山东省德州市2022届高考三模化学试题

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9◀MC&2+,Cerᔠ⚪uvD.ZnCCh-xZn(0H)2ḄᱥḄ,ymol,ZnCO3-xZn(OH)2WYᑮZnO,ᑣḄ,zᓄஹoḄn(Zn஺)==᪷ḄஹZnOḄᱥḄᑡ:,44y+18xy=l128.1ஹy+xy=O.l,cYx=lஹy=0.05,Drᔠ⚪uvᦑ`ᫀ,D஺ூᑖ᪆௃ᐜᑖ᪆(⌕ᡂᑖ,ZnO,ᨵCuOஹPbOஹsgஹFeOஹFe2/ᩖp⏚¡P!",ekn⏚Ḅzᓄấ£¤5ᡂḄ¥¦PbSO4,!,ZnSChஹCuSO4ஹFeSChஹFe(SO4)3,!3§ᐭw⏚yw═⏚y¨,zᓄᑺX£©|}89zᓄ,}89ppH«2⁚P,!",~zᓄ}zᓄ┡!,CuSO4ஹZnSO,!Gᐭᑺ2ḄKḄ¯89¥4¦°±e²³´89µ¶¥¦ᑺ,Zn,¯89·ᡂᓫ!"2,!,ZnSCU,p⏚~}¯ZnSChºᓄ,¥¦WYᑮ»¼zᓄᱥvAஹ!"1Ḅ(⌕ᡂᑖ,Si஺?ஹPbS0v4Bஹw½⏚᪷|}8945zᓄ¾¿675ᡂ~zᓄ}zᓄ═vCஹ8945ᣚ675ᡂ89vDஹÀᔠᱥḄc⚪X£᪷ᐗÂÃ:Äc`ÅÆᱥḄᱥḄ,x,ÇÂÆ,y,ÈᔠÉÊᦪᑡÌᐗÂÃ:Ä஺11.(2ᑖ)ᵨ1mol/LÎo(Ïᑴ1§/s⌲§Gᐭ°)§Ó60mL0.02mol/Lg⏚k;ÎoÖpP×ᵨ1mol/LḄg⏚6§ÓÎØᔠᱥk஺ÙÚÛÜ᝞ÙÚ67p3ḄpHᵯà᳛âᓄãäåæÝÞ

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14Cஹ¯Uᨵᱥᑖaeᨵ6+ஹ<+ஹ9+ஹ+ஹ+DஹW¦⏚[X=>Ḅ1+dᑖj᪀lḄᑨ©W²¦³j᪀ஹ´µj᪀ᑨ©஺14.¹2ᑖ»ᵨCO½N2஺W¿ÀÁÂÃrÄrḄÅÆK=>ḄÇᓄÈ¥É1Aᑘ஺¹9»+CO¹g»UCO2¹g»+N2¹g»/H஺ᙠlÒ11LḄÔÕÖᘤA¹500࠷,ឤÞ»ஹB¹àá500࠷,âÇ»mᑖaᐭO.lmolNz஺0.4molCO,èéÖᘤmN?஺ëᓄ᳛íîïᓄᐵñ᝞ò஺@ᑡCDEFḄG()302520151050100200300400t/sA.AÖᘤmN2஺Ḅëᓄ᳛íîḄïᓄᐵñGòmḄóôaB.Wö¤÷øÖᘤlÒᩭ÷úbóô>Öᘤüᑮþ⊝Ḅ

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RᦋNzOḄ⊝ᓄ᳛bᙠcᓄᑺefḄghijklᑖnᦪḄolZpqrᜧpqtTrᜧᓄE᳛JKᑮH⊝Ḅ

