高考化学模拟试卷（八）（含解析）

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2014
ᓭḕ□□ὃᓄᔁஹ⌱⚪13ᑖ
2013•ᑡ!"#Ḅ%
A&'(ᵨḄ*ᧇ,ᓄ-./0ᐸ2⌕ᡂᑖᙳ678B9ᵨ:;Ḅ2⌕ᡂᑖ%ⅅ;0=>ᡭḄ2⌕ᡂᑖ%@⏚BCCDᙠFᩭHḄIJKL0Mᵨ7ᩔOPQDRᵨ⏀ᙠTUKL2⌕VIWᓄXY0WᓄXYZ67[\XY24ᑖ
2013♦]^_ᵨN⊤abcdefMᦪḄh0ᑡij"#Ḅ%
AA24gNaH▢lmᡠoᵯmqᦪrNAB᪗tuv022.4LwoᨵC,Hyᦪ&r6NA-Cᙠ@⏚Bz,,|cCO
=lmol.L,ᑣcNa
=2mol-L3DKMnOᓄ(HOᑖ0JI32gOᵯmᦪr2N2222A34ᑖ
2014•ₚT0HḄlmMᦪrK,VmLamolLwi.Ḅᐗ⏚HAVmLbmol-LḄᐗBOHᐙᑖᔠ0ᑡᑨ"#Ḅ%2A|Va=Vb,ᔠz,0z,ᔜlmVIᓄ12B|pHHA
+pHBOH
=14,¡V=V0⏚ា£¤ᐰ¦12Cᔠ,:2cH
+cB
?cOH
+cA
VKw,.ID|ᔠz,cOH
=mo|.L,ᑣz,ᕈឋ44ᑖ
2013•«¬_⊤ᡠᑡḄ%®0¯°Ḅᓴ[\ᱥᙳ³ᨵ´0ᑖ᪆⊤ᔜ⚗Ḅ᣸¸¹ºᢥ¹º᣸¸¼6⚗XYr123456,,

1CHCHCHCH஻X„426512818ACHBCHCCHDCH2654204217365310s54ᑖ
2013•ᑡᨵᐵlm¾L¿Àᑏ"#ḄAᔣolmolFeiz,ᐭ᪗tuvCI:2Fe+2I+2CI?2Fe+I+2CI2222BᔣÄ⏚Bz,ᐭKÅC0:CHC00+C0+H0?HC0+2CHCOOH232233.2.2CᔣNaHSOz,ÆdBaOH
z,Çឋ:2H+SO+Ba+2OH?BaSO?+2HO42442-DÈÉ6Êr□᩽ᵯ⛳¦Í⏚Îz,:Cu+2HO?2Cu+O?+4H22764ᑖ
2015•Ï᪥ÑÒᐙᵯᵯÓḄÔᳮ᝞×ᡠa0z,cH
=2.0mol.L,ØᨴlmrSO,aஹbᙳrÚឋᵯ᩽0ᐙᵯÛÜz,Ý⁐ᵫà⁐rá⁐ᑡâᵯÓ0ij"#Ḅ%AãᵯKL0äÜz,Ý⁐ᵫå⁐ræ⁐3+BᐙᵯKL0a᩽ḄXY¿r:VO+2H+e=VO+HO22Cᐙᵯ0b᩽èéêᵯë"᩽0a᩽èéêᵯëì᩽.Dãᵯ,í1.0molᵯmᐳᨵ2.0molHïÛÜðñäÜ74ᑖ
2013ᑡij"#Ḅ%
AHSᐭFeCIz,òJIóå⁐ôõ0ö÷ᐭᑣòJIø⁐ôõ23Bᙠ¦ùúḄ0NaOHz,¦û⏚ᔠXYüḄᨬþrÿ
CᑖNaCOCHCOOCHᵨ23325DḄKIḄCI2ஹ⚪

2814ᑖ
2014•"□$᪥&'()*+,-ᨵ/Ḅ╅ஹ12ᩖ456Ớ+,ỚḄ8ᜫ:⌕ᵫ=ᩖ4ஹ>ᑖஹ?,Ḅ@ABᐝ᯿ஹEFGHIḄJK.2,NO:Q@ᓄឋ:10,Fe,I;TUឋ:SOV;QKI+I?KI3223232+2.QXYZ[\]6Ớ+^_᝞abc:d/X6Ớ+Je-ᨵKIOஹKIஹMgஹFeஹ33.Fe
,ᵨ〉/g>5h6i+⏚⏚ᓄ5kᡠmᑖn4oJpo,q6KSCNrst⁐;po,6v/KIw5sxy⁐5ᵨCCI⃓d5a{s|”t⁐;p~o,6ᐭ〉/KIOwr5q6ᑺ5⁐J3?ᔣpo,6KFeCN
5᪷ᔲmᑮᐹᨵᱯ⁐Ḅ5ecᔲ-36ᨵJᵨ⊤)5⁐ḄJᵨᓄY⊤)J?po,6ᐭv/KIwr5Ḅn:ஹJ2
KIn6ỚᑺḄ*+ᙠ,ᵫ=?,@Ḅᵨ᧕HIỚḄ8ᜫᑏ¡¢᛻aKI¤@ḄᓄY:JkI=KI5ᙠ¥ᩩ§a5eᑴm2KIHOJ©ᱥ4〉ᔠn*+6Ớᑺ5ᐸᳮᵫJ32•22.
3X®Yn¯°
ᱥ±
]2IO+5SO+2H7I+5SO+HOḄ²᳛Ḅ´µ553242¶·bc᝞⊤ᡠ¸4.1O.OlmohLKIO⏚ឋ0.01molLNaSOHOḄ¹bc
º⁐3232J-)Ḅ¹/mLḄ¹/mL/mL/?»ᡠ◤»½/sb5V3525t“c1

