HAZARDSIDENTIFICATION危险识别PotentialHealthEffects对健康可能产生的影响Poisoningmayaffecttheblood,liver,andkidneys.Atincreasedriskfromexposure:Personswithpre-existingrespiratory,kidney,orblooddisordersorgout.中毒可能会影响血液、肝脏及肾脏、接触后危险性增大的有:原先患有呼吸、肾脏、或血液不正常或 痛风的病人。Maybeexcretedinbreastmilk.Thebodylevelsofcopper,sulfur,andzincmayhaveaneffectonthetoxicity.(Basedoninformationonsolublemolybdenumcompounds).可在乳液中排泄出应分开体内铜、硫及锌的含量高低会对其毒性产生影响。(根据可溶性钼化合物的资料)INHALATION吸入Maycauseirritationoftherespiratorytract.可引起上呼吸道刺激SKINCONTACT皮肤接触Maycauseirritation.Chronic:Amongchemistshandlingsolutionsofmolubdenumandtungsten,therewasahighincidenceofgout.可引起刺激、漫性:在接触到钼及钨的溶液的化工人员中,有较高的痛风发生率。EYECONTACT眼接触Maycauseirritation.可引起刺激INGESTION摄入Maybeharmfulifswallowed.若吞咽下则会是有害的。CarcinogenicityInformation致癌性资料Noneofthecomponentspresentinthismaterialatconcentrationsequaltoorgreaterthan0.1%arelistedbyIARC,NTP,OSHAorACGIHasacarcinogen.被IARC,NTP,OSHA或ACGIH列为致癌的,在此物质的成份中没有一个基浓度是等于或大于0.1%的。FIRSTAIDMEASURES急救措施FirstAid急救INHALATION吸入Ifinhaled,removetofreshair.Ifnotbreathing,giveartificialrespiration.Ifbreathingisdifficult,giveoxygen.Callaphysician.若已吸入则移至新鲜空气处,若已停止呼吸则施以人工呼吸,若呼吸困难则输以氧气,请来医生。 SKINCONTACT皮肤接触Flushskinwithwateraftercontact.Washcontaminatedclothingbeforereuse.接触后用水冲洗,在衣服再次穿用前要清洗干净。EYECONTACT眼接触Incaseofcontact,immediatelyflusheyeswithplentyofwaterforatleast15minutes.Callaphysician.万一接触到后,立即用大量的水至少冲洗15分钟,请来医生。INGESTION摄入Ifswallowed,donotinducevomiting.Immediatelygive2glassesofwater.Nevergiveanythingbymouthtoanunconsciousperson.Callaphysician.若已吞咽下去,不要设法呕吐,立即喝二大杯水,千万别给已失去知觉的人从嘴中喂食任何东西,请来医生。NotestoPhysicians提示医生Activatedcharcoalmixturemaybeadministered.Toprepareactivatedcharcoalmixture,suspend50gramsactivatedcharcoalin400mLwaterandmixthoroughly.Administer5mL/kg,or350mLforanaverageadult.可服用活性碳混合物,制备活性碳混合物方法为:将50克活性碳悬浮于400mL水中并混合均匀,服用量为5mL/kg或对一般成年人350mL。FIREFIGHTINGMEASURES消防措施FlammableProperties易燃性质Notafireorexplosionhazard.无着火或爆炸危险Hazardousgases/vaporsproducedinfireareammonia.着火时产生的有害气体/蒸气为氨ExtinguishingMedia灭火介质Usemediaappropriateforsurroundingmaterial.采用适合于周边物质的灭火介质。FireFightingInstructions消防须知 Keeppersonnelremovedandupwindoffire.Wearself-containedbreathingapparatus.Wearfullprotectiveequipment.将人员撤至着火的上风处,戴上自背式呼吸器,穿戴齐全防护设备。Movecontainersfromfireareaifitcanbedonewithoutrisk.Closedcontainersexposedtoheatmayexplode.若可以做到无危险的话,将容器搬离着火区域,密封的容器受热后,可能会发生爆炸。