硫酸装置工艺规程及岗位操作法

硫酸装置工艺规程及岗位操作法

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时间:2018-07-07

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1、宁夏兴尔泰集团中宁兴德化工有限公司硫酸厂企业标准Q/HTL-2011岗位操作及工艺规程宁夏兴尔泰集团中宁兴德化工有限公司2014年9月25日发布目录硫酸生产装置工艺操作规程································································1页供料岗位操作法···················································································19页桥式起重机岗位

2、操作···········································································21页沸腾炉岗位操作法···············································································26页锅炉岗位操作法···········································································

3、········33页排渣岗位操作法···················································································42页净化岗位操作法··················································································46页转化岗位操作法·················································

4、··································56页SO2风机岗位操作法·············································································64页干吸岗位操作法···················································································69页成品岗位操作法·························

5、··························································79页水处理岗位操作法···············································································88页循环水岗位操作法···············································································94页硫酸生产装置工艺操作规

6、程1.0适用范围本标准叙述了以硫铁矿为原料,采用接触法制硫酸的生产装置、生产原理、工艺过程、生产操作和主要工艺指标等。本标准适用于本公司200kt/a硫铁矿制酸及炉气余热发电生产装置。2.0产品简介2.1产品特性2.1.1硫酸的物理性质2.1.1.1硫酸是三氧化硫(SO3)和水(H20)的化合物,一个三氧化硫分子和一个水分子结合得到的就是纯硫酸(H2SO4),纯硫酸的分子量为98.08,是无色、无臭、透明的油状液体。2.1.1.2硫酸的密度硫酸的密度随浓度和温度的不同而发生变化,同一浓度的硫酸,它的

7、密度随温度的升高而降低。因此,同一浓度的硫酸在不同温度下其密度也不同。在20℃时,93%硫酸的密度为1.82g/cm3,98%硫酸的密度为1.84g/cm3。2.1.1.3结晶温度硫酸水溶液的结晶温度随着硫酸含量的不同而在一个极广泛的范围内变化。硫酸的结晶温度表(见下表)硫酸浓度%结晶温度℃硫酸浓度%结晶温度℃75-29.592-17.576-22.292.5-22.015277-15.593-27.078-9.593.5-31.279-5.094-31.980-0.194.5-26.5813.39

8、5-22.6825.995.5-16.5837.596-12.6848.4596.5-9.8858.097-7.0866.597.5-3.7874.698-0.7882.198.5+1.889-1.4994.590-5.599.57.590.5-8.310010.37191-11.5100.58.591.5-14.11016从表中可以看出93.5%的硫酸结晶温度较低,在高寒地区为了避免冬季生产时出现硫酸冻结事故,硫酸厂一般都生产93%的硫酸,结晶温度为-27℃,而98

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