3b554025t2c2b55V0t23c3⊤,ᦪ:tt(À⊤ஹ⊤ᡈ"=");⊤,V=mL(,9((15ᑖ)(2013•ÅÆ')"¥ÇÈ¢”NHIᔜÊËḄÌ
ÍÎ5G᝞ÏÐ¥ᜧ,COḄ-/ᨵᦔᙢÔÕᑭᵨCO×ᡂnᓄYËẆ°Ḅ:⌕Ú⚪(22(1)ᵨᵯÜᔠᡂḄgÝÞßÇàáᨵᜧ/ḄÇÞß⚩ã(ᩖ4)5äå⚩ãeᵨ᝞a@ᓄæç5èéᡂ©ḄᓄY¸C+KMnO+HSO?CO?+MnSO+KSO+HOàবë)k®/ḄCO(g)HO(g)ᑖìíᐭî!|¹n2LḄឤòóᘤ,5^_2CO(g)+HO(g)?CO(g)+H(g),mᑮ᝞a~\ᦪ¸222bc\
QIõ//molö⊝//moløᑮö⊝ᡠ◤»½COHO/minHCO22I65042629002133900abcdt?bc2ᩩ§aö⊝ᦪK=(?bc3,5ùö⊝»5COḄúᓄ᳛ᜧ=>5ᑣa/bḄü(Àᐹüᡈdüþ)(bc4,ù900?»ᙠÿᘤᐭCOஹHOஹCOஹHᙳImol,ᑣ222VV(,"=")(〈(3)ᙠ?2CHOH(I)+30(g)=2CO(g)+4H3222?2CO(g)+0(g)=2C022

4?HO(g)=Hᑏᵬ⏣!ᐰ#$%ᡂ'(ᓄ*+,᝱.Ḅ0ᓄ12344
₝⏚7'89ᐗ;⏚<₝⏚=>NaHCO
?,@⏚ឋB<ᔣ10mLO.OlmohL24,1HCO224..mol-LNaOH?,

52
ÆÇÈᵨᑮḄᴻᘤᨵ$ÍஹᴻÎஹÏᜮÑஹB3
ᑡᨵᐵÆÇÈḄÓÁÔÕÖḄ7BaB×Ớ.Ù⁐<ᡠÛÑÜ3◤ᢣ¢ᑺbBÑÜ3Uᑭᵨaà?,Áᢣ¢ᑺcBÑᵨáâ.ãä´UÛåæ,dB┵_è◤⌕ᵨ±,éãeBÑÜ3<êëìíÑ,☢ïᓄfBÑðñ´<30sᑁ?,ឮô|ᩭḄö⁐¼÷ᦪJ4
gÑÜ3ùὑ0.5000mo|.LKI?,20.00mL,ᑣtuvtḄÅᑖB?BᵫÈஹÈUÛüýþtuvtḄ(ᓄᱥḄᓄ14Bÿ'ூᓄ-⌱3:ᱥ᪀ឋ௃1115ᑖ
2014•□᪥ᨵAஹBஹCஹDஹEஹFᐗAᕜ!⊤#$%&'ᨬ)ḄᐗBᵯ,ឋᨬᜧḄᐗCḄ2P.⍝#ᨵ012ᡂ4ᵯ%F$%᪶᜜ᵯ%ᦪBC᪶᜜ᵯ%ᦪ89D:;ᐗ?ᡂ@⁐ᡈẈ@⁐EO9Dz⁐ḄEOEFᓄᱥDBG?ᡂH%ᓄᔠᱥᐸᨔL᪀᝞NᡠPQRSTUᑡW⚪Y,1
EH%Z᝱\Ḅᵯ%᣸^_`a2
AFḄᑖ%bc᪀d`;F஺ᑖ%#F$%Ḅᩖᓄh_a233
CA᩽᧕klm,ᐸ$o:⌕a3QB?ᡂḄH%ᓄᔠᱥḄᓄ_`Qᵨᐗrs⊤PtH%ᨔ4
uN#GvwxD,3yḄz{`ag-cm,ᑣᨔLḄy}Qᑏx⊤_ᓽGᵨᓄa5
EᓫḄᨔy`☢hᨬzᚮ}QᙠᨔLḄ⚔9☢ᙳᨵ1E$%ᑣEḄᨔy#E$%Ḅᦪ`Qஹூᓄ⌱5:ᨵᓄZẠ௃15ᑖ

61215ᑖ
2014•□᪥᪺⏚Gu✏ᑖHxḄᨵ✏⏚ᐸᨵ1¡ZQ᪺⏚ᵬ£Gᵨ¤¥✏ᑺᵨl§ᧇஹ©§ஹª«ஹ⏀®¯°G`᪺⏚ᵬ£Ḅ=ᑖ±᪀yᐸᑖ%᪀d᝞NᡠPQN#ᳫᳫ8c³´⊤Pᓫµᡈ¶µ
ᵨ·A`$ᧇᔠᡂGḄ¸´᝞UY1
᪺⏚᪀_`:;ᑖ%#᪶ºᐳ¼½¾ᐳᨵ1¿a2
ᓄᔠᱥDGvÀÁḄÂÃᨵQAஹ¡ÂÃBஹFᓄÂÃCஹÄ$ÂÃDஹmÅÂÃ3
ᑏxᓄhÆ_?C?D;?E?H;A4
ᐸ#EḄ=ᑖ±᪀yÇÈᐸ#ᨵGᵨÉ_⊤PQᐸ#XஹYᙳ`H
,ÊᑏxrᔠËÉ_<>ÀÁÌÍÂÃḄᱥḄ᪀_ஹஹஹQ2014ÎÏᓭḕÒ□Ó□ÔÕ#ÖὃᓄÊᔁQÙÚὃTᫀÊ⚪Å᪆ஹ⌱Ý⚪13ᑖ
2013•ÞßUᑡàáâãḄ
AäåæᵨḄçᧇèᓄéêëᐸ:⌕ᡂᑖᙳìlíB¯ᵨîªḄ:⌕ᡂᑖⅅª)ðᡭḄ:⌕ᡂᑖò⏚óCôõᙠöᩭmḄÁøùÆ#úᵨlᩔüýþ