uv⊝ᓄ᳛ᐹlxytTz{#ᘤl|B[ᔠ⚪^_C.᪷~500࠷
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15D.ᙠ⊝ᔣA#ᘤ%&ᐭ0.075molN2஺-OSSmolC஺?Q=:〈Cᑴ=⌲cῶᘙ===ᑣ⊝12D[ᔠ⚪^_0.15X0.375434bᦑ4ᫀj£BCoூᑖ᪆௃Aஹj:;=Ḽ?@ABᓣDE᳛G
K_BஹJ{l|⊝¤¥⚪ZᦪJ{Ḅ¦ᔣ12ᵫM¨©ª«klZᦪN¬®⊝12R¯ᔜ±ᱥ³´BrᜧE᳛G_Cஹ⊝ᦪḄµ¶tT·¸¹ºᐭ»¼ᔠ½?@µ¶Dஹ⊝¾¿kl⊝12஺15.2ᑖÀAiᔣNaOHÂÃ%⌲ÄÄᐭÅÆ⏚H3P0ÀᔜÉÆÊËḄᑖÌᑖᦪX⊝
ÍÊËḄ´BᓰᔜÊË´BÏÐḄᑖᦪÀ-pOHḄᐵZ᝞ᡠ½஺ÓÔpOH=-ᒼº஺-À,%Ö×ØᡂNci2”PO3ÐNaHzPgª±Þ஺iᑡàá0âḄ¯ÀB.H2P0ãḄᵯå⊝ᦪKa=1x10~73mol-L-1C.Na/P%ÂÃ%c”+À>c0/TÀD.pOH=7
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pH=7,C(H+)=c(OH-)᪷~ᵯ₹üឤ£c(Na+)+c(H+)=2c(HPOî)+

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pOHᙶ᪗pOHᜧᑣ⏚ឋᐸᔠ“ᡂNc^HPg&Na/Pg)*+“,-H3Po30ᐗ⏚,23)ᵯ567ᵯ5H3PO3UH++H2P஺3607ᵯ5H2PO3-=H++HPO2-?@Ḽ⏚ឋBCᵯ5DEBC3H3Po3FEBGH2PO3-FEH67ᵯ5DEBC07ᵯ5DEHI⏚ឋBCᑮ6KDEL67ᵯ5MNOPᙠ07ᵯ5RSLH2P03-FEBGHPO.J-FEHᜧ07ᵯ5DEBCWAஹ᪷[\]ᑖ᪆,abac⊤HPO.7,abbc⊤H2P0g,abcc⊤H3P஺3WBஹ07ᵯ5i⊝kᦪ,2᪷[HPO32-&H2Po3-Ḅmnopᓽaba&abbḄmnᔠ07ᵯ5i⊝kᦪKa2=csHtusvw,,-ᙠmnᜐKa2=csH+w,yᙶ᪗pOH,◤⌕ᣚpCH2PO3csH+wWCஹNaH2PO3~ᓽ~NaH2PO3,SLcsH2Po3wᨬᜧᓽbabḄᨬnSLpOHᜧ7,~⏚ឋWDஹpOH=7~ឋᔠᵯ₹ឤcᣚ,2-⍝csNa+w=2csHPOgw+csH2P஺1w஺▅ᔁ$ஹ&⌱'⚪ᐳ5⚪ᐳ39ᑖᑖ16.s9ᑖwஹஹᙠkᵨᵫᐸᱯḄឋ“ᩭ¡Ḅ”஺ᐸᓫ¤ᓄᔠᱥᙠᓄ§ஹ¨©ஹᩞᧇ⚞ᐹᨵᵨ஺°±²ᑡ´⚪ts1ws2ᑖw
