最新-武汉工程大学-有机-真题教学文稿.doc

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1、最新-武汉工程大学-有机-真题精品文档2009-2010学年第2学期考试试题（A）卷课程名称：Organicchemistry任课教师：Yinchuanqi出题教师：LiJunbo审题教师：ChenYunfeng考试方式：closebook考试时间：120mins适用专业：Chemicalengineering09（48credithours）题号一二三四五六总分得分评卷人（答案统一按题目次序做在答题纸上，试卷上答题无效）1.GivetheIUPACnamesordrawstructures（2’×10=2

2、0’）2.Predictthemajorproduct(s)(A-M)ofthefollowingreactions（2’×13=26’）。3.Answerthefollowingquestiions(20’)(1)Whyis40%NaOHaqueoussolutionneededinthedisproportionationofbenzaldehyde?Predicttheproductsofthereactionofbenzaldehydewithformaldehydein40%NaOHaqueous

3、solutionandgivethereasonableexplanation(10’)收集于网络，如有侵权请联系管理员删除精品文档(2)Amongacidhalides,esters,acidanhydridesandamides,Whichkindofcompoundsismostreactiveinnucleophilicsubstitutionreaction?Why?(5’)(3)Proposethegeneralbase-catalyzedmechanismfortheAldolcondensa

4、tion(5’)4.Distinguishthefollowingcompoundsineachgroupbychemicalmethods(5’×2=10’)(1)1-Propanol,propanal,andpropanone;(2)CH3CH2NH2,(CH3CH2)NH,(CH3CH2)3NandCH3COOH.5.Preparethefollowingcompoundsfromgivenstartingmaterialsandotherinorganicreagentsneeded(5’×4=20

5、’)6.CompoundA,C8H10,absorbs3equivalentsofH2oncatalyticreductionoverapalladiumcatalysttoproduceB,C8H16.OnreactionwithKMnO4,compoundAgives,amongotherthings,aketone(酮)thatwasidentifiedascyclopentanone(环戊酮).OntreatmentwithNaNH2inNH3,followedbyreactionwithmethy

6、lbromide,compoundAgivesC,C9H12.ProposedthestructuresforcompoundsA,B,andC(10’)收集于网络，如有侵权请联系管理员删除