7D§ᵨ⏀ᙠÿ
⌕ᓄᓄὃ:Ḅᑖᵨ⌶;!"#Ḅᵨ;$ᔠ&ᓄ;'(Ḅ)*+ᑺḄ-ᡂஹឋ12ᵨ34⚪:ᓄ6ᵨ3ᑖ᪆:A389ᢣ;<ᨵ>?@AᐗCḄᓄᔠᱥEB3FGᡭḄ⌕ᡂᑖ9>⏚?JEC3KL9M"ᑺED3ᢣᨵNᱥᑖOPQROᡈROTUᐸWROᡈROTᡠYᡂZḄᨵNᱥḄ3#[:#\A3]ᓄ^⌕ᡂᑖ9_`ஹa`8,ᦑAdeEB3fgḄ⌕ᡂᑖ9ⅅgFGᡭḄ⌕ᡂᑖ9>⏚?JᦑB┯jEC+KL,KLklᔾ▬"opqḄᩖ1stᡂuvw"xyz{|ᦑC┯jED3kl}~⏚ḄḄ,0H,U,ORTYḄᱥᦑᓄᦑD┯j3ᦑ⌱A:⚪ὃ8ஹ'(Ḅ)*+ᑺḄ-ᡂஹឋ12ᵨᜧKLklᔾ▬"opqḄᩖ1stᡂuvw"xyz{|324ᑖ
2013•ᵨN⊤+'ᦪḄᑡdeḄ93AA24gNaH▢Oᡠ<ᵯO¢ᦪ£NAB᪗¥¦§22.4L¨<ᨵC,H©ᦪª£6NA

8C(ᙠ>⏚J]®c(CO)=lmol-L,ᑣc(Na)=2mol-L3D°
MnO±ᓄwHOᑖ#32gO²³´ᵯOᦪ£2N2222Aὃ:+'ᦪ34⚪:+'ᦪ+µ¶3ITMᑖ᪆\Aஹ·¸n=¹ºᱥ1Ḅ»NaH?O£H¹ºᵯOᦪEBஹ¨ᙠ᪗¥¦§9^¼ECஹ>⏚J]>⏚᪷O"#EDஹ·¸2HO=2HO+O?¾ᔠᐗCᓄᔠ¿Àᓄ¹ºᵯO³´E2222#[:#\Aஹ24gNaHᱥ1Ḅ»£lmol,▢OHᡠ<ᵯO¢ᦪ£2N,ᦑA┯jEABஹ¨ᙠ᪗¥¦§9^¼22.4L¨ᱥ1Ḅ»9lmol,ᦑB┯jEᙠ>⏚J],>⏚᪷O"#Á®cCO
=lmol-L,ᑣcNa
,3,12mol-L,ᦑC┯jEDஹ2HO=2HO+O?32gOᱥ1Ḅ»£lmol,ÃᐗCᓄᔠ¿Ä,1¿Àᓄ£22222,2¿0¿³´ᵯOᦪ£2N,ᦑDdeEAᦑ⌱D:⚪ὃÅÆ'ᦪᵨ⌕9ὃ,1»ᣚºᱥ1Ḅ»¹ºÈÉᦪ^¼᥅˼ÌᵨᩩÎ!"#ᵨÃᓄÏRᵯO³´¹º⚪ª34ᑖ
2014•ₚÑÒÓÔÕT²"ḄOÌ'ᦪ£K,ÖÕ×VmLamol»Lwi.1.1ḄØᐗ⏚HA&VmLbmol»LḄØᐗÙBOHᐙᑖÛᔠᑡᑨÝصdeḄ932

9A(®Va=VbÞßàÛᔠ]²]ᔜOâصãÀᓄäB(pH(HA)+pH(B0H)=14,ᑣV=V²,⏚Ùាæçᐰ12....C(àÛᔠ]:2c(H)+c(B)?c(0H)+c(A)VKw..1D(®Ûᔠ]c(OH)=molL,ᑣà]صᕈឋὃ:⏚ÙÛᔠ²ḄµឋᑨÝìᨵᐵphḄ¹º(4⚪:ᵯï⊝&]ḄpH4⚪(.ᑖ᪆:A(᝞]ᕈឋᑣÞßóc(H)ஹc(OH)ÀE*.B(®pH(HA)+pH(B0H)=14,ôK⏚c(H)Ùc(OH),᝞ᨵØA£õᵯ#1ᑣóõᵯ#1ᒕ÷EC(᪷¸]Ḅᵯ₹ùឤᑨÝEVKw(®Ûᔠ]c(OH)=mol.L,ᑣ(H)=c(OH)(..#[:#\A(᝞HABOH£ûᵯ#1ᑣÛᔠó]ᕈឋÞßóc(H)ஹc(OH)ÀᦑA┯jE“B(®pH(HA)+pH(B0H)=14,ôK⏚c(H)Ùc(OH)ü9ýþÔ⍝⏚
ᔲ⏚ஹ᝞⏚ஹᑣ⏚᝞ஹ⏚ᑣᦑB┯(ᕈឋ,ᙠc(H)+c(B)=c(OH)+c(A),ᑣ2c(H)+c(B),c(OH)+c(A),ᦑC┯;

10."D!"ᔠcOH
=mohL,ᑣH
=cOH
,ᑣ$%&ᕈឋ,ᦑD'(ᦑ⌱D*+:-⚪ὃ0⏚"ᔠḄ&ឋᑨ3456⚪789:-⚪;<=ᔠᵯ?@ḄᵯAᱯ*᩽ឋᑨ3;<ᵯ₹EឤḄᵨ44ᑖ
2013•IJKLM⊤ᡠᑡḄQRSTUḄ%ᓴWXᱥᙳ[ᨵ%]ᑖ᪆_⊤ᔜ⚗Ḅ᣸cdeᢥ$de᣸cg6⚗XM123456,,CHCHCHCH஻X„426512818ACHBCHCCHDCH265420421736S3108ὃ*:ᨵhᓄᔠᱥjḄᡂlᱯmn⚪:ᨵhᱥᑖopᡂqrḄᵨdeᑖ᪆:᜻ᦪ⚗Ḅcuovᦪw%᜻ᦪ⚗RxḄy4Huovᦪz4Ꮤᦪ⚗|᝞$?}:?:᜻ᦪ⚗ḄCuovᦪw%᜻ᦪ⚗RxḄC4Huovᦪz4Ꮤᦪ⚗|᝞$g6⚗ḄCuoᦪ8+18=26,ᓽCH,“ᦑ⌱:A*+:-⚪ὃ0ᨵhᓄᔠᱥjḄᡂlᱯm89ᜧὃ0Ḅde0ᳮ?⚪=ᔠ⚪0de54ᑖ
2013%LM_ᑡᨵᐵAorᑏ'(Ḅ
বAᔣImolFeiqᐭ᪗¡¢_CI:2Fe+2I+2CI?2Fe+I+2CI2222