ACCIDENTALRELEASEMEASURES事故消除措施Safeguards(Personnel)防护(人员)NOTE:ReviewFIREFIGHTINGMEASURESandHANDLING(PERSONNEL)sectionsbeforeproceedingwithclean-up.UseappropriatePERSONALPROTECTIVEEQUIPMENTduringclean-up.注:在清理干净之前,参阅“消防措施”及“处理(人员)”有关章节,在清理时,使用适当的“人员防护设施”。AccidentalReleaseMeasures事故消除措施Withcleanshovel,carefullyplacematerialintoclean,drycontainerandcover.Removefromarea.Flushspillareawithwater.用干净的铲子,小心将物质铲入洗净、干燥的容器中并盖上盖子并搬走,用水冲洗洒出区域。HANDLINGANDSTORAGE运输及贮藏Handling(Personnel)运输(人员)Avoidbreathingdust.Avoidcontactwitheyes,skin,orclothing.Washthoroughlyafterhandling.Washclothingafteruse.避免吸入其尘粒,避免其与眼、皮肤及衣服接触,运输后要彻底洗净,穿过的衣服要洗净。Handling(PhysicalAspects)运输(周边环境)Avoiddustgeneration.Keepawayfromheat,sparksandflames.避免产生尘粒,避免靠近热、火花及火焰。Storage贮藏Donotmixwithstrongacids.Storeinawellventilatedplace.Keepcontainertightlyclosed. 不要与强酸混合堆放,贮藏于通风良好之处,保持容器密闭。Storeinadryplace.贮藏于干燥之处。EXPOSURECONTROLS/PERSONALPROTECTION接触控制/人员防护EngineeringControls工程控制Keepcontainertightlyclosed.Usesufficientventilationtokeepemployeeexposurebelowrecommendedlimits.保持容器密闭,通风良好,使人员接触到的是低于推荐的极限。PersonalProtectiveEquipment人员防护设施EYE/FACEPROTECTION眼/脸防护Wearcoverallchemicalsplashgoggleswhenthepossibilityexistsforeyeorfacecontactfromairbornematerial.当眼及脸当有可能接触到空气中的该物质时,要戴上封闭式化学防溅护目镜。RESPIRATOR呼吸器ANIOSHapprovedairpurifyingrespiratorwithparticulatecartridgeorcanistermaybepermissibleundercertaincircumstanceswhereairborneconcentrationsareexpectedtoexceedexposurelimits.Protectionprovidedbyair-purifyingrespiratorsislimited.UseaNIOSHapprovedpositivepressureair-suppliedrespiratorifthereisanypotentialforanuncontrolledrelease,exposurelevelsarenotknown,oranyothercircumstanceswhereair-purifyingrespiratorsmaynotprovideadequateprotection.在空气中浓度可能超过接触极限的某些场合,允许使用为NIOSH批准的带活性碳过滤器或滤毒筒的空气净化呼吸器,但空气净化呼吸器所提供的防护是有限的,若有下列可能则要用NIOSH批准的正压供气呼吸器:无法控制的泄漏,接触浓度未知,或其它的空气净化呼吸器不能提供足够保护任何场合。PROTECTIVECLOTHING防护服装Wearimperviousclothing,suchasgloves,apron,boots,orwholebodysuitasappropriate.穿上不透水的服装,例如手套、围裙、靴子、或连衣裤。Recommendedglovematerial:Novendorrecommendationonmaterialofconstructionforprotectiveclothing.推荐手套材料:对防护服装的材质,卖主并未推荐。