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2041ᑖ“²2ÌÍ”¥ÂᡂḄÎ2஺஺3ÐSÑÒ஺“Ó£”¥Ôᐭº-஺஺2ᨵᑭÅr2஺஺3ÐSf஻+,ØÙ¨ᐸÚᐗeᑖØÛ⊝ÝÞḄßᑖ᪆ᐸ2ᳮ___________________________________________________________________________________________53ᑖḄᵯᓄä}!åæçMèéᡂêÑ»஺ᐸ2ᳮ¹ÔºᵯSëìíØÐd⌲Y²2᪆¦ÂᡂḄᓫ,ð▬Ḽᙠ᩽஺ᵯS¥ᔜ²2fᓫ,Ḅᵯó᝞t⊤:Co2+Mn2+Nl2+²2fᓫ,Ḅᵯó/V0.2801.1850.257ö⌕ᦋ.qrøùᑖðᙠúûüýÊþÿᵨᵯᓄ஺ᨬ᪆ḄᓫoA.“⏚”B.“pH”C.“┼"D.“═”ூ$ᫀ௃'1)2.5mol/L0⏚12034ஹᤅ78᳛ஹ:;ᢗᧇ>'ᐸ@AB8᳛ḄCDᔠᳮᓽH)'2)CM+KM/+LᡂNOᓄᱥQRSTU╋WQᑖY'3)2MnO]4-3Mn2++2HO=5MnOI+4H+22'4)`abcᙠe2஺஺3Ḅfgh⊝je2c஺3஺)=Li+'aq)+COg'aq)Rqᐭst஺஺2UCOguᔠvᡂHC஺w,yz{CO|Ḅ}4R~e2஺஺3Ḅfgh⊝ᔣfgḄᔣRCᨵᑭe+ᐭf:'5)▢0C0╎ூg᪆௃ூg$௃ᐭᯖᑮᓫRᐭst஺஺2ᨵᑭe2஺஺3fge+RsHMnஹCoஹNi,ᐭ⏚fgᑮYRᐭNaOH⁚pH,ᐭᨴR¡═⏚¢K£Y¤v¥b¦§vᡂOᓄ┶Rᨬᐭ₝⏚ª«ᑮ₝⏚«0'1)ᵫH®R⏚}42.5mol/L1YḄ᳛᳛¯¡R°±ᧇ²³Rᨬᔠ〉Ḅ⏚ᨬᔠ〉Ḅ}42.5mol/L0}4ஹ¦§ᱥµ¶☢ஹ¦§12¸¹AB¦§84Rᑣ»¡YḄ᳛R◀⏚}4᜜RHeẆ¿⏚12ஹ34ஹᤅ78᳛ஹ:;ᢗᧇ>¸ᩩÁUYḄ᳛Ḅᐵa0'2)ᵫYQḄpHÃ⊤H®RÅ“pH”1pHÃs¡R஺஺2+KM/+LᡂNOᓄᱥQRSTUWQᑖY0'3)“═”1¡═⏚¢K£Y¤v¥b¦§vᡂOᓄÆR¦§ḄYÇÈ2MnO1+3M/++2H2஺=5MnOI+4H+02