11Bᔣ£⏚¤qᐭC0:CHC00+C0+H0?HC0+2CHCOOH232233c.CᔣNaHSO¥¦BaOH
§ឋ:2H+SO+Ba+2OH?BaSO?+2HO424422-D¨©ª□᩽ᵯ?⛳4⏚®:Cu+2HO?2Cu+O?+4H22ὃ*:AorḄᑏn⚪:Aon⚪,2•ᑖ᪆:A᪷°AoḄ±uឋLFe,ᑨ3²Ḅ³´ᔲ²AorḄᑏB᪷°⏚ᑴ⏚Ḅuᳮᩭᑖ᪆C᪷°NaHSO
BaOH
§ឋKὅḄᱥ@Ḅz¸2:1;D᪷°ᵯ?□᩽ᩞᧇ»¼Ḅ¨©ᙠᵯ½Ḅ¾ᵨ_ᜫᵯo;▢᩽ÁÂᩞᧇ᝞ÃQ□AoÄᵯoᯠ᪷°Æ=□᩽Ḅᵯ᩽+▢᩽Ḅᵯ᩽.ze?}:?yAÉAoḄ±uឋ:I,Fe,ᡠCIᐜËᓄI,ᯠËᓄFe,ᔣ2ImolFeiqᐭ᪗¡¢_CI[ᨵIÌËᓄAor:2Í.+CI7I+2CI,ᦑA┯22BCHCOOHḄ⏚ឋᜧÏHCO,ᡠÐᵨHCOᩭᑴᜓCHCOOH,ᦑB┯;323233CNaHSO
BaOH
§ឋKὅḄᱥ@Ḅz¸2:1,Ao42.2,22H+SO+Ba+2OH=BaSO?+2HO,ᦑC'(᝞..2”Dᵯ?□᩽Ḅᵯ᩽:2Ag,2e=2Ag;▢᩽Ḅᵯ᩽:Cu+2e=Cu,ᡠ2++Æ:2Ag+Cu=2Ag+Cu,ᦑD┯ᦑ⌱C

12*+:-⚪ὃ0AorᑏÒ(²ḄᓄAoḄᑏÓᓽÔ?}89Ðᜧ-.164ᑖ
2015•ÕÖ᪥ØLÙMÚᐙᵯᵯÜḄuᳮ᝞ÝᡠÞcH
=2.0mol.L,2.▢AoSO,aஹbᙳàឋᵯ᩽ᐙᵯáâã⁐ᵫæ⁐çè⁐_ᑡé$ᵯÜêë'(ḄMAìᵯíâã⁐ᵫî⁐çï⁐+ᵪBᐙᵯ,a᩽Ḅr:VO+2H+e=VO+HO22Cᐙᵯb᩽ñò½ᵯó'᩽a᩽ñò½ᵯóô᩽.Dìᵯõö÷1.0molᵯoᐳᨵ2.0molHùáâú÷ûíâὃ*:uᵯÜ4ᵯ?ÜḄü¾uᳮn⚪:ᵯᓄn⚪3বᑖ᪆:ᐙᵯáâã⁐ᵫæ⁐V
çè⁐V
,bᵯ᩽Äᵯo²±uᑣbᵯ᩽▢᩽aᵯ᩽□᩽aᵯ᩽þᜫᵯo²Ëᓄìᵯaᵯ᩽þÄᵯo²±uᑣaᵯ᩽'᩽bᵯ᩽ô᩽ô᩽þᜫᵯo²Ëᓄ
ᵯ?Üᵯ᩽'ÿ
z..:Aᵯaᵯ᩽V஺ᵯ
ᡂVO,ᑣ⁐ᵫ2!⁐"#$⁐ᦑA&';

132Y+Bᐙᵯa᩽+ᵯ,□᩽a᩽Ḅ
/#V0,e+H0=V0+2HᦑB┯2212Cᐙᵯ3bᵯ᩽#▢᩽a᩽#□᩽ᑣb᩽567ᵯ89᩽a᩽567ᵯ8&᩽ᦑC┯12ᵯ3&᩽▬;
:V0+2H+e=V0+H0,<=ᔣ&᩽?@,BC?22.1.0molᵯ3ᐳᨵ2.0molHGHI?JᦑD&'ᦑ⌱ADLM:N⚪ὃQᵯ,Rᵯ,ᳮᵯ᩽
/ḄTᑏஹᵯ᩽ḄᑨX+YZ[L\]ᵯ^▢□=Ḅ?@_ᔣ#᧕┯L74ᑖ
2013•bcdefgᑡij&'Ḅ+
AkHSlᐭFeCInop!⁐qrstlᐭᑣnou⁐qrvBᙠRxyzḄ{|kNaOHR}⏚ᔠ
Ḅᨬ#Cᑖ=NaCORCHCOOCHᵨ23325DḄKIr"$Ḅdz+CI2ὃL:RxḄyz;[ᵯ^Ḅ⊝qrCᓄḄN^;ᱥ^Ḅᑖ=ஹḄN_⌱ᵨ;Ḅ¡|¢⚪:{|M£⚪ᑖ᪆:A᪷¦HSlᐭFeCI
:HS+2FeCI=2FeCI+S+2HCI,stlᐭHS,232322