#ExposureGuidelines#接触准则ExposureLimitsAMMONIUMMOLYBDATE PEL(OSHA):Particulates(NotOtherwiseRegulated)15mg/m3,8Hr.TWA,totaldust5mg/m3,8Hr.TWA,respirabledust接触最大浓度钼酸铵PEL(OSHA):颗粒(没有另外规定)15mg/m3,8小时暂时工作区,总尘量5mg/m3,8小时工作区,可吸入尘量OtherApplicableExposureLimits其它适用接触最大浓度AMMONIUMMOLYBDATE,TETRAHYDRATEPEL(OSHA):5mg/m3,andsolublecompounds,asMoInsolublecompounds:15mg/m3,TotalDustas8HrTWAsTLV(ACGIH):10mg/m3,insolublecompounds,asMo5mg/m3,solublecompoundsasMo8HrTWAsNoticeofIntendedChanges(1999)Elemental/Metalandinsolublecompounds10mg/m3(Inhalablefraction)3mg/m3(Respirablefraction)0.5mg/m3(Solublecompounds),A3AEL*(DuPont):NoneEstablished钼酸铵,如水合物PEL(OSHA):5mg/m3,及可溶性化合物,钼的不溶性化合物:15mg/m3,总尘量8小时暂时工作区TLV(ACGIH):10mg/m3,不溶性化合物,钼5mg/m3,可溶性化合物钼8小时暂时工作区变更通知(1999)元素/金属及不溶化合物10mg/m3(可吸入部分)3mg/m3(可呼吸部分)0.5mg/m3(可溶化合物),A3AEL*(杜邦):尚未建立*AELisDuPont'sAcceptableExposureLimit.WheregovernmentallyimposedoccupationalexposurelimitswhicharelowerthantheAELareineffect,suchlimitsshalltakeprecedence.*AEL为杜邦公司可接受的接触最大浓度,若政府规定的职业接触最大浓度低于AEL,则采用最大浓度。PHYSICALANDCHEMICALPROPERTIES物理及化学性能PhysicalData物理数据BoilingPoint:190C(374F)DecomposesVaporDensity:2.5(Air=1)MeltingPoint:90C(194F)Hydrates(loseswater)190C(374F)@760mm/Hg SolubilityinWater:>10WT%(Appreciable)~43%(cold)pH:5.0-5.5@5%solutionOdor:OdorlessForm:Solid(crystals)Color:Whitetoyellow-greenSpecificGravity:2.2-2.5(Water=1)沸点:190℃(374℉)分解蒸气密度:2.5(空气=1)溶点:90℃(194℉)颗粒(没有另外规定)190℃(374℉)@760mm/Hg水中溶解度:>10重量%(明显)~43%(冷)PH:5.0-5.5@5%溶液气味:无气味形态:固态(结晶)颜色:白至黄绿色比重:2.2-2.5(水=1)Solventsolubility:Solubleinacids,alkalis,ammoniumchloridesolution.Insolubleinalcohol.溶剂溶解性:溶于酸、碱及铵盐及氯化物溶液中,不溶于酒精。STABILITYANDREACTIVITY稳定性及反应性ChemicalStability化学稳定性Stableatnormaltemperaturesandstorageconditions.在常温贮藏条件下稳定IncompatibilitywithOtherMaterials与其它物质不相容性Incompatiblewithstrongoxidizingagents,strongacids.与强氧化剂,强酸不相容。Decomposition分解性Decomposeswithheat.遇热分解Hazardousgases/vaporsproducedareammoniaandoxidesofnitrogen.产生的危害气体/蒸气为氨及氮氧化物。Polymerization聚合性Polymerizationwillnotoccur.不会发生聚合TOXICOLOGICALINFORMATION毒物学资料 AnimalData动物数据AmmoniumMolybdate动物数据OralLD50(Rats)3883mg/kgIHLLC50(Rats)>1930mg/m3/4h口服LD50(白鼠)3883mg/kgIHLLC50(白鼠)>1930mg/m3/4hAmmoniumMolybdateTetrahydrate钼酸铵四水合物OralLD50(Rats)333mg/kg口服LD50(白鼠)333mg/kgIngestion:Inanimals,largedoseshavecauseddyspnea,anorexia,colic,trembling,andincoordination.Listlessness,anemia,anddeformitiesoftheforelegswerereported.Thereisacorrelationbetweenmolybdenumconcentrationinfoodandincidencesofelevatedxanthineoxidaseactivity,boutanduricemia.Inanimals,molybdenummayinterferewithcoppermetabolism.摄入:在动物身上,大剂量要引起呼吸困难、疼痛、发抖及共济失调,还有报导有:疲倦、贫血及前腿畸形,食物中钼的高的黄嘌呤氧化酶活性之间有相互关系,在动物身上,钼可能会干扰铜的新陈代谢。