21(4)“Ë”1R`abcᙠ§஺஺3Ḅfgh⊝j2஺஺3஺)=Ì+99)+஺஺ᔆ(ᦗ)Rqᐭst஺஺2UCOguᔠvᡂHC஺஺yz{C஺ᡭḄ}4R~e2c஺3Ḅfgh⊝ᔣfgḄᔣRCᨵᑭ+ᐭf:0(5)Y¤v¦§vᡂᓫRᵯgÑb▢᩽¤v¦§RᑣvᡂḄᓫ▬Ḽᙠ▢᩽0ᵫNi2+UC02+ᓫḄᵯÖ×ØSÙR¯ÚᑖYRᑣ§ᙠ“╋”ÛÇÜÝ~ᵨᵯᓄRᦑ$ᫀjC,஺஺2+C஺ḄᵯÖ¯zRqᵯᐜ᪆Rᨬ᪆Ḅᓫ┶஺ூᑖ᪆௃ᐜᑖ᪆ÛÇRàsᯖLᡂקḄᓫRLiஹMnஹCoஹNi,ËqᐭOᓄáR:á⏚┞RMnஹCoஹNi,às⏚LᡂקḄ⏚WRᐭNaOH,ᐭᨴR¡£⏚¢K═Y¤v¥b¦§vᡂOᓄ┶Rᨬᐭ₝⏚ª«ᑮ₝⏚«0(1)uᔠãRH®pH2.51᳛ä¡Rå᳛»¡Sæç0»¡᳛Ḅᨵè⏚12ஹèᢗᧇ>ஹèᜧµ¶☢ஹ»¡34ஹᤅ7¸0(2)pHs¡RNO᪷}4èᜧRë᧕~YQ0(3)᪷íãRH®îsÇOᓄ¦§Rf:bᨵMM+,ᐭMnCh-¤vOᓄ¦§RLᡂOᓄ£0(4)ðh⊝Ḅñ4gòfg4RᓽᑭᵨÚfᵯgḄfgh⊝gòR᪷íá⏚᪷KOᓄáḄ¦§R~fgh⊝óôᔣRᵫ┞YḄfg0(5)Y□YRᵯgsÇbᔣ▢᩽0᪷íᵯÖ⌱÷RH®K«ḄᵯÖµøRCùúᙠ◀û╋eÜÝᵯg஺18.(8ᑖ)MnSO^G஺
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BLᓄ(ND஺B2DB3ᑖD/0nRSḄᓄ(TUNVW-.XYRSZ᳛Ḅ\]ᨵ;RS`a;bᑮMnSfZj•%0ḄlmV஺B3DB2ᑖDᐶopq'(rstẆv3⏚═ᨔYwᑖḄIxᱥz{|ᧇ}~63⏚═ᨔYw+ḄᑖxᱥVMnOyஹSO?ஹS&஺VM&OyḄᓄ(Nᵨ+ᑡ/0B~6SO?ḄᰚV16.8࠷,V44.8࠷D஺জ/0ḄVh-஺ঝᙠ/0ᐭ152.1gMnSO4-2஺ᐙᑖRS`bSO?¦§V19.2g,ᑣM&OஹḄᓄ(NV஺B4DB2ᑖD⛴ᧇ3⏚┡«§¬⛴ᧇ®⏚m¯ᔠᑺᵨ±⏚╆m³ᓄᑺ¬´᪵Ḅ¶·┶§³ᓄᡂº·╎»§Ḅ±⏚¼½ᓽ¿xÀḄÁ±⏚RSÂÃ◀ᐸÅÆ஺ᯠ`ᐭᢣÉᑺᵨ3⏚ÁÊ╆[FeBN4D2BS04D2-6/஺]᪗Ò;ÓÀᡂḄº·┶;ᵫÕ⁐ÖV×Ø⁐VÓÙ஺ᨵᐵÛÜRSTUNV62Mn2++NO3+4POl-+2H+=2[MnHPOP]3~+NO2+%஺ஹNHR+NO]=N2T+2%஺ஹ42[MnBPOD]3-+Fe2+=Mn2++[FeBPOD]3-4242áag⛴ᧇÃὑäåVcnwIlTḄ3⏚ÁÊᢥ᪗Ò;VmL,ᑣ⛴ᧇMnSO4•í஺Ḅ¦§ᑖᦪVBᵨ«aஹcஹVḄ⊤ðN⊤ÉDñÓòóôõᦪÓ`öô,ᑣ÷øùúûBL“ýᜧ”ஹ"”ᡈ"”ூᫀ௃1Na2sO32SO+MnO=MnS0-,ᤅஹᵨᳫஹᓾ!ᨔஹ#$%&ஹ'(224(3)cd-eJabMnO34ভ◤5ᡈ6ூ7᪆௃ூ7௃9:Iᵨ<=⏚?@=⏚ABᑴDEFᓄ=H9:nJEFᓄ=@EFᓄKABLᡂ=⏚┶H9:IIIᵨNaOHRSᔾᦈVW