14§HSFeCI¨
222BᙠRxyzḄ{|◤y3ªd}⏚«<¬ᓄ®ὅ°ᙳ²ᓽ´µ¶
·Ḅᨬᓽ2CCHCOOCH¨¸NaCO32S23DḄKIr5¹º»¼$⁐½¾RỚ=
ÀỚ=¬ᓄ#ᓫ^Ớ⍗ᑮr"$2:AHSlᐭFeCI
:HS+2FeCI=2FeCI+S+2HCI,stlᐭHS,232322§HSFeCI¨
ᡠÅÆop!⁐qrᦑA┯1222BᙠRxyzḄ{|kNaOHR}⏚ᔠ
Ḅᨬ#ᦑB&'2CCHCOOCH¨¸NaCOÇᵨᑖḄ_ᑖ=ᦑC┯1232523DḄKIr5¹º»¼$⁐½¾RỚ=
ÀỚ=¬ᓄ#ᓫ^Ớ⍗ᑮr"$ʨdz#CI,ᦑD┯12zᦑ⌱:BLM:N⚪Ë⌕ὃQÍᓄY
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2014•Ñ□Ò᪥ÔeÕfÖ}×ᨵdzØḄ╅ஹÚÏᩖ^ÜỚ}ỚḄÝᜫË⌕+ᵫ¸ᩖ^ஹßᑖஹàḄ¬Åᐝ᯿ஹãx»äåḄ+.2æç:è¬ᓄឋ10,Fe,I;ឋ:SO,I;?KI+I?KI322323

15z.2.l
ºYZêëìÜỚ}Jí᝞g{|:°dzغÜỚ}Ç×ᨵKIO.KIஹMgஹFeஹ33.Fe,ᵨ〉ØßðÜñ}⏚⏚ᓄkᡠᑖ#4òódòôÜKSCN¼õ⁐;ó«òÜöØKI÷¼p!⁐ᵨCCI⃓°gù¼ú4õ⁐;ó¶òÜᐭ〉ØKIO÷ôÜrᑺ¨"⁐3?ᔣóýòÜKFeCN
᪷¦+ᔲᑮᐹᨵᱯ⁐Ḅᔲ36z*ᨵFeᵨ⊤,⁐ḄFeᵨᓄ⊤32.+10?!"ᐭ$%KI&'()*Ḅ+,-.+5I+6H=3I+3HOஹ0f2Fe+2I=2Fe+Iz2
KI1-"ỚᑺḄ45ᙠ789,!ᵫ;<=!>=Ḅ1ᵨ?᧕ABỚḄCᜫᑏFGHI᛻KKIL>=)*Ḅᓄ+,.4KI+0+2Ho=4KOH+2IMIN;KINᙠ2222OPᩩRKᑴTKIH஺VᱥXY〉ᔠ1-45"ỚᑺᐸᳮᵫKbHOᙠ^_ᩩ3232RK`aIbKI,KI᧕c>=>ᓄỚ᧕ᓣe2.22.3
fg-hiPjb)*ᱥkjl)*2IO+5SO+2H7I+5SO+HOḄm᳛Ḅop33242qrs᝞⊤ᡠ.a.IO.OlmoMKIO⏚ឋNO.OlmohLNaSOHOḄ'xsPjNFy⁐2332zḄ'x/mLNḄ'x/mL/mL/?{ᡠ◤{}/ss5V3525tli1s554025t22s55V0t23

163⊤!ᦪ:t,t(ᡈ"=");⊤!V=40mL(122ὃ:ᱥXḄb␺Ḅs+ᫀqr;ᓄ)*m᳛Ḅop(⚪:ᱥX␺⚪;ᓄ)*m᳛⚪(z.ᑖ᪆.(l)?FeLKFe(CN)N)*aᡂ⁐363+?KIOஹFeᐹᨵ>ᓄឋLKIa>ᓄ)*3(2)஺L>=)*aᡂỚᓫXஹKOH,KIHO(VᱥXY〉ᔠ1-45"ỚᑺLᐸ32ឋஹឋᨵᐵ(3)hi)*m᳛*¡¢£ᑴ¤%s1ஹ2!¥ᨵkjYgV=5,s1kj1ᜧ)*m᳛§;s2ஹ3*£ᑴPjYgᐸ¨ᩩR©gª«ᩭ®(z.®:.(l)?FeLKFe(CN)N)*aᡂ⁐ᑣ᪷ᔲTᑮᐹᨵᱯ⁐2.ḄᔲᨵFe,aᡂ-Fe,322+ᦑ®ᫀ-:Fe;Fe;323..2KIOஹFeᐹᨵ>ᓄឋLKIa>ᓄ)*)*ᑖ-IO+5Mm.2,+6H=3I+3HOஹ2Fe+2I=2Fe+I,222´ᦑ®ᫀ-:IO+5I+6H=3I+3HO;322(2)஺L>=)*aᡂỚᓫXஹKOH,aḄᓄ)*-4KI+O+2HO=4KOH+2I,222KI-HOᙠ^_ᩩRK`aIbKI,KI᧕c>=>ᓄỚ᧕ᓣeᑣVᱥXY〉ᔠ1322-45"Ớᑺᦑ®ᫀ-:4KI+O+2Ho=4KOH+2I;KIHOᙠ^_ᩩRK`aIbKI,222322

17KI᧕c>=>ᓄỚ᧕ᓣe(3)hi)*m᳛*¡¢£ᑴ¤%s1ஹ2!¥ᨵkjYgV=5,s1kjᜧ)*m᳛§ᑣt,t;s2ஹ3*£ᑴPjYgᐸ¨ᩩR©gᑣV=40mL,122ᦑ®ᫀ-:,;40(µ:¶⚪ὃ·ᱥX␺bs+ᫀḄqr-¸⚣ὃº»ḄஹᱥXḄឋX¼aḄ>ᓄ)*ஹop)*m᳛Ḅ-®Ḅᐵ½¾¿ᑖ᪆ÀÁ¼ÂÃÄᔠ*ᵨÀÁḄὃ·¡¢(4)!£ᑴ¤%ÅḄ*ᵨ⚪ÆÇjYᜧ(9((15ᑖ)(2013•ÈÉÊË)"OÌÍI”ÏABᔜÑÒḄ¸j¿ÓÔ᝞ÕÖOᜧ=!COḄ%bᨵᦔᙢÙᑭᵨCOÛᡂ-ᓄÒẆiḄÝ⌕ß⚪(22(1)ᵨᵯáÅᔠᡂḄâãäåÌæçèᨵᜧ%ḄÌäå⚩ê(ᩖX)ìí⚩êᵨ᝞K>ᓄÅîïðñᡂV)*Ḅᓄ+,5C+4KMnO+6HSO?5CO?+44242MnSO+2KSO+6HO4242(2)MYg%ḄCO(g)bHO(g)ᑖ0ᐭᑮ'x-2LḄឤ?óô?ᘤ!ö÷)*2CO(g)+HO(g)?CO(g)+H(g),Tᑮ᝞Køùᦪ.222sùPjúBû%/molü⊝%/molþᑮü⊝ᡠ◤{}COH/minOHCO22I65042629002133900abcdt?
2ᩩ⊝ᦪK=0.17(?
3⊝COḄᓄ᳛ᜧᑣa/bḄ1(ᐹᡈ")(?
4,900?ᙠ%&ᘤ(ᐭCOஹHOஹCOஹHᙳ,lmol,ᑣ%22JV,V/)(0□

