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1、纳米自组装催化剂对劣质催柴加氢性能的研究李思洋⑴，王鼎聪⑵，赵德智W(1、辽宁石油化工人学石油化工学院，辽宁抚顺113001)(2、中国石化抚顺石油化工研究院，辽宁抚顺113001)摘要：采用二次纳米白组装方法制备堆积密度低、金属负载量高的大孔催化剂。X射线衍射、圧汞和氮吸附等结果表明，共孔径大部分集屮在30nm~100nm,占催化剂孔径分布的44.83%。以劣质催化裂化柴油为原料，在微型反应器中评价纳米口组装催化剂对催化裂化柴油的脱硫、脱氮、芳烧饱和的活性，并用现冇工业催化剂为参比剂(F2)做对比。结果表明，纳米自组装催化剂(FA9)加氢精制劣质催化裂化柴油的最高脱硫、脱氮率
2、达99%,而且有较高的芳绘饱和活性。在反应100h后，催化剂FA9仍然具有较高的活性，其脱硫率、脱氮率、芳绘饱和率分别为95.4%、97.50%、62.41%：而参比剂F2脱硫率、脱氮率、芳绘饱和率分别为94.4%、为98.20%、63.85%。计算结果表明，催化剂FA9的单位体积活性金属的硫脱除率是参比剂F2的1.75倍、氮脱除率是参比剂F2的1.72倍、脱芳饱和率是参比剂F2的1.70倍。关键词：纳米口组装催化剂；催化裂化柴油；脱硫；脱氮；芳烧饱和Theresearchnanoself-assemblycatalystforhydrodesulfurizationofFCC
3、dieselLiSi-yang,DingWei,Songguan-long,ZHAODe-zhi⑴：WangDing-cong[21(1、LiaoningShihuaUniversity,FushunLiaoning113001,P.R.China；2.FushunResearchInstituteofPetroleumandPetrochemicals,FushunLiaoning113001,P.R・China)Abstract*Adoptingsecondarynanoself-assemblymethodtopreparemacroporouscatalystwiths
4、mallstackingdensityandhighmetalloading,thedistributionofporevolumecentralizedfrom30to100nni,whichaccountsfor36.13%ofthecatalysttotalporesizedistribution.Thcevaluationofnanoself-assemblycatalystanddesulfurization,denitrificationandaromaticsaturationactivityisperformedinthemicroreactorwithinfe
5、riorcatalyticcrackingdieseloilasrawmaterial,andwithreferenceagentasacontrast.Theresultsshowthatinferiorcatalyticcrackingdieseloilrefiningbyusinghydrogenationtechniqueswithnanoself-assemblycatalyst(FA9)hashighdcsulfurization,dcnit「ificd(ionandaromaticsaturationactivity,andthehighestremovalrat
6、ereached99%.After100hreaction,catalystFA9stillhashighactivity,thedesulfurizationrateofnanoself-assemblycatalystwas95.4%,thedenitrificationratewas97.50%andthearomaticssaturationratewas62.41%;whilethedesulfurizationrateofF2catalystwas94.4%,thedenitrificationratewas98.2%andthearomaticssaturatio
7、nratewas63.85%.Thedesulfurizationrateofnanoself-assemblycatalystmetalactiveofunitvolumeis1.75timesofF2catalyst;thedenitrificationrateofFA9catalystis1.72timesofF2catalyst;thearomaticssaturationrateofFA9catalystis1.70timesofF2catalyst・Keywords:nanos