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25(5)(1ᑖ)Aᧇᑴᜓ(TḄᔠᡂ./(ᵨ123⊤ᑺ⌱)________஺ூᫀ௃(1)C8H15NO3Xᜐஹ!(2)#$%&+HC1(4)32)HO—iY_CHJNHCHOᡈHO—{ஹ8NHCH,CHOᡈHCߟ/ߟ\_A—Q/H2“CH,N.CHC1C12()uᐝ᯿,=5o^ac,-^V^COOHூ>᪆௃ூ>௃@ABCBឋEFGAOᵬ!QR═⏚UVᓄ!B1Y,B%&IᡂE,ᑣ=\\*)EHI^%&IᡂFHI#$%&IᡂC,CHIJKLMiiiOHFHI#$%&IᡂG,GHHI#$%&IᡂK)|1J1Jd)HḄᑖcd஺8”15%஺3)NOḄjVklmḄno⏚ஹ!)NH(2)ᔠᡂ./OডGHHI#$%&IᡂKJL%&yz#$%&)H0•"CClj(3)Dr^£1'CHIJKLMv%&IᡂE,C+D—EḄᓄ|}2d~\3+

26(4)BJ,PBḄᱥᑖcdC8H9%஺2,ᑡᩩজ✏Bᨵ#$!ঝJK!@ỏFe3+HI⁐%&JlFeC"HI⁐%&jᨵ¢!ᡈ!23ᙠ@AঞlHI%&jᨵ¡!ᑖ£᪀¥ᨵஹ—8ஹ«------23VHOHOஹiA=\?ஹNHCHCHO'IIO—HO—^~NWH322_32_3CH323CH2CH2CHO>:112cH2cH0ஹHQj2ஹT13JᐸO᪶°ᐳ²³´ᨵHOQ^H஺¨h-CH2CH2CHOC-

27(2)./(6)GHḄ#$%&)(3)CDIᡂEḄÎ2OCO¾cQEOCBḄ³c#$)(4)✏Bᨵ#$!ᐸO8#$!¢!lÏHI%&ᑣjᨵ¡!᪷Ñ᪶°ᐳ²³´ᨵ6©ªᐸ☢®222111,¼K¢!Ò8#$!ÓÔÕ¡!ÔÖÒ8#$!)(5)ᔠᡂ./Ḅ8×⌕¶ᔠJKᩩᡈὅJKᔠᡂ./ÙÚ᪷Ñ⚪Ü⌕ÝḄᱥEÞᵨßàᡈὅ⌮àºáâF&Ḅ஺20.(6ᑖ)“æO”ᨵᑭÖᐰᳫê᎛ᦋᗐCO2ḄïðᓄᑭᵨᡂẆòóô஺(1)(3ᑖ)õVᓄæö³ᔠᡂõᵬ⏨Ḅ%&ᒹùúFûᐵὶḄ%&Î2iCO(5)+3H2(g)=CH30H(g)+H0(g)AH=-49.01/c/-mor122ii.C02(g)+%(g)UC0(g)+H0(g)AH=+41.17kJ-mol-122iii.2cH30(g)=CH30cH3(g)+H0(g)AH=-24.52kJ•mor123জᑏ஺஺22ᡂCH30cH3Ḅᓄ!"#$஺ঝᙠ'(3.0MPa,n(W)/n(C0)=4,/0123C஺2Ḅ4⊝6ᓄ᳛8ᱥḄ⌱;ឋ᝞>ᡠ@22(⌱;ឋAᢣᡂCᱥDEὑḄ஺஺2ḄᱥDḄGᓰEὑ஺஺2IḄᱥDḄGḄJᑖL)M12NO290C,C0Ḅ4⊝6ᓄ᳛P12ᓣRSTᜧḄVWA_஺᪷Z>[ᦪZ]^300C_CH30cH3Ḅ4⊝8᳛$o(2)(3ᑖ)C“4—஺஺2c᦮ᑴ“2ḄO"$:C“4(g)+C02(g)=2C0(g)+2%(9)஺gḄhij$প[iiᙠlឋmnoᘤ[qᧇLstᑖuvw1.0ஹ2.0,yz{_'(|0஺4⊝_ᵬ~ḄDGᑖᦪ12Ḅᐵ᝞>ᡠ@:

28জaḄqᧇL$஺ঝᨵᑭwRC024⊝6ᓄ᳛ḄA«ᑏᩩঞMCH4Ḅ4⊝6ᓄ᳛$85%,஺஺2Ḅ4⊝6ᓄ᳛$88%,ᑣhijḄ'(4⊝ᦪKp=ᶇ2ᨵᦔᦪ஺ᑖ'=I'xᑖḄᱥDḄGᑖᦪூ¢ᫀ௃প2C05+6H^CHOCHH_gP+3HO5^H=-122.54/c¨-mol-1.12NO223323290C_©ijii$ªijii$ᔾijᓣR124⊝¬ᔣ®¯CO2Ḅ4⊝6ᓄ᳛Tᜧ¨6%21.0¨Tᜧᵬ~ḄᢗᧇஹR1ஹ±'ᡈ³_®´8ᱥᡈᐸ¶ᔠᳮ¢ᫀ¨.26ூ¹᪆௃ூ¹¢»1জᵫ½¾¿Àijix2+iiiÁÂᑮCO2ÄᡂCH30cH3Ḅᓄ!"#$2co2HgP+6H2g=CH30cH3HgP+3HOHgPAH=-122.54©•mor1.2ঝijii$ᔾij12ᓣR4⊝¬ᔣ®¯CO26ᓄ᳛ᓣRijᡂÇᵬÈ$Éij12ᓣRÊCO26ᓄ᳛3ËÌᓣ"2ᜧw3ËCO2Ḅ6ᓄ᳛ᓣRᦑ¢ᫀ$12NO290࠷_©ijii$ªijii$ᔾijᓣR124⊝¬ᔣ®¯஺஺2Ḅ4⊝6ᓄ᳛Tᜧ¨ঝ᪷Z>1300࠷_CO?Ḅ4⊝6ᓄ᳛$30%,CH30cH3Ḅ⌱;20%,ÐCChz{ḄG$amol,ᦑijEὑCO2ḄᱥDḄG$ax30%x20%,ᦑCH30cH3Ḅ4⊝8᳛$"ÕÖ×%=6%¨16nCHQ_16-nCm\2জᵬ~ḄDGᑖᦪ44nC02+16nC“4Ø4a஺°2+“ᵬ~ḄDGᑖᦪÚᜧJrÛÚÜ,ᦑ"'/CH.ᓝaḄqᧇL$1.0¨ঝijii$ᔾijᓣ14⊝¬ᔣ®¯EὑßàḄeg,ijc4g+co2g=2cog+242gAâãᑖäᦪTᜧḄij˱'(4⊝¬ᔣ®¯C024⊝6ᓄ᳛TᜧTᜧåØijᱥᓽᵬ~Ḅç2èᨵᑭwR஺஺24⊝6ᓄ᳛ᑣATᜧᵬ~ḄᢗᧇஹR1ஹ±'ᡈ³_®´8ᱥ¨

29ঞM'qᧇLé"°Ðê{_n(CO2)=lmol,n(CH4)=lmol,ᑡìí#C“4(g)+12C0(g)4-2H2(g)89:Imol110°ஹhij;ᓄ:/molXX2x2x=⊝:^mol1-X1—X2x2xC°2(g)+”2(g):=C°(g)+H2()(g)89:/mol1-x2x2x°JCH4Ḅ4⊝6ᓄ᳛$85%,ᑣ;ᓄ:Imolyyyy=⊝:/mol1-x-y2x-y2x+yyx=0.85,CO2Ḅ4⊝6ᓄ᳛$88%,ÁÂx+y=0.88,y=0.03,ij4⊝ïᔜâãᱥDḄG$n(CH4)=0.15mol,n(CO2)=0.12mol,n(CO)=1.73mol,n(H2)=1.67mol,n(H20)=0.03mol,n&=3.7mol,ÐI'($p,'(LvwᱥDḄGóLhijḄ'(4⊝ᦪ=▾õö=(ᒨXP)X(┳XP)Ø(úxp)x(┳XP)Ø᜜ூᑖ᪆௃(1)জ½¾¿ÀḄjᵨ⌕þÿᑨᑡḄᓄḄᐵḄᱥᑣᙠḄᱥᑣঝ᪷$⚪&'()*ᨵ,-ᓽ-i0-ii,,-Ḅ᪷234567ᓄ809:Ḅᓄ;<ᦪ>?@ABC*290࠷,CO⌱KឋMᜧᓽ-iiᜧO-i,PQ67ᓄ8ὑḄᱥḄ<ᵫ-iḄ31VW11,ᓽXᐜZὑ3m0IH2◤ὑImolCCh,VᡂZὑ3m0IH2◤ὑ3moicChd(2)জ᪷$ᵬiḄ<ᑖᦪkᜧl4knopᑨdঝqrsᓄ᳛ᓽuv⊝xyᔣ{|⌕ᱯ4MC02ḄBuᐸsᓄ᳛Vndঞᔠ᪷$-i0-iiᑡᐵ;ḄQ᎛⌕ᔠᱥḄ<>?O>?op஺

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