18(3)23ᙠ45:?2CHOH(I)+30(g)=2CO(g)+4H3222?2C0(g)+0(g)=2C022?H0(g)=H22ᑏ8ᵬ⏣;<ᐰ>?@ᡂBCᓄDEF᝱ḄHᓄIJKLMCH0H(l)+0(g)=C0(gLz+2HO(l)?H=,442.8KJ/mol2(4)23₝⏚PBQRᐗT⏚₝⏚UV(NaHCO)WFX⏚ឋ(4ᔣ10mL0.01mol«L244HCO224molLNaOHWF[\WFᔜQ^_`aḄᜧᐵcc(Na),c(HCO),c(H)42,2„C(C0),C(0H)249(5)COᙠdᯠfghijCaCOklCaCOPBQmWᱥoᐸK=2.8xlO(CaQ233MWFjNaCOWFqᔠisᡂCaCOtu,wxyzḄCaCIWFjNaCOWFqᔠ2332234.NaCOWFḄ`a,IxlOmol/L,ᑣ@ᡂtuᡠ◤CaCIWFḄᨬ`a,1.12X102324moi/L(ὃ:CᓄklJKLḄ;ᵨᨵᐵklHḄ;ᓄI⊝ḄmWᵯoḄW⊝tuᓄḄo;^_`aᜧḄ[\(⚪:Cᓄkl⚪;ᓄIklḄᓄ;ᓄI⊝⚪;ᵯ^⊝jWFḄPH⚪(

19ᑖ᪆M(1)klC?CO,Dᐗᓄᔠᵫ0ᓣ,+4ᐳᓣ4KMnO?MnSO,2"Mnᐗᓄᔠᵫ+7¡¢,+2,ᐳ¡¢5ᓄᔠᓣ¡ᨬ£¤ᦪ,20,ᦑCḄcᦪ,5,ᦑKMnO
ᦪ4,¦%§ᔠ_¨ឤᐸªᱥoḄcᦪ,(2)?ஹ᪷¦¬L⊝ᔜ®ᑖḄᱥoḄkl¯°ḄᓄIᦪ;ᑭᵨᱥoḄ²³`a²ᐭ⊝ᦪ⊤µL?ஹᵫC஺jHḄᓄIᦪ·y¸,1,ᡠ¹º»ὅᱥoḄ·yRὅᓄ᳛2·y⌕¾coᓄ᳛ᜧHḄᓄ᳛ᑣ¿ᜧHḄᱥoḄ22?ஹᦪḄ`aᖪQC,j⊝ᦪ[\ᑨÂklḄJᔣ¦%Ã(3)᪷¦ᵫ23HᓄIJKLĹ〉ºḄcᦪ(Æ᪀⌼É᪗JKLklHËĹ·lḄcᦪÌ·lḄÍ(4)ᔣ10mLO.OlmohLHCOWFÎ(10mLO.OlmohLNaOHWFRὅាÐ224klᡠÑWF,NaHCOWFNaHCOWFX⏚ឋÒÓHCOḄᵯ^Kaᜧ242424WFPᵯ^@ᡂU^_¦%ᩭÕ^_`aḄᜧ4sz(5)NaCOWFḄ`a,lxl0mol/L,yzqᔠ°WF(cCO)=5xl0mol/L,2332,2*2,᪷¦Ksp=c(CO)c(Ca)tuqᔠWFc(Ca),WFCaCIWFḄz,ᨬ`a,qᔠWFc(Ca)Ḅ2¤(Ã:(1)klC?CO,Dᐗᓄᔠᵫ0ᓣ,+4ᐳᓣ4KMnO?MnSO,z஻Mnᐗᓄᔠᵫ+7¡¢,+2ᐳ¡¢5ᓄᔠᓣ¡ᨬ£¤ᦪ,20,ᦑCḄcᦪ,5,ᦑKMnOcᦪ,4,§ᔠ_¨ឤ°JKL,”5C+4KMnO+6HSO=5CO?+4MnSO+2KSO+6HO42424242

20ᦑÃᫀ,5ஹ4ஹ6=5ஹ4ஹ2ஹ6;(2)?ஹ⊝COḄᱥoḄ,1.6mol,×ØCO(g)+HO(g)?CO(g)+H(g),ÙÚ(mol):2100Ûkl¯°z;ᦑᑭᵨᱥoḄ²³`a⊝ᦪᦑ900?Ûkl⊝ᦪk==0.17,O4X0.41.6X0.6ᦑÃᫀ,0.17;?ஹᵫC஺jHḄᓄIᦪ·y¸,1,ᡠ¹º»ὅᱥoḄ·yRὅᓄ᳛2·y(⌕¾COᓄ᳛ᜧHḄᓄ᳛ᑣ¿ᜧHḄᱥoḄᓽa/bḄ1,22ᦑÃᫀ,:1?ஹᵫÝ900?ÛklḄ⊝ᦪ,0.17,
4,ᙠ900?ᙠ%&ᘤ(ᐭ1X1IxTCOஹHOஹCOஹHᙳ,lmol,ᑣ%`aᖪQc==l,ᜧ⊝ᦪ0.17,ᦑkl222ᔣ⌮klᡠ¹V,V,0⌮ᦑÃᫀ,:,(3))?2CHOH(I)+30(g)=2CO(g)+4H3222?2CO(g)+0(g)=2C022?HO(g)=H

