volume 8 organic electrochemistry

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1、11MethodstoInvestigateMechanismsofElectroorganicReactionsBerndSpeiser....InstitutfurOrganischeChemie,AufderMorgenstelle18,Tubingen,Germany1.1Introduction......................................31.1.1Scope:MethodsofMolecularElectrochemistry...............31.

2、1.2HistoricalDevelopment..............................31.2WhyandHowtoInvestigateMechanismsofElectroorganicReactions41.2.1StepsofElectrodeReactionMechanisms...................41.2.1.1General.........................................41.2.1.2Transport........

3、................................41.2.1.3ElectronTransfer...................................51.2.1.4ChemicalKineticSteps...............................51.2.1.5Adsorption.......................................61.2.2OrganicElectrodeReactionMechanisms........

4、...........61.2.2.1ElectronTransferInitiatesChemistry.....................61.2.2.2NomenclatureofElectrodeReactionMechanisms.............61.2.3FormalDescriptionofEventsatanElectrode................71.2.3.1Current-Potential-TimeRelationships................

5、.....71.2.3.2ConcentrationProfiles...............................71.2.4MethodsofMechanisticElectroorganicChemistry............71.2.4.1Classification.....................................71.2.4.2Controlled-PotentialTechniques........................71.2.4.3Co

6、ntrolled-CurrentTechniques.........................111.2.4.4HydrodynamicVoltammetry...........................121.2.4.5ExhaustiveElectrolysisTechniques.......................131.3HowtoGainAccesstoKinetics,Thermodynamics,andMechanismsofElectroorganicReacti

7、ons............................141.3.1QualitativeandQuantitativeInvestigationofElectrodeReactionMechanisms......................................141.3.2GeneralRecommendationsforMechanisticAnalysis...........1421MethodstoInvestigateMechanismsofElectroorgani

8、cReactions1.3.3SomeMechanisticExamples...........................151.3.3.1PureETReactions..................................151.3.3.2Follow-upReactions.................................171.3.3.3PreequilibriatoETs.....