descriptive inorganic chemistry_2009_1429218142

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1、ThispageintentionallyleftblankDescriptiveInorganicChemistryFIFTHEDITIONGeoffRayner-CanhamSirWilfredGrenfellCollegeMemorialUniversityTinaOvertonUniversityofHullW.H.FREEMANANDCOMPANYNEWYORKPublisher:ClancyMarshallAcquisitionsEditors:JessicaFiorillo/KathrynTreadwayM

2、arketingDirector:JohnBritchMediaEditor:DaveQuinnCoverandTextDesigner:VickiTomaselliSeniorProjectEditor:MaryLouiseByrdIllustrations:NetworkGraphics/AptaraSeniorIllustrationCoordinator:BillPageProductionCoordinator:SusanWeinComposition:AptaraPrintingandBinding:Worl

3、dColorVersaillesLibraryofCongressControlNumber:2009932448ISBN-13:978-1-4292-2434-5ISBN-10:1-4292-1814-2@2010,2006,2003,2000byW.H.FreemanandCompanyAllrightsreservedPrintedintheUnitedStatesofAmericaFirstprintingW.H.FreemanandCompany41MadisonAvenueNewYork,NY10010Hou

4、ndmills,BasingstokeRG216XS,Englandwww.whfreeman.comOverviewCHAPTER1TheElectronicStructureoftheAtom:AReview1CHAPTER2AnOverviewofthePeriodicTable19CHAPTER3CovalentBonding41CHAPTER4MetallicBonding81CHAPTER5IonicBonding93CHAPTER6InorganicThermodynamics113CHAPTER7Solv

5、entSystemsandAcid-BaseBehavior137CHAPTER8OxidationandReduction167CHAPTER9PeriodicTrends191CHAPTER10Hydrogen227CHAPTER11TheGroup1Elements:TheAlkaliMetals245CHAPTER12TheGroup2Elements:TheAlkalineEarthMetals271CHAPTER13TheGroup13Elements291CHAPTER14TheGroup14Element

6、s315CHAPTER15TheGroup15Elements:ThePnictogens363CHAPTER16TheGroup16Elements:TheChalcogens409CHAPTER17TheGroup17Elements:TheHalogens453CHAPTER18TheGroup18Elements:TheNobleGases487CHAPTER19TransitionMetalComplexes499CHAPTER20Propertiesofthe3dTransitionMetals533CHAP

7、TER21Propertiesofthe4dand5dTransitionMetals579CHAPTER22TheGroup12Elements599CHAPTER23OrganometallicChemistry611OntheWebwww.whfreeman.com/descriptive5eCHAPTER24TheRareEarthandActinoidElements651wAppendicesA-1IndexI-1iiiThispageintentionallyleftblankContentsWhatIsD

8、escriptiveInorganicChemistry?xiii3.4MolecularOrbitalsforPeriod2PrefacexvDiatomicMolecules46Acknowledgmentsxix3.5MolecularOrbitalsforHeteronuclearDedicationxxiD