21ߦÝ,Ý+?x4Ñ:2CHOH(l)+2O(g)=2CO(g)+4HO(I)?H=,322885.6KJ/mol;BPCHOH(l)+O(g)=CO(g)+2HO(I)?H=,442.8KJ/mol;322ᦑÃᫀ,MCHOH(l)+O(g)=CO(g)+2HO(I)?H=,442.8KJ/mol;322à1(4)ᔣ10mLO.OlmohLHCOWFÎ(10mL0.Olmol-LNaOHWFRὅា224..ÐklᡠÑWF,NaHCOWFᙠÛWFâãᵯ^8ḄNaEHCO`aᨬᜧ2424...NaHCOWFX⏚ឋÒÓHCOḄᵯ^Kaᜧᡠ¹c(Na),c(HCO),C242424,.+z(H),c(OH),WFᵯ^@ᡂU^_ᦑc(H),c(CO),WFᕈ⏚ᵯ2,.”^æ@Ḅc(CO)ᜧc(OH),WF^_`ac(Na),c(HCO),c(H)2M2.„C(CO),C(OH),24-2.ᦑÃᫀ,:c(Na),c(HCO),c(H),c(CO),c(OH);424212,2.(5)NaCOWFḄ`a,lxl0mol/L,yzqᔠ°WFc(CO)=xlxlO233,4,52+,92,mol/L=5xl0mol/L᪷¦Ksp=c(CO)«c(Ca)=2.8xlOir3┛^_ᨬ32.8X10-95X10-5…`ac(Ca)=mol/L=5.6xl0mol/L,WFCaCIWFḄᨬ`a,z..qᔠWFc(Ca)Ḅ2¤,ᦑWFCaCIWFḄᨬ`a,2x5.6x10,s.4mol/L=1.12xl0mol/L,,4ᦑÃᫀ,:L12xlO(

22é:⚪ὃêCᓄklஹ⊝ᦪḄjëᵨஹHᓄIJKLìᑏஹ^_`aᜧ[\ஹWazḄᨵᐵy⚪Éíᔠឋ\ᜧPîI@ïḄὃêmay5
,᧕┯WFòᶍqᔠ°WFḄ`aô@ᓄ/1014ᑖ
2014•᪻ö÷᪥ùúûüýþÿ
Ḅ⌕ᧇᐸ⌕ᡂᑖḄᓄᱥᩖᐗᐗᩖHSO!"#Ẇ%ឋ'()*+#2.,-ḄᓄᱥḄᓄ'./01%?,-3Ḅ45?ᢥ71*89ᘤ;<8=Ḅ>?ឋ@?A,-BᐭDEᴻG8=BஹCḄIJ᝞71ᡠMᜳᢝ9ᘤᙳḕᶍ"@?STUV>GWᜐYᙢ[[\ᐭH,]C8=^WᜐH_`abcAᜐ⏀ef22?ᐙᑖ!ahᣵ⏀efjᢝk\ᐭl>mnᐰpᓾ1
8=CḄrᵨ■uv>Ḅwx>CO/ᐭByz45{|22
4Ḅ!a8=B}~ᑣ,-Ḅᑖ324%?,-3Ḅ451
ḄrᵨḄ3ḄCl22
ᵨᑮḄEᴻ9ᘤᨵஹEᴻஹᜮGஹ250mL33
ᑡᨵᐵḄrḄdfaỚw⁐ᡠ¢5£◤¥ᢣMᑺb5£¨ᑭᵨª«rᢣMᑺc5Gᵨx¬w®a¨¢¯°8d┵²◤⌕ᵨ]4³e5£´µ¶·5G☢¹ᓄ

23f(5{¼a30sᑁឮ¿ᩭḄÁ⁐jÂᦪJ(4)Ä5£Åὑ0.5000mo|.LKI20.00mL,ᑣ,-Ḅᑖ370%(?(ᵫஹ¨¢ÈÉ^Ê,-ḄᓄᱥḄᓄ'.FeO(56ὃb:1%ᱥḄ*ᡂᡈ43ᱥḄ3(Î⚪:Ð_1%ᦪÑᜐᳮ⚪(ᑖ᪆:ஹ(1)BḄÔ-ᮞᔾᦈ=ᣚ!ÙᡂḄwḄÚ■uv>ᡂᑖ+Ð_Ḅyz⌕¥Û8=ᔾᦈv>Ḅw¢ÜÝᓄÞ@(2)!a8=B}~ᓽl>ᓄ!aÙᡂḄwḄ3¨¢᪷ÑáឤᩭãÉ@?ஹ,-ᐜᵨå3Ḅæç⏚é◀ëᩖìᑮíḄîïḄj\ð>AḄḄîïᓄᡂñòîïjᵨỚᓄóᩭ5Ñôᑖ᪆ãÉ@(1)¨¢AwḄ>õö@(2)᪷Ñæ÷õøᑴ5õúḄᡠ⌱üḄ9ᘤᩭýþ@(3)᪷Ñ5ÿ
Ḅᑖ᪆ᩭᑨ(4)᪷ᐗឤᓄ!"#$%&?(?)*B+,-.ᡂ0Ḅ123᪷4ᐗឤ5g56%&n(O),?78?9.2Fe+2I=2Fe+I,᪷:ὑKI<=>?%&n(Fe)3᪷Feᐗឤ2%&10g56n(Fe),AB4ᓄᱥᓄ"(D:DF((1)G3HI4ᓄJ.ᡂKLJ03᪷M>12ḄNᓄᩭ%&JḄO23BᜐḄQRSTᵨVᔾᦈY.Ḅ0ZI3ᡠ
C)*⌕■^■^_IḄ0ZICO#ᐭB3abcde3ᦑᫀ-:■^_IḄ0ZICOzz#ᐭBabcde(2)cḄh)*B+,3᪷Ḅ1ᓽ.ᡂḄ0Ḅ123ᡠ
4ᐗḄ12ᑖᦪVxl00%=24%,ᦑᫀ-:24%;

