organic chemistry(oxford)

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1、01Whatisorganicchemistry?02.Organicstructures03.Determiningorganicstructures04.Structureofmolecules05.Organicreactions06.Nucleophilicadditiontothecarbonylgroup07.Delocalizationandconjugation08.Acidity,basicity,andpKa09.UsingorganometallicreagentstomakeC–Cbonds10.Co

2、njugateaddition11.Protonnuclearmagneticresonance12.Nucleophilicsubstitutionatthecarbonyl(C=O)group13.Equilibria,rates,andmechanisms:summaryofmechanisticprinciples14.NucleophilicsubstitutionatC=Owithlossofcarbonyloxygen15.Reviewofspectroscopicmethods16.Stereochemist

3、ry17.Nucleophilicsubstitutionatsaturatedcarbon18.Conformationalanalysis19.Eliminationreactions20.Electrophilicadditiontoalkenes21.Formationandreactionsofenolsandenolates22.Electrophilicaromaticsubstitution23.Electrophilicalkenes24.Chemoselectivity:selectivereaction

4、sandprotection25.Synthesisinaction26.Alkylationofenolates27.Reactionsofenolateswithaldehydesandketones:thealdolreaction28.Acylationatcarbon29.Conjugateadditionofenolates30.Retrosyntheticanalysis31.Controllingthegeometryofdoublebonds32.Determinationofstereochemistry

5、byspectroscopicmethods33.Stereoselectivereactionsofcycliccompounds34.DiastereoselectivityPericyclicreactions1:cycloadditions35.Pericyclicreactions2:Sigmatropicandelectrocyclicreactions36.Rearrangements37.Fragmentation38.Radicalreactions39.Synthesisandreactionsofcar

6、benes40.DeterminingreactionmechanismsSaturatedheterocyclesandstereoelectronics41.Aromaticheterocycles1:structuresandreactions42.Aromaticheterocycles2:synthesisAsymmetricsynthesis43.Organo-main-groupchemistry1:sulfur44.Organo-main-groupchemistry2:boron,silicontin45.

7、Organometallicchemistry46.Thechemistryoflife47.Mechanismsinbiologicalchemistry48.Naturalproducts49.Polymerization50.Organicchemistrytoday51.IndexWhatisorganicchemistry?1OrganicchemistryandyouYouarealreadyahighlyskilledorganicchemist.Asyoureadthesewords,youreyesareu

8、singanorganiccompound(retinal)toconvertvisiblelightintonerveimpulses.Whenyoupickedupthisbook,yourmusclesweredoingchemicalreactionsonsugarstogivey