DISPOSALCONSIDERATIONS废弃要点WasteDisposal废物处理Treatment,storage,transportation,anddisposalmustbeinaccordancewithapplicableFederal,State/Provincial,andLocalregulations.Donotflushtosurfacewaterorsanitarysewersystem.处理、贮藏、运输及废弃须符合现行联邦、州/省及地方法规,不要冲洗入地面水及污水系统中。TRANSPORTATIONINFORMATION运输资料ShippingInformation运输资料DOTProperShippingName:NON-REGULATED DOT正确运输名称:没有规定REGULATORYINFORMATION法规资料U.S.FederalRegulations美国联邦法规TSCAInventoryStatus:Reported/Included.TSCA库存状况:已报导/已包括TITLEIIIHAZARDCLASSIFICATIONSSECTIONS311,312第III条危险分类第311,312节Acute:YesChronic:YesFire:NoReactivity:NoPressure:No急性:是慢性:是着火:否反应性:否压力:无OTHERINFORMATION其它资料NFPA,NPCA-HMISNFPA,NPCA-HMISNPCA-HMISRatingHealth:1(ChronicHealthEffects)Flammability:0Reactivity:0NPCA-HMIS等级健康:1(慢性健康影响)易燃性:0反应性:0PersonalProtectionratingtobesuppliedbyuserdependingonuseconditions.个人防护等级视使用条件由用户提供。AdditionalInformation附加资料Technicaldata,basedonJ.T.BakerMSDSdated1/4/94, FisherScientificMSDSdated10/12/92,EastmanKodakCo.MSDSdated11/18/86,E.M.ScienceMSDSdated2/24/94;AcrosOrganicsMSDSdated1/12/96.技术数据根据1994年4月1日的J.T.Baker公司MSDS,1992年12月10日的Fisher科学公司MSDS,1986年11月18日的EastmanKodak公司MSDS,1994年2月24日的E.M.公司MSDS,1996年12月1日的AcrosOrganics公司MSDS。J.T.BakerChemicalCo.222RedSchoolLanePhillipsburg,NJ08865(908)859-2151(Emergency)J.T.Baker化学品公司.雷斯古路222号菲烈斯堡NJ08865(908)859-2151(应急)FisherScientificCo.ChemicalDivision1ReagentLaneFairLawn,NJ07410(201)796-7100(Technical&Emergency)Fisher科学公司化学品部雷琴路1号弗厄·浪,NJ07410(201)796-7100(技术及应急)EastmanKodakCompany343StateStreetRochester,NY14650(716)722-5151(Emergency)(800)225-5352(Techical)(716)458-4014(InNewYorkState)EastmanKodak公司斯泰脱路343号罗彻斯特NY14650(716)722-5151(应急)(800)225-5352(技术)(716)458-4014(在纽约州)E.M.Science480DemocratRoadGibbstown,NJ08027609-354-9200E.M.赛因施公司台蒙克雷路480号吉布斯镇NJ08027609-354-9200AcrosOrganicsJanssenPharmaceuticalaan3a2440Geel,Belgium800-ACROS-01 AcrosOrganics公司杰逊法默修基公司3a2440奇尔·比利时800-阿克罗斯-01----------------------------------------------------------------------ThedatainthisMaterialSafetyDataSheetrelatesonlytothespecificmaterialdesignatedhereinanddoesnotrelatetouseincombinationwithanyothermaterialorinanyprocess.此物质安全数据表中的数据仅与此文中所指定的具体物质有关,而与其它任何物质混合使用无关。DuPontCorporateSHEExcellenceCenterNemoursBuilding-Room2525Wilmington,DE19898(302)774-5723杜邦公司SHE人才中心NemoursBuilding-Room2525Wilmington,DE19898(302)774-5723#Indicatesupdatedsection.#表示修订过的章节EndofMSDSMSDS结束