245.0?(J56ᐜᵨm2Ḅno⏚?Ï:ὑKI<=Ḅ>?ÐÑdᔠ!"§3c3+.i(Fe)=c(KI)=0.5molL,ᡠ
JᐗḄÓᑖO2-F0.5inol/LX0.25LX56g/mol10^xl00%=70%,ᦑᫀ-:70%;?(?)*B+,-.ᡂ0Ḅ123᪷4ᐗឤ35g56n(O)=n(HO)2

25L35g18g/inol==0.075mol,10g56n(O)=0.15mol,250mL20mL35”78?9.2Fe+2I=2Fe+I,n(Fe)=0.02Lx0.5mol/Lx=0.125mol,23.ᦑ1056n(Fe)=n(Fe)=0.125mol,ᦑn(Fe):n(0)=0.125mol:0.15mol=5:6,ᓽᓄ"-:FeO,“ᦑᫀ-:FeO(S6ÕÖ:×⚪V⍝ÚÛᱥ1ḄÜᡂஹc2ᱥ1ḄO2Ḅ⍝Ýᔠὃß⚪3ὃß.ᑖ᪆Dàá⚪Ḅâã3Ýᔠឋå3æçᜧ(~ஹூᓄ-⌱ë3:ᱥ1d᪀Ïឋ1௃11((15ᑖM2014•î□ð᪥òóô)ᨵAஹBஹCஹDஹEஹFöᐗ3AVᕜø⊤ÉyúûᨬýḄᐗ3BVᵯÿឋᨬᜧḄᐗCḄ2P⍝ᨵᡂᵯF᪶᜜ᵯᦪBC᪶᜜ᵯᦪDᐗEᕜE!ᡂ"⁐ᡈẈ"⁐E0&2⁐ḄE0'()ᓄᱥDB,!ᡂ-ᓄᔠᱥᐸᨔ12᪀᝞5ᡠ7(9:;<ᑡ>⚪@*22626i°Q)E-A᝱CḄᵯ᣸EFGIs2s2P3s3P3d;a(2)AFḄᑖIJ᪀KGsp;FOᑖFḄᩖᓄMFN☢PQ!R"(3)CA᩽᧕VWXᐸY⌕NHXᑖJ!ᡂ[\R33(4)]5,^_`DB!ᡂḄ-ᓄᔠᱥḄᓄaFGCaF(ᵨᐗcd⊤7)g24*78aXNA

26,33-ᨔiḄjkGag-cm,ᑣᨔ1Ḅimcmnᑏ`⊤pFᓽ,rᵨᓄstR5
uvEᓫxḄᨔiG☢yzMᨬjᚮmnᙠᨔ1Ḅ⚔~☢yᙳᨵEtᑣEḄᨔiEḄᦪG12ὃ~:2᪀ឋxḄᐵᵨ;ᨔ1Ḅn⚪:ᐗᕜᐗᕜ⊤⚪nᑖ᪆:ᨵAஹBஹCஹDஹEஹF(ᐗAᕜ⊤ᨬḄᐗᑣAGHᐗRBᵯឋᨬᜧḄᐗᑣBGFᐗ;CḄ2p⍝ᨵᡂḄᓫᵯ223᪶᜜ᵯ᣸EGIs2s2pᑣCGNᐗ;F᪶᜜ᵯᦪBC᪶᜜ᵯᦪᑣF᪶᜜ᵯᦪG9+7=16ᑣFGSᐗ;E!ᡂ"⁐nᡈẈ"⁐tḄE02&⁐ḄE0'()ᓄᱥᑣEGCuᐗ;DB,!ᡂ-ᓄᔠᱥ᪷ᨔ12᪀11■§2,vᨔ1FᦪG8,DᦪG8x+6x=4,ᦑᓄaFGDF,DG+21DᐗEᕜᜐWᕜᑣDGCaᐗ¡;n¡;:¡@ᨵAஹBஹCஹDஹEஹF(ᐗAᕜ⊤ᨬḄᐗᑣAGHᐗ;BᵯឋᨬᜧḄᐗᑣBGFᐗ;CḄ2p⍝ᨵᡂḄᓫᵯ223᪶᜜ᵯ᣸EGIs2s2PᑣCGNᐗ;F᪶᜜ᵯᦪBC᪶᜜ᵯᦪᑣF᪶᜜ᵯᦪG9+7=16,ᑣFGSᐗ;E!ᡂ"⁐nᡈẈ"⁐tḄE0&⁐ḄE0'()ᓄᱥᑣEGCuᐗ;DB,!ᡂ-ᓄᔠᱥ᪷ᨔ2

2711~8212᪀,vᨔ1FᦪG8,DᦪG8x+6x=4,ᦑᓄaFGDF,2DG+2DᐗEᕜᜐWᕜᑣDGCaᐗ.22IO(1)EGCuᐗCu-A᝱Cᵯ᣸EFGIs2s2P3s3P3d,6262262610ᦑ;ᫀG:Is2s2P3s3P3d;6-22s(2)HSᑖSḄ¤ᵯᦪ=2+=4,S¥¦spᩖᓄSḄ)ᓄᱥ26-2X32-SOᑖS¤ᵯᦪ=3+=3,S§ᨵ¨ᵯᦑSOGN☢33PQ!3ᦑ;ᫀG:sp;N☢PQ!R(3)NH᩽᧕VWXᐸY⌕NHXᑖJ!ᡂ[\33ᦑ;ᫀG:NHXᑖJ!ᡂ[\R3(4)DFᐗ,!ᡂ-ᓄᔠᱥ᪷ᨔ12᪀,vᨔ1FᦪG8,D11~82ᦪG8X+6X=4,ᦑᓄaFGDF,DG+2DᐗEᕜ2ᜐWᕜᑣDGCaᐗᦑg-ᓄᔠᱥᓄaFGCaF,ᨔ1ḄjkGagcm2

284X78g/mol--1Nmol4X78g/m஺«.4x7gAag-cm_3NAmo11aXNA,33,ᨔ1ḄxGᦑᨔ1ḄimGK!!44X78aXNA3ᦑ;ᫀG:CaF;cm;25
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